Q: Although your textbook lists the rules for converting an ordinary number to
Although your textbook lists the rules for converting an ordinary number to scientific notation, oftentimes students remember such rules better if they put them into their own words. Pretend you are h...
See AnswerQ: True or false? If a theory is disproven, then all
True or false? If a theory is disproven, then all of the observations that support that theory are also disproven. Explain.
See AnswerQ: Write each of the following numbers in standard scientific notation.
Write each of the following numbers in standard scientific notation. a. 97,820 b. 42.14 * 103 c. 0.08214 * 10-3 d. 0.0003914 e. 927.1 f. 4.781 * 102 * 10-3
See AnswerQ: Discuss several political, social, or personal considerations that might affect
Discuss several political, social, or personal considerations that might affect a scientist’s evaluation of a theory. Give examples of how such external forces have influenced scientists in the past....
See AnswerQ: Although reviewing your lecture notes and reading your textbook are important,
Although reviewing your lecture notes and reading your textbook are important, why does the study of chemistry depend so much on problem solving? Can you learn to solve problems yourself just by looki...
See AnswerQ: Why is the ability to solve problems important in the study of
Why is the ability to solve problems important in the study of chemistry? Why is it that the method used to attack a problem is as important as the answer to the problem itself?
See AnswerQ: Students approaching the study of chemistry must learn certain basic facts (
Students approaching the study of chemistry must learn certain basic facts (such as the names and symbols of the most common elements), but it is much more important that they learn to think criticall...
See AnswerQ: The “Chemistry in Focus” segment Chemistry: An Important Component
The “Chemistry in Focus” segment Chemistry: An Important Component of Your Education discusses how studying chemistry can be beneficial not only in your chemistry courses but in your studies in genera...
See AnswerQ: Write each of the following numbers in standard scientific notation.
Write each of the following numbers in standard scientific notation. a. 1/0.00032 b. 103/10-3 c. 103/103 d. 1/55,000 e. (105)(104)(10-4)/(10-2) f. 43.2/(4.32 * 10-5) g. (4.32 * 10-5)/432 h. 1/(...
See AnswerQ: Write each of the following numbers as “ordinary” decimal numbers
Write each of the following numbers as “ordinary” decimal numbers. a. 6.244 * 103 b. 9.117 * 10-2 c. 8.299 * 101 d. 1.771 * 10-4 e. 5.451 * 102 f. 2.934 * 10-5
See AnswerQ: You want to cook some raw noodles to make a pasta dish
You want to cook some raw noodles to make a pasta dish for supper. So, you turn on the gas stovetop (which uses a flame), place a large pot of water over the flame, wait for the water to boil, place t...
See AnswerQ: This section presents several ways our day-to-day lives
This section presents several ways our day-to-day lives have been enriched by chemistry. List three materials or processes involving chemistry that you feel have contributed to such an enrichment, and...
See AnswerQ: Classify each of the following as a physical or chemical change or
Classify each of the following as a physical or chemical change or property. a. Oven cleaners contain sodium hydroxide, which converts the grease/oil spatters inside the oven to water-soluble materia...
See AnswerQ: Classify each of the following as a physical or chemical change or
Classify each of the following as a physical or chemical change or property. a. A fireplace poker glows red when you heat it in the fire. b. A marshmallow turns black when toasted too long in a camp...
See AnswerQ: Consider three 10-g samples of water: one as ice
Consider three 10-g samples of water: one as ice, one as liquid, and one as vapor. How do the volumes of these three samples compare with one another? How is this difference in volume related to the p...
See AnswerQ: Do the proton and the neutron have exactly the same mass?
Do the proton and the neutron have exactly the same mass? How do the masses of the proton and the neutron compare to the mass of the electron? Which particles make the greatest contribution to the mas...
See AnswerQ: The symbols for most elements are based on the first few letters
The symbols for most elements are based on the first few letters of the respective element’s common English name. In some cases, however, the symbol seems to have nothing to do with the element’s comm...
See AnswerQ: Several chemical elements have English names beginning with the letters B,
Several chemical elements have English names beginning with the letters B, N, P, or S. For each letter, list the English names for two elements whose names begin with that letter, and give the symbols...
See AnswerQ: Correct each of the following misstatements from Dalton’s atomic theory.
Correct each of the following misstatements from Dalton’s atomic theory. a. Elements are made of tiny particles called molecules. b. All atoms of a given element are very similar. c. The atoms of a...
See AnswerQ: A given compound always contains the same relative masses of its constituent
A given compound always contains the same relative masses of its constituent elements. How is this related to the relative numbers of each kind of atom present?
See AnswerQ: In lab you report a measured volume of 158.6 mL
In lab you report a measured volume of 158.6 mL of water. Using significant figures as a measure of the error, what range of answers does your reported volume imply? Choose the best answer and justify...
See AnswerQ: For the pin shown in Fig. 2.5, why
For the pin shown in Fig. 2.5, why is the third figure determined for the length of the pin uncertain? Considering that the third figure is uncertain, explain why the length of the pin is indicated as...
See AnswerQ: Compare and contrast the ease with which molecules are able to move
Compare and contrast the ease with which molecules are able to move relative to each other in the three states of matter.
See AnswerQ: Scientists J. J. Thomson and William Thomson (Lord Kelvin
Scientists J. J. Thomson and William Thomson (Lord Kelvin) made numerous contributions to our understanding of the atom’s structure. a. Which subatomic particle did J. J. Thomson discover, and what d...
See AnswerQ: Dalton’s original atomic theory proposed that all atoms of a given element
Dalton’s original atomic theory proposed that all atoms of a given element are identical. Did this turn out to be true after further experimentation was carried out? Explain.
See AnswerQ: Describe how the process of filtration could be used to separate a
Describe how the process of filtration could be used to separate a mixture into its components. Give an example.
See AnswerQ: In a common laboratory experiment in general chemistry, students are asked
In a common laboratory experiment in general chemistry, students are asked to determine the relative amounts of benzoic acid and charcoal in a solid mixture. Benzoic acid is relatively soluble in hot...
See AnswerQ: Of the following isotopes, which are isotopes of the same element
Of the following isotopes, which are isotopes of the same element?
See AnswerQ: You are asked to determine the perimeter of the cover of your
You are asked to determine the perimeter of the cover of your textbook. You measure the length as 34.29 cm and the width as 26.72 cm. How many significant figures should you report for the perimeter?...
See AnswerQ: Evaluate each of the following mathematical expressions, and express the answer
Evaluate each of the following mathematical expressions, and express the answer to the correct number of significant digits. a. 44.2124 + 0.81 + 7.335 b. 9.7789 + 3.3315 - 2.21 c. 0.8891 + 0.225 +...
See AnswerQ: Evaluate each of the following mathematical expressions, and express the answer
Evaluate each of the following mathematical expressions, and express the answer to the correct number of significant digits. a. (4.771 + 2.3)/3.1 b. 5.02 * 102 + 4.1 * 102 c. 1.091 * 103 + 2.21 * 1...
See AnswerQ: Classify each of the following as a physical or chemical change or
Classify each of the following as a physical or chemical change or property. a. Milk curdles if a few drops of lemon juice are added to it. b. Butter turns rancid if it is left exposed at room tempe...
See AnswerQ: Without actually performing the calculations indicated, tell to how many significant
Without actually performing the calculations indicated, tell to how many significant digits the answer to the calculation should be expressed. b. (67.41 + 0.32 + 1.98)/(18.225) c. (2.001 * 10-3)(4.7...
See AnswerQ: We use chemical reactions in our everyday lives, too, not
We use chemical reactions in our everyday lives, too, not just in the science laboratory. Give at least five examples of chemical transformations that you use in your daily activities. Indicate what t...
See AnswerQ: Under ordinary conditions, only a few pure elements occur as liquids
Under ordinary conditions, only a few pure elements occur as liquids. Give an example of a metallic and a nonmetallic element that ordinarily occur as liquids.
See AnswerQ: Evaluate each of the following and write the answer to the appropriate
Evaluate each of the following and write the answer to the appropriate number of significant figures. a. (2.0944 + 0.0003233 + 12.22)/(7.001) b. (1.42 * 102 + 1.021 * 103)/(3.1 * 10-1) c. (9.762 *...
See AnswerQ: Oxygen forms molecules in which there are two oxygen atoms, O2
Oxygen forms molecules in which there are two oxygen atoms, O2. Phosphorus forms molecules in which there are four phosphorus atoms, P4. Does this mean that O2 and P4 are “compounds” because they cont...
See AnswerQ: Perform each of the following conversions, being sure to set up
Perform each of the following conversions, being sure to set up the appropriate conversion factor in each case. a. 12.5 in. to centimeters b. 12.5 cm to inches c. 2513 ft to miles d. 4.53 ft to me...
See AnswerQ: Perform each of the following conversions, being sure to set up
Perform each of the following conversions, being sure to set up the appropriate conversion factor in each case. a. 2.23 m to yards b. 46.2 yd to meters c. 292 cm to inches d. 881.2 in. to centimete...
See AnswerQ: Perform each of the following conversions, being sure to set up
Perform each of the following conversions, being sure to set up the appropriate conversion factor in each case. a. 1.75 mi to kilometers b. 2.63 gal to quarts c. 4.675 calories to joules d. 756.2...
See AnswerQ: Perform each of the following conversions, being sure to set up
Perform each of the following conversions, being sure to set up the appropriate conversion factor in each case. a. 254.3 g to kilograms b. 2.75 kg to grams c. 2.75 kg to pounds d. 2.75 kg to ounce...
See AnswerQ: For the masses and volumes indicated, calculate the density in grams
For the masses and volumes indicated, calculate the density in grams per cubic centimeter. a. mass = 452.1 g; volume = 292 cm3 b. mass = 0.14 lb; volume = 125 mL c. mass = 1.01 kg; volume = 1000 cm...
See AnswerQ: List the names, symbols, and atomic numbers of the top
List the names, symbols, and atomic numbers of the top four elements in Groups 1, 2, 6, and 7.
See AnswerQ: Which subatomic particles contribute most to the atom’s mass? Which subatomic
Which subatomic particles contribute most to the atom’s mass? Which subatomic particles determine the atom’s chemical properties?
See AnswerQ: Read the “Chemistry in Focus” segment A Mystifying Problem,
Read the “Chemistry in Focus” segment A Mystifying Problem, and discuss how David and Susan analyzed the situation, arriving at the theory that the lead glaze on the pottery was responsible for their...
See AnswerQ: Is it possible for the same two elements to form more than
Is it possible for the same two elements to form more than one compound? Is this consistent with Dalton’s atomic theory? Give an example.
See AnswerQ: Iron has a density of 7.87 g/cm3.
Iron has a density of 7.87 g/cm3. If 52.4 g of iron is added to 75.0 mL of water in a graduated cylinder, to what volume reading will the water level in the cylinder rise?
See AnswerQ: You want to make a rectangular box that weighs 2.0
You want to make a rectangular box that weighs 2.0 pounds and floats on water. The width and height of the box are each 5.0 cm long. Choose the minimum length of the box that will keep it afloat on th...
See AnswerQ: The principal goal of alchemists was to convert cheaper, more common
The principal goal of alchemists was to convert cheaper, more common metals into gold. Considering that gold had no particular practical uses (for example, it was too soft to be used for weapons), why...
See AnswerQ: Express each of the following as an “ordinary” decimal number
Express each of the following as an “ordinary” decimal number. a. 3.011 * 1023 e. 4.32002 * 10-4 b. 5.091 * 109 f. 3.001 * 10-2 c. 7.2 * 102 g. 2.9901 * 10-7 d. 1.234 * 105 h. 4.2 * 10-1
See AnswerQ: Make the following conversions. a. 1.25 in
Make the following conversions. a. 1.25 in. to feet and to centimeters b. 2.12 qt to gallons and to liters c. 2640 ft to miles and to kilometers d. 1.254 kg lead to its volume in cubic centimeters...
See AnswerQ: A metal ion with a 2+ charge contains 34 neutrons and
A metal ion with a 2+ charge contains 34 neutrons and 27 electrons. Identify the metal ion and determine its mass number.
See AnswerQ: Which of the following statements is (are) true?
Which of the following statements is (are) true? a. A 1.00-liter bottle contains more soda than a 1.00-quart bottle. b. A man who is 1.52 m tall is taller than a woman who is 5 ft 3 in. tall. c. A...
See AnswerQ: Express each of the following numbers in scientific (exponential) notation
Express each of the following numbers in scientific (exponential) notation. a. 529 b. 240,000,000 c. 301,000,000,000,000,000 d. 78,444 e. 0.0003442 f. 0.000000000902 g. 0.043 h. 0.0821
See AnswerQ: Express each of the following as an “ordinary” decimal number
Express each of the following as an “ordinary” decimal number. a. 2.98 * 10-5 b. 4.358 * 109 c. 1.9928 * 10-6 d. 6.02 * 10-3 e. 1.01 * 10-1 f. 7.87 * 10-3 g. 9.87 * 107 h. 3.7899 * 102 i. 1.0...
See AnswerQ: Rewrite each of the following as an “ordinary” decimal number
Rewrite each of the following as an “ordinary” decimal number. a. 2.789 * 103 b. 2.789 * 10-3 c. 9.3 * 107 d. 4.289 * 101 e. 9.999 * 104 f. 9.999 * 10-5
See AnswerQ: Write each of the following numbers in standard scientific notation.
Write each of the following numbers in standard scientific notation. a. 102.3 * 10-5 b. 32.03 * 10-3 c. 59933 * 102 d. 599.33 * 104 e. 5993.3 * 103 f. 2054 * 10-1 g. 32,000,000 * 10-6 h. 59.93...
See AnswerQ: Evaluate each of the following, and write the answer to the
Evaluate each of the following, and write the answer to the appropriate number of significant figures. a. 149.2 + 0.034 + 2000.34 b. 1.0322 * 103 + 4.34 * 103 c. 4.03 * 10-2 - 2.044 * 10-3 d. 2.09...
See AnswerQ: Evaluate each of the following, and write the answer to the
Evaluate each of the following, and write the answer to the appropriate number of significant figures. a. (0.0432)(2.909)(4.43 * 108) b. (0.8922)/[(0.00932)(4.03 * 102)] c. (3.923 * 102)(2.94)(4.09...
See AnswerQ: Evaluate each of the following, and write the answer to the
Evaluate each of the following, and write the answer to the appropriate number of significant figures. a. (2.9932 * 104)[2.4443 * 102 + 1.0032 * 101] b. [2.34 * 102 + 2.443 * 10-1]/(0.0323) c. (4.3...
See AnswerQ: Perform each of the following conversions, being sure to set up
Perform each of the following conversions, being sure to set up clearly the appropriate conversion factor in each case. a. 8.43 cm to millimeters b. 2.41 * 102 cm to meters c. 294.5 nm to centimete...
See AnswerQ: For the masses and volumes indicated, calculate the density in grams
For the masses and volumes indicated, calculate the density in grams per cubic centimeter. a. mass = 234 g; volume = 2.2 cm3 b. mass = 2.34 kg; volume = 2.2 m3 c. mass = 1.2 lb; volume = 2.1 ft3 d....
See AnswerQ: The “Chemistry in Focus” segment Critical Units! discusses the
The “Chemistry in Focus” segment Critical Units! discusses the importance of unit conversions. Read the segment and make the proper unit conversions to answer the following questions. a. The Mars Cli...
See AnswerQ: Read the “Chemistry in Focus” segment Measurement: Past,
Read the “Chemistry in Focus” segment Measurement: Past, Present, and Future and answer the following questions. a. Give three examples of how developing sophisticated measuring devices is useful in...
See AnswerQ: Express each of the following numbers in standard scientific notation.
Express each of the following numbers in standard scientific notation. a. 0.5012 b. 5,012,000 c. 0.000005012 d. 5.012 e. 5012 f. 0.005012
See AnswerQ: What similarities are there between the solid and liquid states of matter
What similarities are there between the solid and liquid states of matter? What differences are there between these two states?
See AnswerQ: Sketch a flowchart of the steps in the scientific method. Then
Sketch a flowchart of the steps in the scientific method. Then define each part of the method.
See AnswerQ: By how many places must the decimal point be moved, and
By how many places must the decimal point be moved, and in which direction, to convert each of the following to standard scientific notation? a. 5993 b. -72.14 c. 0.00008291 d. 62.357 e. 0.01014...
See AnswerQ: For the measurement 0.003040 meters, indicate which (if
For the measurement 0.003040 meters, indicate which (if any) zeros are significant and which (if any) are not significant. Account for all five zeros in the measurement, and explain your reasoning.
See AnswerQ: What is a compound? What are compounds composed of? What
What is a compound? What are compounds composed of? What is true about the composition of a compound, no matter where we happen to find the compound?
See AnswerQ: On the planet Xgnu, the most common units of length are
On the planet Xgnu, the most common units of length are the blim (for long distances) and the kryll (for shorter distances). Because the Xgnuese have 14 fingers, perhaps it is not surprising that 1400...
See AnswerQ: You pass a road sign saying “New York 110 km.”
You pass a road sign saying “New York 110 km.” If you drive at a constant speed of 100. km/h, how long should it take you to reach New York?
See AnswerQ: Certain elements have special affinities for other elements. This causes them
Certain elements have special affinities for other elements. This causes them to bind together in special ways to form .
See AnswerQ: Suppose your car is rated at 45 mi/gal for highway
Suppose your car is rated at 45 mi/gal for highway use and 38 mi/gal for city driving. If you wanted to write your friend in Spain about your car’s mileage, what ratings in kilometers per liter would...
See AnswerQ: You are in Paris, and you want to buy some peaches
You are in Paris, and you want to buy some peaches for lunch. The sign in the fruit stand indicates that peaches are 2.76 euros per kilogram. Given that there are approximately 1.44 euros to the dolla...
See AnswerQ: For a pharmacist dispensing pills or capsules, it is often easier
For a pharmacist dispensing pills or capsules, it is often easier to weigh the medication to be dispensed rather than to count the individual pills. If a single antibiotic capsule weighs 0.65 g, and a...
See AnswerQ: On the planet Xgnu, the natives have 14 fingers. On
On the planet Xgnu, the natives have 14 fingers. On the official Xgnuese temperature scale (°X), the boiling point of water (under an atmospheric pressure similar to earth’s) is 140 °X, whereas water...
See AnswerQ: For a material to float on the surface of water, the
For a material to float on the surface of water, the material must have a density less than that of water (1.0 g/mL) and must not react with the water or dissolve in it. A spherical ball has a radius...
See AnswerQ: Elemental bromine is a dense, dark-red, pungent-
Elemental bromine is a dense, dark-red, pungent-smelling liquid. Are these characteristics of elemental bromine physical or chemical properties?
See AnswerQ: A gas cylinder having a volume of 10.5 L contains
A gas cylinder having a volume of 10.5 L contains 36.8 g of gas. What is the density of the gas?
See AnswerQ: Using Table 2.8, calculate the volume of 25.
Using Table 2.8, calculate the volume of 25.0 g of each of the following: a. hydrogen gas (at 1 atmosphere pressure) b. mercury c. lead d. water
See AnswerQ: Ethanol and benzene dissolve in each other. When 100. mL
Ethanol and benzene dissolve in each other. When 100. mL of ethanol is dissolved in 1.00 L of benzene, what is the mass of the mixture? (See Table 2.8.)
See AnswerQ: When 2891 is written in scientific notation, the exponent indicating the
When 2891 is written in scientific notation, the exponent indicating the power of 10 is .
See AnswerQ: For each of the following numbers, if the number is rewritten
For each of the following numbers, if the number is rewritten in scientific notation, will the exponent of the power of 10 be positive, negative, or zero? a. 1/103 b. 0.00045 c. 52,550 d. 7.21 e....
See AnswerQ: For each of the following numbers, if the number is rewritten
For each of the following numbers, if the number is rewritten in scientific notation, will the exponent of the power of 10 be positive, negative, or zero? a. 4,915,442 b. 1/1000 c. 0.001 d. 3.75
See AnswerQ: For each of the following numbers, by how many places does
For each of the following numbers, by how many places does the decimal point have to be moved to express the number in standard scientific notation? In each case, is the exponent positive or negative?...
See AnswerQ: For each of the following numbers, by how many places must
For each of the following numbers, by how many places must the decimal point be moved to express the number in standard scientific notation? In each case, will the exponent be positive, negative, or z...
See AnswerQ: For each of the following numbers, by how many places must
For each of the following numbers, by how many places must the decimal point be moved to express the number in standard scientific notation? In each case, will the exponent be positive, negative, or z...
See AnswerQ: can be broken down into the component elements by chemical changes
can be broken down into the component elements by chemical changes.
See AnswerQ: Is the process represented below a physical or chemical change?
Is the process represented below a physical or chemical change?
See AnswerQ: The composition of a given pure compound is always no matter what
The composition of a given pure compound is always no matter what the source of the compound.
See AnswerQ: Which of the following are considered compounds (as opposed to elements
Which of the following are considered compounds (as opposed to elements)? a. He b. F2 c. HCl d. S8
See AnswerQ: Write each of the following numbers in standard scientific notation. See
Write each of the following numbers in standard scientific notation. See the Appendix if you need help multiplying or dividing numbers with exponents. a. 1/102 b. 1/10-2 c. 55/103 d. (3.1 * 106)/1...
See AnswerQ: The fundamental unit of length or distance in the metric system is
The fundamental unit of length or distance in the metric system is the .
See AnswerQ: Draw a piece of lab glassware that can appropriately measure the volume
Draw a piece of lab glassware that can appropriately measure the volume of a liquid as 32.87 mL.
See AnswerQ: Which distance is farther, 100 km or 50 mi?
Which distance is farther, 100 km or 50 mi?
See AnswerQ: The volume 0.250 L could also be expressed as mL
The volume 0.250 L could also be expressed as mL.
See AnswerQ: The distance 10.5 cm could also be expressed as m
The distance 10.5 cm could also be expressed as m.
See AnswerQ: Would an automobile moving at a constant speed of 100 km/
Would an automobile moving at a constant speed of 100 km/h violate a 65-mph speed limit?
See AnswerQ: Write each of the following numbers in standard scientific notation.
Write each of the following numbers in standard scientific notation. a. 1/1033 b. 1/105 c. 1/10-7 d. 1/0.0002 e. 1/3,093,000 f. 1/10-4 g. 1/109 h. 1/0.000015
See AnswerQ: Which weighs more, 0.001 g of water or 1
Which weighs more, 0.001 g of water or 1 mg of water?
See AnswerQ: Which weighs more, 4.25 g of gold or 425
Which weighs more, 4.25 g of gold or 425 mg of gold?
See AnswerQ: The length 500 m can also be expressed as nm.
The length 500 m can also be expressed as nm.
See AnswerQ: A perfect cube of unknown elemental composition has a length of 1
A perfect cube of unknown elemental composition has a length of 1.40 m on each side. The mass of the cube is 21.57 Mg (megagrams). Using this information and Table 2.8, determine the metal used to pre...
See AnswerQ: You are working on a project where you need the volume of
You are working on a project where you need the volume of a box. You take the length, height, and width measurements and then multiply the values together to find the volume. You report the volume of...
See AnswerQ: Indicate the number of significant figures in each of the following:
Indicate the number of significant figures in each of the following: a. This book contains over 500 pages. b. A mile is just over 5000 ft. c. A liter is equivalent to 1.059 qt. d. The population o...
See AnswerQ: Round off each of the following numbers to three significant digits.
Round off each of the following numbers to three significant digits. a. 0.00042557 b. 4.0235 * 10-5 c. 5,991,556 d. 399.85 e. 0.0059998
See AnswerQ: Round off each of the following numbers to the indicated number of
Round off each of the following numbers to the indicated number of significant digits. a. 0.75555 to four digits b. 292.5 to three digits c. 17.005 to four digits d. 432.965 to five digits
See AnswerQ: If iron filings are placed with excess powdered sulfur in a beaker
If iron filings are placed with excess powdered sulfur in a beaker, the iron filings are still attracted by a magnet and could be separated from the sulfur with the magnet. Would this combination of i...
See AnswerQ: If the combination of iron filings and sulfur in Question 25 is
If the combination of iron filings and sulfur in Question 25 is heated strongly, the iron reacts with the sulfur to form a solid that is no longer attracted by the magnet. Would this still represent a...
See AnswerQ: (For Exercises 13–14) Magnesium metal is very malleable
(For Exercises 13–14) Magnesium metal is very malleable and is able to be pounded and stretched into long, thin, narrow “ribbons” that are often used in the introductory chemistry lab as a source of t...
See AnswerQ: What does it mean to say that a solution is a homogeneous
What does it mean to say that a solution is a homogeneous mixture?
See AnswerQ: Given that 1 L = 1000 cm3, determine what conversion factor
Given that 1 L = 1000 cm3, determine what conversion factor is appropriate to convert 350 cm3 to liters; to convert 0.200 L to cubic centimeters.
See AnswerQ: A rectangular solid measures 1.0 m by 2.4
A rectangular solid measures 1.0 m by 2.4 mm by 3.9 dm. What is the volume in liters?
See AnswerQ: Which of the following substances is(are) homogeneous mixture(
Which of the following substances is(are) homogeneous mixture(s)? a. chocolate chip cookie b. iodine crystals (I2) c. air (in this room) d. gasoline (for a car) e. sucrose, C12H22O11 (commonly fo...
See AnswerQ: Perform each of the following conversions, being sure to set up
Perform each of the following conversions, being sure to set up clearly the appropriate conversion factor(s) in each case. a. 908 oz to kilograms b. 12.8 L to gallons c. 125 mL to quarts d. 2.89 g...
See AnswerQ: The mean distance from the earth to the sun is 9.
The mean distance from the earth to the sun is 9.3 3 107 mi. What is this distance in kilometers? in centimeters?
See AnswerQ: Given that one metric ton = 1000 kg, how many metric
Given that one metric ton = 1000 kg, how many metric tons are in 5.3 3 103 lb?
See AnswerQ: Convert the following temperatures to kelvins. a. 0 °
Convert the following temperatures to kelvins. a. 0 °C b. 25 °C c. 37 °C d. 100 °C e. 2175 °C f. 212 °C
See AnswerQ: Carry out the indicated temperature conversions. a. 175 °
Carry out the indicated temperature conversions. a. 175 °F to kelvins b. 255 K to Celsius degrees c. 245 °F to Celsius degrees d. 125 °C to Fahrenheit degrees
See AnswerQ: Classify the following as mixtures or pure substances. a.
Classify the following as mixtures or pure substances. a. the vegetable soup you had for lunch b. the fertilizer your dad spreads on the front lawn in the spring c. the salt you sprinkle on your Fr...
See AnswerQ: What are the fundamental units of mass, length, and temperature
What are the fundamental units of mass, length, and temperature in the metric system?
See AnswerQ: A sample of a liquid solvent has a density of 0.
A sample of a liquid solvent has a density of 0.915 g/mL. What is the mass of 85.5 mL of the liquid?
See AnswerQ: An organic solvent has a density of 1.31 g/
An organic solvent has a density of 1.31 g/mL. What volume is occupied by 50.0 g of the liquid?
See AnswerQ: A solid metal sphere has a volume of 4.2 ft3
A solid metal sphere has a volume of 4.2 ft3. The mass of the sphere is 155 lb. Find the density of the metal sphere in grams per cubic centimeter.
See AnswerQ: A sample containing 33.42 g of metal pellets is poured
A sample containing 33.42 g of metal pellets is poured into a graduated cylinder initially containing 12.7 mL of water, causing the water level in the cylinder to rise to 21.6 mL. Calculate the densit...
See AnswerQ: Convert the following temperatures to Fahrenheit degrees. a. 25
Convert the following temperatures to Fahrenheit degrees. a. 25 °C b. 273 K d. 0 K c. 2196 °C e. 86 °C f. 2273 °C
See AnswerQ: For each of the following descriptions, identify the power of 10
For each of the following descriptions, identify the power of 10 being indicated by the prefix in the measurement. a. The sign on the interstate highway says to tune my AM radio to 540 kilohertz for...
See AnswerQ: Of the three states of matter, and are not very compressible
Of the three states of matter, and are not very compressible.
See AnswerQ: Read the “Chemistry in Focus” segment Concrete—An Ancient
Read the “Chemistry in Focus” segment Concrete—An Ancient Material Made New and classify concrete as an element, a mixture, or a compound. Defend your answer.
See AnswerQ: The “Chemistry in Focus” segment Measurement: Past, Present
The “Chemistry in Focus” segment Measurement: Past, Present, and Future states that hormones can be detected to a level of 1028 g/L. Convert this level to units of pounds per gallon.
See AnswerQ: Give the metric prefix that corresponds to each of the following:
Give the metric prefix that corresponds to each of the following: a. 1000 b. 10-3 c. 10-9 d. 1,000,000 e. 10-1 f. 10-6
See AnswerQ: For each of the mathematical expressions given: a. Tell
For each of the mathematical expressions given: a. Tell the correct number of significant figures for the answer. b. Evaluate the mathematical expression using correct significant figures in the res...
See AnswerQ: The longest river in the world is the Nile River with a
The longest river in the world is the Nile River with a length of 4145 mi. How long is the Nile in cable lengths, meters, and nautical miles? Use these exact conversions to help solve the problem: 6...
See AnswerQ: Secretariat is known as the horse with the fastest run in the
Secretariat is known as the horse with the fastest run in the Kentucky Derby. If Secretariat’s record 1.25-mi run lasted 1 minute 59.2 seconds, what was his average speed in m/s?
See AnswerQ: A friend tells you that it is 69.1 °F
A friend tells you that it is 69.1 °F outside. What is this temperature in Celsius?
See AnswerQ: The hottest temperature recorded in the United States is 134 °F
The hottest temperature recorded in the United States is 134 °F in Greenland Ranch, California. The melting point of phosphorus is 44 °C. At this temperature, would phosphorus be a liquid or a solid?...
See AnswerQ: The density of osmium (the densest metal) is 22.
The density of osmium (the densest metal) is 22.57 g/cm3. What is the mass of a block of osmium with dimensions 1.84 cm * 3.61 cm * 2.10 cm?
See AnswerQ: The radius of a neon atom is 69 pm, and its
The radius of a neon atom is 69 pm, and its mass is 3.35 3 10223 g. What is the density of the atom in grams per cubic centimeter (g/cm3)? Assume the atom is a sphere with volume=4/3πr3.
See AnswerQ: Describe how the process of distillation could be used to separate a
Describe how the process of distillation could be used to separate a solution into its component substances. Give an example.
See AnswerQ: During a filtration or distillation experiment, we separate a mixture into
During a filtration or distillation experiment, we separate a mixture into its individual components. Do the chemical identities of the components of the mixture change during such a process? Explain....
See AnswerQ: If powdered elemental zinc and powdered elemental sulfur are poured into a
If powdered elemental zinc and powdered elemental sulfur are poured into a metal beaker and then heated strongly, a very vigorous chemical reaction takes place, and the zinc sulfide...
See AnswerQ: Students often have trouble relating measurements in the metric system to the
Students often have trouble relating measurements in the metric system to the English system they have grown up with. Give the approximate English system equivalents for each of the following metric s...
See AnswerQ: Classify each of the following as a(n) element,
Classify each of the following as a(n) element, compound, pure substance, homogeneous mixture, and/or heterogeneous mixture. More than one classification is possible, and not all of them may be used....
See AnswerQ: If a piece of hard, white blackboard chalk is heated strongly
If a piece of hard, white blackboard chalk is heated strongly in a flame, the mass of the piece of chalk will decrease, and eventually the chalk will crumble into a fine white dust. Does this change s...
See AnswerQ: has a definite volume but takes the shape of its container
has a definite volume but takes the shape of its container.
See AnswerQ: During a very cold winter, the temperature may remain below freezing
During a very cold winter, the temperature may remain below freezing for extended periods. However, fallen snow can still disappear, even though it cannot melt. This is possible because a solid can va...
See AnswerQ: Discuss the similarities and differences between a liquid and a gas.
Discuss the similarities and differences between a liquid and a gas.
See AnswerQ: True or false? Salad dressing (such as oil and vinegar
True or false? Salad dressing (such as oil and vinegar dressing) separating into layers after standing is an example of a chemical change because the end result looks different from how it started. Ex...
See AnswerQ: The fact that solutions of potassium chromate are bright yellow is an
The fact that solutions of potassium chromate are bright yellow is an example of a property.
See AnswerQ: Solutions containing nickel(II) ion are usually bright green in
Solutions containing nickel(II) ion are usually bright green in color. When potassium hydroxide is added to such a nickel(II) solution, a pale-green fluffy solid forms and settles out of the solution....
See AnswerQ: Solutions containing nickel(II) ion are usually bright green in
Solutions containing nickel(II) ion are usually bright green in color. When potassium hydroxide is added to such a nickel(II) solution, a pale-green fluffy solid forms and settles out of the solution....
See AnswerQ: Classify the following mixtures as homogeneous or heterogeneous. a.
Classify the following mixtures as homogeneous or heterogeneous. a. potting soil b. white wine c. your sock drawer d. window glass e. granite
See AnswerQ: Students often have trouble relating measurements in the metric system to the
Students often have trouble relating measurements in the metric system to the English system they have grown up with. Give the approximate English system equivalents for each of the following metric s...
See AnswerQ: True or false? Mixtures always result in a chemical reaction because
True or false? Mixtures always result in a chemical reaction because they consist of two or more substances and thus combine to create a new product.
See AnswerQ: Distillation and filtration are important methods for separating the components of mixtures
Distillation and filtration are important methods for separating the components of mixtures. Suppose we had a mixture of sand, salt, and water. Describe how filtration and distillation could be used s...
See AnswerQ: Matter in the state has no shape and fills completely whatever container
Matter in the state has no shape and fills completely whatever container holds it.
See AnswerQ: Which of the following describes a chemical property? a.
Which of the following describes a chemical property? a. The density of iron is 7.87 g/cm3. b. A platinum wire glows red when heated. c. An iron bar rusts. d. Aluminum is a silver-colored metal.
See AnswerQ: Which of the following describes a physical change? a.
Which of the following describes a physical change? a. Paper is torn into several smaller pieces. b. Two clear solutions are mixed together to produce a yellow solid. c. A match burns in the air....
See AnswerQ: A given compound always contains the same proportion (by mass)
A given compound always contains the same proportion (by mass) of the elements. This principle became known as .
See AnswerQ: Several elements have chemical symbols beginning with the letter N. For
Several elements have chemical symbols beginning with the letter N. For each of the following chemical symbols, give the name of the corresponding element. a. Ne b. Ni c. N d. No e. Np f. Nb g....
See AnswerQ: Find the symbol in Column 2 for each name in Column 1
Find the symbol in Column 2 for each name in Column 1.
See AnswerQ: Based on the following word descriptions, write the formula for each
Based on the following word descriptions, write the formula for each of the indicated substances. a. a compound whose molecules each contain six carbon atoms and six hydrogen atoms b. an aluminum co...
See AnswerQ: Students often have trouble relating measurements in the metric system to the
Students often have trouble relating measurements in the metric system to the English system they have grown up with. Give the approximate English system equivalents for each of the following metric s...
See AnswerQ: Based on the following word descriptions, write the formula for each
Based on the following word descriptions, write the formula for each of the indicated substances. a. a compound whose molecules contain twice as many oxygen atoms as carbon atoms b. a compound whose...
See AnswerQ: True or false? Rutherford’s bombardment experiments with metal foil suggested that
True or false? Rutherfordâs bombardment experiments with metal foil suggested that the a particles were being deflected by coming near a large, positively charged atomic nucleus.
See AnswerQ: Where are neutrons found in an atom? Are neutrons positively charged
Where are neutrons found in an atom? Are neutrons positively charged, negatively charged, or electrically uncharged?
See AnswerQ: What are the positively charged particles found in the nuclei of atoms
What are the positively charged particles found in the nuclei of atoms called?
See AnswerQ: The proton and the (electron/neutron) have almost equal
The proton and the (electron/neutron) have almost equal masses. The proton and the (electron/neutron) have charges that are equal in magnitude but opposite in nature.
See AnswerQ: An average atomic nucleus has a diameter of about m.
An average atomic nucleus has a diameter of about m.
See AnswerQ: Which particles in an atom are most responsible for the chemical properties
Which particles in an atom are most responsible for the chemical properties of the atom? Where are these particles located in the atom?
See AnswerQ: Explain what we mean when we say that a particular element consists
Explain what we mean when we say that a particular element consists of several isotopes.
See AnswerQ: True or false? The mass number of a nucleus represents the
True or false? The mass number of a nucleus represents the number of protons in the nucleus.
See AnswerQ: For an isolated atom, why do we expect the number of
For an isolated atom, why do we expect the number of electrons present in the atom to be the same as the number of protons in the nucleus of the atom?
See AnswerQ: What is the chief factor that determines the physical state of a
What is the chief factor that determines the physical state of a sample of matter?
See AnswerQ: Students often have trouble relating measurements in the metric system to the
Students often have trouble relating measurements in the metric system to the English system they have grown up with. Give the approximate English system equivalents for each of the following metric s...
See AnswerQ: Why do we not necessarily expect the number of neutrons in the
Why do we not necessarily expect the number of neutrons in the nucleus of an atom to be the same as the number of protons?
See AnswerQ: Which scientist discovered that the nuclei of most atoms contain neutrons as
Which scientist discovered that the nuclei of most atoms contain neutrons as well as protons?
See AnswerQ: For each of the following elements, use the periodic table shown
For each of the following elements, use the periodic table shown in Fig. 4.9 to write the elementâs atomic number, symbol, or name.
See AnswerQ: Write the atomic symbol / for each of the isotopes described below
Write the atomic symbol / for each of the isotopes described below. a. the isotope of carbon with 7 neutrons b. the isotope of carbon with 6 neutrons c. Z = 6, number of neutrons = 8 d. atomic num...
