In a breeder nuclear reactor, nonfissionable is converted to fissionable .
> What is a salt bridge? Why is a salt bridge necessary in a galvanic cell? Can some other method be used in place of the salt bridge?
> For each of the following oxidation–reduction reactions, identify which element is being oxidized and which is being reduced. a. Ca(s) + 2H2O(l) Ca(OH)2(s, aq) + H2(g) b. H2(g) + F2(g) 2HF( g) c. 4Fe(s) + 3O2(g)
> Describe in general terms how an archaeological artifact is dated using carbon-14.
> The element krypton has several radioactive isotopes. Below are listed several of these isotopes along with their half-lives. Which of the isotopes is most stable? Which of the isotopes is “hottest”? If we were to begin a half-life experiment with separa
> Iodide ion, I-, is one of the most easily oxidized species. Balance each of the following oxidation–reduction reactions, which take place in acidic solution, by using the “half-reaction” method. a. IO3-(aq) + I-(aq) I2(aq) b. Cr2O72-(aq)
> Balance each of the following oxidation–reduction reactions, which take place in acidic solution, by using the “half-reaction” method. a. Al(s) + H+(aq) / Al3+(aq) + H2(g) b. S2–(aq) + NO3–(g) / S(s) + NO(g) c. I2(aq) + Cl2(aq) / IO3–(aq) + HCl(g) d.
> Balance each of the following oxidation–reduction reactions, which take place in acidic solution, by using the “half-reaction” method. a. Mg(s) + Hg2+(aq) / Mg2+(aq) + Hg22+(aq) b. NO3–(aq) + Br–(aq) / NO(g) + Br2(l) c. Ni(s) + NO3–(aq) / Ni2+(aq) + NO
> Balance each of the following half-reactions, which take place in acidic solution. a. O2(g) / H2O(l) b. SO42–(aq) / H2SO3(aq) c. H2O 2(aq) / H2O(l) d. NO2–(aq) / NO3–(aq)
> Balance each of the following half-reactions, which take place in acidic solution. a. HClO(aq) Cl-(aq) b. NO(aq) N2O( g) c. N2O(aq) N2( g) d. ClO3-(aq) HClO2(aq)
> Balance each of the following half-reactions. a. 3N2( g) + 2e- 2N3-(aq) b. O22-(aq) O2( g) c. Zn(s) Zn2+(aq) d. F2( g) F-(aq)
> Balance each of the following half-reactions. a. Cu / Cu2+ b. Fe3+ / Fe2+ c. Br– / Br2 d. Fe2+ / Fe
> Why must the number of electrons lost in the oxidation equal the number of electrons gained in the reduction? Is it possible to have “leftover” electrons in a reaction?
> For each of the following oxidation–reduction reactions, identify which element is oxidized and which is reduced. a. 6Na(s) + N2( g) 2Na3N(s) b. Mg(s) + Cl2( g) MgCl2(s) c. 2Al(s) + 3Br2( l ) 2AlBr3(s)
> What is a half-reaction? What does each of the two half- reactions that make up an overall process represent?
> Why is a systematic method for balancing oxidation–reduction reactions necessary? Why can’t these equations be balanced readily by inspection?
> In what two respects must oxidation–reduction reactions be balanced?
> Potassium iodide in solution reacts readily with many reagents. In the following reactions, identify the atoms that are being oxidized and reduced, and specify the oxidizing and reducing agents. a. Cl2( g) + KI(aq) KCl(aq) + I2(s) b. 2
> Complete the following table with the nuclear particle that is produced in each nuclear reaction. Initial Nuclide Product Nuclide Particle Produced 239Pu 94 235 김 Pb BI 214 214 83 Co NI 99- Ru 239 93 239 Pu
> Consider the oxidation–reduction reaction Mg(s) + Cu2+(aq) / Mg2+(aq) + Cu(s) Sketch a galvanic cell that uses this reaction. Which metal ion is reduced? Which metal is oxidized? What half-reaction takes place at the anode in the cell? What half-reactio
> Consider a galvanic cell based on the following oxidation– reduction reaction: 2Al3+(aq) + 3Mg(s) ( 2Al(s) + 3Mg2+(aq) What will the electrode found in the cathode portion of the cell be made of? Explain your answer. a. air b. HCl c. Mg d. Al e. H2
> Each of the following nuclides is known to undergo radioactive decay by production of a ß particle, /. Write a balanced nuclear equation for each process. a. 53 136
> Write a nuclear equation showing the bombardment of beryllium-9 with alpha particles, resulting in production of carbon-12 and a neutron.
> Write a balanced nuclear equation for the bombardment of 7 14
> How many of the following statements regarding the decay of radioactive nuclides are true? a. During a given period of time, a radioactive nucleus with a short half-life is much more likely to decay than one with a long half-life. b. As a nuclide decay
> What do we mean when we say that one radioactive nucleus is “hotter” than another? Which element would have more decay events over a given period of time?
> Complete each of the following nuclear equations by supplying the missing particle. a. 88 226
> Aluminum exists in several isotopic forms, including /Al, /Al, and /Al. Indicate the number of protons and the number of neutrons in each of these isotopes.