See AnswerQ: Write the atomic symbol for each of the isotopes described below.
Write the atomic symbol for each of the isotopes described below. a. Z = 26, A = 54 b. the isotope of iron with 30 neutrons c. number of protons = 26, number of neutrons = 31 d. the isotope of nit...
See AnswerQ: How many protons and neutrons are contained in the nucleus of each
How many protons and neutrons are contained in the nucleus of each of the following atoms? Assuming each atom is uncharged, how many electrons are present?
See AnswerQ: Read the “Chemistry in Focus” segment “Whair” Do
Read the “Chemistry in Focus” segment “Whair” Do You Live? How can isotopes be used to identify the general region of a person’s place of residence?
See AnswerQ: Read the “Chemistry in Focus” segment Isotope Tales. Define
Read the “Chemistry in Focus” segment Isotope Tales. Define the term isotope, and explain how isotopes can be used to answer scientific and historical questions.
See AnswerQ: True or false? The elements are arranged in the periodic table
True or false? The elements are arranged in the periodic table in order of increasing mass.
See AnswerQ: The road sign I just passed says “New York City 100
The road sign I just passed says “New York City 100 km,” which is about mi.
See AnswerQ: In which direction on the periodic table, horizontal or vertical,
In which direction on the periodic table, horizontal or vertical, are elements with similar chemical properties aligned? What are families of elements with similar chemical properties called?
See AnswerQ: List the characteristic physical properties that distinguish the metallic elements from the
List the characteristic physical properties that distinguish the metallic elements from the nonmetallic elements.
See AnswerQ: Where are the metallic elements found on the periodic table? Are
Where are the metallic elements found on the periodic table? Are there more metallic elements or nonmetallic elements?
See AnswerQ: Most, but not all, metallic elements are solids under ordinary
Most, but not all, metallic elements are solids under ordinary laboratory conditions. Which metallic elements are not solids?
See AnswerQ: List five nonmetallic elements that exist as gaseous substances under ordinary conditions
List five nonmetallic elements that exist as gaseous substances under ordinary conditions. Do any metallic elements ordinarily occur as gases?
See AnswerQ: The elements that lie close to the “stair-step”
The elements that lie close to the âstair-stepâ line as shown below in blue are called .
See AnswerQ: Write the number and name (if any) of the group
Write the number and name (if any) of the group (family) to which each of the following elements belongs. a. cesium b. Ra c. Rn d. chlorine e. strontium f. Xe g. Rb
See AnswerQ: Without looking at your textbook or the periodic table, name three
Without looking at your textbook or the periodic table, name three elements in each of the following groups (families). a. halogens b. alkali metals c. alkaline earth metals d. noble/inert gases
See AnswerQ: For each of the following elements, use the periodic table shown
For each of the following elements, use the periodic table shown in Fig. 4.9 to give the chemical symbol, atomic number, and group number and to specify whether each element is a metal, nonmetal, or m...
See AnswerQ: The “Chemistry in Focus” segment Putting the Brakes on Arsenic
The “Chemistry in Focus” segment Putting the Brakes on Arsenic discusses the dangers of arsenic and a possible help against arsenic pollution. Is arsenic a metal, a nonmetal, or a metalloid? What othe...
See AnswerQ: The GPS in my car indicates that I have 100. mi
The GPS in my car indicates that I have 100. mi left until I reach my destination. What is this distance in kilometers?
See AnswerQ: Most substances are composed of rather than elemental substances.
Most substances are composed of rather than elemental substances.
See AnswerQ: Are most of the chemical elements found in nature in the elemental
Are most of the chemical elements found in nature in the elemental form or combined in compounds? Why?
See AnswerQ: The noble gas present in relatively large concentrations in the atmosphere is
The noble gas present in relatively large concentrations in the atmosphere is .
See AnswerQ: Why are the elements of Group 8 referred to as the noble
Why are the elements of Group 8 referred to as the noble or inert gas elements?
See AnswerQ: Molecules of nitrogen gas and oxygen gas are said to be ,
Molecules of nitrogen gas and oxygen gas are said to be , which means they consist of pairs of atoms.
See AnswerQ: Give three examples of gaseous elements that exist as diatomic molecules.
Give three examples of gaseous elements that exist as diatomic molecules. Give three examples of gaseous elements that exist as monatomic species.
See AnswerQ: A simple way to generate elemental hydrogen gas is to pass through
A simple way to generate elemental hydrogen gas is to pass through water.
See AnswerQ: If sodium chloride (table salt) is melted and then subjected
If sodium chloride (table salt) is melted and then subjected to an electric current, elemental gas is produced, along wi...
See AnswerQ: Most of the elements are solids at room temperature. Give three
Most of the elements are solids at room temperature. Give three examples of elements that are liquids at room temperature, and three examples of elements that are gases at room temperature.
See AnswerQ: The two most common elemental forms of carbon are diamond and .
The two most common elemental forms of carbon are diamond and .
See AnswerQ: The tablecloth on my dining room table is 2 m long,
The tablecloth on my dining room table is 2 m long, which is cm or about in.
See AnswerQ: Ions are produced when an atom gains or loses .
Ions are produced when an atom gains or loses .
See AnswerQ: A simple ion with a 3+ charge (for example,
A simple ion with a 3+ charge (for example, Al+3) results when an atom (gains/loses) electrons.
See AnswerQ: An ion that has two more electrons outside the nucleus than there
An ion that has two more electrons outside the nucleus than there are protons in the nucleus will have a charge of .
See AnswerQ: Positive ions are called , whereas negative ions are called .
Positive ions are called , whereas negative ions are called .
See AnswerQ: Simple negative ions formed from single atoms are given names that end
Simple negative ions formed from single atoms are given names that end in .
See AnswerQ: Based on their location in the periodic table, give the symbols
Based on their location in the periodic table, give the symbols for three elements that would be expected to form positive ions in their reactions.
See AnswerQ: True or false? N-3 and P-3 contain
True or false? N-3 and P-3 contain a different number of protons but the same number of electrons. Justify your answer.
See AnswerQ: How many electrons are present in each of the following ions?
How many electrons are present in each of the following ions? a. Ba+2 b. P3- c. Mn2+ d. Mg2+ e. Cs+ f. Pb2-
See AnswerQ: State the number of protons, electrons, and neutrons for /
State the number of protons, electrons, and neutrons for /
See AnswerQ: Who is taller, a man who is 1.62 m
Who is taller, a man who is 1.62 m tall or a woman who is 5 ft 6 in. tall?
See AnswerQ: For the following processes that show the formation of ions, use
For the following processes that show the formation of ions, use the periodic table to indicate the number of electrons and protons present in both the ion and the neutral atom from which the ion is m...
See AnswerQ: For the following ions, indicate whether electrons must be gained or
For the following ions, indicate whether electrons must be gained or lost from the parent neutral atom, and how many electrons must be gained or lost. a. O2+ b. P3- c. Cr3+ d. Sn2+ e. Rb+ f. Pb2...
See AnswerQ: For each of the following atomic numbers, use the periodic table
For each of the following atomic numbers, use the periodic table to write the formula (including the charge) for the simple ion that the element is most likely to form. a. 53 b. 38 c. 55 d. 88 e....
See AnswerQ: On the basis of the element’s location in the periodic table,
On the basis of the element’s location in the periodic table, indicate what simple ion each of the following elements is most likely to form. a. P b. Ra c. At d. Rn e. Cs f. Se
See AnswerQ: List some properties of a substance that would lead you to believe
List some properties of a substance that would lead you to believe it consists of ions. How do these properties differ from those of nonionic compounds?
See AnswerQ: Why does a solution of sodium chloride in water conduct an electric
Why does a solution of sodium chloride in water conduct an electric current?
See AnswerQ: Why does an ionic compound conduct an electric current when the compound
Why does an ionic compound conduct an electric current when the compound is melted but not when it is in the solid state?
See AnswerQ: Why must the total number of positive charges in an ionic compound
Why must the total number of positive charges in an ionic compound equal the total number of negative charges?
See AnswerQ: For each of the following positive ions, use the concept that
For each of the following positive ions, use the concept that a chemical compound must have a net charge of zero to predict the formula of the simple compounds that the positive ions would form with t...
See AnswerQ: For each of the following negative ions, use the concept that
For each of the following negative ions, use the concept that a chemical compound must have a net charge of zero to predict the formula of the simple compounds that the negative ions would form with t...
See AnswerQ: The fundamental SI unit of length is the meter. However,
The fundamental SI unit of length is the meter. However, we often deal with larger or smaller lengths or distances for which multiples or fractions of the fundamental unit are more useful. For each of...
See AnswerQ: For each of the following elements, give the chemical symbol and
For each of the following elements, give the chemical symbol and atomic number. a. astatine b. xenon c. radium d. strontium e. lead f. selenium g. argon h. cesium
See AnswerQ: Give the group number (if any) in the periodic table
Give the group number (if any) in the periodic table for the elements listed in Problem 85. If the group has a family name, give that name. From problem 85: For each of the following elements, give t...
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. Dalton was the first to theorize that atoms consist of smaller particles called electrons, protons, and neutrons. b. Dalton’s atomic theory didn’t...
See AnswerQ: Which of the following is(are) true regarding 37Cl-
Which of the following is(are) true regarding 37Cl- and 40Ar? a. same group number on the periodic table b. same number of protons c. same number of neutrons d. same number of electrons
See AnswerQ: Carbohydrates, a class of compounds containing the elements carbon, hydrogen
Carbohydrates, a class of compounds containing the elements carbon, hydrogen, and oxygen, were originally thought to contain one water molecule (H2O) for each carbon atom present. The carbohydrate glu...
See AnswerQ: When iron rusts in moist air, the product is typically a
When iron rusts in moist air, the product is typically a mixture of two iron–oxygen compounds. In one compound, there is an equal number of iron and oxygen atoms. In the other compound, there are thre...
See AnswerQ: How many protons and neutrons are contained in the nucleus of each
How many protons and neutrons are contained in the nucleus of each of the following atoms? For an atom of the element, how many electrons are present?
See AnswerQ: Though the common isotope of aluminum has a mass number of 27
Though the common isotope of aluminum has a mass number of 27, isotopes of aluminum have been isolated (or prepared in nuclear reactors) with mass numbers of 24, 25, 26, 28, 29, and 30. How many neutr...
See AnswerQ: How many electrons are present in each of the following ions?
How many electrons are present in each of the following ions? a. Se2- b. Br- c. Cr3+ d. Rb+ e. Bi3+ f. Cu2+
See AnswerQ: Which English unit of length or distance is most comparable in scale
Which English unit of length or distance is most comparable in scale to each of the following metric system units for making measurements? a. a centimeter b. a meter c. a kilometer
See AnswerQ: Give the chemical symbol for each of the following elements.
Give the chemical symbol for each of the following elements. a. barium b. potassium c. cesium d. lead e. platinum f. gold
See AnswerQ: Which of the following series of elements is not matched with the
Which of the following series of elements is not matched with the correct description? a. F, Cl, Br—halogens b. He, Ne, Ar—noble gases c. Mg, Ca, Sr—alkaline earth metals d. Fe, Co, Ni—transition...
See AnswerQ: Give the chemical symbol for each of the following elements.
Give the chemical symbol for each of the following elements. a. silver b. aluminum c. cadmium d. antimony e. tin f. arsenic
See AnswerQ: For each of the following chemical symbols, give the name of
For each of the following chemical symbols, give the name of the corresponding element. a. Te b. Pd c. Zn d. Si e. Cs f. Bi g. F h. Ti
See AnswerQ: Write the simplest formula for each of the following substances, listing
Write the simplest formula for each of the following substances, listing the elements in the order given. a. a molecule containing one carbon atom and two oxygen atoms b. a compound containing one a...
See AnswerQ: For each of the following atomic numbers, write the name and
For each of the following atomic numbers, write the name and chemical symbol of the corresponding element. (Refer to Figure 4.9.) a. 7 b. 10 c. 11 d. 28 e. 22 f. 18 g. 36 h. 54
See AnswerQ: Write the atomic symbol /for each of the isotopes described below
Write the atomic symbol /for each of the isotopes described below. a. Z = 6, number of neutrons = 7 b. the isotope of carbon with a mass number of 13 c. Z = 6, A = 13 d. Z = 19, A = 44 e. the iso...
See AnswerQ: How many protons and neutrons are contained in the nucleus of each
How many protons and neutrons are contained in the nucleus of each of the following atoms? In an atom of each element, how many electrons are present?
See AnswerQ: For each of the following elements, use the table shown in
For each of the following elements, use the table shown in Fig. 4.9 to give the chemical symbol and atomic number and to specify whether the element is a metal or a nonmetal. Also give the named famil...
See AnswerQ: The unit of volume in the metric system is the liter,
The unit of volume in the metric system is the liter, which consists of 1000 milliliters. How many liters or milliliters is each of the following common English system measurements approximately equiv...
See AnswerQ: Read the “Chemistry in Focus” segment A Four-Wheel
Read the “Chemistry in Focus” segment A Four-Wheel-Drive Nanocar. It discusses carbon and copper atoms. Both atoms have stable isotopes. Example 4.2 had you consider the isotopes of carbon. Copper exi...
See AnswerQ: Provide the name of the element that corresponds to each symbol given
Provide the name of the element that corresponds to each symbol given in the following table.
See AnswerQ: Provide the symbols for the elements given in the following table.
Provide the symbols for the elements given in the following table.
See AnswerQ: Complete the following table to predict whether the given atom will gain
Complete the following table to predict whether the given atom will gain or lose electrons in forming an ion.
See AnswerQ: Using the periodic table, complete the following table. /
Using the periodic table, complete the following table.
See AnswerQ: Which of the following is(are) correct? a
Which of the following is(are) correct? a. 40Ca2+ contains 20 protons and 18 electrons. b. Rutherford created the cathode-ray tube and was the founder of the charge-to-mass ratio of an electron. c....
See AnswerQ: Chemistry is an intimidating academic subject for many students. You are
Chemistry is an intimidating academic subject for many students. You are not alone if you are afraid of not doing well in this course! Why do you suppose the study of chemistry is so intimidating for...
See AnswerQ: was the first scientist to recognize the importance of careful measurements
was the first scientist to recognize the importance of careful measurements.
See AnswerQ: Which metric system unit is most appropriate for measuring the length of
Which metric system unit is most appropriate for measuring the length of an insect such as a beetle? a. meters b. millimeters c. megameters d. kilometers
See AnswerQ: In addition to his important work on the properties of gases,
In addition to his important work on the properties of gases, what other valuable contributions did Robert Boyle make to the development of the study of chemistry?
See AnswerQ: What are the three most abundant elements (by mass) in
What are the three most abundant elements (by mass) in the human body?
See AnswerQ: What are the five most abundant elements (by mass) in
What are the five most abundant elements (by mass) in the earth’s crust, oceans, and atmosphere?
See AnswerQ: Read the “Chemistry in Focus” segment Trace Elements: Small
Read the “Chemistry in Focus” segment Trace Elements: Small but Crucial, and answer the following questions. a. What is meant by the term trace element? b. Name two essential trace elements in the b...
See AnswerQ: Give the symbols and names for the elements whose chemical symbols consist
Give the symbols and names for the elements whose chemical symbols consist of only one letter.
See AnswerQ: Being a scientist is very much like being a detective. Detectives
Being a scientist is very much like being a detective. Detectives such as Sherlock Holmes or Miss Marple perform a very systematic analysis of a crime to solve it, much like a scientist does when addr...
See AnswerQ: In science, what is the difference between a law and a
In science, what is the difference between a law and a theory? Provide examples of each.
See AnswerQ: Observations may be either qualitative or quantitative. Quantitative observations are usually
Observations may be either qualitative or quantitative. Quantitative observations are usually referred to as measurements. List five examples of qualitative observations you might make around your hom...
See AnswerQ: Use the periodic table shown in Fig. 4.9 to
Use the periodic table shown in Fig. 4.9 to find the symbol or name for each of the following elements
See AnswerQ: Use the periodic table inside the front cover of this book to
Use the periodic table inside the front cover of this book to find the symbol or name for each of the following elements.
See AnswerQ: When a measuring scale is used properly to the limit of precision
When a measuring scale is used properly to the limit of precision, the last significant digit recorded for the measurement is said to be uncertain. Explain.
See AnswerQ: For each of the following chemical symbols, give the name of
For each of the following chemical symbols, give the name of the corresponding element. a. K b. Ge c. P d. C e. N f. Na g. Ne h. I
See AnswerQ: What were the four fundamental substances postulated by the Greeks?
What were the four fundamental substances postulated by the Greeks?
See AnswerQ: When a large or small number is written in standard scientific notation
When a large or small number is written in standard scientific notation, the number is expressed as the product of a number between 1 and 10, multiplied by the appropriate power of 10. For each of the...
See AnswerQ: Classify the following as mixtures or pure substances. a.
Classify the following as mixtures or pure substances. a. a multivitamin tablet b. the blue liquid in your car’s windshield reservoir c. a ham and cheese omelet d. a diamond
See AnswerQ: Classify the following mixtures as heterogeneous or homogeneous. a.
Classify the following mixtures as heterogeneous or homogeneous. a. soil b. mayonnaise c. Italian salad dressing d. the wood from which the desk you are studying on is made e. sand at the beach
See AnswerQ: Why can the length of the pin shown in Fig. 2
Why can the length of the pin shown in Fig. 2.5 not be recorded as 2.850 cm?
See AnswerQ: Indicate the number of significant figures in each of the following:
Indicate the number of significant figures in each of the following: a. 250. b. 250 c. 2.5 * 102 d. 250.0
See AnswerQ: Indicate the number of significant figures implied in each of the following
Indicate the number of significant figures implied in each of the following statements: a. The population of the United States in 2016 was 324 million. b. One minute is equivalent to 60 seconds. c....
See AnswerQ: When we round off a number, if the number to the
When we round off a number, if the number to the right of the digit to be rounded is greater than 5, then we should
See AnswerQ: In a multiple-step calculation, is it better to round
In a multiple-step calculation, is it better to round off the numbers to the correct number of significant figures in each step of the calculation or to round off only the final answer? Explain.
See AnswerQ: Round off each of the following numbers to three significant digits,
Round off each of the following numbers to three significant digits, and express the result in standard scientific notation. a. 254,931 b. 0.00025615 c. 47.85 * 103 d. 0.08214 * 105
See AnswerQ: Round off each of the following numbers to two significant digits,
Round off each of the following numbers to two significant digits, and express the result in standard scientific notation. a. 1,566,311 b. 2.7651 * 10-3 c. 0.07759 d. 0.0011672
See AnswerQ: Round off each of the following numbers to the indicated number of
Round off each of the following numbers to the indicated number of significant digits and write the answer in standard scientific notation. a. 4341 * 102 to three significant digits b. 93.441 * 103...
See AnswerQ: When a large or small number is written in standard scientific notation
When a large or small number is written in standard scientific notation, the number is expressed as the product of a number between 1 and 10, multiplied by the appropriate power of 10. For each of the...
See AnswerQ: Round off each of the following numbers to the indicated number of
Round off each of the following numbers to the indicated number of significant digits, and write the answer in standard scientific notation. a. 0.00034159 to two digits b. 103.351 * 102 to five digi...
See AnswerQ: Consider the calculation indicated below: / Explain
Consider the calculation indicated below: Explain why the answer to this calculation should be reported to only two significant digits.
See AnswerQ: The following water measurements are made: 18 mL of water measured
The following water measurements are made: 18 mL of water measured with a beaker, 128.7 mL of water measured with a graduated cylinder, and 23.45 mL of water measured with a buret. If all of these wat...
See AnswerQ: When the calculation (2.31)(4.9795 *
When the calculation (2.31)(4.9795 * 103)/(1.9971 * 104) is performed, how many significant digits should be reported for the answer? You should not need to perform the calculation.
See AnswerQ: Which of the following are true? a. P4 is
Which of the following are true? a. P4 is considered a compound. b. Metal rusting on a car is a chemical change. c. Dissolving sugar in water is a chemical change. d. Sodium chloride (NaCl) is a h...
See AnswerQ: When the sum 4.9965 + 2.11 + 3
When the sum 4.9965 + 2.11 + 3.887 is calculated, to how many decimal places should the answer be reported? You should not need to perform the calculation.
See AnswerQ: How many digits after the decimal point should be reported when the
How many digits after the decimal point should be reported when the calculation (10,434 -9.3344) is performed?
See AnswerQ: The processes of melting and evaporation involve changes in the of a
The processes of melting and evaporation involve changes in the of a substance.
See AnswerQ: Without actually performing the calculations indicated, tell to how many significant
Without actually performing the calculations indicated, tell to how many significant digits the answer to the calculation should be expressed. a. (0.196)(0.08215)(295)/(1.1) b. (4.215 + 3.991 + 2.44...
See AnswerQ: Will the power of 10 have a positive or a negative exponent
Will the power of 10 have a positive or a negative exponent when each of the following numbers is rewritten in standard scientific notation? a. 42,751 b. 1253 c. 0.002045 d. 0.1089
See AnswerQ: Which of the following contains an element, a compound, and
Which of the following contains an element, a compound, and a mixture? a. copper, silicon dioxide (SiO2), copper(II) sulfate (CuSO4) b. hydrogen, carbon dioxide (CO2), water (H2O) c. chili, pizza,...
See AnswerQ: How many significant digits should be used to report the answer to
How many significant digits should be used to report the answer to each of the following calculations? Do not perform the calculations. a. (2.7518 + 9.01 + 3.3349)/(2.1) b. (2.7751 * 1.95)/(.98) c....
See AnswerQ: Which of the following best describes the air around you on a
Which of the following best describes the air around you on a typical day? (Assume the air is made up of ,80% nitrogen and ,20% oxygen. Ignore other gases such as water vapor and carbon dioxide.). a....
See AnswerQ: A represents a ratio based on an equivalence statement between two measurements
A represents a ratio based on an equivalence statement between two measurements.
See AnswerQ: How many significant figures are understood for the numbers in the following
How many significant figures are understood for the numbers in the following definition: 1 in. = 2.54 cm?
See AnswerQ: Given that 1 mi = 1760 yd, determine what conversion factor
Given that 1 mi = 1760 yd, determine what conversion factor is appropriate to convert 1849 yd to miles; to convert 2.781 mi to yards.
See AnswerQ: Given that 1 in. = 2.54 cm exactly,
Given that 1 in. = 2.54 cm exactly, indicate what conversion factor is appropriate to convert 3.25 in. to centimeters and to convert 46.12 cm to inches.
See AnswerQ: For Exercises 57 and 58, apples cost $1.75
For Exercises 57 and 58, apples cost $1.75 per pound. What conversion factor is appropriate to express the cost of 5.3 lb of apples?
See AnswerQ: For Exercises 57 and 58, apples cost $1.75
For Exercises 57 and 58, apples cost $1.75 per pound. What conversion factor could be used to determine how many pounds of apples could be bought for $25.00?
See AnswerQ: Sketch the apparatus commonly used for simple distillation in the laboratory,
Sketch the apparatus commonly used for simple distillation in the laboratory, identifying each component.
See AnswerQ: Will the power of 10 have a positive, negative, or
Will the power of 10 have a positive, negative, or zero exponent when each of the following numbers is rewritten in standard scientific notation? a. 0.08331 b. 2.8 c. 0.0491 d. 70,892,000
See AnswerQ: The properties of a compound are often very different from the properties
The properties of a compound are often very different from the properties of the elements making up the compound. Water is an excellent example of this idea. Discuss.
See AnswerQ: Which of the following best describes the substance XeF4? a
Which of the following best describes the substance XeF4? a. element b. compound c. heterogeneous mixture d. homogeneous mixture
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. A spoonful of sugar is a mixture. b. Only elements are pure substances. c. Air is a mixture of gases. d. Gasoline is a pure substance. e. Compou...
See AnswerQ: 12.01 g of carbon contains 6.02 * 1023
12.01 g of carbon contains 6.02 * 1023 carbon atoms. What is the mass in grams of 1.89 * 1025 carbon atoms?
See AnswerQ: Los Angeles and Honolulu are 2558 mi apart. What is this
Los Angeles and Honolulu are 2558 mi apart. What is this distance in kilometers?
See AnswerQ: The United States has high-speed trains running between Boston and
The United States has high-speed trains running between Boston and New York capable of speeds up to 160 mi/h. Are these trains faster or slower than the fastest trains in the United Kingdom, which rea...
See AnswerQ: The radius of an atom is on the order of 10210 m
The radius of an atom is on the order of 10210 m. What is this radius in centimeters? in inches? in nanometers?
See AnswerQ: The temperature scale used in everyday life in most of the world
The temperature scale used in everyday life in most of the world except the United States is the scale.
See AnswerQ: The point of water is at 32° on the Fahrenheit temperature
The point of water is at 32° on the Fahrenheit temperature scale.
See AnswerQ: The normal boiling point of water is °F, or °
The normal boiling point of water is °F, or °C.
See AnswerQ: What are the two characteristic properties of matter?
What are the two characteristic properties of matter?
See AnswerQ: On both the Celsius and Kelvin temperature scales, there are degrees
On both the Celsius and Kelvin temperature scales, there are degrees between the normal freezing and boiling points of water.
See AnswerQ: On which temperature scale (°F, °C, or K
On which temperature scale (°F, °C, or K) does 1 degree represent the smallest change in temperature?
See AnswerQ: Make the following temperature conversions: a. 44.2
Make the following temperature conversions: a. 44.2 °C to kelvins b. 891 K to °C c. 220 °C to kelvins d. 273.1 K to °C
See AnswerQ: Carry out the indicated temperature conversions. a. 2153 °
Carry out the indicated temperature conversions. a. 2153 °F to kelvins b. 2153 °C to kelvins c. 555 °C to Fahrenheit degrees d. 224 °F to Celsius degrees
See AnswerQ: Convert the following Fahrenheit temperatures to Celsius degrees. a.
Convert the following Fahrenheit temperatures to Celsius degrees. a. a chilly morning in early autumn, 45 °F b. a hot, dry day in the Arizona desert, 115 °F c. the temperature in winter when my car...
See AnswerQ: Convert the following Celsius temperatures to Fahrenheit degrees. a.
Convert the following Celsius temperatures to Fahrenheit degrees. a. the boiling temperature of ethyl alcohol, 78.1 °C b. a hot day at the beach on a Greek isle, 40. °C c. the lowest possible tempe...
See AnswerQ: The “Chemistry in Focus” segment Tiny Thermometers states that the
The “Chemistry in Focus” segment Tiny Thermometers states that the temperature range for the carbon nanotube gallium thermometers is 50 °C to 500 °C. a. What properties of gallium make it useful in a...
See AnswerQ: Perform the indicated temperature conversions. a. 275 K to
Perform the indicated temperature conversions. a. 275 K to °C b. 82 °F to °C c. 221 °C to °F d. 240 °F to °C (Notice anything unusual about your answer?)
See AnswerQ: What does the density of a substance represent?
What does the density of a substance represent?
See AnswerQ: A sample of matter that is “rigid” has (stronger
A sample of matter that is “rigid” has (stronger/weaker) forces among the particles in the sample than does a sample that is not rigid.
See AnswerQ: A kilogram of lead occupies a much smaller volume than a kilogram
A kilogram of lead occupies a much smaller volume than a kilogram of water because has a much higher density.
See AnswerQ: If a solid block of glass, with a volume of exactly
If a solid block of glass, with a volume of exactly 100 in.3, is placed in a basin of water that is full to the brim, then of water will overflow from the basin.
See AnswerQ: Is the density of a gaseous substance likely to be larger or
Is the density of a gaseous substance likely to be larger or smaller than the density of a liquid or solid substance at the same temperature? Why?
See AnswerQ: What property of density makes it useful as an aid in identifying
What property of density makes it useful as an aid in identifying substances?
See AnswerQ: Referring to Table 2.8, which substance listed is most
Referring to Table 2.8, which substance listed is most dense? Which substance is least dense? For the two substances you have identified, for which one would a 1.00-g sample occupy the larger volume?...
See AnswerQ: Referring to Table 2.8, determine whether magnesium, ethanol
Referring to Table 2.8, determine whether magnesium, ethanol, silver, or salt is the least dense. From table 2.8:
See AnswerQ: In a sample of a gaseous substance, more than 99%
In a sample of a gaseous substance, more than 99% of the overall volume of the sample is empty space. How is this fact reflected in the properties of a gaseous substance compared with the properties o...
See AnswerQ: For the masses and volumes indicated, calculate the density in grams
For the masses and volumes indicated, calculate the density in grams per cubic centimeter. a. mass = 4.53 kg; volume = 225 cm3 b. mass = 26.3 g; volume = 25.0 mL c. mass = 1.00 lb; volume = 500. cm...
See AnswerQ: The element bromine at room temperature is a liquid with a density
The element bromine at room temperature is a liquid with a density of 3.12 g/mL. Calculate the mass of 125 mL of bromine. What volume does 85.0 g of bromine occupy?
See AnswerQ: Indicate the number of significant digits in the answer when each of
Indicate the number of significant digits in the answer when each of the following expressions is evaluated (you do not have to evaluate the expression). a. (6.25)/(74.1143) b. (1.45)(0.08431)(6.022...
See AnswerQ: Although some elements are found in an isolated state, most elements
Although some elements are found in an isolated state, most elements are found combined as with other elements.
See AnswerQ: Write each of the following numbers in standard scientific notation, rounding
Write each of the following numbers in standard scientific notation, rounding off the numbers to three significant digits. a. 424.6174 b. 0.00078145 c. 26,755 d. 0.0006535 e. 72.5654
See AnswerQ: By how many places must the decimal point be moved, and
By how many places must the decimal point be moved, and in which direction, to convert each of the following to “ordinary” decimal numbers? a. 4.311 * 106 b. 7.895 * 10-5 c. 8.712 * 101 d. 4.995 *...
See AnswerQ: Sunflower oil has a density of 0.920 g/mL
Sunflower oil has a density of 0.920 g/mL. What is the mass of 4.50 L of sunflower oil? What volume (in L) would 375 g of sunflower oil occupy?
See AnswerQ: If 1000. mL of linseed oil has a mass of 929
If 1000. mL of linseed oil has a mass of 929 g, calculate the density of linseed oil.
See AnswerQ: A material will float on the surface of a liquid if the
A material will float on the surface of a liquid if the material has a density less than that of the liquid. Given that the density of water is approximately 1.0 g/mL under many conditions, will a blo...
See AnswerQ: For Exercises 13–14 Magnesium metal is very malleable and is
For Exercises 13–14 Magnesium metal is very malleable and is able to be pounded and stretched into long, thin, narrow “ribbons” that are often used in the introductory chemistry lab as a source of the...
See AnswerQ: Which of the following is/are examples of a chemical change
Which of the following is/are examples of a chemical change? a. carving wood b. snow melting c. dry ice subliming (solid CO2 vaporizing into a gas, passing the liquid state) d. burning cookies in...
See AnswerQ: Use the information in Table 2.8 to calculate the volume
Use the information in Table 2.8 to calculate the volume of 50.0 g of each of the following substances. a. sodium chloride b. mercury c. benzene d. silver From table 2.8:
See AnswerQ: Use the information in Table 2.8 to calculate the mass
Use the information in Table 2.8 to calculate the mass of 50.0 cm3 of each of the following substances. a. gold b. iron c. lead d. aluminum From table 2.8:
See AnswerQ: How do we know when a chemical reaction is taking place?
How do we know when a chemical reaction is taking place? Can you think of an example of how each of the five senses (sight, hearing, taste, touch, smell) might be used in detecting when a chemical rea...
See AnswerQ: Write the name of each of the following ionic substances, using
Write the name of each of the following ionic substances, using -ous or -ic endings to indicate the charge of the cation. a. CuCl b. Fe2O3 c. Hg2Cl2 d. MnCl2 e. TiO2 f. PbO
See AnswerQ: Write the name of each of the following ionic substances, using
Write the name of each of the following ionic substances, using -ous or -ic endings to indicate the charge of the cation. a. CoCl2 b. CrBr3 c. PbO d. SnO2 e. Co2O3 f. FeCl3
See AnswerQ: Write the name of each of the following binary compounds of nonmetallic
Write the name of each of the following binary compounds of nonmetallic elements. a. KrF2 b. Se2S6 c. AsH3 d. XeO4 e. BrF3 f. P2S5
See AnswerQ: Write the name for each of the following binary compounds of nonmetallic
Write the name for each of the following binary compounds of nonmetallic elements. a. ClF5 b. XeCl2 c. SeO2 d. N2O3 e. I2Cl6 f. CS2
See AnswerQ: Balance each of the following equations that describe precipitation reactions.
Balance each of the following equations that describe precipitation reactions. a. Na2SO4(aq) + CaCl2 (aq) CaSO4(s) + NaCl(aq) b. Co(C2H3O2) 2 (aq) + Na2S(aq)...
See AnswerQ: The formulas Na2O and N2O look very similar. What is the
The formulas Na2O and N2O look very similar. What is the name for each compound? Why do we use a different naming convention between the two compounds?
See AnswerQ: For each of the following precipitation reactions, complete and balance the
For each of the following precipitation reactions, complete and balance the equation, indicating clearly which product is the precipitate. If no reaction would be expected, so indicate. a. (NH4)2SO4(...
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, predict the identity of the precipitate that forms when aqueous solutions of the following substances are mixed. If no precipitate is l...
See AnswerQ: What is a net ionic equation? What species are shown in
What is a net ionic equation? What species are shown in such an equation, and which species are not shown?
See AnswerQ: Lead(II) nitrate is added to four separate beakers that
Lead(II) nitrate is added to four separate beakers that contain the following: Beaker 1 (sodium chloride) Beaker 2 (sodium hydroxide) Beaker 3 (sodium phosphate) Beaker 4 (sodium sulfate) After t...
See AnswerQ: Why is water an important solvent? Although you have not yet
Why is water an important solvent? Although you have not yet studied water in detail, can you think of some properties of water that make it so important?
See AnswerQ: Based on the general solubility rules given in Table 7.1
Based on the general solubility rules given in Table 7.1, propose five combinations of aqueous ionic reagents that likely would form a precipitate when they are mixed. Write the balanced full molecula...
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, write a balanced molecular equation for the precipitation reactions that take place when the following aqueous solutions are mixed. Und...
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, write a balanced molecular equation for the precipitation reactions that take place when the following aqueous solutions are mixed. Und...
See AnswerQ: Balance each of the following equations that describe precipitation reactions.
Balance each of the following equations that describe precipitation reactions. a. CaCl2(aq) + AgNO3(aq) Ca(NO3)2(aq) + AgCl(s) b. AgNO3(aq) + K2CrO4(aq) A...
See AnswerQ: Balance each of the following chemical equations. a. FeCl3
Balance each of the following chemical equations. a. FeCl3(aq) + KOH(aq) Fe(OH)3(s) + KCl(aq) b. Pb(C2H3O2)2(aq) + KI(aq) PbI2(s) + KC2H3O2(aq) c. P4O10(s)...
See AnswerQ: Balance each of the following chemical equations. a. K2SO4
Balance each of the following chemical equations. a. K2SO4(aq) + BaCl2(aq) BaSO4(s) + KCl(aq) b. Fe(s) + H2O(g) FeO(s) + H2(g) c. NaOH(aq) + HClO4(aq...
See AnswerQ: Balance each of the following chemical equations. a. Na2SO4
Balance each of the following chemical equations. a. Na2SO4(aq) + CaCl2(aq) CaSO4(s) + NaCl(aq) b. Fe(s) + H2O(g) Fe3O4(s) + H2(g) c. Ca(OH)2(aq...
See AnswerQ: Balance each of the following chemical equations. a. Fe3O4
Balance each of the following chemical equations. a. Fe3O4(s) + H2(g) Fe(l) + H2O(g) b. K2SO4(aq) + BaCl2(aq) BaSO4(s) + KCl(aq) c. HCl(aq...
See AnswerQ: Balance each of the following chemical equations. a. NaCl
Balance each of the following chemical equations. a. NaCl(s) + SO2(g) + H2O(g) + O2 (g) Na2SO4(s) + HCl(g) b. Br2 (l) + I2 (s) IBr3(s) c. Ca3N2 (s) + H2O(l)...
See AnswerQ: Balance each of the following chemical equations. a. KO2
Balance each of the following chemical equations. a. KO2(s) + H2O(l) KOH(aq) + O2 (g) + H2O2 (aq) b. Fe2O3(s) + HNO3(aq) Fe(NO3)3(aq) + H2O(l) c. NH3(g) + O2...
See AnswerQ: Describe briefly what happens when an ionic substance is dissolved in water
Describe briefly what happens when an ionic substance is dissolved in water.
See AnswerQ: Balance each of the following chemical equations. a. Ba
Balance each of the following chemical equations. a. Ba(NO3)2(aq) + Na2CrO4(aq) BaCrO4(s) + NaNO3(aq) b. PbCl2(aq) + K2SO4(aq) PbSO4(s) + KCl(aq) c. C2H5OH(l...
See AnswerQ: What salt would form when each of the following strong acid/
What salt would form when each of the following strong acid/ strong base reactions takes place? a. HCl(aq) + KOH(aq) b. RbOH(aq) + HNO3(aq) c. HClO4(aq) + NaOH(aq) d. HBr(aq) + CsOH(aq)
See AnswerQ: Complete the following acid–base reactions by indicating the acid and
Complete the following acid–base reactions by indicating the acid and base that must have reacted in each case to produce the indicated salt. a. +...
See AnswerQ: What do we mean when we say that the transfer of electrons
What do we mean when we say that the transfer of electrons can be the “driving force” for a reaction? Give an example of a reaction where this happens.