> The element zinc in nature consists of five isotopes with higher than 0.5% natural abundances, with mass numbers 64, 66, 67, 68, and 70. Write the nuclear symbol for each of these isotopes. How many protons does each contain? How many neutrons does each
> Zirconium consists of five primary isotopes, of mass numbers and abundances shown below: Zr-90………...51.5% Zr-91………….11.2% Zr-92………...17.1% Zr-94……….17.4% Zr-96…………2.8% Write the nuclear symbol,
> Each of the following nuclides is known to undergo radioactive decay by production of a ß particle, /. Write a balanced nuclear equation for each process. a. / b. / c. /
> The fission of 92 235
> Each of the following isotopes has been used medically for the purpose indicated. Suggest reasons why the particular element might have been chosen for this purpose. a. cobalt-57, for study of the body’s use of vitamin B12 b. calcium-47, for study of b
> Supply the missing particle, and state the type of decay for each of the following nuclear processes. a. + ? He b. + ? Pa
> The most common type of nuclear reactor uses the nuclide as its fissionable material.
> are radioactive substances that physicians introduce into the body to enable them to study the absorption and metabolism of the substance or to analyze the functioning of an organ or gland that can make use of the substance.
> What is the half-life of a radioactive nucleus? Does a given type of nucleus always have the same half-life? Do nuclei of different elements have the same half-life?
> At which electrode (anode/cathode) do species gain electrons in a galvanic cell?
> What is an oxidizing agent? Is an oxidizing agent itself oxidized or reduced when it acts on another species?
> The sum of the oxidation states of the atoms in a polyatomic ion is equal to the overall of the ion.
> In assigning oxidation states for a covalently bonded molecule, we assume that the more element controls both electrons of the covalent bond.
> Reduction may be described as a(n) of electrons or as a decrease in .
> Another name for the term oxidation state is .
> Reactions in which one or more are transferred between species are called oxidation–reduction reactions.
> Explain the difference between somatic damage from radiation and genetic damage. Which type causes immediate damage to the exposed individual?
> Although aluminum is one of the most abundant metals on earth, its price until the 1890s made it a “precious metal” like gold and platinum. Why?
> How does an electrolysis cell differ from a galvanic cell?
> What is meant by a nuclear bombardment process? Give an example of such a process, and describe what the net result of the process is.
> The “Chemistry in Focus” segment Stainless Steel: It’s the Pits discusses the fact that stainless steel can corrode if there is a deficit of chromium. How does chromium protect stainless steel?
> Pure iron ordinarily rusts quickly, but steel does not corrode nearly as fast. How does steel resist corrosion?
> is the process of returning metals to their natural state—the ores from which they were originally obtained. This process involves of the metal.
> What are some advantages of using lithium ion batteries in electrical devices? What is a disadvantage?
> Write the chemical equation for the overall cell reaction that occurs in a lead storage automobile battery. What species is oxidized in such a battery? What species is reduced? Why can such a battery be “recharged”?
> Consider the oxidation–reduction reaction Zn(s) + Pb2+(aq) Zn2+(aq) + Pb(s) Sketch a galvanic cell that uses this reaction. Which metal ion is reduced? Which metal is oxidized? What half-reaction takes place at the anode in the
> Consider the oxidation–reduction reaction Al(s) + Ni2+(aq) Al3+(aq) + Ni(s) Sketch a galvanic cell that makes use of this reaction. Which metal ion is reduced? Which metal is oxidized? What half- reaction takes place at the anode in
> What type of reaction takes place at the cathode in a galvanic cell? At the anode?
> In which direction do electrons flow in a galvanic cell, from anode to cathode or vice versa?
> In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation numbers. a. 4KClO3(s) + C6H12O6(s) / 4KCl(s) + 6H2O(l) + 6CO2(g) b. 2C8H18(l) + 25O2(g) / 16CO2(g) + 18H2O(l) c. PCl3(g) + Cl2
> During nuclear , a large nucleus is transformed into lighter nuclei. During nuclear , small nuclei are combined to make a heavier nucleus. Both processes release energy, but nuclear
> How do the forces that hold an atomic nucleus together compare in strength with the forces between atoms in a molecule?