See AnswerQ: Balance each of the following oxidation–reduction reactions. a
Balance each of the following oxidation–reduction reactions. a. Co(s) + Br2(l) CoBr3(s) b. Al(s) + H2SO4(aq) Al2(SO4)3(aq) + H2(g) c. Na(s) + H2O(l...
See AnswerQ: Balance each of the following oxidation–reduction chemical reactions.
Balance each of the following oxidation–reduction chemical reactions. a. P4(s) + O2(g) P4O10(s) b. MgO(s) + C(s) Mg(s) + CO(g) c. Sr(s) + H2O(l)...
See AnswerQ: a. Give two examples each of a single-displacement reaction
a. Give two examples each of a single-displacement reaction and of a double-replacement reaction. How are the two reaction types similar, and how are they different? b. Give two examples each of a re...
See AnswerQ: True or false? Coefficients can be fractions when balancing a chemical
True or false? Coefficients can be fractions when balancing a chemical equation. Whether true or false, explain why this can or cannot occur.
See AnswerQ: Identify each of the following unbalanced reaction equations as belonging to one
Identify each of the following unbalanced reaction equations as belonging to one or more of the following categories: precipitation, acid–base, or oxidation–reduction. a. K2SO4(aq) + Ba(NO3)2(aq)...
See AnswerQ: Identify each of the following unbalanced reaction equations as belonging to one
Identify each of the following unbalanced reaction equations as belonging to one or more of the following categories: precipitation, acid–base, or oxidation– reduction. a. H2O2(aq)...
See AnswerQ: How do chemists know that the ions behave independently of one another
How do chemists know that the ions behave independently of one another when an ionic solid is dissolved in water?
See AnswerQ: The reaction between ammonium perchlorate and aluminum is discussed in the “
The reaction between ammonium perchlorate and aluminum is discussed in the “Chemistry in Focus” segment Oxidation– Reduction Reactions Launch the Space Shuttle. The reaction is labeled as an oxidation...
See AnswerQ: What is a synthesis or combination reaction? Give an example.
What is a synthesis or combination reaction? Give an example. Can such reactions also be classified in other ways? Give an example of a synthesis reaction that is also a combustion reaction. Give an e...
See AnswerQ: What is a decomposition reaction? Give an example. Can such
What is a decomposition reaction? Give an example. Can such reactions also be classified in other ways?
See AnswerQ: Complete and balance each of the following combustion reactions. a
Complete and balance each of the following combustion reactions. a. C6H6(l) + O2(g) b. C5H12(l) + O2(g) c. C2H6O(l) + O2(g)
See AnswerQ: Complete and balance each of the following combustion reactions. a
Complete and balance each of the following combustion reactions. a. CH4(g) + O2(g) b. C2H2(g) + O2(g) c. C10H8(s) + O2(g)
See AnswerQ: A metal ion with a 2+ charge has 23 electrons and
A metal ion with a 2+ charge has 23 electrons and forms a compound with a halogen ion that contains 17 protons. a. What is the identity of the metal ion? b. What is the identity of the halogen ion a...
See AnswerQ: Complete Table 5.A by writing the names and formulas for
Complete Table 5.A by writing the names and formulas for the ionic compounds formed when the cations listed across the top combine with the anions shown in the left-hand column.
See AnswerQ: Complete Table 5.B by writing the formulas for the ionic
Complete Table 5.B by writing the formulas for the ionic compounds formed when the anions listed across the top combine with the cations shown in the left-hand column.
See AnswerQ: Balance each of the following chemical equations. a. Cl2
Balance each of the following chemical equations. a. Cl2(g) + KBr(aq) Br2 (l) + KCl(aq) b. Cr(s) + O2 (g) Cr2O3(s) c. P4(s) + H2 (g)...
See AnswerQ: Balance each of the following chemical equations. a. SiCl4
Balance each of the following chemical equations. a. SiCl4(l) + Mg(s) Si(s) + MgCl2(s) b. NO(g) + Cl2(g) NOCl(g) c. MnO2(s) + Al(s)...
See AnswerQ: Suppose you are trying to help your friend understand the general solubility
Suppose you are trying to help your friend understand the general solubility rules for ionic substances in water. Explain in general terms to your friend what the solubility rules mean, and give an ex...
See AnswerQ: For each of the following atomic numbers, use the periodic table
For each of the following atomic numbers, use the periodic table to write the formula (including the charge) for the simple ion that the element is most likely to form. a. 36 b. 31 c. 52 d. 81 e....
See AnswerQ: For the following pairs of ions, use the principle of electrical
For the following pairs of ions, use the principle of electrical neutrality to predict the formula of the binary compound that the ions are most likely to form. a. Na+ and S2- b. K+ and Cl- c. Ba2+...
See AnswerQ: Which of the following statements about chemical equations is (are)
Which of the following statements about chemical equations is (are) true? a. When balancing a chemical equation, you can never change the coefficient in front of any chemical formula. b. The coeffic...
See AnswerQ: Write the name of each of the following ionic substances, using
Write the name of each of the following ionic substances, using the system that includes a Roman numeral to specify the charge of the cation. a. FeBr2 b. CoS c. Co2S3 d. SnO2 e. Hg2Cl2 f. HgCl2...
See AnswerQ: A member of the alkali metal family whose most stable ion contains
A member of the alkali metal family whose most stable ion contains 36 electrons forms a compound with chlorine. What is the correct formula for this compound?
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, predict which of the following substances are not likely to be soluble in water. Indicate which specific rule(s) led to your conclusion...
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, predict which of the following substances are likely to be appreciably soluble in water. Indicate which specific rule(s) led to your co...
See AnswerQ: Write the name of each of the following ionic substances, using
Write the name of each of the following ionic substances, using the system that includes a Roman numeral to specify the charge of the cation. a. SnCl4 b. Fe2S3 c. PbO2 d. Cr2S3 e. CuO f. Cu2O
See AnswerQ: Write the name of each of the following ionic substances, using
Write the name of each of the following ionic substances, using the system that includes a Roman numeral to specify the charge of the cation. a. FeI3 b. MnCl2 c. HgO d. Cu2S e. CoO f. SnBr4
See AnswerQ: The “Chemistry in Focus” segment Sugar of Lead discusses Pb
The “Chemistry in Focus” segment Sugar of Lead discusses Pb(C2H3O2)2, which originally was known as sugar of lead. a. Why was it called sugar of lead? b. What is the systematic name for Pb(C2H3O2)2?...
See AnswerQ: Give the name of each of the following simple binary ionic compounds
Give the name of each of the following simple binary ionic compounds. a. LiI b. MgF2 c. SrO d. AlBr3 e. CaS f. Na2O
See AnswerQ: These days many products are available to whiten teeth at home.
These days many products are available to whiten teeth at home. Many of these products contain a peroxide that bleaches stains from the teeth. What evidence is there that the bleaching process is a ch...
See AnswerQ: Phosphorus trichloride is used in the manufacture of certain pesticides and may
Phosphorus trichloride is used in the manufacture of certain pesticides and may be synthesized by direct combination of its constituent elements. Write the unbalanced chemical equation for this proces...
See AnswerQ: Pure silicon, which is needed in the manufacturing of electronic components
Pure silicon, which is needed in the manufacturing of electronic components, may be prepared by heating silicon dioxide (sand) with carbon at high temperatures, releasing carbon monoxide gas. Write th...
See AnswerQ: Nitrous oxide gas (systematic name: dinitrogen monoxide) is used
Nitrous oxide gas (systematic name: dinitrogen monoxide) is used by some dental practitioners as an anesthetic. Nitrous oxide (and water vapor as by-product) can be produced in small quantities in the...
See AnswerQ: Solid zinc is added to an aqueous solution containing dissolved hydrogen chloride
Solid zinc is added to an aqueous solution containing dissolved hydrogen chloride to produce gaseous hydrogen that bubbles out of the solution and zinc chloride that remains dissolved in the water. Wr...
See AnswerQ: Acetylene gas (C2H2) is often used by plumbers, welders
Acetylene gas (C2H2) is often used by plumbers, welders, and glass blowers because it burns in oxygen with an intensely hot flame. The products of the combustion of acetylene are carbon dioxide and wa...
See AnswerQ: The burning of high-sulfur fuels has been shown to cause
The burning of high-sulfur fuels has been shown to cause the phenomenon of “acid rain.” When a high-sulfur fuel is burned, the sulfur is converted to sulfur dioxide (SO2) and sulfur trioxide (SO3). Wh...
See AnswerQ: The Group 2 metals (Ba, Ca, Sr) can
The Group 2 metals (Ba, Ca, Sr) can be produced in the elemental state by the reaction of their oxides with aluminum metal at high temperatures, also producing solid aluminum oxide as a by-product. Wr...
See AnswerQ: There are fears that the protective ozone layer around the earth is
There are fears that the protective ozone layer around the earth is being depleted. Ozone, O3, is produced by the interaction of ordinary oxygen gas in the atmosphere with ultraviolet light and lightn...
See AnswerQ: Carbon tetrachloride was widely used for many years as a solvent until
Carbon tetrachloride was widely used for many years as a solvent until its harmful properties became well established. Carbon tetrachloride may be prepared by the reaction of natural gas (methane, CH4...
See AnswerQ: In each of the following, identify which names are incorrect for
In each of the following, identify which names are incorrect for the given formulas, and give the correct name. a. CaH2, calcium hydride b. PbCl2, lead(IV) chloride c. CrI3, chromium(III) iodide d...
See AnswerQ: Although these days many people have “self-cleaning” ovens
Although these days many people have “self-cleaning” ovens, if your oven gets really dirty you may have to resort to one of the spray-on oven cleaner preparations sold in supermarkets. What evidence i...
See AnswerQ: When elemental phosphorus, P4, burns in oxygen gas, it
When elemental phosphorus, P4, burns in oxygen gas, it produces an intensely bright light, a great deal of heat, and massive clouds of white solid phosphorus(V) oxide (P2O5) product. Given these prope...
See AnswerQ: Calcium oxide is sometimes very challenging to store in the chemistry laboratory
Calcium oxide is sometimes very challenging to store in the chemistry laboratory. This compound reacts with moisture in the air and is converted to calcium hydroxide. If a bottle of calcium oxide is l...
See AnswerQ: Although they were formerly called the inert gases, the heavier elements
Although they were formerly called the inert gases, the heavier elements of Group 8 do form relatively stable compounds. For example, at high temperatures in the presence of an appropriate catalyst, x...
See AnswerQ: The element tin often occurs in nature as the oxide, SnO2
The element tin often occurs in nature as the oxide, SnO2. To produce pure tin metal from this sort of tin ore, the ore usually is heated with coal (carbon). This produces pure molten tin, with the ca...
See AnswerQ: Nitric acid, HNO3, can be produced by reacting high-
Nitric acid, HNO3, can be produced by reacting high-pressure ammonia gas with oxygen gas at around 750 °C in the presence of a platinum catalyst. Water is a by-product of the reaction. Write the unbal...
See AnswerQ: When balancing chemical equations, beginning students are often tempted to change
When balancing chemical equations, beginning students are often tempted to change the numbers within a formula (the subscripts) to balance the equation. Why is this never permitted? What effect does c...
See AnswerQ: The “Chemistry in Focus” segment The Beetle That Shoots Straight
The “Chemistry in Focus” segment The Beetle That Shoots Straight discusses the bombardier beetle and the chemical reaction of the decomposition of hydrogen peroxide. H2O2 (aq)...
See AnswerQ: Balance the equation for the reaction of potassium with water.
Balance the equation for the reaction of potassium with water. K(s) + H2O(l) H2(g) + KOH(aq)
See AnswerQ: Although this is no longer generally recommended, in the past,
Although this is no longer generally recommended, in the past, small cuts and abrasions on the skin were frequently cleaned using hydrogen peroxide solution. What evidence is there that treating a wou...
See AnswerQ: In each of the following, identify which names are incorrect for
In each of the following, identify which names are incorrect for the given formulas, and give the correct name. a. CuCl2, copper(I) chloride b. Ag2O, silver oxide c. Li2O, lithium oxide d. CaS, ca...
See AnswerQ: Acetylene gas, C2H2, is used in welding because it generates
Acetylene gas, C2H2, is used in welding because it generates an extremely hot flame when it is combusted with oxygen. The heat generated is sufficient to melt the metals being welded together. Carbon...
See AnswerQ: When balancing a chemical equation, which of the following statements is
When balancing a chemical equation, which of the following statements is false? a. Subscripts in the reactants must be conserved in the products. b. Coefficients are used to balance the atoms on bot...
See AnswerQ: Crude gunpowders often contain a mixture of potassium nitrate and charcoal (
Crude gunpowders often contain a mixture of potassium nitrate and charcoal (carbon). When such a mixture is heated until reaction occurs, a solid residue of potassium carbonate is produced. The explos...
See AnswerQ: The following demonstration takes place in a two-step process:
The following demonstration takes place in a two-step process: First, solid calcium carbide (CaC2) reacts with liquid water to produce acetylene gas (C2H2) and aqueous calcium hydroxide. Second, the a...
See AnswerQ: Methanol (methyl alcohol), CH3OH, is a very important industrial
Methanol (methyl alcohol), CH3OH, is a very important industrial chemical. Formerly, methanol was prepared by heating wood to high temperatures in the absence of air. The complex compounds present in...
See AnswerQ: You have probably had the unpleasant experience of discovering that a flashlight
You have probably had the unpleasant experience of discovering that a flashlight battery has gotten old and begun to leak. Is there evidence that this change is due to a chemical reaction?
See AnswerQ: The Hall process is an important method by which pure aluminum is
The Hall process is an important method by which pure aluminum is prepared from its oxide (alumina, Al2O3) by indirect reaction with graphite (carbon). Balance the following equation, which is a simpl...
See AnswerQ: Iron oxide ores, commonly a mixture of FeO and Fe2O3,
Iron oxide ores, commonly a mixture of FeO and Fe2O3, are given the general formula Fe3O4. They yield elemental iron when heated to a very high temperature with either carbon monoxide or elemental hyd...
See AnswerQ: When steel wool (iron) is heated in pure oxygen gas
When steel wool (iron) is heated in pure oxygen gas, the steel wool bursts into flame and a fine powder consisting of a mixture of iron oxides (FeO and Fe2O3) forms. Write separate unbalanced equation...
See AnswerQ: One method of producing hydrogen peroxide is to add barium peroxide to
One method of producing hydrogen peroxide is to add barium peroxide to water. A precipitate of barium oxide forms, which may then be filtered off to leave a solution of hydrogen peroxide. Write the ba...
See AnswerQ: A common experiment to determine the relative reactivity of metallic elements is
A common experiment to determine the relative reactivity of metallic elements is to place a pure sample of one metal into an aqueous solution of a compound of another metallic element. If the pure m...
See AnswerQ: When elemental boron, B, is burned in oxygen gas,
When elemental boron, B, is burned in oxygen gas, the product is diboron trioxide. If the diboron trioxide is then reacted with a measured quantity of water, it reacts with the water to form what is c...
See AnswerQ: A common experiment in introductory chemistry courses involves heating a weighed mixture
A common experiment in introductory chemistry courses involves heating a weighed mixture of potassium chlorate, KClO3, and potassium chloride. Potassium chlorate decomposes when heated, producing pota...
See AnswerQ: A common demonstration in chemistry courses involves adding a tiny speck of
A common demonstration in chemistry courses involves adding a tiny speck of manganese(IV) oxide to a concentrated hydrogen peroxide, H2O2, solution. Hydrogen peroxide is unstable, and it decomposes qu...
See AnswerQ: Write a balanced chemical equation for the complete combustion of pentene,
Write a balanced chemical equation for the complete combustion of pentene, C7H14. In combustion, pentene reacts with oxygen to produce carbon dioxide and water.
See AnswerQ: Glass is a mixture of several compounds, but a major constituent
Glass is a mixture of several compounds, but a major constituent of most glass is calcium silicate, CaSiO3. Glass can be etched by treatment with hydrogen fluoride: HF attacks the calcium silicate of...
See AnswerQ: If you’ve ever left bread in a toaster too long, you
If you’ve ever left bread in a toaster too long, you know that the bread eventually burns and turns black. What evidence is there that this represents a chemical process?
See AnswerQ: Balance the following chemical equation. LiAlH4(s) +
Balance the following chemical equation. LiAlH4(s) + AlCl3(s) AlH3(s) + LiCl(s)
See AnswerQ: If you had a “sour stomach,” you might try an
If you had a “sour stomach,” you might try an over-the-counter antacid tablet to relieve the problem. Can you think of evidence that the action of such an antacid is a chemical reaction?
See AnswerQ: When iron wire is heated in the presence of sulfur, the
When iron wire is heated in the presence of sulfur, the iron soon begins to glow, and a chunky, blue-black mass of iron(II) sulfide is formed. Write the unbalanced chemical equation for this reaction....
See AnswerQ: When finely divided solid sodium is dropped into a flask containing chlorine
When finely divided solid sodium is dropped into a flask containing chlorine gas, an explosion occurs and a fine powder of sodium chloride is deposited on the walls of the flask. Write the unbalanced...
See AnswerQ: A common lecture demonstration called “elephant’s toothpaste” demonstrates the reaction
A common lecture demonstration called “elephant’s toothpaste” demonstrates the reaction of hydrogen peroxide producing water and oxygen gas. Write the unbalanced chemical equation for this process.
See AnswerQ: When a strip of magnesium metal is heated in oxygen, it
When a strip of magnesium metal is heated in oxygen, it bursts into an intensely white flame and produces a finely powdered dust of magnesium oxide. Write the unbalanced chemical equation for this pro...
See AnswerQ: Which of the following statements is false for the reaction of hydrogen
Which of the following statements is false for the reaction of hydrogen gas with oxygen gas to produce water? (a, b, and c represent coefficients) a H2(g) + b O2(g) c H2O(g) a. T...
See AnswerQ: When solid red phosphorus, P4, is burned in air,
When solid red phosphorus, P4, is burned in air, the phosphorus combines with oxygen, producing a choking cloud of tetraphosphorus decoxide. Write the unbalanced chemical equation for this reaction.
See AnswerQ: What are the substances to the left of the arrow in a
What are the substances to the left of the arrow in a chemical equation called? To the right of the arrow? What does the arrow itself mean?
See AnswerQ: When copper(II) oxide is boiled in an aqueous solution
When copper(II) oxide is boiled in an aqueous solution of sulfuric acid, a strikingly blue solution of copper(II) sulfate forms along with additional water. Write the unbalanced chemical equation for...
See AnswerQ: When lead(II) sulfide is heated to high temperatures in
When lead(II) sulfide is heated to high temperatures in a stream of pure oxygen gas, solid lead(II) oxide forms with the release of gaseous sulfur dioxide. Write the unbalanced chemical equation for t...
See AnswerQ: Which of the following statements about chemical reactions is false?
Which of the following statements about chemical reactions is false? a. When balancing a chemical equation, all subscripts must be conserved. b. When one coefficient is doubled, the rest of the coef...
See AnswerQ: Balance the following chemical equation: CuSO4(aq) +
Balance the following chemical equation: CuSO4(aq) + KI(s) CuI(s) + I2(s) + K2SO4(aq)
See AnswerQ: Using different shapes to distinguish between different elements, draw a balanced
Using different shapes to distinguish between different elements, draw a balanced equation for the following reaction at the microscopic level. NH3(g) + O2(g) NO(g) + H2O(g)
See AnswerQ: Balance the following chemical equations. MnO2(s) +
Balance the following chemical equations. MnO2(s) + CO(g) Mn2O3(aq) + CO2(g) Al(s) + H2SO4(aq) Al2(SO4)3(aq) + H2(g) C4H10(g) + O2(g)...
See AnswerQ: If a sample of pure hydrogen gas is ignited very carefully,
If a sample of pure hydrogen gas is ignited very carefully, the hydrogen burns gently, combining with the oxygen gas of the air to form water vapor. Write the unbalanced chemical equation for this rea...
See AnswerQ: For the unbalanced chemical equation HCl(g) + O2(
For the unbalanced chemical equation HCl(g) + O2(g) H2O(g) + Cl2(g) a. list the reactant(s). b. list the product(s).
See AnswerQ: In a chemical reaction, the total number of atoms present after
In a chemical reaction, the total number of atoms present after the reaction is complete is (larger than/smaller than/the same as) the total number of atoms present before the reaction began.
See AnswerQ: Using the general solubility rules given in Table 7.1,
Using the general solubility rules given in Table 7.1, which of the following ions will form a precipitate with SO42-? a. Ba2+ b. Na+ c. NH4+ d. At least two of the above ions will form a precipit...
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, for each of the following compounds, explain why the compound would be expected to be appreciably soluble in water. Indicate which of t...
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, for each of the following compounds, explain why the compound would not be expected to be appreciably soluble in water. Indicate which...
See AnswerQ: What is a “driving force”? What are some of the
What is a “driving force”? What are some of the driving forces discussed in this section that tend to make reactions likely to occur? Can you think of any other possible driving forces?
See AnswerQ: A solution of zinc nitrate is mixed with a solution of potassium
A solution of zinc nitrate is mixed with a solution of potassium hydroxide. A precipitate forms. Complete and balance the equation for this reaction, including the phases of each reactant and product....
See AnswerQ: Which of the following most accurately describes a spectator ion?
Which of the following most accurately describes a spectator ion? a. An ion that is used up in a chemical reaction; it is limiting. b. An ion that participates in a chemical reaction but is always p...
See AnswerQ: Write the balanced molecular, complete ionic, and net ionic equations
Write the balanced molecular, complete ionic, and net ionic equations for the reaction between nickel(II) chloride and sodium sulfide.
See AnswerQ: Many chromate (CrO42-) salts are insoluble, and most have
Many chromate (CrO42-) salts are insoluble, and most have brilliant colors that have led to their being used as pigments. Write balanced net ionic equations for the reactions of Cu2+, Co3+, Ba2+, and...
See AnswerQ: Liquid hydrazine, N2H4, has been used as a fuel for
Liquid hydrazine, N2H4, has been used as a fuel for rockets. When the rocket is to be launched, a catalyst causes the liquid hydrazine to decompose quickly into elemental nitrogen and hydrogen gases....
See AnswerQ: The procedures and principles of qualitative analysis are covered in many introductory
The procedures and principles of qualitative analysis are covered in many introductory chemistry laboratory courses. In qualitative analysis, students learn to analyze mixtures of the common positive...
See AnswerQ: Many plants are poisonous because their stems and leaves contain oxalic acid
Many plants are poisonous because their stems and leaves contain oxalic acid, H2C2O4, or sodium oxalate, Na2C2O4; when ingested, these substances cause swelling of the respiratory tract and suffocatio...
See AnswerQ: A reaction in aqueous solution that results in the formation of a
A reaction in aqueous solution that results in the formation of a solid is called a reaction.
See AnswerQ: Another step in the qualitative analysis of cations (see Exercise 28
Another step in the qualitative analysis of cations (see Exercise 28) involves precipitating some of the metal ions as the insoluble sulfides (followed by subsequent treatment of the mixed sulfide pre...
See AnswerQ: What is meant by a strong acid? Are the strong acids
What is meant by a strong acid? Are the strong acids also strong electrolytes? Explain.
See AnswerQ: What is meant by a strong base? Are the strong bases
What is meant by a strong base? Are the strong bases also strong electrolytes? Explain.
See AnswerQ: The same net ionic process takes place when any strong acid reacts
The same net ionic process takes place when any strong acid reacts with any strong base. Write the equation for that process.
See AnswerQ: Write the formulas and names of three common strong acids and strong
Write the formulas and names of three common strong acids and strong bases.
See AnswerQ: If 1000 NaOH units were dissolved in a sample of water,
If 1000 NaOH units were dissolved in a sample of water, the NaOH would produce Na1 ions and OH2 ions.
See AnswerQ: What is a salt? Give two balanced chemical equations showing how
What is a salt? Give two balanced chemical equations showing how a salt is formed when an acid reacts with a base.
See AnswerQ: If electricity of sufficient voltage is passed into a solution of potassium
If electricity of sufficient voltage is passed into a solution of potassium iodide in water, a reaction takes place in which elemental hydrogen gas and elemental iodine are produced, leaving a solutio...
See AnswerQ: Write balanced equations showing how three of the common strong acids ionize
Write balanced equations showing how three of the common strong acids ionize to produce hydrogen ion.
See AnswerQ: Along with the three strong acids emphasized in the chapter (HCl
Along with the three strong acids emphasized in the chapter (HCl, HNO3, and H2SO4), hydrobromic acid, HBr, and perchloric acid, HClO4, are also strong acids. Write equations for the dissociation of ea...
See AnswerQ: When writing the chemical equation for a reaction, how do you
When writing the chemical equation for a reaction, how do you indicate that a given reactant is dissolved in water? How do you indicate that a precipitate has formed as a result of the reaction?
See AnswerQ: What is an oxidation–reduction reaction? What is transferred during
What is an oxidation–reduction reaction? What is transferred during such a reaction?
See AnswerQ: Give an example of a simple chemical reaction that involves the transfer
Give an example of a simple chemical reaction that involves the transfer of electrons from a metallic element to a nonmetallic element.
See AnswerQ: The thermite reaction produces so much energy (heat) that the
The thermite reaction produces so much energy (heat) that the iron is initially formed as a liquid. 2Al(s) + Fe2O3(s) 2Fe(s) + Al2O3(s) Describe the transfer of electrons for both...
See AnswerQ: If atoms of the metal calcium were to react with molecules of
If atoms of the metal calcium were to react with molecules of the nonmetal fluorine, F2, how many electrons would each calcium atom lose? How many electrons would each fluorine atom gain? How many cal...
See AnswerQ: If oxygen molecules, O2, were to react with magnesium atoms
If oxygen molecules, O2, were to react with magnesium atoms, how many electrons would each magnesium atom lose? How many electrons would each oxygen atom gain? How many magnesium atoms would be needed...
See AnswerQ: For the reaction Mg(s) + Cl2(g)
For the reaction Mg(s) + Cl2(g) MgCl2(s), illustrate how electrons are gained and lost during the reaction.
See AnswerQ: For the reaction 2Na(s) + O2(g)
For the reaction 2Na(s) + O2(g) Na2O2(s), show how electrons are gained and lost by the atoms.
See AnswerQ: Silver oxide may be decomposed by strong heating into silver metal and
Silver oxide may be decomposed by strong heating into silver metal and oxygen gas. Write the unbalanced chemical equation for this process.
See AnswerQ: How do we define a combustion reaction? In addition to the
How do we define a combustion reaction? In addition to the chemical products, what other products do combustion reactions produce? Give two examples of balanced chemical equations for combustion react...
See AnswerQ: Reactions involving the combustion of fuel substances make up a subclass of
Reactions involving the combustion of fuel substances make up a subclass of reactions.
See AnswerQ: When the ionic solute K3PO4 is dissolved in water, what can
When the ionic solute K3PO4 is dissolved in water, what can you say about the number of potassium ions (K+) present in the solution compared with the number of phosphate ions (PO43-) in the solution?...
See AnswerQ: What is meant by a strong electrolyte? Give two examples of
What is meant by a strong electrolyte? Give two examples of substances that behave in solution as strong electrolytes.
See AnswerQ: Name each of the following binary compounds, using the periodic table
Name each of the following binary compounds, using the periodic table to determine whether the compound is likely to be ionic (containing a metal and a nonmetal) or nonionic (containing only nonmetals...
See AnswerQ: What is a binary chemical compound? What are the two major
What is a binary chemical compound? What are the two major types of binary chemical compounds? Give three examples of each type of binary compound.
See AnswerQ: Many over-the-counter antacid tablets are now formulated using
Many over-the-counter antacid tablets are now formulated using calcium carbonate as the active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for...
See AnswerQ: Name each of the following binary compounds, using the periodic table
Name each of the following binary compounds, using the periodic table to determine whether the compound is likely to be ionic (containing a metal and a nonmetal) or nonionic (containing only nonmetals...
See AnswerQ: Name each of the following binary compounds, using the periodic table
Name each of the following binary compounds, using the periodic table to determine whether the compound is likely to be ionic (containing a metal or a nonmetal) or nonionic (containing only nonmetals)...
See AnswerQ: What is a polyatomic ion? Give examples of five common polyatomic
What is a polyatomic ion? Give examples of five common polyatomic ions.
See AnswerQ: A(n) is a polyatomic ion containing at least one
A(n) is a polyatomic ion containing at least one oxygen atom and one or more atoms of at least one other element.
See AnswerQ: For the oxyanions of sulfur, the ending -ite is used
For the oxyanions of sulfur, the ending -ite is used for SO32- to indicate that it contains than does SO42-.
See AnswerQ: In naming oxyanions, when there are more than two members in
In naming oxyanions, when there are more than two members in the series for a given element, what prefixes are used to indicate the oxyanions in the series with the fewest and the most oxygen atoms?
See AnswerQ: Complete the following list by filling in the missing names or formulas
Complete the following list by filling in the missing names or formulas of the oxyanions of chlorine.
See AnswerQ: A series of oxyanions of iodine, comparable to the series for
A series of oxyanions of iodine, comparable to the series for chlorine discussed in the text, also exists. Write the formulas and names for the oxyanions of iodine.
See AnswerQ: Write the formula for each of the following phosphorus- containing ions
Write the formula for each of the following phosphorus- containing ions, including the overall charge of the ion. a. phosphide b. phosphate c. phosphite d. hydrogen phosphate
See AnswerQ: Write the formula for each of the following carbon-containing ions
Write the formula for each of the following carbon-containing ions, including the overall charge of the ion. a. cyanide b. carbonate c. hydrogen carbonate d. acetate
See AnswerQ: Write the formulas for the following compounds (refer to your answers
Write the formulas for the following compounds (refer to your answers to Problem 30). a. sodium cyanide b. calcium carbonate c. potassium hydrogen carbonate d. magnesium acetate
See AnswerQ: Carbon occurs in several common polyatomic anions. List the formulas of
Carbon occurs in several common polyatomic anions. List the formulas of as many such anions as you can, along with the names of the anions.
See AnswerQ: Give the name of each of the following polyatomic ions.
Give the name of each of the following polyatomic ions. a. HCO3- b. C2H3O2- c. CN- d. OH- e. NO2- f. HPO42-
See AnswerQ: Give the name of each of the following polyatomic ions.
Give the name of each of the following polyatomic ions. a. NH4+ b. H2PO4- c. SO42- d. HSO3- e. ClO4- f. IO3-
See AnswerQ: Name each of the following compounds, which contain polyatomic ions.
Name each of the following compounds, which contain polyatomic ions. a. NH4NO3 b. Ca(HCO3)2 c. MgSO4 d. Na2HPO4 e. KClO4 f. Ba(C2H3O2)2
See AnswerQ: Name each of the following compounds, which contain polyatomic ions.
Name each of the following compounds, which contain polyatomic ions. a. NaMnO4 b. AlPO4 c. CrCO3 d. Ca(ClO)2 e. BaCO3 f. CaCrO4
See AnswerQ: Many acids contain the element in addition to hydrogen.
Many acids contain the element in addition to hydrogen.
See AnswerQ: Name each of the following acids. a. HCl
Name each of the following acids. a. HCl b. H2SO4 c. HNO3 d. HI e. HNO2 f. HClO3 g. HBr h. HF i. HC2H3O2
See AnswerQ: In naming ionic compounds, we always name the second.
In naming ionic compounds, we always name the second.
See AnswerQ: Name each of the following acids. a. HOCl
Name each of the following acids. a. HOCl b. H2SO3 c. HBrO3 d. HOI e. HBrO4 f. H2S g. H2Se h. H3PO3
See AnswerQ: Write the formula for each of the following simple binary ionic compounds
Write the formula for each of the following simple binary ionic compounds. a. cobalt(II) chloride b. cobaltic chloride c. sodium phosphide d. iron(II) oxide e. calcium hydride f. manganese(IV) o...
See AnswerQ: Write the formula for each of the following simple binary ionic compounds
Write the formula for each of the following simple binary ionic compounds. a. magnesium fluoride b. ferric iodide c. mercuric sulfide d. barium nitride e. plumbous chloride f. stannic fluoride...
See AnswerQ: Write the formula for each of the following binary compounds of nonmetallic
Write the formula for each of the following binary compounds of nonmetallic elements. a. carbon disulfide b. water c. dinitrogen trioxide d. dichlorine heptoxide e. carbon dioxide f. ammonia g....
See AnswerQ: Write the formula for each of the following binary compounds of nonmetallic
Write the formula for each of the following binary compounds of nonmetallic elements. a. diphosphorus monoxide b. sulfur dioxide c. diphosphorus pentoxide d. carbon tetrachloride e. nitrogen trib...
See AnswerQ: Write the formula for each of the following compounds that contain polyatomic
Write the formula for each of the following compounds that contain polyatomic ions. Be sure to enclose the polyatomic ion in parentheses if more than one such ion is needed to balance the oppositely c...
See AnswerQ: Write the formula for each of the following compounds that contain polyatomic
Write the formula for each of the following compounds that contain polyatomic ions. Be sure to enclose the polyatomic ion in parentheses if more than one such ion is needed to balance the oppositely c...
See AnswerQ: Write the formula for each of the following acids. a
Write the formula for each of the following acids. a. hydrosulfuric acid b. perbromic acid c. acetic acid d. hydrobromic acid e. chlorous acid f. hydroselenic acid g. sulfurous acid h. perchlo...
See AnswerQ: Write the formula for each of the following acids. a
Write the formula for each of the following acids. a. hydrocyanic acid b. nitric acid c. sulfuric acid d. phosphoric acid e. hypochlorous acid f. hydrobromic acid g. bromous acid h. hydrofluo...
See AnswerQ: Write the formula for each of the following substances. a
Write the formula for each of the following substances. a. sodium peroxide b. calcium chlorate c. rubidium hydroxide d. zinc nitrate e. ammonium dichromate f. hydrosulfuric acid g. calcium brom...
See AnswerQ: In a simple binary ionic compound, which ion (cation/
In a simple binary ionic compound, which ion (cation/anion) has the same name as its parent element?
See AnswerQ: Write the formula for each of the following substances. a
Write the formula for each of the following substances. a. calcium hydrogen sulfate b. zinc phosphate c. iron(III) perchlorate d. cobaltic hydroxide e. potassium chromate f. aluminum dihydrogen...
See AnswerQ: Iron forms both 2+ and 3+ cations. Write formulas
Iron forms both 2+ and 3+ cations. Write formulas for the oxide, sulfide, and chloride compound of each iron cation, and give the name of each compound in both the nomenclature method that uses Roman...
See AnswerQ: Before an electrocardiogram (ECG) is recorded for a cardiac patient
Before an electrocardiogram (ECG) is recorded for a cardiac patient, the ECG leads are usually coated with a moist paste containing sodium chloride. What property of an ionic substance such as NaCl is...
See AnswerQ: Nitrogen and oxygen form numerous binary compounds, including NO, NO2
Nitrogen and oxygen form numerous binary compounds, including NO, NO2, N2O4, N2O5, and N2O. Give the name of each of these oxides of nitrogen.
See AnswerQ: On some periodic tables, hydrogen is listed both as a member
On some periodic tables, hydrogen is listed both as a member of Group 1 and as a member of Group 7. Write an equation showing the formation of H+ ion and an equation showing the formation of H- ion.
See AnswerQ: Examine the following table of formulas and names. Which of the
Examine the following table of formulas and names. Which of the compounds is/are named correctly? Formula……………………………………..Name a. Al2S3………………………………………dialuminum trisulfate b. CuNO3……………………………………….…cop...
See AnswerQ: Complete the following list by filling in the missing oxyanion or oxyacid
Complete the following list by filling in the missing oxyanion or oxyacid for each pair.
See AnswerQ: Name the following compounds. a. Ca(C2H3O2)
Name the following compounds. a. Ca(C2H3O2) 2 b. PCl3 c. Cu(MnO4) 2 d. Fe2 (CO3) 3 e. LiHCO3 f. Cr2S3 g. Ca(CN) 2
See AnswerQ: Name the following compounds. a. AuBr3 b.
Name the following compounds. a. AuBr3 b. Co(CN)3 c. MgHPO4 d. B2H6 e. NH3 f. Ag2SO4 g. Be(OH)2
See AnswerQ: Name the following compounds. a. HClO3 b.
Name the following compounds. a. HClO3 b. CoCl3 c. B2O3 d. H2O e. HC2H3O2 f. Fe(NO3)3 g. CuSO4
See AnswerQ: Although we write the formula of sodium chloride as NaCl, we
Although we write the formula of sodium chloride as NaCl, we realize that NaCl is an ionic compound and contains no molecules. Explain.
See AnswerQ: A compound has the general formula X2O, with X representing an
A compound has the general formula X2O, with X representing an unknown element or ion and O representing oxygen. Which of the following could not be a name for this compound? a. sodium oxide b. iron...
See AnswerQ: Most metallic elements form oxides, and often the oxide is the
Most metallic elements form oxides, and often the oxide is the most common compound of the element that is found in the earth’s crust. Write the formulas for the oxides of the following metallic eleme...
See AnswerQ: Consider a hypothetical simple ion M2+. Determine the formula of the
Consider a hypothetical simple ion M2+. Determine the formula of the compound this ion would form with each of the following anions. a. acetate b. permanganate c. oxide d. hydrogen phosphate e. h...
See AnswerQ: Consider a hypothetical element M, which is capable of forming stable
Consider a hypothetical element M, which is capable of forming stable simple cations that have charges of 1+, 2+, and 3+, respectively. Write the formulas of the compounds formed by the various M cati...
See AnswerQ: If aqueous solutions of potassium chromate and barium chloride are mixed,
If aqueous solutions of potassium chromate and barium chloride are mixed, a bright yellow solid (barium chromate) forms and settles out of the mixture, leaving potassium chloride in solution. Write a...
See AnswerQ: When hydrogen sulfide, H2S, gas is bubbled through a solution
When hydrogen sulfide, H2S, gas is bubbled through a solution of lead(II) nitrate, Pb(NO3)2, a black precipitate of lead(II) sulfide, PbS, forms, and nitric acid, HNO3, is produced. Write the unbalanc...
See AnswerQ: If an electric current is passed through aqueous solutions of sodium chloride
If an electric current is passed through aqueous solutions of sodium chloride, sodium bromide, and sodium iodide, the elemental halogens are produced at one electrode in each case, with hydrogen gas b...
See AnswerQ: The noble metals gold, silver, and platinum are often used
The noble metals gold, silver, and platinum are often used in fashioning jewelry because they are relatively .
See AnswerQ: The elements of Group 7 (fluorine, chlorine, bromine,
The elements of Group 7 (fluorine, chlorine, bromine, and iodine) consist of molecules containing atom(s) .
See AnswerQ: For a metallic element that forms two stable cations, the ending
For a metallic element that forms two stable cations, the ending is used to indicate the cation of lower charge and the ending...
See AnswerQ: Under what physical state at room temperature do each of the halogen
Under what physical state at room temperature do each of the halogen elements exist?
See AnswerQ: When an atom gains two electrons, the ion formed has a
When an atom gains two electrons, the ion formed has a charge of .
See AnswerQ: An ion with one less electron than it has protons has a
An ion with one less electron than it has protons has a charge.
See AnswerQ: An atom that has lost three electrons will have a charge of
An atom that has lost three electrons will have a charge of .
See AnswerQ: An ion with two more electrons than it has protons has a
An ion with two more electrons than it has protons has a charge.
See AnswerQ: For each of the negative ions listed in column 1, use
For each of the negative ions listed in column 1, use the periodic table to find in column 2 the total number of electrons the ion contains. A given answer may be used more than once. Column 1…………………...
See AnswerQ: For each of the following processes that show the formation of ions
For each of the following processes that show the formation of ions, complete the process by indicating the number of electrons that must be gained or lost to form the ion. Indicate the total number o...
See AnswerQ: What does “balancing” an equation accomplish?
What does “balancing” an equation accomplish?
See AnswerQ: Balance the following chemical equations. Fe(s) +
Balance the following chemical equations. Fe(s) + O2(g) Fe2O3(s) PbO2(s) PbO(s) + O2(g) H2O2(l) O2(g) + H2O(l)
See AnswerQ: Give the name of each of the following simple binary ionic compounds
Give the name of each of the following simple binary ionic compounds. a. BeO b. MgI2 c. Na2S d. Al2O3 e. HCl f. LiF g. Ag2S h. CaH2
See AnswerQ: We indicate the charge of a metallic element that forms more than
We indicate the charge of a metallic element that forms more than one cation by adding a(n) after the name of the cation.
See AnswerQ: In which of the following pairs is the name incorrect? Give
In which of the following pairs is the name incorrect? Give the correct name for the formulas indicated. a. Ag2O, disilver monoxide b. N2O, dinitrogen monoxide c. Fe2O3, iron(II) oxide d. PbO2, pl...
See AnswerQ: Why are the physical states of the reactants and products often indicated
Why are the physical states of the reactants and products often indicated when writing a chemical equation?
See AnswerQ: Write the name of each of the following ionic substances, using
Write the name of each of the following ionic substances, using -ous or -ic endings to indicate the charge of the cation. a. SnCl2 b. FeO c. SnO2 d. PbS e. Co2S3 f. CrCl2
See AnswerQ: Name each of the following binary compounds. a. XeF6
Name each of the following binary compounds. a. XeF6 b. OF2 c. AsI3 d. N2O4 e. Cl2O f. SF6
See AnswerQ: Name each of the following compounds. a. Fe(
Name each of the following compounds. a. Fe(C2H3O2)3 b. BrF c. K2O2 d. SiBr4 e. Cu(MnO4)2 f. CaCrO4
See AnswerQ: Which oxyanion of nitrogen contains a larger number of oxygen atoms,
Which oxyanion of nitrogen contains a larger number of oxygen atoms, the nitrate ion or the nitrite ion?
See AnswerQ: Examine the following table of formulas and names. Which of the
Examine the following table of formulas and names. Which of the compounds is/are named incorrectly? Formula……………………………………….Name a. Al2S3……………………dialuminum trisulfide b. KClO3……………………….potassium chlor...
See AnswerQ: Write the formula for each of the following chromium-containing ions
Write the formula for each of the following chromium-containing ions, including the overall charge of the ion. a. chromous b. chromate c. chromic d. dichromate
See AnswerQ: Give the name of each of the following polyatomic anions.
Give the name of each of the following polyatomic anions. a. CO32- b. ClO3- c. SO42- d. PO43- e. ClO4- f. MnO4-
See AnswerQ: Name each of the following compounds, which contain polyatomic ions.
Name each of the following compounds, which contain polyatomic ions. a. LiH2PO4 b. Cu(CN)2 c. Pb(NO3)2 d. Na2HPO4 e. NaClO2 f. Co2(SO4)3
See AnswerQ: Give the name of each of the following simple binary ionic compounds
Give the name of each of the following simple binary ionic compounds. a. NaBr b. MgCl2 c. AlP d. SrBr2 e. AgI f. K2S
See AnswerQ: The notation “(l)” after a substance’s formula indicates it exists
The notation “(l)” after a substance’s formula indicates it exists in the state.
See AnswerQ: Write the formula for each of the following binary compounds of nonmetallic
Write the formula for each of the following binary compounds of nonmetallic elements. a. sulfur dioxide b. dinitrogen monoxide c. xenon tetrafluoride d. tetraphosphorus decoxide e. phosphorus pen...
See AnswerQ: Write the formula of each of the following ionic substances.
Write the formula of each of the following ionic substances. a. sodium dihydrogen phosphate b. lithium perchlorate c. copper(II) hydrogen carbonate d. potassium acetate e. barium peroxide f. ces...
See AnswerQ: Write the formula for each of the following compounds, which contain
Write the formula for each of the following compounds, which contain polyatomic ions. Be sure to enclose the polyatomic ion in parentheses if more than one such ion is needed to balance the oppositely...
See AnswerQ: Complete the following table to predict whether the given atom will gain
Complete the following table to predict whether the given atom will gain or lose electrons in forming the ion most likely to form when in ionic compounds.
See AnswerQ: What are the formulas of the compounds that correspond to the names
What are the formulas of the compounds that correspond to the names given in the following table?
See AnswerQ: What are the names of the compounds that correspond to the formulas
What are the names of the compounds that correspond to the formulas given in the following table?
See AnswerQ: Provide the name of the acid that corresponds to the formula given
Provide the name of the acid that corresponds to the formula given in the following table.
See AnswerQ: Which of the following statements is(are) correct?
Which of the following statements is(are) correct? a. The symbols for the elements magnesium, aluminum, and xenon are Mn, Al, and Xe, respectively. b. The elements P, As, and Bi are in the same fami...
See AnswerQ: Elemental boron is produced in one industrial process by heating diboron trioxide
Elemental boron is produced in one industrial process by heating diboron trioxide with magnesium metal, also producing magnesium oxide as a by-product. Write the unbalanced chemical equation for this...
See AnswerQ: Merchants usually sell small nuts, washers, and bolts by weight
Merchants usually sell small nuts, washers, and bolts by weight (like jelly beans!) rather than by individually counting the items. Suppose a particular type of washer weighs 0.110 g on the average. W...
See AnswerQ: Write the balanced chemical equation for the complete combustion of heptene,
Write the balanced chemical equation for the complete combustion of heptene, C7H14. In combustion, heptene reacts with oxygen to produce carbon dioxide and water. What is the mole ratio that would ena...
See AnswerQ: If you have equal mole samples of NO2 and F2, which
If you have equal mole samples of NO2 and F2, which of the following must be true? a. The number of molecules in each sample is the same. b. The number of atoms in each sample is the same. c. The m...
See AnswerQ: A strikingly beautiful copper compound with the common name “blue vitriol
A strikingly beautiful copper compound with the common name “blue vitriol” has the following elemental composition: 25.45% Cu, 12.84% S, 4.036% H, 57.67% O. Determine the empirical formula of the comp...
See AnswerQ: Calculate the number of grams of cobalt that contain the same number
Calculate the number of grams of cobalt that contain the same number of atoms as 2.24 g of iron.
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this book, calculate the mass in grams of each of the following samples. a. 0.341 mole of potassium nitride b. 2.62 mmol of neon (1 mm...
See AnswerQ: For each of the following unbalanced equations, calculate how many moles
For each of the following unbalanced equations, calculate how many moles of the second reactant would be required to react completely with 0.413 moles of the first reactant. a. Co(s) + F2(g)...
See AnswerQ: For each of the following unbalanced equations, calculate how many moles
For each of the following unbalanced equations, calculate how many moles of the second reactant would be required to react completely with 0.557 grams of the first reactant. a. Al(s) + Br2(l)...
See AnswerQ: When elemental carbon is burned in the open atmosphere, with plenty
When elemental carbon is burned in the open atmosphere, with plenty of oxygen gas present, the product is carbon dioxide. C(s) + O2(g) CO2(g) However, when the amount of oxygen present...
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this text, calculate how many moles of each element the following masses represent. a. 1.5 mg of chromium b. 2.0 * 10-3 g of strontium...
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this text, calculate the mass in grams of each of the following samples. a. 5.0 moles of potassium b. 0.000305 mole of mercury c. 2.3...
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this text, calculate the number of atoms present in each of the following samples. a. 2.89 g of gold b. 0.000259 mole of platinum c....
See AnswerQ: For each of the following balanced chemical equations, calculate how many
For each of the following balanced chemical equations, calculate how many moles of product(s) would be produced if 0.500 mole of the first reactant were to react completely. a. CO2(g) + 4H2(g)...
See AnswerQ: Calculate the molar mass for each of the following substances.
Calculate the molar mass for each of the following substances. a. ferrous sulfate b. mercuric iodide c. stannic oxide d. cobaltous chloride e. cupric nitrate
See AnswerQ: Calculate the molar mass for each of the following substances.
Calculate the molar mass for each of the following substances. a. adipic acid, C6H10O4 b. caffeine, C8H10N4O2 c. eicosane, C20H42 d. cyclohexanol, C6H11OH e. vinyl acetate, C4H6O2 f. dextrose, C...
See AnswerQ: Calculate the number of moles of the indicated substance present in each
Calculate the number of moles of the indicated substance present in each of the following samples. a. 21.2 g of ammonium sulfide b. 44.3 g of calcium nitrate c. 4.35 g of dichlorine monoxide d. 1....
See AnswerQ: Calculate the number of moles of the indicated substance present in each
Calculate the number of moles of the indicated substance present in each of the following samples. a. 1.28 g of iron(II) sulfate b. 5.14 mg of mercury(II) iodide c. 9.21 µg of tin(IV) oxide d. 1.26...
See AnswerQ: If you have equal-mole samples of each of the following
If you have equal-mole samples of each of the following compounds, which compound contains the greatest number of oxygen atoms? a. magnesium nitrate b. dinitrogen pentoxide c. iron(III) phosphate...
See AnswerQ: Calculate the mass in grams of each of the following samples.
Calculate the mass in grams of each of the following samples. a. 3.09 moles of ammonium carbonate b. 4.01 * 10-6 moles of sodium hydrogen carbonate c. 88.02 moles of carbon dioxide d. 1.29 mmol of...
See AnswerQ: Calculate the number of molecules present in each of the following samples
Calculate the number of molecules present in each of the following samples. a. 3.45 g of C6H12O6 b. 3.45 moles of C6H12O6 c. 25.0 g of ICl5 d. 1.00 g of B2H6 e. 1.05 mmol of Al(NO3)3
See AnswerQ: Calculate the number of moles of hydrogen atoms present in each of
Calculate the number of moles of hydrogen atoms present in each of the following samples. a. 2.71 g of ammonia b. 0.824 mole of water c. 6.25 mg of sulfuric acid d. 451 g of ammonium carbonate
See AnswerQ: Although we tend to make less use of mercury these days because
Although we tend to make less use of mercury these days because of the environmental problems created by its improper disposal, mercury is still an important metal because of its unusual property of e...
See AnswerQ: Calculate the percent by mass of the element mentioned first in the
Calculate the percent by mass of the element mentioned first in the formulas for each of the following compounds. a. sodium azide, NaN3 b. copper(II) sulfate, CuSO4 c. gold(III) chloride, AuCl3 d....
See AnswerQ: For each of the following unbalanced chemical equations, calculate how many
For each of the following unbalanced chemical equations, calculate how many moles of each product would be produced by the complete conversion of 0.125 mole of the reactant indicated in boldface. Stat...
See AnswerQ: Ammonium nitrate has been used as a high explosive because it is
Ammonium nitrate has been used as a high explosive because it is unstable and decomposes into several gaseous substances. The rapid expansion of the gaseous substances produces the explosive force. N...
See AnswerQ: A 1.2569-g sample of a new compound has
A 1.2569-g sample of a new compound has been analyzed and found to contain the following masses of elements: carbon, 0.7238 g; hydrogen, 0.07088 g; nitrogen, 0.1407 g; oxygen, 0.3214 g. Calculate the...
See AnswerQ: In the “Chemistry in Focus” segment Cars of the Future
In the “Chemistry in Focus” segment Cars of the Future, the claim is made that the combustion of gasoline for some cars causes about 1 lb of CO2 to be produced for each mile traveled. Estimate the gas...
See AnswerQ: When 2.004 g of calcium is heated in pure nitrogen
When 2.004 g of calcium is heated in pure nitrogen gas, the sample gains 0.4670 g of nitrogen. Calculate the empirical formula of the calcium nitride formed.
See AnswerQ: Explain how one determines which reactant in a process is the limiting
Explain how one determines which reactant in a process is the limiting reactant. Does this depend only on the masses of the reactant present? Give an example of how to determine the limiting reactant...
See AnswerQ: When 1.00 g of metallic chromium is heated with elemental
When 1.00 g of metallic chromium is heated with elemental chlorine gas, 3.045 g of a chromium chloride salt results. Calculate the empirical formula of the compound.
See AnswerQ: When barium metal is heated in chlorine gas, a binary compound
When barium metal is heated in chlorine gas, a binary compound forms that consists of 65.95% Ba and 34.05% Cl by mass. Calculate the empirical formula of the compound.
See AnswerQ: Determine the molar mass for the following compounds to four significant figures
Determine the molar mass for the following compounds to four significant figures.
See AnswerQ: Vitamin B12, cyanocobalamin, is essential for human nutrition. Its
Vitamin B12, cyanocobalamin, is essential for human nutrition. Its molecular formula is C63H88CoN14O14P. A lack of this vitamin in the diet can lead to anemia. Cyanocobalamin is the form of the vitami...
See AnswerQ: For each of the following unbalanced reactions, suppose exactly 5.
For each of the following unbalanced reactions, suppose exactly 5.00 moles of each reactant are taken. Determine which reactant is limiting, and also determine what mass of the excess reagent will rem...
See AnswerQ: For each of the following balanced chemical equations, calculate how many
For each of the following balanced chemical equations, calculate how many grams of the product(s) would be produced by complete reaction of 0.125 mole of the first reactant. a. AgNO3(aq) + LiOH(aq)...
See AnswerQ: For each of the following unbalanced chemical equations, suppose that exactly
For each of the following unbalanced chemical equations, suppose that exactly 5.00 g of each reactant is taken. Determine which reactant is limiting, and calculate what mass of each product is expecte...
See AnswerQ: Consider samples of phosphine (PH3), water (H2O), hydrogen
Consider samples of phosphine (PH3), water (H2O), hydrogen sulfide (H2S), and hydrogen fluoride (HF), each with a mass of 119 g. Rank the compounds from the least to the greatest number of hydrogen at...
See AnswerQ: For each of the following unbalanced chemical equations, suppose 10.
For each of the following unbalanced chemical equations, suppose 10.0 g of each reactant is taken. Show by calculation which reactant is the limiting reagent. Calculate the mass of each product that i...
See AnswerQ: For each of the following unbalanced chemical equations, suppose that exactly
For each of the following unbalanced chemical equations, suppose that exactly 1.00 g of each reactant is taken. Determine which reactant is limiting, and calculate what mass of the product in boldface...
See AnswerQ: A compound with molar mass 180.1 g/mol has
A compound with molar mass 180.1 g/mol has the following composition by mass: C ………...40.0% H ………... 6.70% O ………...53.3% Determine the empirical and molecular formulas of the compound.
See AnswerQ: For each of the following unbalanced chemical equations, suppose 1.
For each of the following unbalanced chemical equations, suppose 1.00 g of each reactant is taken. Show by calculation which reactant is limiting. Calculate the mass of each product that is expected....
See AnswerQ: For each of the following unbalanced chemical equations, suppose that exactly
For each of the following unbalanced chemical equations, suppose that exactly 15.0 g of each reactant are taken. Using Before–Change–After (BCA) tables, determine which reactant is limiting, and calcu...
See AnswerQ: Lead(II) carbonate, also called “white lead,”
Lead(II) carbonate, also called “white lead,” was formerly used as a pigment in white paints. However, because of its toxicity, lead can no longer be used in paints intended for residential homes. Lea...
See AnswerQ: Copper(II) sulfate has been used extensively as a fungicide
Copper(II) sulfate has been used extensively as a fungicide (kills fungus) and herbicide (kills plants). Copper(II) sulfate can be prepared in the laboratory by reaction of copper(II) oxide with sulfu...
See AnswerQ: Hydrogen peroxide is used as a cleaning agent in the treatment of
Hydrogen peroxide is used as a cleaning agent in the treatment of cuts and abrasions for several reasons. It is an oxidizing agent that can directly kill many microorganisms; it decomposes upon contac...
See AnswerQ: For each of the following balanced chemical equations, calculate how many
For each of the following balanced chemical equations, calculate how many moles and how many grams of each product would be produced by the complete conversion of 0.50 mole of the reactant indicated i...
See AnswerQ: Silicon carbide, SiC, is one of the hardest materials known
Silicon carbide, SiC, is one of the hardest materials known. Surpassed in hardness only by diamond, it is sometimes known commercially as carborundum. Silicon carbide is used primarily as an abrasive...
See AnswerQ: Your text talks about several sorts of “yield” when experiments
Your text talks about several sorts of “yield” when experiments are performed in the laboratory. Students often confuse these terms. Define, compare, and contrast what are meant by theoretical yield,...
See AnswerQ: An air bag is deployed by utilizing the following reaction (the
An air bag is deployed by utilizing the following reaction (the nitrogen gas produced inflates the air bag): 2NaN3(s) 2Na(s) + 3N2(g) If 10.5 g of NaN3 is decomposed, what theoretica...
See AnswerQ: The compound sodium thiosulfate pentahydrate, Na2S2O3.5H2O, is important
The compound sodium thiosulfate pentahydrate, Na2S2O3.5H2O, is important commercially to the photography business as “hypo,” because it has the ability to dissolve unreacted silver salts from photogra...
See AnswerQ: Alkali metal hydroxides are sometimes used to “scrub” excess carbon
Alkali metal hydroxides are sometimes used to “scrub” excess carbon dioxide from the air in closed spaces (such as submarines and spacecraft). For example, lithium hydroxide reacts with carbon dioxide...
See AnswerQ: Although they were formerly called the inert gases, at least the
Although they were formerly called the inert gases, at least the heavier elements of Group 8 do form relatively stable compounds. For example, xenon combines directly with elemental fluorine at elevat...
See AnswerQ: Solid copper can be produced by passing gaseous ammonia over solid copper
Solid copper can be produced by passing gaseous ammonia over solid copper(II) oxide at high temperatures. The other products of the reaction are nitrogen gas and water vapor. The balanced equation for...
See AnswerQ: Natural waters often contain relatively high levels of calcium ion, Ca21
Natural waters often contain relatively high levels of calcium ion, Ca21, and hydrogen carbonate ion (bicarbonate), HCO3-, from the leaching of minerals into the water. When such water is used commerc...
See AnswerQ: One process for the commercial production of baking soda (sodium hydrogen
One process for the commercial production of baking soda (sodium hydrogen carbonate) involves the following reaction, in which the carbon dioxide is used in its solid form (“dry ice”) both to serve as...
See AnswerQ: When the sugar glucose, C6H12O6, is burned in air,
When the sugar glucose, C6H12O6, is burned in air, carbon dioxide and water vapor are produced. Write the balanced chemical equation for this process, and calculate the theoretical yield of carbon dio...
See AnswerQ: For each of the following unbalanced equations, indicate how many moles
For each of the following unbalanced equations, indicate how many moles of the second reactant would be required to react exactly with 0.275 mole of the first reactant. State clearly the mole ratio us...
See AnswerQ: When elemental copper is strongly heated with sulfur, a mixture of
When elemental copper is strongly heated with sulfur, a mixture of CuS and Cu2S is produced, with CuS predominating. Cu(s) + S(s) / CuS(s) 2Cu(s) + S(s) / Cu2S(s) What is the theoretical yield...
See AnswerQ: Barium chloride solutions are used in chemical analysis for the quantitative precipitation
Barium chloride solutions are used in chemical analysis for the quantitative precipitation of sulfate ion from solution. Ba2+(aq) + SO42–(aq) / BaSO4(s) Suppose a solution is known to contain on the...
See AnswerQ: The traditional method of analysis for the amount of chloride ion present
The traditional method of analysis for the amount of chloride ion present in a sample is to dissolve the sample in water and then slowly to add a solution of silver nitrate. Silver chloride is very in...
See AnswerQ: For each of the following reactions, give the balanced equation for
For each of the following reactions, give the balanced equation for the reaction and state the meaning of the equation in terms of numbers of individual molecules and in terms of moles of molecules....
See AnswerQ: For each of the following balanced reactions, calculate how many moles
For each of the following balanced reactions, calculate how many moles of each product would be produced by complete conversion of 0.50 mole of the reactant indicated in boldface. Indicate clearly the...
See AnswerQ: For each of the following balanced equations, indicate how many moles
For each of the following balanced equations, indicate how many moles of the product could be produced by complete reaction of 1.00 g of the reactant indicated in boldface. Indicate clearly the mole r...
See AnswerQ: Using the average atomic masses given inside the front cover of the
Using the average atomic masses given inside the front cover of the text, calculate the mass in grams of each of the following samples. a. 5.0 moles of nitric acid b. 0.000305 mole of mercury c. 2....
See AnswerQ: For each of the following incomplete and unbalanced equations, indicate how
For each of the following incomplete and unbalanced equations, indicate how many moles of the second reactant would be required to react completely with 0.145 mole of the first reactant. a. BaCl2(aq)...
See AnswerQ: One step in the commercial production of sulfuric acid, H2SO4,
One step in the commercial production of sulfuric acid, H2SO4, involves the conversion of sulfur dioxide, SO2, into sulfur trioxide, SO3. 2SO2(g) + O2(g) / 2SO3(g) If 150 kg of SO2 reacts completely,...
See AnswerQ: Many metals occur naturally as sulfide compounds; examples include ZnS and
Many metals occur naturally as sulfide compounds; examples include ZnS and CoS. Air pollution often accompanies the processing of these ores, because toxic sulfur dioxide is released as the ore is con...
See AnswerQ: For each of the following unbalanced equations, indicate how many moles
For each of the following unbalanced equations, indicate how many moles of the first product are produced if 0.625 mole of the second product forms. State clearly the mole ratio used for each conversi...
See AnswerQ: When elemental copper is placed in a solution of silver nitrate,
When elemental copper is placed in a solution of silver nitrate, the following oxidation–reduction reaction takes place, forming elemental silver: Cu(s) + 2AgNO3(aq) / Cu(NO3)2(aq) + 2Ag(s) What mass...
See AnswerQ: When small quantities of elemental hydrogen gas are needed for laboratory work
When small quantities of elemental hydrogen gas are needed for laboratory work, the hydrogen is often generated by chemical reaction of a metal with acid. For example, zinc reacts with hydrochloric ac...
See AnswerQ: The gaseous hydrocarbon acetylene, C2H2, is used in welders’ torches
The gaseous hydrocarbon acetylene, C2H2, is used in welders’ torches because of the large amount of heat released when acetylene burns with oxygen. 2C2H2(g) + 5O2(g) / 4CO2(g) + 2H2O(g) How many gram...
See AnswerQ: For each of the following unbalanced chemical equations, suppose exactly 5
For each of the following unbalanced chemical equations, suppose exactly 5.0 g of each reactant is taken. Determine which reactant is limiting, and calculate what mass of each product is expected, ass...
See AnswerQ: For each of the following unbalanced chemical equations, suppose 25.
For each of the following unbalanced chemical equations, suppose 25.0 g of each reactant is taken. Show by calculation which reactant is limiting. Calculate the theoretical yield in grams of the produ...
See AnswerQ: Hydrazine, N2H4, emits a large quantity of energy when it
Hydrazine, N2H4, emits a large quantity of energy when it reacts with oxygen, which has led to hydrazine’s use as a fuel for rockets: N2H4(l) + O2(g) / N2(g) + 2H2O(g) How many moles of each of the g...
See AnswerQ: Consider the following reaction: 4NH3(g) + 5O2
Consider the following reaction: 4NH3(g) + 5O2(g) ( 4NO(g) + 6H2O(g) a. If a container were to have only 10 molecules of O2(g) and 10 molecules of NH3(g), how many total molecules (reactant and produ...
See AnswerQ: Over the years, the thermite reaction has been used for welding
Over the years, the thermite reaction has been used for welding railroad rails, in incendiary bombs, and to ignite solid fuel rocket motors. The reaction is Fe2O3(s) + 2Al(s) / 2Fe(l) + Al2O3(s) a. W...
See AnswerQ: Ammonia gas reacts with sodium metal to form sodium amide (NaNH2
Ammonia gas reacts with sodium metal to form sodium amide (NaNH2) and hydrogen gas. The unbalanced chemical equation for this reaction is as follows: NH3(g) + Na(s) NaNH2(s) +...
See AnswerQ: Sulfur dioxide gas reacts with sodium hydroxide to form sodium sulfite and
Sulfur dioxide gas reacts with sodium hydroxide to form sodium sulfite and water. The unbalanced chemical equation for this reaction is as follows: SO2(g) + NaOH(s) Na2SO3(s) + H...
See AnswerQ: What is meant by a state function? Give an example.
What is meant by a state function? Give an example.
See AnswerQ: The production capacity for acrylonitrile (C3H3N) in the United States
The production capacity for acrylonitrile (C3H3N) in the United States is over 2 billion pounds per year. Acrylonitrile, the building block for polyacrylonitrile fibers and a variety of plastics, is p...
See AnswerQ: How are the temperature of an object and the thermal energy of
How are the temperature of an object and the thermal energy of an object related?
See AnswerQ: How is the calorie defined? How does a Calorie differ from
How is the calorie defined? How does a Calorie differ from a calorie? How is the joule related to the calorie?
See AnswerQ: Convert the following numbers of calories or kilocalories into joules or kilojoules
Convert the following numbers of calories or kilocalories into joules or kilojoules. a. 7845 cal b. 4.55 * 104 cal c. 62.142 kcal d. 43,024 cal
See AnswerQ: The “Chemistry in Focus” segment Nature Has Hot Plants discusses
The “Chemistry in Focus” segment Nature Has Hot Plants discusses thermogenic, or heat-producing, plants. For some plants, enough heat is generated to increase the temperature of the blossom by 15 °C....
See AnswerQ: The enthalpy change for the reaction of hydrogen gas with fluorine gas
The enthalpy change for the reaction of hydrogen gas with fluorine gas to produce hydrogen fluoride is 2542 kJ for the equation as written: H2(g) + F2(g) 2HF(g) ∆H = -542 kJ a. Wh...
See AnswerQ: For the reaction S(s) + O2(g)
For the reaction S(s) + O2(g) SO2(g), ∆H = -296 kJ per mole of SO2 formed. a. Calculate the quantity of heat released when 1.00 g of sulfur is burned in oxygen. b. Calculate the qu...
See AnswerQ: When ethanol (grain alcohol, C2H5OH) is burned in oxygen
When ethanol (grain alcohol, C2H5OH) is burned in oxygen, approximately 1360 kJ of heat energy is released per mole of ethanol. C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(g) a. What...
See AnswerQ: Given the following hypothetical data: X(g) +
Given the following hypothetical data: X(g) + Y(g) XY(g) for which ∆H = a kJ X(g) + Z(g) XZ(g) for which ∆H = b kJ Calculate ∆H for the reaction Y(g) + XZ(g)...
See AnswerQ: Given the following data: C(s) + O2
Given the following data: C(s) + O2(g) CO2(g) ∆H = -393 kJ 2CO(g) + O2(g) 2CO2(g) ∆H = -566 kJ Calculate ∆H for the reaction 2C(s) + O2(g) CO...
See AnswerQ: In Fig. 10.1, what kind of energy does
In Fig. 10.1, what kind of energy does ball A possess initially when at rest at the top of the hill? What kind of energies are involved as ball A moves down the hill? What kind of energy does ball A p...
See AnswerQ: Given the following data: S(s) + 3
Given the following data: S(s) + 3/2 O2(g) SO3(g) ∆H = -395.2 kJ 2SO2(g) + O2(g) 2SO3(g) ∆H = -198.2 kJ Calculate ∆H for the reaction S(s) + O2(g)...
See AnswerQ: Given the following data: C2H2(g) + 5
Given the following data: C2H2(g) + 5/2O2(g) 2CO2(g) + H2O(l) ∆H = -1300. kJ C(s) + O2(g) CO2(g) ∆H = -394 kJ H2(g) + 1/2O2(g) H2O...
See AnswerQ: What does petroleum consist of? What are some “fractions”
What does petroleum consist of? What are some “fractions” into which petroleum is refined? How are these fractions related to the sizes of the molecules involved?
See AnswerQ: What is the “greenhouse effect”? Why is a certain level
What is the “greenhouse effect”? Why is a certain level of greenhouse gases beneficial, but too high a level dangerous to life on earth? What is the most common greenhouse gas?
See AnswerQ: A 50.0-g sample of water at 100.
A 50.0-g sample of water at 100. °C is poured into a 50.0-g sample of water at 25 °C. What will be the final temperature of the water?
See AnswerQ: A 25.0-g sample of pure iron at 85
A 25.0-g sample of pure iron at 85 °C is dropped into 75 g of water at 20. °C. What is the final temperature of the water–iron mixture?
See AnswerQ: For each of the substances listed in Table 10.1,
For each of the substances listed in Table 10.1, calculate the quantity of heat required to heat 150. g of the substance by 11.2 °C.
See AnswerQ: The overall reaction in commercial heat packs can be represented as
The overall reaction in commercial heat packs can be represented as 4Fe(s) + 3O2(g) 2Fe2O3(s) ∆H = -1652 kJ a. How much heat is released when 4.00 moles of iron is reacted with ex...
See AnswerQ: Consider the following equations: 3A + 6B 3D ∆H
Consider the following equations: 3A + 6B 3D ∆H = -403 kJ/mol E + 2F A ∆H = -105.2 kJ/mol C E + 3D ∆H = +64.8 kJ/mol Suppose the first equation is revers...
See AnswerQ: It has been determined that the body can generate 5500 kJ of
It has been determined that the body can generate 5500 kJ of energy during one hour of strenuous exercise. Perspiration is the body’s mechanism for eliminating this heat. How many grams and how many l...
See AnswerQ: Use the average atomic masses given inside the front cover of this
Use the average atomic masses given inside the front cover of this book to calculate the number of moles of the element present in each of the following samples. a. 4.95 g of neon b. 72.5 g of nicke...
See AnswerQ: Which of the following reactions is/are endothermic? a
Which of the following reactions is/are endothermic? a. CO2(s) CO2(g) b. NH3(g) NH3(l) c. 2H2(g) + O2(g) 2H2O(g) d. H2O(l) H2O(s) e. Cl2(g...
See AnswerQ: A swimming pool, 10.0 m by 4.0
A swimming pool, 10.0 m by 4.0 m, is filled with water to a depth of 3.0 m at a temperature of 20.2 °C. How much energy is required to raise the temperature of the water to 24.6 °C?
See AnswerQ: Calculate ∆H for the reaction N2H4(l) +
Calculate âH for the reaction N2H4(l) + O2(g) N2(g) + 2H2O(l) given the following data:
See AnswerQ: The “Chemistry in Focus” segment Atmospheric Effects discusses the greenhouse
The “Chemistry in Focus” segment Atmospheric Effects discusses the greenhouse effect. How do the greenhouse gases CO2, H2O, and CH4 have an effect on the temperature of the atmosphere?
See AnswerQ: Describe briefly why the study of electromagnetic radiation has been important to
Describe briefly why the study of electromagnetic radiation has been important to our understanding of the arrangement of electrons in atoms.
See AnswerQ: What does it mean to say that the hydrogen atom has discrete
What does it mean to say that the hydrogen atom has discrete energy levels? How is this fact reflected in the radiation that excited hydrogen atoms emit?
See AnswerQ: How does the Bohr theory account for the observed phenomenon of the
How does the Bohr theory account for the observed phenomenon of the emission of discrete wavelengths of light by excited atoms?
See AnswerQ: What major assumption (that was analogous to what had already been
What major assumption (that was analogous to what had already been demonstrated for electromagnetic radiation) did de Broglie and Schrödinger make about the motion of tiny particles?
See AnswerQ: Section 11.6 uses a “firefly” analogy to illustrate
Section 11.6 uses a “firefly” analogy to illustrate how the wave mechanical model for the atom differs from Bohr’s model. Explain this analogy.
See AnswerQ: Your text describes the probability map for an s orbital using an
Your text describes the probability map for an s orbital using an analogy to the earth’s atmosphere. Explain this analogy.
See AnswerQ: The “Chemistry in Focus” segment Plastic That Talks and Listens
The “Chemistry in Focus” segment Plastic That Talks and Listens! discusses polyvinylidene difluoride (PVDF). What is the empirical formula of PVDF? Note: An empirical formula is the simplest whole-num...
See AnswerQ: Use the average atomic masses given inside the front cover of this
Use the average atomic masses given inside the front cover of this book to calculate the number of moles of the element present in each of the following samples. a. 49.2 g of sulfur b. 7.44 * 104 kg...
See AnswerQ: What overall shape do the 2p and 3p orbitals have? How
What overall shape do the 2p and 3p orbitals have? How do the 2p orbitals differ from the 3p orbitals? How are they similar?
See AnswerQ: Although a hydrogen atom has only one electron, the hydrogen atom
Although a hydrogen atom has only one electron, the hydrogen atom possesses a complete set of available orbitals. What purpose do these additional orbitals serve?
See AnswerQ: Where are the valence electrons found in an atom, and why
Where are the valence electrons found in an atom, and why are these particular electrons most important to the chemical properties of the atom?
See AnswerQ: Write the complete orbital diagram for each of the following elements,
Write the complete orbital diagram for each of the following elements, using boxes to represent orbitals and arrows to represent electrons. a. helium, Z = 2 b. neon, Z = 10 c. krypton, Z = 36 d. x...
See AnswerQ: What are some of the physical properties that distinguish the metallic elements
What are some of the physical properties that distinguish the metallic elements from the nonmetals? Are these properties absolute, or do some nonmetallic elements exhibit some metallic properties (and...
See AnswerQ: Give some similarities that exist among the elements of Group 1.
Give some similarities that exist among the elements of Group 1.
See AnswerQ: Where are the most nonmetallic elements located on the periodic table?
Where are the most nonmetallic elements located on the periodic table? Why do these elements pull electrons from metallic elements so effectively during a reaction?
See AnswerQ: The “Chemistry in Focus” segment Fireworks discusses some of the
The “Chemistry in Focus” segment Fireworks discusses some of the chemicals that give rise to the colors of fireworks. How do these colors support the existence of quantized energy levels in atoms?
See AnswerQ: In each of the following groups, which element is least reactive
In each of the following groups, which element is least reactive? a. Group 1 b. Group 7 c. Group 2 d. Group 6
See AnswerQ: Arrange the following sets of elements in order of increasing atomic size
Arrange the following sets of elements in order of increasing atomic size. a. Sn, Xe, Rb, Sr b. Rn, He, Xe, Kr c. Pb, Ba, Cs, At
See AnswerQ: Use the average atomic masses given inside the front cover of this
Use the average atomic masses given inside the front cover of this book to calculate the mass in grams of each of the following samples. a. 0.251 mole of lithium b. 1.51 moles of aluminum c. 8.75 *...
See AnswerQ: An unknown element is a nonmetal and has a valence-electron
An unknown element is a nonmetal and has a valence-electron configuration of ns2np4. a. How many valence electrons does this element have? b. Possible identities for this element include which of th...
See AnswerQ: One bit of evidence that the present theory of atomic structure is
One bit of evidence that the present theory of atomic structure is “correct” lies in the magnetic properties of matter. Atoms with unpaired electrons are attracted by magnetic fields and thus are said...
See AnswerQ: Without referring to your textbook or a periodic table, write the
Without referring to your textbook or a periodic table, write the full electron configuration, the orbital box diagram, and the noble gas shorthand configuration for the elements with the following at...
See AnswerQ: Without referring to your textbook or a periodic table, write the
Without referring to your textbook or a periodic table, write the full electron configuration, the orbital box diagram, and the noble gas shorthand configuration for the elements with the following at...
See AnswerQ: In the text (Section 11.6) it was mentioned
In the text (Section 11.6) it was mentioned that current theories of atomic structure suggest that all matter and all energy demonstrate both particle-like and wave-like properties under the appropria...
See AnswerQ: Which of the following statements is(are) true regarding the
Which of the following statements is(are) true regarding the atom? a. Negatively charged particles are embedded in a positively charged cloud throughout the atom. b. As verified by Rutherford, only...
See AnswerQ: Answer each of the following questions. Be thorough in your answers
Answer each of the following questions. Be thorough in your answers, and provide complete support. a. Write the ground-state electron configuration for oxygen. b. Draw the orbital diagram for the gr...
See AnswerQ: Why do we believe that the three electrons in the 2p sublevel
Why do we believe that the three electrons in the 2p sublevel of nitrogen occupy different orbitals?
See AnswerQ: When describing the electrons in an orbital, we use arrows pointing
When describing the electrons in an orbital, we use arrows pointing upward and downward / to indicate what property?
See AnswerQ: Why can only two electrons occupy a particular orbital? What is
Why can only two electrons occupy a particular orbital? What is this idea called?
See AnswerQ: Use the average atomic masses given inside the front cover of this
Use the average atomic masses given inside the front cover of this book to calculate the mass in grams of each of the following samples. a. 0.00552 mole of calcium b. 6.25 mmol of boron (1 mmol = 1⁄...
See AnswerQ: How does the energy of a principal energy level depend on the
How does the energy of a principal energy level depend on the value of n? Does a higher value of n mean a higher or lower energy?
See AnswerQ: The number of sublevels in a principal energy level (increases/
The number of sublevels in a principal energy level (increases/ decreases) as n increases.
See AnswerQ: According to the Pauli exclusion principle, a given orbital can contain
According to the Pauli exclusion principle, a given orbital can contain only electrons.
See AnswerQ: According to the Pauli exclusion principle, the electrons within a given
According to the Pauli exclusion principle, the electrons within a given orbital must have spins.
See AnswerQ: Which of the following orbital designations is(are) possible?
Which of the following orbital designations is(are) possible? a. 1s b. 2p c. 2d d. 4f
See AnswerQ: Which of the following orbital designations is(are) not possible
Which of the following orbital designations is(are) not possible? a. 3f b. 5s c. 4d d. 1p
See AnswerQ: Which orbital is the first to be filled in any atom?
Which orbital is the first to be filled in any atom? Why?
See AnswerQ: When a hydrogen atom is in its ground state, in which
When a hydrogen atom is in its ground state, in which orbital is its electron found? Why?
See AnswerQ: How are the electron arrangements in a given group (vertical column
How are the electron arrangements in a given group (vertical column) of the periodic table related? How is this relationship manifested in the properties of the elements in the given group?
See AnswerQ: Write the full electron configuration (1s22s2, etc.) for each
Write the full electron configuration (1s22s2, etc.) for each of the following elements. a. magnesium, Z = 12 b. lithium, Z = 3 c. oxygen, Z = 8 d. sulfur, Z = 16
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this book, calculate the number of atoms present in each of the following samples. a. 1.50 g of silver, Ag b. 0.0015 mole of copper, C...
See AnswerQ: What does the wavelength of electromagnetic radiation represent? How is the
What does the wavelength of electromagnetic radiation represent? How is the wavelength of radiation related to the energy of the photons of the radiation?
See AnswerQ: To which element does each of the following electron configurations correspond?
To which element does each of the following electron configurations correspond? a. 1s22s22p63s23p2 b. 1s22s2 c. 1s22s22p6 d. 1s22s22p63s23p6
See AnswerQ: Write the full electron configuration (1s22s2, etc.) for each
Write the full electron configuration (1s22s2, etc.) for each of the following elements. a. phosphorus, Z = 15 b. calcium, Z = 20 c. potassium, Z = 19 d. boron, Z = 5
See AnswerQ: To which element does each of the following electron configurations correspond?
To which element does each of the following electron configurations correspond? a. 1s22s22p63s23p64s23d104p4 b. 1s22s22p63s23p64s23d1 c. 1s22s22p63s23p4 d. 1s22s22p63s23p64s23d104p65s24d105p5
See AnswerQ: Write the complete orbital diagram for each of the following elements,
Write the complete orbital diagram for each of the following elements, using boxes to represent orbitals and arrows to represent electrons. a. aluminum, Z = 13 b. phosphorus, Z = 15 c. bromine, Z =...
See AnswerQ: The “Chemistry in Focus” segment A Magnetic Moment discusses the
The “Chemistry in Focus” segment A Magnetic Moment discusses the ability to levitate a frog in a magnetic field because electrons, when sensing a strong magnetic field, respond by opposing it. This is...
See AnswerQ: For each of the following, give an atom and its complete
For each of the following, give an atom and its complete electron configuration that would be expected to have the indicated number of valence electrons. a. two b. four c. six d. eight
See AnswerQ: Why do we believe that the valence electrons of calcium and potassium
Why do we believe that the valence electrons of calcium and potassium reside in the 4s orbital rather than in the 3d orbital?
See AnswerQ: Would you expect the valence electrons of rubidium and strontium to reside
Would you expect the valence electrons of rubidium and strontium to reside in the 5s or the 4d orbitals? Why?
See AnswerQ: Using the symbol of the previous noble gas to indicate the core
Using the symbol of the previous noble gas to indicate the core electrons, write the electron configuration for each of the following elements. a. arsenic, Z = 33 b. titanium, Z = 22 c. strontium,...
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this book, calculate the indicated quantities. a. the mass in grams of 125 iron atoms b. the mass in amu of 125 iron atoms c. the num...
See AnswerQ: What do we mean by the frequency of electromagnetic radiation? Is
What do we mean by the frequency of electromagnetic radiation? Is the frequency the same as the speed of the electromagnetic radiation?
See AnswerQ: To which element does each of the following abbreviated electron configurations refer
To which element does each of the following abbreviated electron configurations refer? a. [Ne]3s23p1 b. [Ar]4s1 c. [Ar]4s23d104p5 d. [Kr]5s24d105p2
See AnswerQ: Using the symbol of the previous noble gas to indicate the core
Using the symbol of the previous noble gas to indicate the core electrons, write the electron configuration for each of the following elements. a. scandium, Z = 21 b. yttrium, Z = 39 c. lanthanum,...
See AnswerQ: How many valence electrons does each of the following atoms have?
How many valence electrons does each of the following atoms have? a. rubidium, Z = 37 b. arsenic, Z = 33 c. aluminum, Z = 13 d. nickel, Z = 28
See AnswerQ: How many 3d electrons are found in each of the following elements
How many 3d electrons are found in each of the following elements? a. nickel, Z = 28 b. vanadium, Z = 23 c. manganese, Z = 25 d. iron, Z = 26
See AnswerQ: Based on the elements’ locations on the periodic table, how many
Based on the elements’ locations on the periodic table, how many 4d electrons would be predicted for each of the following elements? a. ruthenium, Z = 44 b. palladium, Z = 46 c. tin, Z = 50 d. iro...
See AnswerQ: For each of the following elements, indicate which set of orbitals
For each of the following elements, indicate which set of orbitals is filled last. a. radium, Z = 88 b. iodine, Z = 53 c. gold, Z = 79 d. lead, Z = 82
See AnswerQ: Write the valence-electron configuration of each of the following elements
Write the valence-electron configuration of each of the following elements, basing your answer on the element’s location on the periodic table. a. uranium, Z = 92 b. manganese, Z = 25 c. mercury, Z...
See AnswerQ: Write the valence shell electron configuration of each of the following elements
Write the valence shell electron configuration of each of the following elements, basing your answer on the element’s location on the periodic table. a. rubidium, Z = 37 b. barium, Z = 56 c. titani...
See AnswerQ: The “Chemistry in Focus” segment The Chemistry of Bohrium discusses
The “Chemistry in Focus” segment The Chemistry of Bohrium discusses element 107, bohrium (Bh). What is the expected electron configuration of Bh?
See AnswerQ: For each of the following unbalanced equations, calculate how many grams
For each of the following unbalanced equations, calculate how many grams of each product would be produced by complete reaction of 12.5 g of the reactant indicated in boldface. Indicate clearly the mo...
See AnswerQ: The “Chemistry in Focus” segment Light as a Sex Attractant
The “Chemistry in Focus” segment Light as a Sex Attractant discusses fluorescence. In fluorescence, ultraviolet radiation is absorbed and intense white visible light is emitted. Is ultraviolet radiati...
See AnswerQ: What types of ions do the metals and the nonmetallic elements form
What types of ions do the metals and the nonmetallic elements form? Do the metals lose or gain electrons in doing this? Do the nonmetallic elements gain or lose electrons in doing this?
See AnswerQ: Give some similarities that exist among the elements of Group 7.
Give some similarities that exist among the elements of Group 7.
See AnswerQ: Which of the following elements most easily gives up electrons during reactions
Which of the following elements most easily gives up electrons during reactions: Li, K, or Cs? Explain your choice.
See AnswerQ: Which elements in a given period (horizontal row) of the
Which elements in a given period (horizontal row) of the periodic table lose electrons most easily? Why?
See AnswerQ: Why do the metallic elements of a given period (horizontal row
Why do the metallic elements of a given period (horizontal row) typically have much lower ionization energies than do the nonmetallic elements of the same period?
See AnswerQ: What are the metalloids? Where are the metalloids found on the
What are the metalloids? Where are the metalloids found on the periodic table?
See AnswerQ: In each of the following sets of elements, which element would
In each of the following sets of elements, which element would be expected to have the highest ionization energy? a. Cs, K, Li b. Ba, Sr, Ca c. I, Br, Cl d. Mg, Si, S
See AnswerQ: In each of the following sets of elements, indicate which element
In each of the following sets of elements, indicate which element has the smallest atomic size. a. Na, K, Rb b. Na, Si, S c. N, P, As d. N, O, F
See AnswerQ: Consider the bright line spectrum of hydrogen shown in Fig. 11
Consider the bright line spectrum of hydrogen shown in Fig. 11.10. Which line in the spectrum represents photons with the highest energy? With the lowest energy?
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this book, calculate how many moles of each substance the following masses represent. a. 4.15 g of silicon, Si b. 2.72 mg of gold(III)...
See AnswerQ: The speed at which electromagnetic radiation moves through a vacuum is called
The speed at which electromagnetic radiation moves through a vacuum is called the .
See AnswerQ: The portion of the electromagnetic spectrum between wavelengths of approximately 400 and
The portion of the electromagnetic spectrum between wavelengths of approximately 400 and 700 nanometers is called the region.
See AnswerQ: A beam of light can be thought of as consisting of a
A beam of light can be thought of as consisting of a stream of light particles called .
See AnswerQ: The lowest possible energy state of an atom is called the state
The lowest possible energy state of an atom is called the state.
See AnswerQ: The energy levels of hydrogen (and other atoms) are ,
The energy levels of hydrogen (and other atoms) are , which means that only certain values of energy are allowed.
See AnswerQ: According to Bohr, the electron in the hydrogen atom moved around
According to Bohr, the electron in the hydrogen atom moved around the nucleus in circular paths called .
See AnswerQ: When lithium salts are heated in a flame, they emit red
When lithium salts are heated in a flame, they emit red light. When copper salts are heated in a flame in the same manner, they emit green light. Why do we know that lithium salts will never emit gree...
See AnswerQ: Which of the following statements is false concerning orbitals? a
Which of the following statements is false concerning orbitals? a. An orbital is a region of space where an electron might be found with 90% probability. b. As an electron absorbs more energy, the o...
See AnswerQ: Electrons found in the outermost principal energy level of an atom are
Electrons found in the outermost principal energy level of an atom are referred to as electrons.
See AnswerQ: The of electromagnetic radiation represents the number of waves passing a given
The of electromagnetic radiation represents the number of waves passing a given point in space each second.
See AnswerQ: Give the name and calculate the molar mass for each of the
Give the name and calculate the molar mass for each of the following substances. a. H3PO4 b. Fe2O3 c. NaClO4 d. PbCl2 e. HBr f. Al(OH)3
See AnswerQ: The current model of the atom in which essentially all of an
The current model of the atom in which essentially all of an atom’s mass is contained in a very small nucleus, whereas most of an atom’s volume is due to the space in which the atom’s electrons move,...
See AnswerQ: Write the general valence configuration (for example, ns1 for Group
Write the general valence configuration (for example, ns1 for Group 1) for the group in which each of the following elements is found. a. barium, Z = 56 b. bromine, Z = 35 c. tellurium, Z = 52 d....
See AnswerQ: How many valence electrons does each of the following atoms have?
How many valence electrons does each of the following atoms have? a. titanium, Z = 22 b. iodine, Z = 53 c. radium, Z = 88 d. manganese, Z = 25
See AnswerQ: What do we mean by the average atomic mass of an element
What do we mean by the average atomic mass of an element? What is “averaged” to arrive at this number?
See AnswerQ: What do the coefficients of a balanced chemical equation tell us about
What do the coefficients of a balanced chemical equation tell us about the proportions in which atoms and molecules react on an individual (microscopic) basis?
See AnswerQ: Using the average atomic masses for each of the following elements (
Using the average atomic masses for each of the following elements (see the table inside the front cover of this book), calculate the number of atoms present in each of the following samples. a. 40.0...
See AnswerQ: What is the average atomic mass (in amu) of iron
What is the average atomic mass (in amu) of iron atoms? What would 299 iron atoms weigh? How many iron atoms are present in a sample of iron that has a mass of 5529.2 amu?
See AnswerQ: The atomic mass of copper is 63.55 amu. What
The atomic mass of copper is 63.55 amu. What would be the mass of 75 copper atoms? How many copper atoms are contained in a sample of copper that has a mass of 6100.8 amu?
See AnswerQ: There are iron atoms present in 55.85 g of iron
There are iron atoms present in 55.85 g of iron.
See AnswerQ: There are 6.022 * 1023 zinc atoms present in g
There are 6.022 * 1023 zinc atoms present in g of zinc.
See AnswerQ: Give the name and calculate the molar mass for each of the
Give the name and calculate the molar mass for each of the following substances. a. KHCO3 b. Hg2Cl2 c. H2O2 d. BeCl2 e. Al2(SO4)3 f. KClO3
See AnswerQ: Suppose you have a sample of sodium weighing 11.50 g
Suppose you have a sample of sodium weighing 11.50 g. How many atoms of sodium are present in the sample? What mass of potassium would you need to have the same number of potassium atoms as there are...
See AnswerQ: Consider a sample of silver weighing 300.0 g. How
Consider a sample of silver weighing 300.0 g. How many atoms of silver are present in the sample? What mass of copper would you need for the copper sample to contain the same number of atoms as the si...
See AnswerQ: What mass of hydrogen contains the same number of atoms as 7
What mass of hydrogen contains the same number of atoms as 7.00 g of nitrogen?
See AnswerQ: What mass of cobalt contains the same number of atoms as 57
What mass of cobalt contains the same number of atoms as 57.0 g of fluorine?
See AnswerQ: If an average sodium atom has a mass of 3.82
If an average sodium atom has a mass of 3.82 * 10-23 g, what is the mass of a magnesium atom in grams?
See AnswerQ: If an average fluorine atom has a mass of 3.16
If an average fluorine atom has a mass of 3.16 * 10-23 g, what is the average mass of a chlorine atom in grams?
See AnswerQ: Which has the smaller mass, 1 mole of He atoms or
Which has the smaller mass, 1 mole of He atoms or 4 moles of H atoms?
See AnswerQ: Which weighs less, 0.25 mole of xenon atoms or
Which weighs less, 0.25 mole of xenon atoms or 2.0 moles of carbon atoms?
See AnswerQ: What quantity serves as the conversion factor between the mass of a
What quantity serves as the conversion factor between the mass of a sample and how many moles the sample contains?
See AnswerQ: What does it mean to say that the balanced chemical equation for
What does it mean to say that the balanced chemical equation for a reaction describes the stoichiometry of the reaction?
See AnswerQ: Write the formula and calculate the molar mass for each of the
Write the formula and calculate the molar mass for each of the following substances. a. barium chloride b. aluminum nitrate c. iron(II) chloride d. sulfur dioxide e. calcium acetate
See AnswerQ: The vigorous reaction between aluminum and iodine gives the balanced equation:
The vigorous reaction between aluminum and iodine gives the balanced equation: 2Al(s) + 3I2(s) 2AlI3(s). What do the coefficients in this balanced chemical equation tell us about the prop...
See AnswerQ: Although mass is a property of matter we can conveniently measure in
Although mass is a property of matter we can conveniently measure in the laboratory, the coefficients of a balanced chemical equation are not directly interpreted on the basis of mass. Explain why.
See AnswerQ: Which of the following statements is true for the reaction of nitrogen
Which of the following statements is true for the reaction of nitrogen gas with hydrogen gas to produce ammonia (NH3)? Choose the best answer. a. Subscripts can be changed to balance this equation, j...
See AnswerQ: Consider the reaction represented by the chemical equation C(s
Consider the reaction represented by the chemical equation C(s) + O2(g) CO2(g) Because the coefficients of the balanced chemical equation are all equal to 1, we know that exact...
See AnswerQ: The of a substance is the mass (in grams) of
The of a substance is the mass (in grams) of 1 mole of the substance.
See AnswerQ: Describe in your own words how the molar mass of the compound
Describe in your own words how the molar mass of the compound below may be calculated.
See AnswerQ: “Smelling salts,” which are used to revive someone who has
“Smelling salts,” which are used to revive someone who has fainted, typically contain ammonium carbonate, (NH4)2CO3. Ammonium carbonate decomposes readily to form ammonia, carbon dioxide, and water. T...
See AnswerQ: Calcium carbide, CaC2, can be produced in an electric furnace
Calcium carbide, CaC2, can be produced in an electric furnace by strongly heating calcium oxide (lime) with carbon. The unbalanced equation is CaO(s) + C(s) CaC2(s) + CO(g) Calcium...
See AnswerQ: Boron nitride reacts with iodine monofluoride in trichlorofluoromethane at 230°C
Boron nitride reacts with iodine monofluoride in trichlorofluoromethane at 230°C to produce pure nitrogen triiodide and by-product (BF3). BN + 3IF NI3 + BF3 a. What mass of iodine mono...
See AnswerQ: If baking soda (sodium hydrogen carbonate) is heated strongly,
If baking soda (sodium hydrogen carbonate) is heated strongly, the following reaction occurs: 2NaHCO3(s) Na2CO3(s) + H2O(g) + CO2(g) Calculate the mass of sodium carbonate that wi...
See AnswerQ: Define the amu. What is one amu equivalent to in grams
Define the amu. What is one amu equivalent to in grams?
See AnswerQ: Write the formula and calculate the molar mass for each of the
Write the formula and calculate the molar mass for each of the following substances. a. carbon dioxide b. aluminum phosphate c. iron(III) carbonate d. lead(II) nitrate e. strontium chloride
See AnswerQ: Although we usually think of substances as “burning” only in
Although we usually think of substances as “burning” only in oxygen gas, the process of rapid oxidation to produce a flame may also take place in other strongly oxidizing gases. For example, when iron...
See AnswerQ: When yeast is added to a solution of glucose or fructose,
When yeast is added to a solution of glucose or fructose, the sugars are said to undergo fermentation, and ethyl alcohol is produced. C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g) This is...
See AnswerQ: Sulfurous acid is unstable in aqueous solution and gradually decomposes to water
Sulfurous acid is unstable in aqueous solution and gradually decomposes to water and sulfur dioxide gas (which explains the choking odor associated with sulfurous acid solutions). H2SO3(aq)...
See AnswerQ: Small quantities of ammonia gas can be generated in the laboratory by
Small quantities of ammonia gas can be generated in the laboratory by heating an ammonium salt with a strong base. For example, ammonium chloride reacts with sodium hydroxide according to the followin...
See AnswerQ: Elemental phosphorus burns in oxygen with an intensely hot flame, producing
Elemental phosphorus burns in oxygen with an intensely hot flame, producing a brilliant light and clouds of the oxide product. These properties of the combustion of phosphorus have led to its being us...
See AnswerQ: For the balanced chemical equation for the combination reaction of hydrogen gas
For the balanced chemical equation for the combination reaction of hydrogen gas and oxygen gas 2H2(g) + O2(g) 2H2O(g) explain why we know that 2 g of H2 reacting with 1 g of O2 wil...
See AnswerQ: represents the ability to do work or to produce heat.
represents the ability to do work or to produce heat.
See AnswerQ: If common sugars are heated too strongly, they char as they
If common sugars are heated too strongly, they char as they decompose into carbon and water vapor. For example, if sucrose (table sugar) is heated, the reaction is C12H22O11(s) 12C...
See AnswerQ: Thionyl chloride, SOCl2, is used as a very powerful drying
Thionyl chloride, SOCl2, is used as a very powerful drying agent in many synthetic chemistry experiments in which the presence of even small amounts of water would be detrimental. The unbalanced chemi...
See AnswerQ: A is a device used to determine the heat associated with a
A is a device used to determine the heat associated with a chemical reaction.
See AnswerQ: Calculate the number of moles of the indicated substance present in each
Calculate the number of moles of the indicated substance present in each of the following samples. a. 21.4 mg of nitrogen dioxide b. 1.56 g of copper(II) nitrate c. 2.47 g of carbon disulfide d. 5...
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. A balanced equation relates the numbers of molecules of reactants and products (or numbers of moles of reactants and products). b. To convert betwee...
See AnswerQ: In studying heat flows for chemical processes, what do we mean
In studying heat flows for chemical processes, what do we mean by the terms system and surroundings?
See AnswerQ: The mass fraction of an element present in a compound can be
The mass fraction of an element present in a compound can be obtained by comparing the mass of the particular element present in 1 mole of the compound to the mass of the compound.
See AnswerQ: If the amount of a sample doubles, what happens to the
If the amount of a sample doubles, what happens to the percent composition of each element in the compound?
See AnswerQ: Consider the equation: 2A + B 5C. If 10.
Consider the equation: 2A + B 5C. If 10.0 g of A reacts with 5.00 g of B, how is the limiting reactant determined? Choose the best answer and explain. a. Choose the reactant w...
See AnswerQ: Balance the following chemical equation, and then answer the question below
Balance the following chemical equation, and then answer the question below. CuSO4(aq) + KI(s) CuI(s) + I2(s) + K2SO4(aq) Which reactant is the limiting reactant? Choose the best...
See AnswerQ: When a chemical system evolves energy, where does the energy go
When a chemical system evolves energy, where does the energy go?
See AnswerQ: The combustion of methane, CH4, is an exothermic process.
The combustion of methane, CH4, is an exothermic process. Therefore, the products of this reaction must possess (higher/ lower) total potential energy than do the reactants.
See AnswerQ: Consider the gasoline in your car’s gas tank. What happens to
Consider the gasoline in your car’s gas tank. What happens to the energy stored in the gasoline when you drive your car? Although the total energy in the universe remains constant, can the energy stor...
See AnswerQ: Although the total energy of the universe will remain constant, why
Although the total energy of the universe will remain constant, why will energy no longer be useful once everything in the universe is at the same temperature?
See AnswerQ: Calculate the number of moles of the indicated substance present in each
Calculate the number of moles of the indicated substance present in each of the following samples. a. 47.2 g of aluminum oxide b. 1.34 kg of potassium bromide c. 521 mg of germanium d. 56.2 µg of...
See AnswerQ: Why are petroleum products especially useful as sources of energy?
Why are petroleum products especially useful as sources of energy?
See AnswerQ: Why is the “quality” of energy decreasing in the universe
Why is the “quality” of energy decreasing in the universe?
See AnswerQ: What experimental evidence about a new compound must be known before its
What experimental evidence about a new compound must be known before its formula can be determined?
See AnswerQ: Explain to a friend who has not yet taken a chemistry course
Explain to a friend who has not yet taken a chemistry course what is meant by the empirical formula of a compound.
See AnswerQ: Give the empirical formula that corresponds to each of the following molecular
Give the empirical formula that corresponds to each of the following molecular formulas. a. sodium peroxide, Na2O2 b. terephthalic acid, C8H6O4 c. phenobarbital, C12H12N2O3 d. 1,4-dichloro-2-buten...
See AnswerQ: Which of the following pairs of compounds have the same empirical formula
Which of the following pairs of compounds have the same empirical formula? a. acetylene, C2H2, and benzene, C6H6 b. ethane, C2H6, and butane, C4H10 c. nitrogen dioxide, NO2, and dinitrogen tetroxid...
See AnswerQ: What are the four “stages” of coal formation? How
What are the four “stages” of coal formation? How do the four types of coal differ?
See AnswerQ: Are the following processes exothermic or endothermic? a. When
Are the following processes exothermic or endothermic? a. When solid KBr is dissolved in water, the solution gets colder. b. Natural gas (CH4) is burned in a furnace. c. When concentrated sulfuric...
See AnswerQ: A is some factor that tends to make a process occur.
A is some factor that tends to make a process occur.
See AnswerQ: The text explains that one reason why the actual yield for a
The text explains that one reason why the actual yield for a reaction may be less than the theoretical yield is side reactions. Suggest some other reasons why the percent yield for a reaction might no...
See AnswerQ: Calculate the number of moles of the indicated substance in each of
Calculate the number of moles of the indicated substance in each of the following samples. a. 41.5 g of MgCl2 b. 135 mg of Li2O c. 1.21 kg of Cr d. 62.5 g of H2SO4 e. 42.7 g of C6H6 f. 135 g of...
See AnswerQ: By now, you are familiar with enough chemical compounds to begin
By now, you are familiar with enough chemical compounds to begin to write your own chemical reaction equations. Write two examples of what we mean by a combustion reaction.
See AnswerQ: According to his prelaboratory theoretical yield calculations, a student’s experiment should
According to his prelaboratory theoretical yield calculations, a student’s experiment should have produced 1.44 g of magnesium oxide. When he weighed his product after reaction, only 1.23 g of magnesi...
See AnswerQ: Balance each of the following equations that describe synthesis reactions.
Balance each of the following equations that describe synthesis reactions. a. CaO(s) + H2O(l) Ca(OH)2(s) b. Fe(s) + O2(g) Fe2O3(s) c. P2O5(s) + H2O(l)...
See AnswerQ: Balance each of the following equations that describe synthesis reactions.
Balance each of the following equations that describe synthesis reactions. a. Fe(s) + S8(s) FeS(s) b. Co(s) + O2(g) Co2O3(s) c. Cl2O7(g) + H2O(l) HClO4(aq)
See AnswerQ: Balance each of the following equations that describe decomposition reactions.
Balance each of the following equations that describe decomposition reactions. a. CaSO4(s) CaO(s) + SO3(g) b. Li2CO3(s) Li2O(s) + CO2(g) c. LiHCO3(s) Li2CO3...
See AnswerQ: Balance each of the following equations that describe oxidation– reduction reactions
Balance each of the following equations that describe oxidation– reduction reactions. a. Al(s) + Br2(l) AlBr3(s) b. Zn(s) + HClO4(aq) Zn(ClO4)2(aq) + H2(g) c. Na(s) +...
See AnswerQ: When 3.269 g of zinc is heated in pure oxygen
When 3.269 g of zinc is heated in pure oxygen, the sample gains 0.800 g of oxygen in forming the oxide. Calculate the empirical formula of zinc oxide.
See AnswerQ: Which of the following ions form compounds with Ag+ that are
Which of the following ions form compounds with Ag+ that are generally soluble in water? a. S2- b. Cl2 c. NO3- d. SO42- e. Na+
See AnswerQ: Without first writing a full molecular or ionic equation, write the
Without first writing a full molecular or ionic equation, write the net ionic equations for any precipitation reactions that occur when aqueous solutions of the following compounds are mixed. If no re...
See AnswerQ: Complete and balance each of the following molecular equations for strong acid
Complete and balance each of the following molecular equations for strong acid/strong base reactions. Underline the formula of the salt produced in each reaction. a. HNO3(aq) + KOH(aq)...
See AnswerQ: Calculate the number of moles of the indicated substance present in each
Calculate the number of moles of the indicated substance present in each of the following samples. a. 1.95 * 10-3 g of lithium carbonate b. 4.23 kg of calcium chloride c. 1.23 mg of strontium chlor...
See AnswerQ: A favorite demonstration among chemistry instructors, to show that the properties
A favorite demonstration among chemistry instructors, to show that the properties of a compound differ from those of its constituent elements, involves iron filings and powdered sulfur. If the instruc...
See AnswerQ: Which of the following correctly identifies the precipitate formed when aqueous solutions
Which of the following correctly identifies the precipitate formed when aqueous solutions of the following substances are mixed? Mixed Solutions……………………………………Precipitate Formed a. Na2SO4 (aq) + BaCl...
See AnswerQ: When 1.00 mg of lithium metal is reacted with fluorine
When 1.00 mg of lithium metal is reacted with fluorine gas (F2), the resulting fluoride salt has a mass of 3.73 mg. Calculate the empirical formula of lithium fluoride.
See AnswerQ: Below are indicated the formulas of some salts. Such salts could
Below are indicated the formulas of some salts. Such salts could be formed by the reaction of the appropriate strong acid and strong base (with the other product of the reaction being, of course, wate...
See AnswerQ: For each of the following unbalanced molecular equations, write the corresponding
For each of the following unbalanced molecular equations, write the corresponding balanced net ionic equation for the reaction. a. HCl(aq) + AgNO3(aq) AgCl(s) + HNO3(aq) b. CaCl...
See AnswerQ: Write the balanced molecular, complete ionic, and net ionic equations
Write the balanced molecular, complete ionic, and net ionic equations for the reaction of ammonium sulfide with iron(III) chloride.
See AnswerQ: What strong acid and what strong base would react in aqueous solution
What strong acid and what strong base would react in aqueous solution to produce the following salts? a. potassium perchlorate, KClO4 b. cesium nitrate, CsNO3 c. potassium chloride, KCl d. sodium...
See AnswerQ: For the reaction 2Al(s) + 3I2(s)
For the reaction 2Al(s) + 3I2(s) 2AlI3(s), show how electrons are gained and lost by the atoms.
See AnswerQ: For the reaction 16Fe(s) + 3S8(s)
For the reaction 16Fe(s) + 3S8(s) 8Fe2S3(s), show how electrons are gained and lost by the atoms.
See AnswerQ: A compound with empirical formula C2H5O was found in a separate experiment
A compound with empirical formula C2H5O was found in a separate experiment to have a molar mass of approximately 90 g. What is the molecular formula of the compound?
See AnswerQ: Calculate the mass in grams of each of the following samples.
Calculate the mass in grams of each of the following samples. a. 1.25 moles of aluminum chloride b. 3.35 moles of sodium hydrogen carbonate c. 4.25 millimoles of hydrogen bromide (1 millimole = 1⁄1...
See AnswerQ: What are the molecular and empirical formulas for the following molecule?
What are the molecular and empirical formulas for the following molecule? Explain your reasoning.
See AnswerQ: Which of the following statements is/are true regarding solutions?
Which of the following statements is/are true regarding solutions? a. If a solute is dissolved in water, then the resulting solution is considered aqueous. b. If two solutions are mixed and no chemi...
See AnswerQ: Balance each of the following equations that describe synthesis reactions.
Balance each of the following equations that describe synthesis reactions. a. FeO(s) + O2(g) Fe2O3(s) b. CO(g) + O2(g) CO2(g) c. H2(g) + Cl2(g)...
See AnswerQ: Balance each of the following equations that describe decomposition reactions.
Balance each of the following equations that describe decomposition reactions. a. NaHCO3(s) Na2CO3(s) + H2O(g) + CO2(g) b. NaClO3(s) NaCl(s)...
See AnswerQ: A compound with empirical formula CH was found by experiment to have
A compound with empirical formula CH was found by experiment to have a molar mass of approximately 78 g. What is the molecular formula of the compound?
See AnswerQ: A compound with the empirical formula CH2 was found to have a
A compound with the empirical formula CH2 was found to have a molar mass of approximately 84 g. What is the molecular formula of the compound?
See AnswerQ: True or false? For the reaction represented by the balanced chemical
True or false? For the reaction represented by the balanced chemical equation Mg(OH)2(aq) + 2HCl(aq) 2H2O(l) + MgCl2(aq) for 0.40 mole of Mg(OH)2, 0.20 mol of HCl will be needed.
See AnswerQ: For each of the following metals, how many electrons will the
For each of the following metals, how many electrons will the metal atoms lose when the metal reacts with a nonmetal? a. sodium b. potassium c. magnesium d. barium e. aluminum
See AnswerQ: For each of the following nonmetals, how many electrons will each
For each of the following nonmetals, how many electrons will each atom of the nonmetal gain in reacting with a metal? a. oxygen b. fluorine c. nitrogen d. chlorine e. sulfur
See AnswerQ: Hydrogen gas reacts with each of the halogen elements to form the
Hydrogen gas reacts with each of the halogen elements to form the hydrogen halides (HF, HCl, HBr, HI). Calculate the percent by mass of hydrogen in each of these compounds.
See AnswerQ: Calculate the mass in grams of each of the following samples.
Calculate the mass in grams of each of the following samples. a. 6.14 * 10-4 moles of sulfur trioxide b. 3.11 * 105 moles of lead(IV) oxide c. 0.495 mole of chloroform, CHCl3 d. 2.45 * 10-8 moles...
See AnswerQ: Consider the balanced equation C3H8(g) + 5O2(
Consider the balanced equation C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(g) What mole ratio enables you to calculate the number of moles of oxygen needed to react exactly with a given number...
See AnswerQ: When a sodium chromate solution and aluminum bromide solution are mixed,
When a sodium chromate solution and aluminum bromide solution are mixed, a precipitate forms. Complete and balance the equation for this reaction, including the phases of each reactant and product.
See AnswerQ: Corrosion of metals costs us billions of dollars annually, slowly destroying
Corrosion of metals costs us billions of dollars annually, slowly destroying cars, bridges, and buildings. Corrosion of a metal involves the oxidation of the metal by the oxygen in the air, typically...
See AnswerQ: Consider a solution with the following ions present: NO3-,
Consider a solution with the following ions present: NO3-, Pb2+, K+, Ag+, Cl-, SO42-, PO43- All are allowed to react, and there are plenty available of each. List all of the solids that will form usi...
See AnswerQ: Find the item in column 2 that best explains or completes the
Find the item in column 2 that best explains or completes the statement or question in column 1. Column 1 (1) 1 amu (2) 1008 amu (3) mass of the “average” atom of an element (4) number of carbon a...
See AnswerQ: For the following chemical reactions, determine the precipitate produced when the
For the following chemical reactions, determine the precipitate produced when the two reactants listed below are mixed together. Indicate ânoneâ if no precipitate w...
See AnswerQ: For the following chemical reactions, determine the precipitate produced when the
For the following chemical reactions, determine the precipitate produced when the two reactants listed below are mixed together. Indicate ânoneâ if no precipitate w...
See AnswerQ: Given that the molar mass of carbon tetrachloride, CCl4, is
Given that the molar mass of carbon tetrachloride, CCl4, is 153.8 g, calculate the mass in grams of 1 molecule of CCl4.
See AnswerQ: You have a sample of copper (Cu) and a sample
You have a sample of copper (Cu) and a sample of aluminum (Al). You have an equal number of atoms in each sample. Which of the following statements concerning the masses of the samples is true? a. Th...
See AnswerQ: A compound was analyzed and found to contain the following percentages of
A compound was analyzed and found to contain the following percentages of elements by mass: carbon, 79.89%; hydrogen, 20.11%. a. Determine the empirical formula of the compound. b. Which of the foll...
See AnswerQ: Calculate the mass in grams of each of the following samples.
Calculate the mass in grams of each of the following samples. a. 0.251 mole of ethyl alcohol, C2H6O b. 1.26 moles of carbon dioxide c. 9.31 * 10-4 moles of gold(III) chloride d. 7.74 moles of sodi...
See AnswerQ: Calculate the number of grams of lithium that contain the same number
Calculate the number of grams of lithium that contain the same number of atoms as 1.00 kg of zirconium.
See AnswerQ: A certain transition metal ion (Mn+) forms a compound with
A certain transition metal ion (Mn+) forms a compound with oxygen (MxOy). The molar mass of the compound is 250.2 g/ mol. If the charge on the transition metal ion is 13, what is the identity of the t...
See AnswerQ: Although exact isotopic masses are known with great precision for most elements
Although exact isotopic masses are known with great precision for most elements, we use the average mass of an element’s atoms in most chemical calculations. Explain.
See AnswerQ: Using the average atomic masses given in Table 8.1,
Using the average atomic masses given in Table 8.1, calculate the number of atoms present in each of the following samples. a. 160,000 amu of oxygen b. 8139.81 amu of nitrogen c. 13,490 amu of alum...
See AnswerQ: If an average sodium atom weighs 22.99 amu, how
If an average sodium atom weighs 22.99 amu, how many sodium atoms are contained in 1.98 * 1013 amu of sodium? What will 3.01 * 1023 sodium atoms weigh?
See AnswerQ: If sodium peroxide is added to water, elemental oxygen gas is
If sodium peroxide is added to water, elemental oxygen gas is generated: Na2O2(s) + H2O(l) NaOH(aq) + O2(g) Suppose 3.25 g of sodium peroxide is added to a large excess of water. Wha...
See AnswerQ: Before going to lab, a student read in his lab manual
Before going to lab, a student read in his lab manual that the percent yield for a difficult reaction to be studied was likely to be only 40. % of the theoretical yield. The student’s prelab stoichiom...
See AnswerQ: Consider the following unbalanced chemical equation for the combustion of pentane (
Consider the following unbalanced chemical equation for the combustion of pentane (C5H12): C5H12(l) + O2(g) CO2(g) + H2O(l) If a 20.4-gram sample of pentane is burned in...
See AnswerQ: A 0.4230-g sample of impure sodium nitrate (
A 0.4230-g sample of impure sodium nitrate (contains sodium nitrate plus inert ingredients) was heated, converting all the sodium nitrate to 0.2339 g of sodium nitrite and oxygen gas. Determine the pe...
See AnswerQ: Calculate the mass in grams of each of the following samples.
Calculate the mass in grams of each of the following samples. a. 0.994 mole of benzene, C6H6 b. 4.21 moles of calcium hydride c. 1.79 * 10-4 moles of hydrogen peroxide, H2O2 d. 1.22 mmol of glucos...
See AnswerQ: Consider the following unbalanced chemical equation. LiOH(s)
Consider the following unbalanced chemical equation. LiOH(s) + CO2(g) / Li2CO3(s) + H2O(l) If 67.4 g of lithium hydroxide reacts with excess carbon dioxide, what mass of lithium carbonate will be pro...
See AnswerQ: Consider the following unbalanced chemical equation: H2S(g)
Consider the following unbalanced chemical equation: H2S(g) + O2(g) SO2(g) + H2O(g) Determine the maximum number of moles of SO2 produced from 8.0 moles of H2S and 3.0 moles...
See AnswerQ: What do we mean by thermodynamics? What is the first law
What do we mean by thermodynamics? What is the first law of thermodynamics?
See AnswerQ: The energy, E, of a system represents the sum of
The energy, E, of a system represents the sum of the kinetic and potential energies of all particles within the system.
See AnswerQ: Calculate ∆E for each of the following cases. a
Calculate ∆E for each of the following cases. a. q = +65 kJ, w = -22 kJ b. q = +200. kJ, w = -73 kJ c. q = -18 kJ, w = -40. kJ
See AnswerQ: If q for a process is a positive number, then the
If q for a process is a positive number, then the system is (gaining/losing) energy.
See AnswerQ: For an endothermic process, q will have a (positive/
For an endothermic process, q will have a (positive/negative) sign.
See AnswerQ: How many anions are there in 5.00 g of calcium
How many anions are there in 5.00 g of calcium bromide?
See AnswerQ: What is meant by potential energy? Give an example of an
What is meant by potential energy? Give an example of an object or material that possesses potential energy.
See AnswerQ: The percent by mass of nitrogen is 46.7% for
The percent by mass of nitrogen is 46.7% for a species containing only nitrogen and oxygen. Which of the following could be this species? a. N2O5 b. N2O c. NO2 d. NO e. NO3
See AnswerQ: Calculate the number of molecules present in each of the following samples
Calculate the number of molecules present in each of the following samples. a. 4.75 mmol of phosphine, PH3 b. 4.75 g of phosphine, PH3 c. 1.25 * 10-2 g of lead(II) acetate, Pb(CH3CO2)2 d. 1.25 * 1...
See AnswerQ: A system absorbs 215 kJ of heat, and 116 kJ of
A system absorbs 215 kJ of heat, and 116 kJ of work is done on it. Calculate ∆E.
See AnswerQ: What mass of sodium hydroxide has the same number of oxygen atoms
What mass of sodium hydroxide has the same number of oxygen atoms as 100.0 g of ammonium carbonate?
See AnswerQ: Write the conversion factors that would be necessary to perform each of
Write the conversion factors that would be necessary to perform each of the following conversions: a. an energy given in calories to its equivalent in joules b. an energy given in joules to its equi...
See AnswerQ: Topical hydrocortisone is often used to treat a variety of skin conditions
Topical hydrocortisone is often used to treat a variety of skin conditions, such as insect bites, eczema, and rashes. Each molecule of hydrocortisone contains 21 atoms of carbon (plus other atoms). Th...
See AnswerQ: If 8.40 kJ of heat is needed to raise the
If 8.40 kJ of heat is needed to raise the temperature of a sample of metal from 15 °C to 20 °C, how many kilojoules of heat will be required to raise the temperature of the same sample of metal from 2...
See AnswerQ: If it takes 654 J of energy to warm a 5.
If it takes 654 J of energy to warm a 5.51-g sample of water, how much energy would be required to warm 55.1 g of water by the same amount?
See AnswerQ: Convert the following numbers of calories or kilocalories into joules and kilojoules
Convert the following numbers of calories or kilocalories into joules and kilojoules (Remember: kilo means 1000.) a. 75.2 kcal b. 75.2 cal c. 1.41 * 103 cal d. 1.41 kcal
See AnswerQ: Convert the following numbers of calories into kilocalories. (Remember:
Convert the following numbers of calories into kilocalories. (Remember: kilo means 1000.) a. 8254 cal b. 41.5 cal c. 8.231 * 103 cal d. 752,900 cal
See AnswerQ: Calculate the number of moles for each compound in the following table
Calculate the number of moles for each compound in the following table.
See AnswerQ: a. How many atoms of carbon are present in 1.
a. How many atoms of carbon are present in 1.0 g of CH4O? b. How many atoms of carbon are present in 1.0 g of CH3CH2OH? c. How many atoms of nitrogen are present in 25.0 g of CO(NH2)2?
See AnswerQ: How are the different types of electromagnetic radiation similar? How do
How are the different types of electromagnetic radiation similar? How do they differ?
See AnswerQ: Calculate the number of molecules present in each of the following samples
Calculate the number of molecules present in each of the following samples. a. 3.54 moles of sulfur dioxide, SO2 b. 3.54 g of sulfur dioxide, SO2 c. 4.46 * 1025 g of ammonia, NH3 d. 4.46 * 1025 mo...
See AnswerQ: Convert the following numbers of kilojoules into kilocalories. (Remember:
Convert the following numbers of kilojoules into kilocalories. (Remember: kilo means 1000.) a. 652.1 kJ b. 1.00 kJ c. 4.184 kJ d. 4.351 * 103 kJ
See AnswerQ: The chemical formula for aspirin is C9H8O4. What is the mass
The chemical formula for aspirin is C9H8O4. What is the mass percent for each element in 1 mole of aspirin? (Give your answer to four significant figures.)
See AnswerQ: Arrange the following substances in order of increasing mass percent of nitrogen
Arrange the following substances in order of increasing mass percent of nitrogen. a. NO b. N2O c. NH3 d. SNH
See AnswerQ: Perform the indicated conversions. a. 625.2 cal
Perform the indicated conversions. a. 625.2 cal into kilojoules b. 82.41 kJ into joules c. 52.61 kcal into joules d. 124.2 kJ into kilocalories
See AnswerQ: What is the kinetic energy of a particle of mass m moving
What is the kinetic energy of a particle of mass m moving through space with velocity ν?
See AnswerQ: Perform the indicated conversions. a. 91.74 kcal
Perform the indicated conversions. a. 91.74 kcal into calories b. 1.781 kJ into calories c. 4.318 * 103 J into kilocalories d. 9.173 * 104 cal into kilojoules
See AnswerQ: If 69.5 kJ of heat is applied to a 1012
If 69.5 kJ of heat is applied to a 1012-g block of metal, the temperature of the metal increases by 11.4 8(C. Calculate the specific heat capacity of the metal in J/g 8(C.
See AnswerQ: What quantity of heat energy must have been applied to a block
What quantity of heat energy must have been applied to a block of aluminum weighing 42.7 g if the temperature of the block of aluminum increased by 15.2 °C? (See Table 10.1.) Table 10.1
See AnswerQ: If 125 J of heat energy is applied to a block of
If 125 J of heat energy is applied to a block of silver weighing 29.3 g, by how many degrees will the temperature of the silver increase? (See Table 10.1.)
See AnswerQ: If 100. J of heat energy is applied to a 25
If 100. J of heat energy is applied to a 25-g sample of mercury, by how many degrees will the temperature of the sample of mercury increase? (See Table 10.1.)
See AnswerQ: Calculate the number of moles of carbon atoms present in each of
Calculate the number of moles of carbon atoms present in each of the following samples. a. 1.271 g of ethanol, C2H5OH b. 3.982 g of 1,4-dichlorobenzene, C6H4Cl2 c. 0.4438 g of carbon suboxide, C3O2...
See AnswerQ: What quantity of heat is required to raise the temperature of 55
What quantity of heat is required to raise the temperature of 55.5 g of gold from 20 8C to 45 8C? (See Table 10.1.)
See AnswerQ: The “Chemistry in Focus” segment Coffee: Hot and Quick
The “Chemistry in Focus” segment Coffee: Hot and Quick(lime) discusses self-heating cups of coffee using the chemical reaction between quicklime, CaO(s), and water. Is this reaction endothermic or exo...
See AnswerQ: In the “Chemistry in Focus” segment Firewalking: Magic or
In the “Chemistry in Focus” segment Firewalking: Magic or Science?, it is claimed that one reason people can walk on hot coals is that human tissue is mainly composed of water. Because of this, a larg...
See AnswerQ: The enthalpy change for a reaction that occurs at constant pressure is
The enthalpy change for a reaction that occurs at constant pressure is (higher than/lower than/the same as) the heat for that reaction.
See AnswerQ: The “Chemistry in Focus” segment Burning Calories discusses calories in
The “Chemistry in Focus” segment Burning Calories discusses calories in food. If a food is said to contain 350 calories per serving, determine this value in terms of joules.
See AnswerQ: Where did the energy stored in wood, coal, petroleum,
Where did the energy stored in wood, coal, petroleum, and natural gas originally come from?
See AnswerQ: What does natural gas consist of? Where is natural gas commonly
What does natural gas consist of? Where is natural gas commonly found?
See AnswerQ: What was tetraethyl lead used for in the petroleum industry? Why
What was tetraethyl lead used for in the petroleum industry? Why is it no longer commonly used?
See AnswerQ: What does it mean to say that “energy spread” and
What does it mean to say that “energy spread” and “matter spread” are driving forces in chemical reactions?
See AnswerQ: Calculate the number of moles of sulfur atoms present in each of
Calculate the number of moles of sulfur atoms present in each of the following samples. a. 2.01 g of sodium sulfate b. 2.01 g of sodium sulfite c. 2.01 g of sodium sulfide d. 2.01 g of sodium thio...
See AnswerQ: If a reaction occurs readily but has an endothermic heat of reaction
If a reaction occurs readily but has an endothermic heat of reaction, what must be the driving force for the reaction?
See AnswerQ: Does a double-displacement reaction such as NaCl(aq
Does a double-displacement reaction such as NaCl(aq) + AgNO3(aq) AgCl(s) + NaNO3(aq) result in a matter spread or in a concentration of matter?
See AnswerQ: What do we mean by entropy? Why does the entropy of
What do we mean by entropy? Why does the entropy of the universe increase during a spontaneous process?
See AnswerQ: A chunk of ice at room temperature melts, even though the
A chunk of ice at room temperature melts, even though the process is endothermic. Why?
See AnswerQ: Which of the following is an endothermic process? a.
Which of the following is an endothermic process? a. combustion of gasoline in a car engine b. sublimation of carbon dioxide; CO2(s) CO2(g) c. water condensing on a cold pipe d. freezing...
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. Energy is changed in form in a process, but it is not produced or consumed. b. Heat is a flow of energy between two objects due to a temperature di...
See AnswerQ: Perform the indicated conversions. a. 85.21 cal
Perform the indicated conversions. a. 85.21 cal into joules b. 672.1 J into calories c. 8.921 kJ into joules d. 556.3 cal into kilojoules
See AnswerQ: Calculate the amount of energy required (in calories) to heat
Calculate the amount of energy required (in calories) to heat 145 g of water from 22.3 °C to 75.0 °C.
See AnswerQ: It takes 1.25 kJ of energy to heat a certain
It takes 1.25 kJ of energy to heat a certain sample of pure silver from 12.0 °C to 15.2 °C. Calculate the mass of the sample of silver.
See AnswerQ: Students often confuse what is meant by heat and temperature. Define
Students often confuse what is meant by heat and temperature. Define each. How are the two concepts related?
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this book, calculate the number of moles of each substance contained in the following masses. a. 2.01 * 10-2 g of silver b. 45.2 mg of...
See AnswerQ: What quantity of heat energy would have to be applied to a
What quantity of heat energy would have to be applied to a 25.1-g block of iron in order to raise the temperature of the iron sample by 17.5 °C? (See Table 10.1.)
See AnswerQ: The specific heat capacity of gold is 0.13 J/
The specific heat capacity of gold is 0.13 J/g °C. Calculate the specific heat capacity of gold in cal/g °C.
See AnswerQ: Calculate the amount of energy required (in joules) to heat
Calculate the amount of energy required (in joules) to heat 2.5 kg of water from 18.5 °C to 55.0 °C.
See AnswerQ: If 10. J of heat is applied to 5.0
If 10. J of heat is applied to 5.0-g samples of each of the substances listed in Table 10.1, which substance’s temperature will increase the most? Which substance’s temperature will increase the least...
See AnswerQ: If 7.24 kJ of heat is applied to a 952
If 7.24 kJ of heat is applied to a 952-g block of metal, the temperature increases by 10.7 °C. Calculate the specific heat capacity of the metal in J/g °C.
See AnswerQ: A system releases 213 kJ of heat and has a calculated ∆
A system releases 213 kJ of heat and has a calculated ∆E of -45 kJ. How much work was done on the system?
See AnswerQ: Calculate ∆E for each of the following. a.
Calculate ∆E for each of the following. a. q = -47 kJ, w = +88 kJ b. q = +82 kJ, w = +47 kJ c. q = +47 kJ, w = 0 d. In which of these cases do the surroundings do work on the system?
See AnswerQ: Calculate the enthalpy change when 5.00 g of propane is
Calculate the enthalpy change when 5.00 g of propane is burned with excess oxygen according to the reaction C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(l) ∆H = -2221 kJ/mol
See AnswerQ: Which of the following processes is(are) exothermic?
Which of the following processes is(are) exothermic? a. combustion of methane (e.g., Bunsen burner) b. melting of ice c. evaporation of acetone (e.g., fingernail polish remover) d. steam condensin...
See AnswerQ: The specific heat capacity of graphite is 0.71 J/
The specific heat capacity of graphite is 0.71 J/g °C. Calculate the energy required to raise the temperature of 2.4 moles of graphite by 25.0 °C.
See AnswerQ: Using the average atomic masses given inside the front cover of this
Using the average atomic masses given inside the front cover of this book, calculate the mass in grams of each of the following samples. a. 2.17 moles of germanium, Ge b. 4.24 mmol of lead(II) chlor...
See AnswerQ: Consider the reaction B2H6(g) + 3O2(g
Consider the reaction B2H6(g) + 3O2(g) B2O3(s) + 3H2O(g) ∆H = -2035 kJ Calculate the amount of heat released when 54.0 g of diborane is combusted.
See AnswerQ: The random motions of the components of an object constitute the of
The random motions of the components of an object constitute the of that object.
See AnswerQ: An atom has a small charged core called the nucleus, with
An atom has a small charged core called the nucleus, with charged electrons moving in the space around the nucleus.
See AnswerQ: The energy of a photon of visible light emitted by an excited
The energy of a photon of visible light emitted by an excited atom is the energy change that takes place within the atom itself.
See AnswerQ: Light waves move through space at a speed of meters per second
Light waves move through space at a speed of meters per second.
See AnswerQ: How does the attractive force that the nucleus exerts on an electron
How does the attractive force that the nucleus exerts on an electron change with the principal energy level of the electron?
See AnswerQ: Based on the ground-state electron configuration of iodine, how
Based on the ground-state electron configuration of iodine, how many electrons occupy the p and d orbitals?
See AnswerQ: Element X, which has a valence shell configuration of ns2np4,
Element X, which has a valence shell configuration of ns2np4, was isolated in a laboratory. Which of the following statements is(are) true concerning element X? a. Element X has chemical properties s...
See AnswerQ: Write the full electron configuration (1s22s2, etc.) for each
Write the full electron configuration (1s22s2, etc.) for each of the following elements. a. bromine, Z = 35 b. xenon, Z = 54 c. barium, Z = 56 d. selenium, Z = 34
See AnswerQ: Write the complete orbital diagram for each of the following elements,
Write the complete orbital diagram for each of the following elements, using boxes to represent orbitals and arrows to represent electrons. a. scandium, Z = 21 b. sulfur, Z = 16 c. potassium, Z = 1...
See AnswerQ: Calculate the percent by mass of each element in the following compounds
Calculate the percent by mass of each element in the following compounds. a. HClO3 b. UF4 c. CaH2 d. Ag2S e. NaHSO3 f. MnO2
See AnswerQ: What does the ground state of an atom represent?
What does the ground state of an atom represent?
See AnswerQ: How many valence electrons does each of the following atoms have?
How many valence electrons does each of the following atoms have? a. nitrogen, Z = 7 b. chlorine, Z = 17 c. sodium, Z = 11 d. aluminum, Z = 13
See AnswerQ: What name is given to the series of ten elements in which
What name is given to the series of ten elements in which the electrons are filling the 3d sublevel?
See AnswerQ: Rank the following elements in order of increasing atomic size: Ge
Rank the following elements in order of increasing atomic size: Ge, S, F, Rb, Mn.
See AnswerQ: Using the symbol of the previous noble gas to indicate core electrons
Using the symbol of the previous noble gas to indicate core electrons, write the valence shell electron configuration for each of the following elements. a. titanium, Z = 22 b. selenium, Z = 34 c....
See AnswerQ: Arrange the following atoms in order of increasing size (assuming all
Arrange the following atoms in order of increasing size (assuming all atoms are in their ground states). a. [Kr]5s24d105p6 b. [Kr]5s24d105p1 c. [Kr]5s24d105p3
See AnswerQ: Write the shorthand valence shell electron configuration of each of the following
Write the shorthand valence shell electron configuration of each of the following elements, basing your answer on the element’s location on the periodic table. a. nickel, Z = 28 b. niobium, Z = 41...
See AnswerQ: Which of the following statements about the periodic table is false?
Which of the following statements about the periodic table is false? a. Elements in the same column have similar reactivities because their valence electrons tend to be located in the same types of o...
See AnswerQ: In each of the following sets of elements, indicate which element
In each of the following sets of elements, indicate which element shows the most active chemical behavior. a. B, Al, In b. Na, Al, S c. B, C, F
See AnswerQ: In each of the following sets of elements, indicate which element
In each of the following sets of elements, indicate which element has the smallest atomic size. a. Ba, Ca, Ra b. P, Si, Al c. Rb, Cs, K
See AnswerQ: Calculate the percent by mass of each element in the following compounds
Calculate the percent by mass of each element in the following compounds. a. ZnO b. Na2S c. Mg(OH)2 d. H2O2 e. CaH2 f. K2O
See AnswerQ: Determine the maximum number of electrons that can have each of the
Determine the maximum number of electrons that can have each of the following designations: 2f, 2dxy, 3p, 5dyz, and 4p.
See AnswerQ: An excited atom can release some or all of its excess energy
An excited atom can release some or all of its excess energy by emitting a(n) and thus move to a lower energy state.
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. The 2s orbital in the hydrogen atom is larger than the 3s orbital also in the hydrogen atom. b. The Bohr model of the hydrogen atom has been found...
See AnswerQ: Give the electron configurations for the following atoms. Do not use
Give the electron configurations for the following atoms. Do not use the noble gas notation. Write out the complete electron configuration.
See AnswerQ: Identify the following three elements. a. The ground-
Identify the following three elements. a. The ground-state electron configuration is [Kr]5s24d105p4. b. The ground-state electron configuration is [Ar]4s23d104p2. c. An excited state of this elemen...
See AnswerQ: Give the electron configurations for the following atoms. Use the noble
Give the electron configurations for the following atoms. Use the noble gas notation.
See AnswerQ: Compare the atomic sizes of each pair of atoms. State the
Compare the atomic sizes of each pair of atoms. State the larger atom for each pair.
See AnswerQ: Compare the ionization energies of each pair of atoms. State the
Compare the ionization energies of each pair of atoms. State the atom with the larger ionization energy for each pair.
See AnswerQ: Three elements have the electron configurations 1s22s22p63s2, 1s22s22p63s23p4, and 1s22s22p63s23p64s2
Three elements have the electron configurations 1s22s22p63s2, 1s22s22p63s23p4, and 1s22s22p63s23p64s2. The first ionization energies of these elements (not in the same order) are 0.590, 0.999, and 0.7...
See AnswerQ: How is the energy carried per photon of light related to the
How is the energy carried per photon of light related to the wavelength of the light? Does short-wavelength light carry more energy or less energy than long-wavelength light?
See AnswerQ: Calculate the percent by mass of the element listed first in the
Calculate the percent by mass of the element listed first in the formulas for each of the following compounds. a. methane, CH4 b. sodium nitrate, NaNO3 c. carbon monoxide, CO d. nitrogen dioxide,...
See AnswerQ: When an atom energy from outside, the atom goes from a
When an atom energy from outside, the atom goes from a lower energy state to a higher energy state.
See AnswerQ: Because a given element’s atoms emit only certain photons of light,
Because a given element’s atoms emit only certain photons of light, only certain are occurring in those particular atoms.
See AnswerQ: How does the energy possessed by an emitted photon compare to the
How does the energy possessed by an emitted photon compare to the difference in energy levels that gave rise to the emission of the photon?
See AnswerQ: The energy levels of hydrogen (and other atoms) are said
The energy levels of hydrogen (and other atoms) are said to be , which means that only certain energy values are allowed.
See AnswerQ: What questions were left unanswered by Rutherford’s experiments?
What questions were left unanswered by Rutherford’s experiments?
See AnswerQ: When a tube containing hydrogen atoms is energized by passing several thousand
When a tube containing hydrogen atoms is energized by passing several thousand volts of electricity into the tube, the hydrogen emits light that, when passed through a prism, resolves into the â...
See AnswerQ: What are the essential points of Bohr’s theory of the structure of
What are the essential points of Bohr’s theory of the structure of the hydrogen atom?
See AnswerQ: According to Bohr, what happens to the electron when a hydrogen
According to Bohr, what happens to the electron when a hydrogen atom absorbs a photon of light of sufficient energy?
See AnswerQ: Why was Bohr’s theory for the hydrogen atom initially accepted, and
Why was Bohr’s theory for the hydrogen atom initially accepted, and why was it ultimately discarded?
See AnswerQ: Discuss briefly the difference between an orbit (as described by Bohr
Discuss briefly the difference between an orbit (as described by Bohr for hydrogen) and an orbital (as described by the more modern, wave mechanical picture of the atom).
See AnswerQ: Calculate the percent by mass of the element listed first in the
Calculate the percent by mass of the element listed first in the formulas for each of the following compounds. a. copper(II) bromide, CuBr2 b. copper(I) bromide, CuBr c. iron(II) chloride, FeCl2 d...
See AnswerQ: In the 1920s, de Broglie and Schrödinger developed what is now
In the 1920s, de Broglie and Schrödinger developed what is now called wave mechanics or quantum mechanics. Which of the following statements with regard to this model is(are) true? a. The position of...
See AnswerQ: What is electromagnetic radiation? At what speed does electromagnetic radiation travel
What is electromagnetic radiation? At what speed does electromagnetic radiation travel?
See AnswerQ: Consider the following representation of a set of p orbitals for an
Consider the following representation of a set of p orbitals for an atom: Which of the following statements is(are) true? a. The areas represented by the p orbitals are positively charged clouds wi...
See AnswerQ: What are the differences between the 2s orbital and the 1s orbital
What are the differences between the 2s orbital and the 1s orbital of hydrogen? How are they similar?
See AnswerQ: The higher the principal energy level, n, the (closer
The higher the principal energy level, n, the (closer to/farther from) the nucleus is the electron.
See AnswerQ: When the electron in hydrogen is in the n = 3 principal
When the electron in hydrogen is in the n = 3 principal energy level, the atom is in a/an state.
See AnswerQ: Calculate the percent by mass of the element listed first in the
Calculate the percent by mass of the element listed first in the formulas for each of the following compounds. a. adipic acid, C6H10O4 b. ammonium nitrate, NH4NO3 c. caffeine, C8H10N4O2 d. chlorin...
See AnswerQ: Using the average atomic masses for each of the following elements (
Using the average atomic masses for each of the following elements (see the table inside the cover of this book), calculate the mass (in amu) of each of the following samples. a. 125 carbon atoms b....
See AnswerQ: What is the mass percent of oxygen in each of the following
What is the mass percent of oxygen in each of the following compounds? a. carbon dioxide b. sodium nitrate c. iron(III) phosphate d. ammonium carbonate e. aluminum sulfate
See AnswerQ: For each of the following samples of ionic substances, calculate the
For each of the following samples of ionic substances, calculate the number of moles and mass of the positive ions present in each sample. a. 4.25 g of ammonium iodide, NH4I b. 6.31 moles of ammoniu...
See AnswerQ: For each of the following ionic substances, calculate the percentage of
For each of the following ionic substances, calculate the percentage of the overall molar mass of the compound that is represented by the negative ions in the substance. a. ammonium sulfide b. calci...
See AnswerQ: Lead(II) oxide from an ore can be reduced to
Lead(II) oxide from an ore can be reduced to elemental lead by heating in a furnace with carbon. PbO(s) + C(s) Pb(l) + CO(g) Calculate the expected yield of lead if 50.0 kg of lead...
See AnswerQ: If steel wool (iron) is heated until it glows and
If steel wool (iron) is heated until it glows and is placed in a bottle containing pure oxygen, the iron reacts spectacularly to produce iron(III) oxide. Fe(s) + O2(g) Fe2O3(s)...
See AnswerQ: A common method for determining how much chloride ion is present in
A common method for determining how much chloride ion is present in a sample is to precipitate the chloride from an aqueous solution of the sample with silver nitrate solution and then to weigh the si...
See AnswerQ: Although many sulfate salts are soluble in water, calcium sulfate is
Although many sulfate salts are soluble in water, calcium sulfate is not (Table 7.1). Therefore, a solution of calcium chloride will react with sodium sulfate solution to produce a precipitate of calc...
See AnswerQ: A compound was analyzed and was found to contain the following percentages
A compound was analyzed and was found to contain the following percentages of the elements by mass: barium, 89.56%; oxygen, 10.44%. Determine the empirical formula of the compound.
See AnswerQ: A compound was analyzed and was found to contain the following percentages
A compound was analyzed and was found to contain the following percentages of the elements by mass: nitrogen, 11.64%; chlorine, 88.36%. Determine the empirical formula of the compound.
See AnswerQ: A 0.5998-g sample of a new compound has
A 0.5998-g sample of a new compound has been analyzed and found to contain the following masses of elements: carbon, 0.2322 g; hydrogen, 0.05848 g; oxygen, 0.3091 g. Calculate the empirical formula of...
See AnswerQ: For each of the following reactions, give the balanced chemical equation
For each of the following reactions, give the balanced chemical equation for the reaction and state the meaning of the equation in terms of individual molecules and in terms of moles of molecules. a....
See AnswerQ: A compound was analyzed and was found to contain the following percentages
A compound was analyzed and was found to contain the following percentages of the elements by mass: boron, 78.14%; hydrogen, 21.86%. Determine the empirical formula of the compound.
See AnswerQ: If a 1.271-g sample of aluminum metal is
If a 1.271-g sample of aluminum metal is heated in a chlorine gas atmosphere, the mass of aluminum chloride produced is 6.280 g. Calculate the empirical formula of aluminum chloride.
See AnswerQ: By now, you are familiar with enough chemical compounds to begin
By now, you are familiar with enough chemical compounds to begin to write your own chemical reaction equations. Write two examples each of what we mean by a synthesis reaction and by a decomposition r...
See AnswerQ: A compound was analyzed and was found to contain the following percentages
A compound was analyzed and was found to contain the following percentages of the elements by mass: tin, 45.56%; chlorine, 54.43%. Determine the empirical formula of the compound.
See AnswerQ: If cobalt metal is mixed with excess sulfur and heated strongly,
If cobalt metal is mixed with excess sulfur and heated strongly, a sulfide is produced that contains 55.06% cobalt by mass. Calculate the empirical formula of the sulfide.
See AnswerQ: If 1.25 g of aluminum metal is heated in an
If 1.25 g of aluminum metal is heated in an atmosphere of fluorine gas, 3.89 g of aluminum fluoride results. Determine the empirical formula of aluminum fluoride.
See AnswerQ: If 2.50 g of aluminum metal is heated in a
If 2.50 g of aluminum metal is heated in a stream of fluorine gas, it is found that 5.28 g of fluorine will combine with the aluminum. Determine the empirical formula of the compound that results.
See AnswerQ: Distinguish between the molecular equation, the complete ionic equation, and
Distinguish between the molecular equation, the complete ionic equation, and the net ionic equation for a reaction in solution. Which type of equation most clearly shows the species that actually reac...
See AnswerQ: A compound was analyzed and was found to contain the following percentages
A compound was analyzed and was found to contain the following percentages of the elements by mass: lithium, 46.46%; oxygen, 53.54%. Determine the empirical formula of the compound.
See AnswerQ: A compound has the following percentage composition by mass: copper,
A compound has the following percentage composition by mass: copper, 33.88%; nitrogen, 14.94%; oxygen, 51.18%. Determine the empirical formula of the compound.
See AnswerQ: For each of the following reactions, give the balanced equation for
For each of the following reactions, give the balanced equation for the reaction and state the meaning of the equation in terms of the numbers of individual molecules and in terms of moles of molecule...
See AnswerQ: When lithium metal is heated strongly in an atmosphere of pure nitrogen
When lithium metal is heated strongly in an atmosphere of pure nitrogen, the product contains 59.78% Li and 40.22% N on a mass basis. Determine the empirical formula of the compound.
See AnswerQ: For the cations listed in the left-hand column, give
For the cations listed in the left-hand column, give the formulas of the precipitates that would form with each of the anions in the right-hand column. If no precipitate is expected for a particular c...
See AnswerQ: Tetraphenylporphyrin is a synthetic compound that resembles naturally occurring porphyrins. Porphyrins
Tetraphenylporphyrin is a synthetic compound that resembles naturally occurring porphyrins. Porphyrins are found in hemoglobin and cytochromes, which are important to biological functions in humans. T...
See AnswerQ: On the basis of the general solubility rules given in Table 7
On the basis of the general solubility rules given in Table 7.1, predict the identity of the precipitate that forms when aqueous solutions of the following substances are mixed. If no precipitate is l...
See AnswerQ: Phosphorus and chlorine form two binary compounds, in which the percentages
Phosphorus and chlorine form two binary compounds, in which the percentages of phosphorus are 22.55% and 14.87%, respectively. Calculate the empirical formulas of the two binary phosphorus–chlorine co...
See AnswerQ: How does the molecular formula of a compound differ from the empirical
How does the molecular formula of a compound differ from the empirical formula? Can a compound’s empirical and molecular formulas be the same? Explain.
See AnswerQ: A compound used in the nuclear industry has the following composition:
A compound used in the nuclear industry has the following composition: uranium, 67.61%; fluorine, 32.39%. Determine the empirical formula of the compound.
See AnswerQ: A binary compound of boron and hydrogen has the following percentage composition
A binary compound of boron and hydrogen has the following percentage composition: 78.14% boron, 21.86% hydrogen. If the molar mass of the compound is determined by experiment to be between 27 and 28 g...
See AnswerQ: A compound has been analyzed and has been found to have the
A compound has been analyzed and has been found to have the following composition: copper, 66.75%; phosphorus, 10.84%; oxygen, 22.41%. Determine the empirical formula of the compound.
See AnswerQ: Using the average atomic masses given inside the front cover of the
Using the average atomic masses given inside the front cover of the text, calculate how many moles of each substance the following masses represent. a. 4.21 g of copper(II) sulfate b. 7.94 g of bari...
See AnswerQ: If you spilled a cup of freshly brewed hot tea on yourself
If you spilled a cup of freshly brewed hot tea on yourself, you would be burned. If you spilled the same quantity of iced tea on yourself, you would not be burned. Explain.
See AnswerQ: Balance the equation for each of the following oxidation– reduction chemical
Balance the equation for each of the following oxidation– reduction chemical reactions. a. Na(s) + O2(g) Na2O2(s) b. Fe(s) + H2SO4(aq) FeSO4(aq) + H2(g) c. Al2O3(s)...
See AnswerQ: Identify each of the following unbalanced reaction equations as belonging to one
Identify each of the following unbalanced reaction equations as belonging to one or more of the following categories: precipitation, acid–base, or oxidation–reduction. a. Fe(s) + H2SO4(aq)...
See AnswerQ: A compound containing only sulfur and nitrogen is 69.6%
A compound containing only sulfur and nitrogen is 69.6% S by mass. The molar mass is 184 g/mol. What is the correct name for this compound?
See AnswerQ: Use the periodic table shown in Fig. 4.9 to
Use the periodic table shown in Fig. 4.9 to determine the atomic mass (per mole) or molar mass of each of the substances in column 1, and find that mass in column 2. Column 1â¦&ac...
See AnswerQ: Write a balanced oxidation–reduction equation for the reaction of each
Write a balanced oxidation–reduction equation for the reaction of each of the metals in the left-hand column with each of the nonmetals in the right-hand column. Ba……………O2 K………………S Mg…………..Cl2 Rb………....
See AnswerQ: Fill in the following table as if it is a well plate
Fill in the following table as if it is a well plate and you are mixing two aqueous compounds at a time to see if a precipitate forms. If a precipitate is expected to form, indicate that by writing th...
See AnswerQ: Although the metals of Group 2 of the periodic table are not
Although the metals of Group 2 of the periodic table are not nearly as reactive as those of Group 1, many of the Group 2 metals will combine with common nonmetals, especially at elevated temperatures....
See AnswerQ: When a 2.118-g sample of copper is heated
When a 2.118-g sample of copper is heated in an atmosphere in which the amount of oxygen present is restricted, the sample gains 0.2666 g of oxygen in forming a reddish-brown oxide. However, when 2.11...
See AnswerQ: A compound having an approximate molar mass of 165–170 g
A compound having an approximate molar mass of 165–170 g has the following percentage composition by mass: carbon, 42.87%; hydrogen, 3.598%; oxygen, 28.55%; nitrogen, 25.00%. Determine the empirical a...
See AnswerQ: Consider the balanced chemical equation 4Al(s) + 3O2
Consider the balanced chemical equation 4Al(s) + 3O2(g) 2Al2O3(s). What mole ratio would you use to calculate how many moles of oxygen gas would be needed to react comp...
See AnswerQ: True or false? When solutions of barium hydroxide and sulfuric acid
True or false? When solutions of barium hydroxide and sulfuric acid are mixed, the net ionic equation is: Ba2+(aq) + SO42-(aq) BaSO4(s) because only the species involved in making t...
See AnswerQ: Classify the reactions represented by the following unbalanced equations by as many
Classify the reactions represented by the following unbalanced equations by as many methods as possible. Balance the equations. a. I4O9(s) I2O6(s) + I2(s) + O2(g) b. Mg(s) +...
See AnswerQ: Calculate the mass of carbon in grams, the percent carbon by
Calculate the mass of carbon in grams, the percent carbon by mass, and the number of individual carbon atoms present in each of the following samples. a. 7.819 g of carbon suboxide, C3O2 b. 1.53 * 1...
See AnswerQ: Consider a hypothetical compound composed of elements X, Y, and
Consider a hypothetical compound composed of elements X, Y, and Z with the empirical formula X2YZ3. Given that the atomic masses of X, Y, and Z are 41.2, 57.7, and 63.9, respectively, calculate the pe...
See AnswerQ: Give a balanced molecular chemical equation to illustrate each of the following
Give a balanced molecular chemical equation to illustrate each of the following types of reactions. a. a synthesis (combination) reaction b. a precipitation reaction c. a double-displacement reacti...
See AnswerQ: A binary compound of magnesium and nitrogen is analyzed, and 1
A binary compound of magnesium and nitrogen is analyzed, and 1.2791 g of the compound is found to contain 0.9240 g of magnesium. When a second sample of this compound is treated with water and heated,...
See AnswerQ: Calculate the number of atoms of each element present in each of
Calculate the number of atoms of each element present in each of the following samples. a. 4.21 g of water b. 6.81 g of carbon dioxide c. 0.000221 g of benzene, C6H6 d. 2.26 moles of C12H22O11
See AnswerQ: Calculate the mass in grams of each of the following samples.
Calculate the mass in grams of each of the following samples. a. 10,000,000,000 nitrogen molecules b. 2.49 * 1020 carbon dioxide molecules c. 7.0983 moles of sodium chloride d. 9.012 * 10-6 moles...
See AnswerQ: Calculate the mass in grams of hydrogen present in 2.500
Calculate the mass in grams of hydrogen present in 2.500 g of each of the following compounds. a. benzene, C6H6 b. calcium hydride, CaH2 c. ethyl alcohol, C2H5OH d. serine, C3H7O3N
See AnswerQ: Which of the following substances exhibit hydrogen bonding interactions? a
Which of the following substances exhibit hydrogen bonding interactions? a. CCl2H2 b. BeF2 c. NO3- d. HCN
See AnswerQ: Some properties of potassium metal are summarized in the following table:
Some properties of potassium metal are summarized in the following table: Normal melting point…………………….63.5 °C Normal boiling point……………………765.7 °C Molar heat of fusion…………….2.334 kJ/mol Molar heat...
See AnswerQ: Are changes in state physical or chemical changes for molecular solids?
Are changes in state physical or chemical changes for molecular solids? Why?
See AnswerQ: Why is there no change in intramolecular forces when a solid is
Why is there no change in intramolecular forces when a solid is melted? Are intramolecular forces stronger or weaker than intermolecular forces?
See AnswerQ: The molar heat of vaporization of carbon disulfide, CS2, is
The molar heat of vaporization of carbon disulfide, CS2, is 28.4 kJ/mol at its normal boiling point of 46 °C. How much energy (heat) is required to vaporize 1.0 g of CS2 at 46 °C? How much heat is evo...
See AnswerQ: For each of the following sets of pressure/volume data,
For each of the following sets of pressure/volume data, calculate the new volume of the gas sample after the pressure change is made. Assume that the temperature and the amount of gas remain the same....
See AnswerQ: Which is stronger, a dipole–dipole attraction between two molecules
Which is stronger, a dipole–dipole attraction between two molecules or a covalent bond between two atoms within the same molecule? Explain.
See AnswerQ: For a liquid to boil, the intermolecular forces in the liquid
For a liquid to boil, the intermolecular forces in the liquid must be overcome. Based on the types of intermolecular forces present, arrange the expected boiling points of the liquid states of the fol...
See AnswerQ: Discuss the types of intermolecular forces acting in the liquid state of
Discuss the types of intermolecular forces acting in the liquid state of each of the following substances. a. N2 b. NH3 c. He d. CO2 (linear, nonpolar)
See AnswerQ: Discuss the types of intermolecular forces acting in the liquid state of
Discuss the types of intermolecular forces acting in the liquid state of each of the following substances. a. Ar b. H2O c. SeO2 d. BF3 (trigonal planar, nonpolar)
See AnswerQ: What do we mean when we say a liquid is volatile?
What do we mean when we say a liquid is volatile? Do volatile liquids have large or small vapor pressures? What types of intermolecular forces occur in highly volatile liquids?
See AnswerQ: Which type of bonding, ionic or covalent, generally results in
Which type of bonding, ionic or covalent, generally results in higher boiling points? Explain.
See AnswerQ: What types of intermolecular forces exist in a crystal of ice?
What types of intermolecular forces exist in a crystal of ice? How do these forces differ from the types of intermolecular forces that exist in a crystal of solid oxygen?
See AnswerQ: The envisions a metal as a cluster of positive ions through which
The envisions a metal as a cluster of positive ions through which the valence electrons are able to move freely.
See AnswerQ: Water is unusual in that its solid form (ice) is
Water is unusual in that its solid form (ice) is less dense than its liquid form. Discuss some implications of this fact.
See AnswerQ: Water at 100 °C (its normal boiling point) could
Water at 100 °C (its normal boiling point) could certainly give you a bad burn if it were spilled on the skin, but steam at 100 °C could give you a much worse burn. Explain.
See AnswerQ: For each of the following sets of pressure/volume data,
For each of the following sets of pressure/volume data, calculate the new volume of the gas sample after the pressure change is made. Assume that the temperature and the amount of gas remain the same....
See AnswerQ: Formaldehyde has the formula CH2O, where C is the central atom
Formaldehyde has the formula CH2O, where C is the central atom. The molecules in a sample of formaldehyde are attracted to each other by a combination of a. dipole–dipole forces and ionic forces. b....
See AnswerQ: Draw the Lewis structures for the following species to assist you in
Draw the Lewis structures for the following species to assist you in answering the questions: SeCl2, ICl, BH3, NO2-. a. Which of the species is(are) polar? b. Which of the species exhibits hydrogen-b...
See AnswerQ: The “Chemistry in Focus” segment Gorilla Glass discusses the glass
The “Chemistry in Focus” segment Gorilla Glass discusses the glass currently used for products such as smartphones. Which addition to common glass is not an ionic solid?
See AnswerQ: The “Chemistry in Focus” segment Diamonds in the Ruff discusses
The “Chemistry in Focus” segment Diamonds in the Ruff discusses using the ashes of pets to produce diamonds. A diamond is an atomic solid. Why? Why are diamonds also referred to as network solids?
See AnswerQ: Which of the following compound(s) exhibit only London dispersion
Which of the following compound(s) exhibit only London dispersion intermolecular forces? Which compound(s) exhibit hydrogen-bonding forces? Considering only the compounds without hydrogen-bonding inte...
See AnswerQ: Identify the most important type of forces (ionic, hydrogen bonding
Identify the most important type of forces (ionic, hydrogen bonding, dipoleâdipole, or London dispersion forces) among atoms or molecules present in the solids of each of the followi...
See AnswerQ: Rank the following compounds from lowest to highest boiling point.
Rank the following compounds from lowest to highest boiling point. a. CH3CH2CH2Cl b. CH3CH2Cl c. CH3CH2CH2CH2Cl d. CH3Cl
See AnswerQ: Rank the following compounds from lowest to highest melting point.
Rank the following compounds from lowest to highest melting point. a. CH4 b. MgO c. H2O d. H2S
See AnswerQ: The energy required to break a given chemical bond is called the
The energy required to break a given chemical bond is called the .
See AnswerQ: What sorts of elements react to form ionic compounds?
What sorts of elements react to form ionic compounds?
See AnswerQ: For each of the following sets of pressure/volume data,
For each of the following sets of pressure/volume data, calculate the missing quantity. Assume that the temperature and the amount of gas remain constant. a. V = 19.3 L at 102.1 kPa; V = 10.0 L at ?...
See AnswerQ: Describe the type of bonding that exists in the Cl2(g
Describe the type of bonding that exists in the Cl2(g) molecule. How does this type of bonding differ from that found in the HCl(g) molecule? How is it similar?
See AnswerQ: What are the common units used to measure pressure? Which unit
What are the common units used to measure pressure? Which unit is an experimental unit derived from the device used to measure atmospheric pressure?
See AnswerQ: The relative ability of an atom in a molecule to attract electrons
The relative ability of an atom in a molecule to attract electrons to itself is called the atom’s .
See AnswerQ: Make the indicated pressure conversions. a. 14.9
Make the indicated pressure conversions. a. 14.9 psi to atmospheres b. 795 torr to atmospheres c. 743 mm Hg to kilopascals d. 99,436 Pa to kilopascals
See AnswerQ: A bond between atoms having a (small/large) difference
A bond between atoms having a (small/large) difference in electronegativity will be ionic.
See AnswerQ: What factor determines the relative level of polarity of a polar covalent
What factor determines the relative level of polarity of a polar covalent bond?
See AnswerQ: The introduction to this chapter says that “we live immersed in
The introduction to this chapter says that “we live immersed in a gaseous solution.” What does that mean?
See AnswerQ: In each of the following groups, which element is the most
In each of the following groups, which element is the most electronegative? Which is the least electronegative? a. Cs, Ba, At b. Ba, Sr, Ra c. O, Rb, Mg
See AnswerQ: On the basis of the electronegativity values given in Fig. 12
On the basis of the electronegativity values given in Fig. 12.3, indicate whether each of the following bonds would be expected to be ionic, covalent, or polar covalent. a. O-O b. Al-O c. B-O From...
See AnswerQ: The molar heat of fusion of benzene is 9.92 kJ
The molar heat of fusion of benzene is 9.92 kJ/mol. Its molar heat of vaporization is 30.7 kJ/mol. Calculate the heat required to melt 8.25 g of benzene at its normal melting point. Calculate the heat...
See AnswerQ: On the basis of the electronegativity values given in Fig. 12
On the basis of the electronegativity values given in Fig. 12.3, indicate whether each of the following bonds would be expected to be covalent, polar covalent, or ionic. a. S-S b. S-H c. S-K From...
See AnswerQ: The volume of a sample of ideal gas is inversely proportional to
The volume of a sample of ideal gas is inversely proportional to the of the gas at constant temperature.
See AnswerQ: A mathematical expression that summarizes Boyle’s law is .
A mathematical expression that summarizes Boyle’s law is .
See AnswerQ: Make the indicated pressure conversions. a. 17.3
Make the indicated pressure conversions. a. 17.3 psi to kilopascals b. 1.15 atm to psi c. 4.25 atm to mm Hg d. 224 psi to atmospheres
See AnswerQ: Pretend that you’re talking to a friend who has not yet taken
Pretend that you’re talking to a friend who has not yet taken any science courses, and describe how you would explain Boyle’s law to her.
See AnswerQ: In Fig. 13.4, when additional mercury is added
In Fig. 13.4, when additional mercury is added to the righthand arm of the J-shaped tube, the volume of the gas trapped above the mercury in the left-hand arm of the J-tube decreases. Explain.
See AnswerQ: Which bond in each of the following pairs has less ionic character
Which bond in each of the following pairs has less ionic character? a. Na-O or Na-N b. K-S or K-P c. Na-Cl or K-Cl d. Na-Cl or Mg-Cl
See AnswerQ: What volume of gas would result if 225 mL of neon gas
What volume of gas would result if 225 mL of neon gas is compressed from 1.02 atm to 2.99 atm at constant temperature?
See AnswerQ: Why is the presence of a dipole moment in the water molecule
Why is the presence of a dipole moment in the water molecule so important? What are some properties of water that are determined by its polarity?
See AnswerQ: In each of the following diatomic molecules, which end of the
In each of the following diatomic molecules, which end of the molecule is negative relative to the other end? a. hydrogen chloride, HCl b. carbon monoxide, CO c. bromine monofluoride, BrF
See AnswerQ: The molar heats of fusion and vaporization for water are 6.
The molar heats of fusion and vaporization for water are 6.02 kJ/mol and 40.6 kJ/mol, respectively, and the specific heat capacity of liquid water is 4.18 J/g °C. What quantity of heat energy is requi...
See AnswerQ: In each of the following diatomic molecules, which end of the
In each of the following diatomic molecules, which end of the molecule is positive relative to the other end? a. hydrogen fluoride, HF b. chlorine monofluoride, ClF c. iodine monochloride, ICl
See AnswerQ: For each of the following bonds, draw a figure indicating the
For each of the following bonds, draw a figure indicating the direction of the bond dipole, including which end of the bond is positive and which is negative. a. C-F b. Si-C c. C-O d. B-C
See AnswerQ: For each of the following bonds, draw a figure indicating the
For each of the following bonds, draw a figure indicating the direction of the bond dipole, including which end of the bond is positive and which is negative. a. S-P b. S-F c. S-Cl d. S-Br
See AnswerQ: For each of the following bonds, draw a figure indicating the
For each of the following bonds, draw a figure indicating the direction of the bond dipole, including which end of the bond is positive and which is negative. a. Si-H b. P-H c. S-H d. Cl-H
See AnswerQ: For each of the following bonds, draw a figure indicating the
For each of the following bonds, draw a figure indicating the direction of the bond dipole, including which end of the bond is positive and which is negative. a. H-C b. N-O c. N-S d. N-C
See AnswerQ: A sample of gas in a balloon has an initial temperature of
A sample of gas in a balloon has an initial temperature of 18 °C and a volume of 1340 L. If the temperature changes to 87 °C and there is no overall change of pressure or amount of gas, what is the ne...
See AnswerQ: The metallic elements lose electrons when reacting, and the resulting positive
The metallic elements lose electrons when reacting, and the resulting positive ions have an electron configuration analogous to the noble gas element.
See AnswerQ: Nonmetals form negative ions by (losing/gaining) enough electrons
Nonmetals form negative ions by (losing/gaining) enough electrons to achieve the electron configuration of the next noble gas.
See AnswerQ: If the pressure on a 1.04-L sample of
If the pressure on a 1.04-L sample of gas is doubled at constant temperature, what will be the new volume of the gas?
See AnswerQ: A sample of helium gas with a volume of 29.2
A sample of helium gas with a volume of 29.2 mL at 785 mm Hg is compressed at constant temperature until its volume is 15.1 mL. What will be the new pressure in the sample?
See AnswerQ: The boiling points of the noble gas elements are listed below.
The boiling points of the noble gas elements are listed below. Comment on the trend in the boiling points. Why do the boiling points vary in this manner?
See AnswerQ: Which simple ion would each of the following elements be expected to
Which simple ion would each of the following elements be expected to form? Which noble gas has an analogous electron configuration to each of the ions? a. bromine, Z = 35 b. cesium, Z = 55 c. phosp...
See AnswerQ: For each of the following numbers of electrons, give the formula
For each of the following numbers of electrons, give the formula of a positive ion that would have that number of electrons, and write the complete electron configuration for each ion. a. 10 electron...
See AnswerQ: What is the expected ground-state electron configuration for Te-
What is the expected ground-state electron configuration for Te-2?
See AnswerQ: If a 375-mL sample of neon gas is heated from
If a 375-mL sample of neon gas is heated from 24 °C to 72 °C at constant pressure, what will be the volume of the sample at the higher temperature?
See AnswerQ: A sample of gas has a volume of 127 mL in a
A sample of gas has a volume of 127 mL in a boiling water bath at 100 °C. Calculate the volume of the sample of gas at 10 °C intervals after the heat source is turned off and the gas sample begins to...
See AnswerQ: Name the noble gas atom that has the same electron configuration as
Name the noble gas atom that has the same electron configuration as each of the ions in the following compounds. a. barium sulfide, BaS b. strontium fluoride, SrF2 c. magnesium oxide, MgO d. alumi...
See AnswerQ: Atoms form ions so as to achieve electron configurations similar to those
Atoms form ions so as to achieve electron configurations similar to those of the noble gases. For the following pairs of noble gas configurations, give the formulas of two simple ionic compounds that...
See AnswerQ: Is the formula we write for an ionic compound the molecular formula
Is the formula we write for an ionic compound the molecular formula or the empirical formula? Why?
See AnswerQ: If 1.04 g of chlorine gas occupies a volume of
If 1.04 g of chlorine gas occupies a volume of 872 mL at a particular temperature and pressure, what volume will 2.08 g of chlorine gas occupy under the same conditions?
See AnswerQ: Why are cations always smaller than the atoms from which they are
Why are cations always smaller than the atoms from which they are formed?
See AnswerQ: The normal boiling point of water is unusually high, compared to
The normal boiling point of water is unusually high, compared to the boiling points of H2S, H2Se, and H2Te. Explain this observation in terms of the hydrogen bonding that exists in water, but that doe...
See AnswerQ: Why are anions always larger than the atoms from which they are
Why are anions always larger than the atoms from which they are formed?
See AnswerQ: What pressure (in atmospheres) is required to compress 1.
What pressure (in atmospheres) is required to compress 1.00 L of gas at 760. mm Hg pressure to a volume of 50.0 mL?
See AnswerQ: Under what conditions do real gases behave most ideally?
Under what conditions do real gases behave most ideally?
See AnswerQ: Pretend that you’re talking to a friend who has not yet taken
Pretend that you’re talking to a friend who has not yet taken any science courses, and describe how you would explain the concept of absolute zero to him.
See AnswerQ: Figures 13.7 and 13.8 show volume/temperature
Figures 13.7 and 13.8 show volume/temperature data for several samples of gases. Why do all the lines seem to extrapolate to the same point at 2273 °C? Explain.
See AnswerQ: Why are the valence electrons of an atom the only electrons likely
Why are the valence electrons of an atom the only electrons likely to be involved in bonding to other atoms?
See AnswerQ: The volume of a sample of ideal gas is proportional to its
The volume of a sample of ideal gas is proportional to its temperature (K) at constant pressure.
See AnswerQ: What type of structure must each atom in a compound usually exhibit
What type of structure must each atom in a compound usually exhibit for the compound to be stable?
See AnswerQ: When elements in the second and third periods occur in compounds,
When elements in the second and third periods occur in compounds, what number of electrons in the valence shell represents the most stable electron arrangement? Why?
See AnswerQ: How many electrons are involved when two atoms in a molecule are
How many electrons are involved when two atoms in a molecule are connected by a “double bond”? Write the Lewis structure of a molecule containing a double bond.
See AnswerQ: What does it mean when we say that in forming bonds,
What does it mean when we say that in forming bonds, atoms try to achieve an electron configuration analogous to a noble gas?
See AnswerQ: What does it mean when two atoms in a molecule are connected
What does it mean when two atoms in a molecule are connected by a “triple bond”? Write the Lewis structure of a molecule containing a triple bond.
See AnswerQ: Write the simple Lewis structure for each of the following atoms.
Write the simple Lewis structure for each of the following atoms. a. I (Z = 53) b. Al (Z = 13) c. Xe (Z = 54) d. Sr (Z = 38)
See AnswerQ: Write the simple Lewis structure for each of the following atoms.
Write the simple Lewis structure for each of the following atoms. a. Mg (Z = 12) b. Br (Z = 35) c. S (Z = 16) d. Si (Z = 14)
See AnswerQ: At what temperature will a 1.0-g sample of
At what temperature will a 1.0-g sample of neon gas exert a pressure of 500. torr in a 5.0-L container?
See AnswerQ: At what temperature would 4.25 g of oxygen gas,
At what temperature would 4.25 g of oxygen gas, O2, exert a pressure of 784 mm Hg in a 2.51-L container?
See AnswerQ: What pressure exists in a 200-L tank containing 5.
What pressure exists in a 200-L tank containing 5.0 kg of neon gas at 300. K?
See AnswerQ: Which flask will have the higher pressure: a 5.00
Which flask will have the higher pressure: a 5.00-L flask containing 4.15 g of helium at 298 K, or a 10.0-L flask containing 56.2 g of argon at 303 K?
See AnswerQ: Suppose a 24.3-mL sample of helium gas at
Suppose a 24.3-mL sample of helium gas at 25 °C and 1.01 atm is heated to 50. °C and compressed to a volume of 15.2 mL. What will be the pressure of the sample?
See AnswerQ: Which of the following species exhibits resonance? CH4, OCl2
Which of the following species exhibits resonance? CH4, OCl2, NO2-, HCN (C is the central atom)
See AnswerQ: The “Chemistry in Focus” segment Broccoli—Miracle Food?
The “Chemistry in Focus” segment Broccoli—Miracle Food? discusses the health benefits of eating broccoli and gives a Lewis structure for sulforaphane, a chemical in broccoli. Draw possible resonance s...
See AnswerQ: Figure 13.1 shows an experiment that can be used effectively
Figure 13.1 shows an experiment that can be used effectively to demonstrate the pressure exerted by the atmosphere. Write an explanation of this experiment to a friend who has not yet taken any scienc...
See AnswerQ: When 50 mL of liquid water at 25 °C is added
When 50 mL of liquid water at 25 °C is added to 50 mL of ethanol (ethyl alcohol), also at 25 °C, the combined volume of the mixture is considerably less than 100 mL. Give a possible explanation.
See AnswerQ: The “Chemistry in Focus” segment Hiding Carbon Dioxide discusses attempts
The “Chemistry in Focus” segment Hiding Carbon Dioxide discusses attempts at sequestering (storing) underground CO2 produced at power plants so as to diminish the greenhouse effect. Draw all resonance...
See AnswerQ: A mathematical expression that summarizes Charles’s law is .
A mathematical expression that summarizes Charles’s law is .
See AnswerQ: Suppose a 375-mL sample of neon gas at 78 °
Suppose a 375-mL sample of neon gas at 78 °C is cooled to 22 °C at constant pressure. What will be the new volume of the neon sample?
See AnswerQ: Suppose 1.25 L of argon is cooled from 291 K
Suppose 1.25 L of argon is cooled from 291 K to 78 K. What will be the new volume of the argon sample?
See AnswerQ: Suppose a 125-mL sample of argon is cooled from 450
Suppose a 125-mL sample of argon is cooled from 450 K to 250 K at constant pressure. What will be the volume of the sample at the lower temperature?
See AnswerQ: What is the geometric structure of the water molecule? How many
What is the geometric structure of the water molecule? How many pairs of valence electrons are there on the oxygen atom in the water molecule? What is the approximate H-O-H bond angle in water?
See AnswerQ: What is the geometric structure of the ammonia molecule? How many
What is the geometric structure of the ammonia molecule? How many pairs of electrons surround the nitrogen atom in NH3? What is the approximate H-N-H bond angle in ammonia?
See AnswerQ: What is the geometric structure of the boron trifluoride molecule, BF3
What is the geometric structure of the boron trifluoride molecule, BF3? How many pairs of valence electrons are present on the boron atom in BF3? What are the approximate F-B-F bond angles in BF3?
See AnswerQ: What is the geometric structure of the SiF4 molecule? How many
What is the geometric structure of the SiF4 molecule? How many pairs of valence electrons are present on the silicon atom of SiF4? What are the approximate F-Si-F bond angles in SiF4?
See AnswerQ: Why is the geometric structure of a molecule important, especially for
Why is the geometric structure of a molecule important, especially for biological molecules?
See AnswerQ: For each of the following sets of volume/temperature data,
For each of the following sets of volume/temperature data, calculate the missing quantity after the change is made. Assume that the pressure and the amount of gas remain the same. a. V = 2.03 L at 24...
See AnswerQ: At conditions of constant temperature and pressure, the volume of a
At conditions of constant temperature and pressure, the volume of a sample of ideal gas is proportional to the number of moles of gas present.
See AnswerQ: How is the structure around a given atom related to repulsion between
How is the structure around a given atom related to repulsion between valence electron pairs on the atom?
See AnswerQ: Why are all diatomic molecules linear, regardless of the number of
Why are all diatomic molecules linear, regardless of the number of valence electron pairs on the atoms involved?
See AnswerQ: What do we assume about the volume of the actual molecules themselves
What do we assume about the volume of the actual molecules themselves in a sample of gas, compared to the bulk volume of the gas overall? Why?
See AnswerQ: Although both the BF3 and NF3 molecules contain the same number of
Although both the BF3 and NF3 molecules contain the same number of atoms, the BF3 molecule is flat, whereas the NF3 molecule is trigonal pyramidal. Explain.
See AnswerQ: Temperature is a measure of the average of the molecules in a
Temperature is a measure of the average of the molecules in a sample of gas.
See AnswerQ: For the indicated atom in each of the following molecules or ions
For the indicated atom in each of the following molecules or ions, give the number and arrangement of the electron pairs around that atom. a. S in SO32- b. S in HSO3- c. S in HS-
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following molecules. a. NCl3 b. H2Se c. SiCl4
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following molecules. a. CBr4 b. PH3 c. OCl2
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following polyatomic ions. a. sulfate ion, SO42- b. phosphate ion, PO43- c. ammonium ion, NH4+
See AnswerQ: Explain how the atoms in covalent molecules achieve electron configurations similar to
Explain how the atoms in covalent molecules achieve electron configurations similar to those of the noble gases. How does this differ from the situation in ionic compounds?
See AnswerQ: What conditions are considered “standard temperature and pressure” (STP
What conditions are considered “standard temperature and pressure” (STP) for gases? Suggest a reason why these particular conditions might have been chosen for STP.
See AnswerQ: For each of the following molecules or ions, indicate the bond
For each of the following molecules or ions, indicate the bond angle expected between the central atom and any two adjacent hydrogen atoms. a. H2O b. NH3 c. NH4+ d. CH4
See AnswerQ: For each of the following molecules or ions, indicate the bond
For each of the following molecules or ions, indicate the bond angle expected between the central atom and any two adjacent chlorine atoms. a. Cl2O b. NCl3 c. CCl4 d. C2Cl4
See AnswerQ: The “Chemistry in Focus” segment Taste—It’s the Structure
The “Chemistry in Focus” segment Taste—It’s the Structure That Counts discusses artificial sweeteners. What are the expected bond angles around the nitrogen atom in aspartame?
See AnswerQ: A mathematical expression that summarizes Avogadro’s law is .
A mathematical expression that summarizes Avogadro’s law is .
See AnswerQ: Consider the following order: Li < N < F. For
Consider the following order: Li < N < F. For which of the following properties does the order show the correct trend? a. size b. electronegativity c. metallic character d. number of unpaired elec...
See AnswerQ: In ionic bonding, a. the electrons are shared between
In ionic bonding, a. the electrons are shared between the atoms. b. the process of forming an ionic bond is highly endothermic overall. c. the bonding that occurs is usually between two nonmetal at...
See AnswerQ: The geometric arrangement of electron pairs around a given atom is determined
The geometric arrangement of electron pairs around a given atom is determined principally by the tendency to minimize between the electron pairs.
See AnswerQ: Arrange the following bonds from the least polar to the most polar
Arrange the following bonds from the least polar to the most polar bond: C-F, Na-F, Ga-F, Si-F
See AnswerQ: In each case, which of the following pairs of bonded elements
In each case, which of the following pairs of bonded elements forms the more polar bond? a. Br-Cl or Br-F b. As-S or As-O c. Pb-C or Pb-Si
See AnswerQ: Which simple ion would each of the following elements be expected to
Which simple ion would each of the following elements be expected to form? What noble gas has an analogous electron configuration to each of the ions? a. chlorine, Z = 17 b. strontium, Z = 38 c. ox...
See AnswerQ: Which of the following statements is false concerning bonding? a
Which of the following statements is false concerning bonding? a. Elements with extremely different electronegativities tend to form ionic bonds with each other. b. In an N-O bond, electron density...
See AnswerQ: A(n) chemical bond represents the equal sharing of a
A(n) chemical bond represents the equal sharing of a pair of electrons between two nuclei.
See AnswerQ: For each of the following pairs of elements, identify which element
For each of the following pairs of elements, identify which element would be expected to be more electronegative. It should not be necessary to look at a table of actual electronegativity values. a....
See AnswerQ: On the basis of the electronegativity values given in Fig. 12
On the basis of the electronegativity values given in Fig. 12.3, indicate whether each of the following bonds would be expected to be ionic, covalent, or polar covalent. a. H-O b. O-O c. H-H d. H-...
See AnswerQ: Which of the following molecules contain polar covalent bonds? a
Which of the following molecules contain polar covalent bonds? a. carbon monoxide, CO b. chlorine, Cl2 c. iodine monochloride, ICl d. phosphorus, P4
See AnswerQ: Consider the following unbalanced chemical equation for the combination reaction of sodium
Consider the following unbalanced chemical equation for the combination reaction of sodium metal and chlorine gas: Na(s) + Cl2(g) / NaCl(s) What volume of chlorine gas, measured at STP, is necessary...
See AnswerQ: The electrons involved in a C-F bond could be considered
The electrons involved in a C-F bond could be considered a. closer to C because carbon has a larger radius and thus exerts greater control over the shared electrons. b. closer to F because fluorine...
See AnswerQ: For each of the following bonds, draw a figure indicating the
For each of the following bonds, draw a figure indicating the direction of the bond dipole, including which end of the bond is positive and which is negative. a. N-Cl b. N-P c. N-S d. N-C
See AnswerQ: Which of the following contains a metal ion that does not have
Which of the following contains a metal ion that does not have a noble gas electron configuration? AgCl, BaCl2, TiO2, ScF3, KNO3
See AnswerQ: What simple ion does each of the following elements most commonly form
What simple ion does each of the following elements most commonly form? a. sodium b. iodine c. potassium d. calcium e. sulfur f. magnesium g. aluminum h. nitrogen
See AnswerQ: For each of the following sets of volume/temperature data,
For each of the following sets of volume/temperature data, calculate the missing quantity. Assume that the pressure and the mass of gas remain constant. a. V = 2.01 * 102 L at 1150 °C; V = 5.00 L at...
See AnswerQ: A widely used weather instrument called a barometer can be built from
A widely used weather instrument called a barometer can be built from a long, thin tube of glass that is sealed at one end. The tube is completely filled with mercury and then inverted into a small po...
See AnswerQ: Which noble gas has the same electron configuration as each of the
Which noble gas has the same electron configuration as each of the ions in the following compounds? a. calcium bromide, CaBr2 b. aluminum selenide, Al2Se3 c. strontium oxide, SrO d. potassium sulf...
See AnswerQ: For each of the following pairs, indicate which is smaller.
For each of the following pairs, indicate which is smaller. a. Rb+ or Na+ b. Mg2+ or Al3+ c. F- or I- d. Na+ or K+
See AnswerQ: Write the Lewis structure for each of the following atoms.
Write the Lewis structure for each of the following atoms. a. He (Z = 2) b. Br (Z = 35) c. Sr (Z = 38) d. Ne (Z = 10) e. I (Z = 53) f. Ra (Z = 88)
See AnswerQ: Welders commonly use an apparatus that contains a tank of acetylene (
Welders commonly use an apparatus that contains a tank of acetylene (C2H2) gas and a tank of oxygen gas. When burned in pure oxygen, acetylene generates a large amount of heat. 2C2H2(g) + 5O2(g) / 2H2...
See AnswerQ: Consider the following reaction: Zn(s)+ 2HCl(
Consider the following reaction: Zn(s)+ 2HCl(aq) ZnCl2(aq) + H2(g) What mass of zinc metal should be taken so as to produce 125 mL of H2 measured at STP when reacted with excess...
See AnswerQ: Select which of the following ions has the Lewis structure:
Select which of the following ions has the Lewis structure: a. B22- b. C22- c. N22- d. O22- e. F22-
See AnswerQ: Write a Lewis structure for each of the following simple molecules.
Write a Lewis structure for each of the following simple molecules. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. For those molecules that exhibit...
See AnswerQ: Chemicals placed in a microwave oven and exposed to microwave radiation can
Chemicals placed in a microwave oven and exposed to microwave radiation can increase in temperature if they possess a net dipole moment. Which of the following molecules can get hot in an operating mi...
See AnswerQ: Sulfur trioxide, SO3, is produced in enormous quantities each year
Sulfur trioxide, SO3, is produced in enormous quantities each year for use in the synthesis of sulfuric acid. S(s) + O2(g) SO2(g) 2SO2(g) + O2(g) 2SO3(g) What volume...
See AnswerQ: For each of the following sets of volume/temperature data,
For each of the following sets of volume/temperature data, calculate the missing quantity. Assume that the pressure and the mass of gas remain constant. a. V = 25.0 L at 0 °C; V = 50.0 L at? °C b. V...
See AnswerQ: For the indicated atom in each of the following molecules, give
For the indicated atom in each of the following molecules, give the number and the arrangement of the electron pairs around that atom. a. C in CCl4 b. Ge in GeH4 c. B in BF3
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following molecules. a. Cl2O b. OF2 c. SiCl4
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following polyatomic ions. a. chlorate ion b. chlorite ion c. perchlorate ion
See AnswerQ: For each of the following molecules, indicate the bond angle expected
For each of the following molecules, indicate the bond angle expected between the central atom and any two adjacent chlorine atoms. a. Cl2O b. CCl4 c. BeCl2 d. BCl3
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following molecules or ions containing multiple bonds. a. SO2 b. SO3 c. HCO3- (hydrogen is bonded to oxygen) d. HCN
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following molecules or ions containing multiple bonds. a. CO32- b. HNO3 (hydrogen is bonded to oxygen) c. NO2- d. C2H2
See AnswerQ: What is the expected ground-state electron configuration for the element
What is the expected ground-state electron configuration for the element with one unpaired 5p electron that forms a covalent compound with fluorine?
See AnswerQ: When doing any calculation involving gas samples, we must express the
When doing any calculation involving gas samples, we must express the temperature in terms of the temperature scale.
See AnswerQ: Classify the bonding in each of the following molecules as ionic,
Classify the bonding in each of the following molecules as ionic, polar covalent, or nonpolar covalent. a. H2 b. K3P c. NaI d. SO2 e. HF f. CCl4 g. CF4 h. K2S
See AnswerQ: Compare the electronegativities of each pair of atoms. State the element
Compare the electronegativities of each pair of atoms. State the element of each pair that has the greater electronegativity.
See AnswerQ: For each of the following sets of volume/temperature data,
For each of the following sets of volume/temperature data, calculate the missing quantity after the change is made. Assume that the pressure and the amount of gas remain the same. a. V = 9.14 L at 24...
See AnswerQ: List the bonds P-Cl, P-F, O
List the bonds P-Cl, P-F, O-F, and Si-F from least polar to most polar.
See AnswerQ: For a mixture of gases in the same container, the total
For a mixture of gases in the same container, the total pressure exerted by the mixture of gases is the of the pressures that those gases would exert if they were alone...
See AnswerQ: Write electron configurations for the most stable ion formed by each of
Write electron configurations for the most stable ion formed by each of the following elements. Do not use the noble gas notation. Write out the complete electron configuration.
See AnswerQ: Which of the following compounds or ions exhibit resonance? a
Which of the following compounds or ions exhibit resonance? a. O3 b. CNO- c. AsI3 d. CO32- e. AsF3
See AnswerQ: The formulas of several chemical substances are given in the table below
The formulas of several chemical substances are given in the table below. For each substance in the table, give its chemical name and predict its molecular structure.
See AnswerQ: Carbon dioxide gas, in the dry state, may be produced
Carbon dioxide gas, in the dry state, may be produced by heating calcium carbonate. CaCO3(s) / CaO(s) + CO2(g) What volume of CO2, collected dry at 55 °C and a pressure of 774 torr, is produced by co...
See AnswerQ: You have 1 mole of an ideal gas in a balloon.
You have 1 mole of an ideal gas in a balloon. How must the volume change so that the pressure in the balloon doubles and the temperature in °C is halved (assume the temperature is a positive value)?...
See AnswerQ: What is the pressure inside a 10.0-L flask
What is the pressure inside a 10.0-L flask containing 14.2 g of N2 at 26 °C?
See AnswerQ: Suppose two separate 100.0-L tanks are to be
Suppose two separate 100.0-L tanks are to be filled, one with helium and one with hydrogen. What mass of each gas is needed to produce a pressure of 2.70 atm in its respective tank at 24 °C?
See AnswerQ: At what temperature does 4.00 g of helium gas have
At what temperature does 4.00 g of helium gas have a pressure of 1.00 atm in a 22.4-L vessel?
See AnswerQ: On the basis of their electron configurations, predict the formula of
On the basis of their electron configurations, predict the formula of the simple binary ionic compounds likely to form when the following pairs of elements react with each other. a. aluminum, Al, and...
See AnswerQ: If 10.0 g of liquid helium at 1.7
If 10.0 g of liquid helium at 1.7 K is completely vaporized, what volume does the helium occupy at STP?
See AnswerQ: If 0.214 mole of argon gas occupies a volume of
If 0.214 mole of argon gas occupies a volume of 652 mL at a particular temperature and pressure, what volume would 0.375 mole of argon occupy under the same conditions?
See AnswerQ: Convert the following pressures into mm Hg. a. 0
Convert the following pressures into mm Hg. a. 0.903 atm b. 2.1240 * 106 Pa c. 445 kPa d. 342 torr
See AnswerQ: If the pressure on a 2.10 * 104 mL sample
If the pressure on a 2.10 * 104 mL sample of gas is doubled at constant temperature, what will be the new volume of the gas?
See AnswerQ: A sample of a gas at 0.780 atm occupies a
A sample of a gas at 0.780 atm occupies a volume of 0.501 L. If the temperature remains constant, what will be the new pressure if the volume increases to 0.794 L?
See AnswerQ: An expandable vessel contains 729 mL of gas at 22 °C
An expandable vessel contains 729 mL of gas at 22 °C. What volume will the gas sample in the vessel have if it is placed in a boiling water bath (100. °C)?
See AnswerQ: If a gaseous mixture is made of 3.50 g of
If a gaseous mixture is made of 3.50 g of He and 5.75 g of Ar in an evacuated 2.05-L container at 25 °C, what will be the partial pressure of Ar in the container?
See AnswerQ: If a 0.475-L sample of neon gas is
If a 0.475-L sample of neon gas is heated from 27 °C to 82 °C at constant pressure, what will be the volume of the sample at the higher temperature?
See AnswerQ: If 5.12 g of oxygen gas occupies a volume of
If 5.12 g of oxygen gas occupies a volume of 6.21 L at a certain temperature and pressure, what volume will 25.0 g of oxygen gas occupy under the same conditions?
See AnswerQ: If 0.00901 mole of neon gas at a particular temperature
If 0.00901 mole of neon gas at a particular temperature and pressure occupies a volume of 242 mL, what volume would 0.00703 mole of neon occupy under the same conditions?
See AnswerQ: On the basis of their electron configurations, predict the formula of
On the basis of their electron configurations, predict the formula of the simple binary ionic compound likely to form when the following pairs of elements react with each other. a. aluminum and bromi...
See AnswerQ: If 3.25 moles of argon gas occupies a volume of
If 3.25 moles of argon gas occupies a volume of 100. L at a particular temperature and pressure, what volume does 14.15 moles of argon occupy under the same conditions?
See AnswerQ: If 2.71 g of argon gas occupies a volume of
If 2.71 g of argon gas occupies a volume of 4.21 L, what volume will 1.29 moles of argon occupy under the same conditions?
See AnswerQ: If two gases that do not react with each other are placed
If two gases that do not react with each other are placed in the same container, they will completely with each other.
See AnswerQ: What mass of neon gas is required to fill a 5.
What mass of neon gas is required to fill a 5.00-L container to a pressure of 1.02 atm at 25 °C?
See AnswerQ: Why are the dipole–dipole interactions between polar molecules not important
Why are the dipole–dipole interactions between polar molecules not important in the vapor phase?
See AnswerQ: Describe a simple mercury barometer. How is such a barometer used
Describe a simple mercury barometer. How is such a barometer used to measure the pressure of the atmosphere?
See AnswerQ: On the basis of the smaller units that make up the crystals
On the basis of the smaller units that make up the crystals, cite three types of crystalline solids. For each type of crystalline solid, give an example of a substance that forms that type of solid.
See AnswerQ: How do ionic solids differ in structure from molecular solids? What
How do ionic solids differ in structure from molecular solids? What are the fundamental particles in each? Give two examples of each type of solid and indicate the individual particles that make up th...
See AnswerQ: Describe in general terms the structure of ionic solids such as NaCl
Describe in general terms the structure of ionic solids such as NaCl. How are the ions packed in the crystal?
See AnswerQ: Ionic solids are generally considerably harder than most molecular solids. Explain
Ionic solids are generally considerably harder than most molecular solids. Explain.
See AnswerQ: When dry ammonia gas (NH3) is bubbled into a 125
When dry ammonia gas (NH3) is bubbled into a 125-mL sample of water, the volume of the sample (initially, at least) decreases slightly. Suggest a reason for this.
See AnswerQ: For each of the following pairs, indicate which species is smaller
For each of the following pairs, indicate which species is smaller. Explain your reasoning in terms of the electron structure of each species. a. H or H- b. N or N3- c. Al or Al3+ d. F or Cl
See AnswerQ: For each of the following pairs, indicate which species is larger
For each of the following pairs, indicate which species is larger. Explain your reasoning in terms of the electron structure of each species. a. Mg2+ or Mg b. Ca2+ or K+ c. Rb+ or Br- d. Se2- or S...
See AnswerQ: For each of the following pairs, indicate which is smaller.
For each of the following pairs, indicate which is smaller. a. Fe or Fe3+ b. Cl or Cl- c. Al3+ or Na+
See AnswerQ: For each of the following pairs, indicate which is larger.
For each of the following pairs, indicate which is larger. a. I or F b. F or F- c. Na+ or F-
See AnswerQ: Given the following sets of values for three of the gas variables
Given the following sets of values for three of the gas variables, calculate the unknown quantity. a. P = 782.4 mm Hg; V = ?; n = 0.1021 mol; T = 26.2 °C b. P = ? mm Hg; V = 27.5 mL; n = 0.007812 mol...
See AnswerQ: Consider a sample of ice being heated from -5 °C
Consider a sample of ice being heated from -5 °C to +5 °C. Describe on both a macroscopic and a microscopic basis what happens to the ice as the temperature reaches 0 °C.
See AnswerQ: Explain what the “duet” and “octet” rules are
Explain what the “duet” and “octet” rules are and how they are used to describe the arrangement of electrons in a molecule.
See AnswerQ: Show how Boyle’s gas law can be derived from the ideal gas
Show how Boyle’s gas law can be derived from the ideal gas law.
See AnswerQ: Show how Charles’s gas law can be derived from the ideal gas
Show how Charles’s gas law can be derived from the ideal gas law.
See AnswerQ: Given each of the following sets of values for an ideal gas
Given each of the following sets of values for an ideal gas, calculate the unknown quantity. a. P = 782 mm Hg; V =? n = 0.210 mol; T = 27 °C b. P =? mm Hg; V = 644 mL; n = 0.0921 mol; T = 303 K c....
See AnswerQ: What mass of helium gas is needed to pressurize a 100.
What mass of helium gas is needed to pressurize a 100.0-L tank to 255 atm at 25 °C? What mass of oxygen gas would be needed to pressurize a similar tank to the same specifications?
See AnswerQ: If you’ve ever opened a bottle of rubbing alcohol or other solvent
If you’ve ever opened a bottle of rubbing alcohol or other solvent on a warm day, you may have heard a little “whoosh” as the vapor that had built up above the liquid escapes. Describe on a microscopi...
See AnswerQ: Give the total number of valence electrons in each of the following
Give the total number of valence electrons in each of the following molecules. a. N2O b. B2H6 c. C3H8 d. NCl3
See AnswerQ: Give the total number of valence electrons in each of the following
Give the total number of valence electrons in each of the following molecules. a. B2O3 b. CO2 c. C2H6O d. NO2
See AnswerQ: Write a Lewis structure for each of the following simple molecules.
Write a Lewis structure for each of the following simple molecules. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. a. NBr3 b. HF c. CBr4 d. C2H...
See AnswerQ: Compare and contrast the bonding found in the H2 (g)
Compare and contrast the bonding found in the H2 (g) and HF(g) molecules with that found in NaF(s).
See AnswerQ: Write a Lewis structure for each of the following simple molecules.
Write a Lewis structure for each of the following simple molecules. Show all bonding valence electrons pairs as lines and all nonbonding valence electron pairs as dots. a. H2S b. SiF4 c. C2H4 d. C...
See AnswerQ: Write a Lewis structure for each of the following simple molecules.
Write a Lewis structure for each of the following simple molecules. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. a. C2H6 b. NF3 c. C4H10 d. S...
See AnswerQ: In carbon compounds a given group of atoms can often be arranged
In carbon compounds a given group of atoms can often be arranged in more than one way. This means that more than one structure may be possible for the same atoms. For example, both the molecules dieth...
See AnswerQ: What do we mean by a dynamic equilibrium? Describe how the
What do we mean by a dynamic equilibrium? Describe how the development of a vapor pressure above a liquid represents such an equilibrium.
See AnswerQ: Consider Fig. 14.10. Imagine you are talking to
Consider Fig. 14.10. Imagine you are talking to a friend who has not taken any science courses, and explain how the figure demonstrates the concept of vapor pressure and enables it to be measured. Fr...
See AnswerQ: Write a Lewis structure for each of the following polyatomic ions.
Write a Lewis structure for each of the following polyatomic ions. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. For those ions that exhibit reson...
See AnswerQ: Write a Lewis structure for each of the following polyatomic ions.
Write a Lewis structure for each of the following polyatomic ions. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. For those ions that exhibit reson...
See AnswerQ: Write a Lewis structure for each of the following polyatomic ions.
Write a Lewis structure for each of the following polyatomic ions. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. For those ions that exhibit reson...
See AnswerQ: Write a Lewis structure for each of the following polyatomic ions.
Write a Lewis structure for each of the following polyatomic ions. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. For those ions that exhibit reson...
See AnswerQ: A tank contains a mixture of 52.5 g of oxygen
A tank contains a mixture of 52.5 g of oxygen gas and 65.1 g of carbon dioxide gas at 27 °C. The total pressure in the tank is 9.21 atm. Calculate the partial pressure (in atm) of each gas in the mixt...
See AnswerQ: What evidence do we have that the solid form of water is
What evidence do we have that the solid form of water is less dense than the liquid form of water at its freezing/melting point?
See AnswerQ: What mass of neon gas would be required to fill a 3
What mass of neon gas would be required to fill a 3.00-L flask to a pressure of 925 mm Hg at 26 °C? What mass of argon gas would be required to fill a similar flask to the same pressure at the same te...
See AnswerQ: Explain why the measured properties of a mixture of gases depend only
Explain why the measured properties of a mixture of gases depend only on the total number of moles of particles, not on the identity of the individual gas particles. How is this observation summarized...
See AnswerQ: Determine the partial pressure of each gas as shown in this figure
Determine the partial pressure of each gas as shown in this figure. Note: The relative numbers of each type of gas are depicted in the figure.
See AnswerQ: We often collect small samples of gases in the laboratory by bubbling
We often collect small samples of gases in the laboratory by bubbling the gas into a bottle or flask containing water. Explain why the gas becomes saturated with water vapor and how we must take the p...
See AnswerQ: What general principles determine the molecular structure (shape) of a
What general principles determine the molecular structure (shape) of a molecule?
See AnswerQ: If a gaseous mixture is made of 2.41 g of
If a gaseous mixture is made of 2.41 g of He and 2.79 g of Ne in an evacuated 1.04-L container at 25 °C, what will be the partial pressure of each gas and the total pressure in the container?
See AnswerQ: Suppose that 1.28 g of neon gas and 2.
Suppose that 1.28 g of neon gas and 2.49 g of argon gas are confined in a 9.87-L container at 27 °C. What would be the pressure in the container?
See AnswerQ: Although the valence electron pairs in ammonia have a tetrahedral arrangement,
Although the valence electron pairs in ammonia have a tetrahedral arrangement, the overall geometric structure of the ammonia molecule is not described as being tetrahedral. Explain.
See AnswerQ: Small quantities of hydrogen gas can be prepared in the laboratory by
Small quantities of hydrogen gas can be prepared in the laboratory by the addition of aqueous hydrochloric acid to metallic zinc. Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g) Typically, the hyd...
See AnswerQ: For the indicated atom in each of the following molecules or ions
For the indicated atom in each of the following molecules or ions, give the number and arrangement of the electron pairs around that atom. a. As in AsO43- b. Se in SeO42- c. S in H2S
See AnswerQ: What does it mean to say that a bond is polar?
What does it mean to say that a bond is polar? Give two examples of molecules with polar bonds. Indicate in your examples the direction of the polarity.
See AnswerQ: Consider the following molecules: CH3OH, CH4, H2O, C2H6
Consider the following molecules: CH3OH, CH4, H2O, C2H6. a. Draw the Lewis structure for each molecule, and indicate whether each is polar or nonpolar. b. At room temperature, two of these compounds...
See AnswerQ: How is the phenomenon of temperature explained on the basis of the
How is the phenomenon of temperature explained on the basis of the kinetic molecular theory? What microscopic property of gas molecules is reflected in the temperature measured?
See AnswerQ: Explain, in terms of the kinetic molecular theory, how an
Explain, in terms of the kinetic molecular theory, how an increase in the temperature of a gas confined to a rigid container causes an increase in the pressure of the gas.
See AnswerQ: Which substance in each pair would be expected to have a lower
Which substance in each pair would be expected to have a lower boiling point? Explain your reasoning. a. CH3OH or CH3CH2CH2OH b. CH3CH3 or CH3CH2OH c. H2O or CH4
See AnswerQ: Using the VSEPR theory, predict the molecular structure of each of
Using the VSEPR theory, predict the molecular structure of each of the following polyatomic ions. a. dihydrogen phosphate ion, H2PO4- b. perchlorate ion, ClO4- c. sulfite ion, SO32-
See AnswerQ: Calcium oxide can be used to “scrub” carbon dioxide from
Calcium oxide can be used to “scrub” carbon dioxide from air. CaO(s) + CO2(g) CaCO3(s) What mass of CO2 could be absorbed by 1.25 g of CaO? What volume would this CO2 occupy at S...
See AnswerQ: Which substance in each pair would be expected to be more volatile
Which substance in each pair would be expected to be more volatile at a particular temperature? Explain your reasoning. a. H2O(l) or H2S(l) b. H2O(l) or CH3OH(l) c. CH3OH(l) or CH3CH2OH(l)
See AnswerQ: Consider the following reaction for the combustion of octane, C8H18:
Consider the following reaction for the combustion of octane, C8H18: 2C8H18(l) + 25O2(g) / 16CO2(g) + 18H20(l) What volume of oxygen gas at STP would be needed for the complete combustion of 10.0 g o...
See AnswerQ: For each of the following molecules, predict both the molecular structure
For each of the following molecules, predict both the molecular structure and bond angles around the central atom. a. SeS2 b. SeS3 c. SO2 d. CS2
See AnswerQ: Ammonia and gaseous hydrogen chloride combine to form ammonium chloride.
Ammonia and gaseous hydrogen chloride combine to form ammonium chloride. NH3(g) + HCl(g) NH4Cl(s) If 4.21 L of NH3(g) at 27 °C and 1.02 atm is combined with 5.35 L of HCl(g) at 26 °C...
See AnswerQ: Explain the difference between intramolecular and intermolecular forces.
Explain the difference between intramolecular and intermolecular forces.
See AnswerQ: Calcium carbide, CaC2, reacts with water to produce acetylene gas
Calcium carbide, CaC2, reacts with water to produce acetylene gas, C2H2. CaC2(s) + 2H2O(l) C2H2(g) + Ca(OH)2(s) What volume of acetylene at 25 °C and 1.01 atm is generated by th...
See AnswerQ: Although we generally think of combustion reactions as involving oxygen gas,
Although we generally think of combustion reactions as involving oxygen gas, other rapid oxidation reactions are also referred to as combustions. For example, if magnesium metal is placed into chlorin...
See AnswerQ: If water is added to magnesium nitride, ammonia gas is produced
If water is added to magnesium nitride, ammonia gas is produced when the mixture is heated. Mg3N2(s) + 3H2O(l) 3MgO(s) + 2NH3(g) If 10.3 g of magnesium nitride is trea...
See AnswerQ: Two molecules that contain the same number of each kind of atom
Two molecules that contain the same number of each kind of atom but that have different molecular structures are said to be isomers of each other. For example, both ethyl alcohol and dimethyl ether (s...
See AnswerQ: Consider the following unbalanced chemical equation in which element X is unknown
Consider the following unbalanced chemical equation in which element X is unknown: X(s) + F2(g) ( XF3(s) If 9.15 g of element X(s) is completely reacted with 4.00 L of fluorine gas at 250 °C and...
See AnswerQ: A common prank on college campuses is to switch the salt and
A common prank on college campuses is to switch the salt and sugar on dining hall tables, which is usually easy because the substances look so much alike. Yet, despite the similarity in their appearan...
See AnswerQ: The forces holding together a molecular solid are much (stronger/
The forces holding together a molecular solid are much (stronger/ weaker) than the forces between particles in an ionic solid.
See AnswerQ: A mixture contains 5.00 g each of O2, N2
A mixture contains 5.00 g each of O2, N2, CO2, and Ne gas. Calculate the volume of this mixture at STP. Calculate the partial pressure of each gas in the mixture at STP.
See AnswerQ: Dinitrogen monoxide, N2O, reacts with propane, C3H8, to
Dinitrogen monoxide, N2O, reacts with propane, C3H8, to form nitrogen, N2; carbon dioxide, CO2; and water, H2O. a. Write a balanced chemical equation for this reaction, treating all substances as gas...
See AnswerQ: On the basis of the electronegativity values given in Fig. 12
On the basis of the electronegativity values given in Fig. 12.3, indicate which is the more polar bond in each of the following pairs. a. N-P or N-O b. N-C or N-O c. N-S or N-C d. N-F or N-S
See AnswerQ: Describe in detail the microscopic processes that take place when a solid
Describe in detail the microscopic processes that take place when a solid melts and when a liquid boils. What kind of forces must be overcome? Are any chemical bonds broken during these processes?
See AnswerQ: Explain the overall trend in the following melting points in terms of
Explain the overall trend in the following melting points in terms of the forces among particles in the solids indicated. Hydrogen, H2………………….-259 °C Ethyl alcohol, C2H5OH………-114 °C Water, H2O………………...
See AnswerQ: During the making of steel, iron(II) oxide is
During the making of steel, iron(II) oxide is reduced to metallic iron by treatment with carbon monoxide gas. FeO(s) + CO(g) / Fe(s) + CO2(g) Suppose 1.45 kg of Fe reacts. What volume of CO(g) is req...
See AnswerQ: What is a network solid? Give an example of a network
What is a network solid? Give an example of a network solid and describe the bonding in such a solid. How does a network solid differ from a molecular solid?
See AnswerQ: What is an alloy? Explain the differences in structure between substitutional
What is an alloy? Explain the differences in structure between substitutional and interstitial alloys. Give an example of each type.
See AnswerQ: On the basis of their electron configurations, predict the formula of
On the basis of their electron configurations, predict the formula of the simple binary ionic compound likely to form when the following pairs of elements react with each other. a. sodium, Na, and se...
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. At constant temperature, the lighter the gas molecules, the faster the average velocity of the gas molecules. b. At constant temperature, the heavi...
See AnswerQ: Consider the flasks in the following diagrams. /
Consider the flasks in the following diagrams. Assuming the connecting tube has negligible volume, draw what each diagram will look like after the stopcock between the two flasks is opened. Also, so...
See AnswerQ: When a person has a severe fever, one therapy to reduce
When a person has a severe fever, one therapy to reduce the fever is an “alcohol rub.” Explain how the evaporation of alcohol from the person’s skin removes heat energy from the body.
See AnswerQ: What is the total number of valence electrons in each of the
What is the total number of valence electrons in each of the following molecules? a. HNO3 b. H2SO4 c. H3PO4 d. HClO4
See AnswerQ: Write a Lewis structure for each of the following simple molecules.
Write a Lewis structure for each of the following simple molecules. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. a. GeH4 b. ICl c. NI3 d. PF3...
See AnswerQ: In each of the following groups, which element is the most
In each of the following groups, which element is the most electronegative? Which is the least electro negative? a. K, Na, H b. F, Br, Na c. B, N, F
See AnswerQ: When ammonium carbonate is heated, three gases are produced by its
When ammonium carbonate is heated, three gases are produced by its decomposition. (NH4)2CO3(s) 2NH3(g) + CO2(g) + H2O(g) What total volume of gas is produced, measured at 45...
See AnswerQ: A helium tank contains 25.2 L of helium at 8
A helium tank contains 25.2 L of helium at 8.40 atm pressure. Determine how many 1.50-L balloons at 755 mm Hg can be inflated with the gas in the tank, assuming that the tank will also have to contain...
See AnswerQ: Carbon dioxide gas, saturated with water vapor, can be produced
Carbon dioxide gas, saturated with water vapor, can be produced by the addition of aqueous acid to calcium carbonate. CaCO3(s) + 2H+(aq) / Ca2+(aq) + H2O(l) + CO2(g) How many moles of CO2(g), collect...
See AnswerQ: Why is the molecular structure of H2O nonlinear, whereas that of
Why is the molecular structure of H2O nonlinear, whereas that of BeF2 is linear, even though both molecules consist of three atoms?
See AnswerQ: As weather balloons rise from the earth’s surface, the pressure of
As weather balloons rise from the earth’s surface, the pressure of the atmosphere becomes less, tending to cause the volume of the balloons to expand. However, the temperature is much lower in the upp...
See AnswerQ: What are some important uses of water, both in nature and
What are some important uses of water, both in nature and in industry? What is the liquid range for water?
See AnswerQ: Describe, on both a microscopic and a macroscopic basis, what
Describe, on both a microscopic and a macroscopic basis, what happens to a sample of water as it is cooled from room temperature to 50 °C below its normal freezing point.
See AnswerQ: Cake mixes and other packaged foods that require cooking often contain special
Cake mixes and other packaged foods that require cooking often contain special directions for use at high elevations. Typically these directions indicate that the food should be cooked longer above 50...
See AnswerQ: A 2.50-L container at 1.00 atm
A 2.50-L container at 1.00 atm and 248°C is filled with 5.41 g of a monatomic gas. a. Determine the identity of the gas. b. Assuming the 2.50-L container is a large elastic balloon, predict what wil...
See AnswerQ: For each of the following sets of pressure/volume data,
For each of the following sets of pressure/volume data, calculate the missing quantity. Assume that the temperature and the amount of gas remain constant. a. V = 123 L at 4.56 atm; V =? at 1002 mm Hg...
See AnswerQ: Convert the following pressures into pascals. a. 774 torr
Convert the following pressures into pascals. a. 774 torr b. 0.965 atm c. 112.5 kPa d. 801 mm Hg
See AnswerQ: What do we call the energies required, respectively, to melt
What do we call the energies required, respectively, to melt and to vaporize 1 mole of a substance? Which of these energies is always larger for a given substance? Why?
See AnswerQ: Consider the following series of atoms or ions: S2-, S
Consider the following series of atoms or ions: S2-, S, S2+, Cs+, Sr2+. a. Which of the species has the smallest size? b. Which of the species has the largest ionization energy?
See AnswerQ: A particular balloon is designed by its manufacturer to be inflated to
A particular balloon is designed by its manufacturer to be inflated to a volume of no more than 2.5 L. If the balloon is filled with 2.0 L of helium at sea level, is released, and rises to an altitude...
See AnswerQ: What are London dispersion forces and how do they arise in a
What are London dispersion forces and how do they arise in a nonpolar molecule? Are London forces typically stronger or weaker than dipole–dipole attractions between polar molecules? Are London forces...
See AnswerQ: Describe in detail the microscopic processes that take place when a liquid
Describe in detail the microscopic processes that take place when a liquid boils. What kind of forces must be overcome? Are any chemical bonds broken during these processes?
See AnswerQ: Arrange the atoms and/or ions in the following groups in
Arrange the atoms and/or ions in the following groups in order of decreasing size. a. O, O+, O2- b. Fe2+, Ni2+, Zn2+ c. Ca2+, K+, Cl-
See AnswerQ: For each of the following sets of volume/temperature data,
For each of the following sets of volume/temperature data, calculate the missing quantity. Assume that the pressure and the amount of gas remain constant. a. V = 22.4 L at 0 °C; V = 44.4 L at? K b....
See AnswerQ: Although the noble gas elements are monatomic and could not give rise
Although the noble gas elements are monatomic and could not give rise to dipole–dipole forces or hydrogen bonding, these elements still can be liquefied and solidified. Explain.
See AnswerQ: You have a gas in a container fitted with a piston,
You have a gas in a container fitted with a piston, and you change one of the conditions of the gas such that a change takes place, as shown below: State three distinct changes you can make to accom...
See AnswerQ: Given each of the following sets of values for three of the
Given each of the following sets of values for three of the gas variables, calculate the unknown quantity. a. P = 21.2 atm; V = 142 mL; n = 0.432 mol; T =? K b. P =? atm; V = 1.23 mL; n = 0.000115 m...
See AnswerQ: Make the indicated pressure conversions. a. 1.54
Make the indicated pressure conversions. a. 1.54 * 105 Pa to atmospheres b. 1.21 atm to pascals c. 97,345 Pa to mm Hg d. 1.32 kPa to pascals
See AnswerQ: Given each of the following sets of values for three of the
Given each of the following sets of values for three of the gas variables, calculate the unknown quantity. a. P = 1.034 atm; V = 21.2 mL; n = 0.00432 mol; T =? K b. P =? atm; V = 1.73 mL; n = 0.0001...
See AnswerQ: Describe, on a microscopic basis, the processes of evaporation and
Describe, on a microscopic basis, the processes of evaporation and condensation. Which process requires an input of energy? Why?
See AnswerQ: Which of the following statements about intermolecular forces is(are)
Which of the following statements about intermolecular forces is(are) true? a. London dispersion forces are the only type of intermolecular force that nonpolar molecules exhibit. b. Molecules that ha...
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. LiF will have a higher vapor pressure at 25 °C than H2S. b. HF will have a lower vapor pressure at 250 °C than HBr. c. Cl2 will have a higher boil...
See AnswerQ: A 22-g sample of neon gas exerts a pressure of
A 22-g sample of neon gas exerts a pressure of 2.0 atm at a certain temperature and volume. What pressure does a 44-g sample of argon gas exert at these conditions of temperature and volume?
See AnswerQ: If 3.20 g of nitrogen gas occupies a volume of
If 3.20 g of nitrogen gas occupies a volume of 1.71 L at 0 °C and a pressure of 1.50 atm, what would the volume become if 8.80 g of nitrogen gas were added at constant conditions of temperature and pr...
See AnswerQ: An aluminum can contain a small amount of water and is boiled
An aluminum can contain a small amount of water and is boiled with the lid removed. The heat is then turned off, and the can is sealed. Over time, the can crumples. a. Why doesnâ...
See AnswerQ: A mixture at 33 °C contains H2 at 325 torr,
A mixture at 33 °C contains H2 at 325 torr, N2 at 475 torr, and O2 at 650. torr. a. What is the total pressure of the gases in the system? b. Which gas contains the greatest number of moles?
See AnswerQ: You have two rigid gas cylinders. Gas cylinder A has a
You have two rigid gas cylinders. Gas cylinder A has a volume of 48.2 L and contains N2(g) at 8.35 atm at 25 °C. Gas cylinder B has a volume of 22.0 L and contains He(g) at 25 °C. When the two cylinde...
See AnswerQ: Consider the following chemical equation: N2(g) +
Consider the following chemical equation: N2(g) + 3H2(g) 2NH3(g) What volumes of nitrogen gas and hydrogen gas, each measured at 11 °C and 0.998 atm, are needed to produce 5.00...
See AnswerQ: Discuss the similarities and differences between the arrangements of molecules and the
Discuss the similarities and differences between the arrangements of molecules and the forces between molecules in liquid water versus steam, and in liquid water versus ice.
See AnswerQ: The following demonstration takes place in a two-step process:
The following demonstration takes place in a two-step process: First, solid calcium carbide (CaC2) reacts with liquid water to produce acetylene gas (C2H2) and aqueous calcium hydroxide. Second, the a...
See AnswerQ: Consider the following unbalanced chemical equation: Cu2S(s)
Consider the following unbalanced chemical equation: Cu2S(s) + O2(g) Cu2O(s) + SO2(g) What volume of oxygen gas, measured at 27.5 °C and 0.998 atm, is required to react with...
See AnswerQ: When sodium bicarbonate, NaHCO3(s), is heated, sodium
When sodium bicarbonate, NaHCO3(s), is heated, sodium carbonate is produced, with the evolution of water vapor and carbon dioxide gas. 2NaHCO3(s) / Na2CO3(s) + H2O(g) + CO2(g) What total volume of ga...
See AnswerQ: What volume does 35 moles of N2 occupy at STP?
What volume does 35 moles of N2 occupy at STP?
See AnswerQ: A sample of oxygen gas has a volume of 125 L at
A sample of oxygen gas has a volume of 125 L at 25 °C and a pressure of 0.987 atm. Calculate the volume of this oxygen sample at STP.
See AnswerQ: Consider the flasks in the following diagrams. /
Consider the flasks in the following diagrams. a. Which is greater, the initial pressure of helium or the initial pressure of neon? How much greater? b. Assuming the connecting tube has negligible...
See AnswerQ: What volume of CO2 measured at STP is produced when 27.
What volume of CO2 measured at STP is produced when 27.5 g of CaCO3 is decomposed? CaCO3(s) / CaO(s) + CO2(g)
See AnswerQ: Concentrated hydrogen peroxide solutions are explosively decomposed by traces of transition metal
Concentrated hydrogen peroxide solutions are explosively decomposed by traces of transition metal ions (such as Mn or Fe): 2H2O2(aq) 2H2O(l) + O2(g) What volume of pure O2(g)...
See AnswerQ: The “Chemistry in Focus” segment The Chemistry of Air Bags
The “Chemistry in Focus” segment The Chemistry of Air Bags discusses how the decomposition of sodium azide inflates the air bag. Use the balanced chemical equation in the segment to determine the mass...
See AnswerQ: The “Chemistry in Focus” segment Breath Fingerprinting discusses using breath
The “Chemistry in Focus” segment Breath Fingerprinting discusses using breath analysis to diagnose diseases. The volume of the average human breath is approximately 500 mL, and carbon dioxide (CO2) ma...
See AnswerQ: Which of the following molecules contain polar covalent bonds? a
Which of the following molecules contain polar covalent bonds? a. water, H2O b. carbon monoxide, CO c. fluorine, F2 d. nitrogen, N2
See AnswerQ: Complete the following table for an ideal gas. /
Complete the following table for an ideal gas.
See AnswerQ: A glass vessel contains 28 g of nitrogen gas. Assuming ideal
A glass vessel contains 28 g of nitrogen gas. Assuming ideal behavior, which of the processes listed below would double the pressure exerted on the walls of the vessel? a. Adding 28 g of oxygen gas...
See AnswerQ: A steel cylinder contains 150.0 moles of argon gas at
A steel cylinder contains 150.0 moles of argon gas at a temperature of 25 °C and a pressure of 8.93 MPa. After some argon has been used, the pressure is 2.00 MPa at a temperature of 19 °C. What mass o...
See AnswerQ: A certain flexible weather balloon contains helium gas at a volume of
A certain flexible weather balloon contains helium gas at a volume of 855 L. Initially, the balloon is at sea level where the temperature is 25 °C and the barometric pressure is 730 torr. The balloon...
See AnswerQ: A large flask with a volume of 936 mL is evacuated and
A large flask with a volume of 936 mL is evacuated and found to have a mass of 134.66 g. It is then filled to a pressure of 0.967 atm at 31 °C with a gas of unknown molar mass and then reweighed to gi...
See AnswerQ: A 20.0-L nickel container was charged with 0
A 20.0-L nickel container was charged with 0.859 atm of xenon gas and 1.37 atm of fluorine gas at 400 °C. The xenon and fluorine react to form xenon tetrafluoride. What mass of xenon tetrafluoride can...
See AnswerQ: Consider the unbalanced chemical equation: CaSiO3(s) +
Consider the unbalanced chemical equation: CaSiO3(s) + HF(g) / CaF2(aq) + SiF4(g) + H2O(l) Suppose a 32.9-g sample of CaSiO3 is reacted with 31.8 L of HF at 27.0 °C and 1.00 atm. Assuming the reactio...
See AnswerQ: Which of the following statements is(are) true?
Which of the following statements is(are) true? a. If the number of moles of a gas is doubled, the volume will double, assuming the pressure and temperature of the gas remain constant. b. If the tempe...
See AnswerQ: Determine the pressure in a 125-L tank containing 56.
Determine the pressure in a 125-L tank containing 56.2 kg of oxygen gas at 21 °C.
See AnswerQ: What volume will 2.04 g of helium gas occupy at
What volume will 2.04 g of helium gas occupy at 100. °C and 785 mm Hg pressure?
See AnswerQ: Which of the following molecules contain polar covalent bonds? a
Which of the following molecules contain polar covalent bonds? a. phosphorus, P4 b. oxygen, O2 c. ozone, O3 d. hydrogen fluoride, HF
See AnswerQ: At what temperature (in °C) will a 5.
At what temperature (in °C) will a 5.00-g sample of neon gas exert a pressure of 1.10 atm in a 7.00-L container?
See AnswerQ: Suppose that a 1.25-g sample of neon gas
Suppose that a 1.25-g sample of neon gas is confined in a 10.1-L container at 25 °C. What will be the pressure in the container? Suppose the temperature is then raised to 50 °C. What will the new pres...
See AnswerQ: Suppose that 1.29 g of argon gas is confined to
Suppose that 1.29 g of argon gas is confined to a volume of 2.41 L at 29 °C. What would be the pressure in the container? What would the pressure become if the temperature were raised to 42 °C without...
See AnswerQ: What will the volume of the sample become if 459 mL of
What will the volume of the sample become if 459 mL of an ideal gas at 27 °C and 1.05 atm is cooled to 15 °C and 0.997 atm?
See AnswerQ: The “Chemistry in Focus” segment Snacks Need Chemistry, Too
The “Chemistry in Focus” segment Snacks Need Chemistry, Too! discusses why popcorn “pops.” You can estimate the pressure inside a kernel of popcorn at the time of popping by using the ideal gas law. B...
See AnswerQ: Make the indicated pressure conversions. a. 45.2
Make the indicated pressure conversions. a. 45.2 kPa to atmospheres b. 755 mm Hg to atmospheres c. 802 torr to kilopascals d. 1.04 atm to millimeters of mercury
See AnswerQ: A sample of oxygen gas is saturated with water vapor at 27
A sample of oxygen gas is saturated with water vapor at 27 °C. The total pressure of the mixture is 772 torr, and the vapor pressure of water is 26.7 torr at 27 °C. What is the partial pressure of the...
See AnswerQ: A 500.-mL sample of O2 gas at 24 °C
A 500.-mL sample of O2 gas at 24 °C was prepared by decomposing a 3% aqueous solution of hydrogen peroxide, H2O2, in the presence of a small amount of manganese catalyst by the reaction 2H2O2 (aq)...
See AnswerQ: What is a scientific law? What is a theory? How
What is a scientific law? What is a theory? How do these concepts differ? Does a law explain a theory, or does a theory attempt to explain a law?
See AnswerQ: When is a scientific theory considered to be successful? Are all
When is a scientific theory considered to be successful? Are all theories successful? Will a theory that has been successful in the past necessarily be successful in the future?
See AnswerQ: On the basis of the electronegativity values given in Fig. 12
On the basis of the electronegativity values given in Fig. 12.3, indicate which is the more polar bond in each of the following pairs. a. H-F or H-Cl b. H-Cl or H-I c. H-Br or H-Cl d. H-I or H-Br...
See AnswerQ: Collisions of the molecules in a sample of gas with the walls
Collisions of the molecules in a sample of gas with the walls of the container are responsible for the gas’s observed .
See AnswerQ: The kinetic molecular theory of gases suggests that gas particles exert attractive
The kinetic molecular theory of gases suggests that gas particles exert attractive or repulsive forces on each other.
See AnswerQ: What is the molar volume of a gas? Do all gases
What is the molar volume of a gas? Do all gases that behave ideally have the same molar volume?
See AnswerQ: Consider the following reaction: C(s) + O2
Consider the following reaction: C(s) + O2(g) CO2(g) What volume of oxygen gas at 25 °C and 1.02 atm would be required to react completely with 1.25 g of carbon?
See AnswerQ: Make the indicated pressure conversions. a. 699 mm Hg
Make the indicated pressure conversions. a. 699 mm Hg to atmospheres b. 18.2 psi to mm Hg c. 862 mm Hg to torr d. 795 mm Hg to psi
See AnswerQ: Many transition metal salts are hydrates: they contain a fixed number
Many transition metal salts are hydrates: they contain a fixed number of water molecules bound per formula unit of the salt. For example, copper(II) sulfate most commonly exists as the pentahydrate, C...
See AnswerQ: What volume does a mixture of 14.2 g of He
What volume does a mixture of 14.2 g of He and 21.6 g of H2 occupy at 28 °C and 0.985 atm?
See AnswerQ: A sample of helium gas occupies a volume of 25.2
A sample of helium gas occupies a volume of 25.2 mL at 95 °C and a pressure of 892 mm Hg. Calculate the volume of the gas at STP.
See AnswerQ: Consider the following chemical equation: N2(g) +
Consider the following chemical equation: N2(g) + 3H2(g) ( 2NH3(g) What minimum total volume of reactant gases is needed to produce 4.00 g of ammonia if the volume of each gas is measured at 11 °C an...
See AnswerQ: Gases have (higher/lower) densities than liquids or solids
Gases have (higher/lower) densities than liquids or solids.
See AnswerQ: On the basis of the electronegativity values given in Fig. 12
On the basis of the electronegativity values given in Fig. 12.3, indicate which is the more polar bond in each of the following pairs. a. O-Cl or O-Br b. N-O or N-F c. P-S or P-O d. H-O or H-N Fr...
See AnswerQ: The forces that connect two hydrogen atoms to an oxygen atom in
The forces that connect two hydrogen atoms to an oxygen atom in a water molecule are (intermo lecular/intramolecular), but the forces that hold water molecules close together in an ice cube are (inter...
See AnswerQ: The energy required to melt 1 mole of a solid is called
The energy required to melt 1 mole of a solid is called the .
See AnswerQ: The following data have been collected for substance X. Construct a
The following data have been collected for substance X. Construct a heating curve for substance X. (The drawing does not need to be absolutely to scale, but it should clearly show relative differences...
See AnswerQ: The molar heat of fusion of aluminum metal is 10.79
The molar heat of fusion of aluminum metal is 10.79 kJ/mol, whereas its heat of vaporization is 293.4 kJ/mol. a. Why is the heat of fusion of aluminum so much smaller than the heat of vaporization?...
See AnswerQ: The molar heats of fusion and vaporization for silver are 11.
The molar heats of fusion and vaporization for silver are 11.3 kJ/mol and 250. kJ/mol, respectively. Silver’s normal melting point is 962 °C, and its normal boiling point is 2212 °C. What quantity of...
See AnswerQ: It requires 113 J to melt 1.00 g of sodium
It requires 113 J to melt 1.00 g of sodium metal at its normal melting point of 98 °C. Calculate the molar heat of fusion of sodium.
See AnswerQ: Consider the iodine monochloride molecule, ICl. Because chlorine is more
Consider the iodine monochloride molecule, ICl. Because chlorine is more electronegative than iodine, this molecule is a dipole. How would you expect iodine monochloride molecules in the gaseous state...
See AnswerQ: Liquids and solids are (more/less) compressible than are
Liquids and solids are (more/less) compressible than are gases.
See AnswerQ: Dipole–dipole forces become as the distance between the dipoles decreases
Dipole–dipole forces become as the distance between the dipoles decreases (gets closer together).
See AnswerQ: The text implies that hydrogen bonding is a special case of very
The text implies that hydrogen bonding is a special case of very strong dipole–dipole interactions possible among only certain atoms. What atoms in addition to hydrogen are necessary for hydrogen bond...
See AnswerQ: Which bond in each of the following pairs has the greater ionic
Which bond in each of the following pairs has the greater ionic character? a. Na-F or Na-I b. Ca-S or Ca-O c. Li-Cl or Cs-Cl d. Mg-N or Mg-P
See AnswerQ: are relatively weak forces that exist among noble gas atoms and
are relatively weak forces that exist among noble gas atoms and nonpolar molecules that involve an accidental dipole that induces a momentary dipole in a neighbor.
See AnswerQ: What type of intermolecular forces is active in the liquid state of
What type of intermolecular forces is active in the liquid state of each of the following substances? a. Ne b. CO c. CH3OH d. Cl2
See AnswerQ: Discuss the types of intermolecular forces acting in the liquid state of
Discuss the types of intermolecular forces acting in the liquid state of each of the following substances. a. Xe b. NH3 c. F2 d. ICl
See AnswerQ: The heats of fusion of three substances are listed below. Explain
The heats of fusion of three substances are listed below. Explain the trend this list reflects. HI…………………2.87 kJ/mol HBr………………2.41 kJ/mol HCl………………1.99 kJ/mol
See AnswerQ: What is evaporation? What is condensation? Which of these processes
What is evaporation? What is condensation? Which of these processes is endothermic and which is exothermic?
See AnswerQ: Although water and ammonia differ in molar mass by only one unit
Although water and ammonia differ in molar mass by only one unit, the boiling point of water is over 100 °C higher than that of ammonia. What forces in liquid water that do not exist in liquid ammonia...
See AnswerQ: What are crystalline solids? What kind of microscopic structure do such
What are crystalline solids? What kind of microscopic structure do such solids have? How is this microscopic structure reflected in the macroscopic appearance of such solids?
See AnswerQ: The enthalpy (∆H) of vaporization of water is about seven
The enthalpy (∆H) of vaporization of water is about seven times larger than water’s enthalpy of fusion (41 kJ/mol vs. 6 kJ/mol). What does this tell us about the relative similarities among the solid,...
See AnswerQ: What types of forces exist between the individual particles in an ionic
What types of forces exist between the individual particles in an ionic solid? Are these forces relatively strong or relatively weak?
See AnswerQ: Ionic solids do not conduct electricity in the solid state, but
Ionic solids do not conduct electricity in the solid state, but are strong conductors in the liquid state and when dissolved in water. Explain.
See AnswerQ: How are the three states of matter similar, and how do
How are the three states of matter similar, and how do they differ?
See AnswerQ: For each of the following sets of pressure/volume data,
For each of the following sets of pressure/volume data, calculate the missing quantity. Assume that the temperature and the amount of gas remain constant. a. V = 53.2 mL at 785 mm Hg; V = ? mL at 700...
See AnswerQ: The “Chemistry in Focus” segment Metal with a Memory discusses
The “Chemistry in