> Nitric acid is a very strong acid, but is also a very strong oxidizing agent, and generally behaves as the latter. It will dissolve many metals. Balance the following oxidation–reduction reactions of nitric acid. a. Cu(s) + HNO3(aq) Cu2+(
> Each of the following nuclides is known to undergo radioactive decay by production of an alpha particle, /. Write a balanced nuclear equation for each process. a. / b. / c. /
> Each of the following nuclides is known to undergo radioactive decay by production of a beta particle, /. Write a balanced nuclear equation for each process. a. /C b. / c. /
> Complete each of the following nuclear equations by supplying the missing particle. a. 80 201
> How is 6 14
> Naturally occurring magnesium consists primarily of three isotopes, of mass numbers 24, 25, and 26. How many protons does each of these nuclides contain? How many neutrons does each of these nuclides contain? Write nuclear symbols for each of these isoto
> Technetium-99 has been used as a radiographic agent in bone scans ( 43 99
> Although naturally occurring potassium consists mostly of the isotope of mass number 39 (93.25%), isotopes of mass number 41 (6.73%) and 40 (0.01%) also are present. Write the nuclear symbol for each of the isotopes of potassium. How many neutrons are pr
> In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation states. a. 2Cu(s) + S(s) / Cu2S b. 2Cu2O(s) + O2(g) / 4CuO(s) c. 4B(s) + 3O2(g) / 2B2O3(s) d. 6Na(s) + N2(g) / 2Na3N(s)
> The following isotopes (listed with their half-lives) have been used in the medical and biologic sciences. Arrange these isotopes in order of their relative decay activities: 3H (12.2 years), 24Na (15 hours), 131I (8 days), 60Co (5.3 years), 14C (5730 ye
> Consider the isotopes of radium listed in Table 19.3. Which isotope is most stable against decay? Which isotope is “hottest”? From table 19.3: Half-life Nuclide 12 days 깰Ra 3.6 days 224 껍Ra 15 days Ra 225 276Ra 16
> Although magnesium metal does not react with water at room temperature, it does react vigorously with steam at higher temperatures, releasing elemental hydrogen gas from the water. Mg(s) + 2H2O(g) Mg(OH)2(s) + H2( g) Identify which e
> Iron ores, usually oxides of iron, are converted to the pure metal by reaction in a blast furnace with carbon (coke). The carbon is first reacted with air to form carbon monoxide, which in turn reacts with the iron oxides as follows: F2O3(s) + 3CO(g)
> Pennies in the United States consist of a zinc core that is electroplated with a thin coating of copper. Zinc dissolves in hydrochloric acid, but copper does not. If a small scratch is made on the surface of a penny, it is possible to dissolve away the z
> Write a balanced nuclear equation showing the bombardment of /with deuterium atoms (the isotope of hydrogen with A = 2, /) to produce /and an alpha particle.
> Write a balanced nuclear equation showing the bombardment of / with alpha particles to produce /and a neutron.
> What does a gamma ray represent? Is a γ ray a particle? Is there a change in mass or atomic number when a nucleus produces only a γ ray?
> What does a nuclear transformation represent? How is a nuclear transformation performed?
> Complete each of the following nuclear equations by supplying the missing particle. a. 89 210
> In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation numbers. a. 2Al(s) + 3S(s) Al2S3(s) b. CH4( g) + 2O2( g) CO2( g) + 2H2O( g) c. 2Fe2O3(s) +
> For each of the following oxidation–reduction reactions, identify which element is being oxidized and which is being reduced. a. Cl2( g) + I2( g) 2ICl( g) b. Cl2( g) + 2Li(s) 2LiCl(s) c. 2Na(s) + 2H2O( l )
> Complete each of the following nuclear equations by supplying the missing particle. a. ? 2 4
> Complete each of the following nuclear equations by supplying the missing particle. a. 88 226
> Which of the following nuclear processes results in a decrease in the neutron-to-proton ratio? Justify your answer. a. ß-particle production b. Positron production c. Electron capture d. α-particle production e. γ-ray production
> Give the nuclear symbol for each of the following. a. a beta particle b. an alpha particle c. a neutron d. a proton
> What is the oxidation state of manganese in each of the following substances? a. MnCl2 b. KMnO4 c. MnO2 d. Mn(C2H3O2)3
> What is the oxidation state of nitrogen in each of the following substances? a. N2 b. NH3 c. NO2 d. NaNO3
> Naturally occurring sulfur consists primarily (94.9%) of the isotope with mass number 32, but small amounts of the isotopes with mass numbers 33, 34, and 36 also are present. Write the nuclear symbol for each of the isotopes of sulfur. How many neutrons
> What do we mean when we say a nucleus has undergone an electron capture process? What type of electron is captured by the nucleus in this process?
> Because the chemistry of an atom is determined by the number and arrangement of its , the properties of the nucleus do not strongly affect the chemical behavior of an atom.
> What is a decay series?
> In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation numbers. a. Fe(s) + CuSO4(aq) FeSO4(aq) + Cu(s) b. Cl2( g) + 2NaBr(aq) 2NaCl(aq) + Br2(
> When a nucleus emits a neutron, does the atomic number of the nucleus change? Does the mass number of the nucleus change? Explain.
> When a nucleus emits a beta particle, by how many atomic mass units does the mass of the nucleus change? By how many units does the atomic number of the nucleus change? Explain.
> For the nuclide , identify the mass number and the atomic number.
> What is meant by saying an element exists in several isotopic forms? Do isotopes of a given element have similar chemical properties? Explain.
> The sum of the numbers of neutrons and protons is the .
> What does the atomic number of an atom represent?
> How large is a typical atomic nucleus, and how does the size of the nucleus of an atom compare with the overall size of the atom?
> The major use of alkanes has been in reactions, as a source of heat and light.
> Tetraethyl lead, (C2H5)4Pb, was added to gasoline in the past as a(n) agent.
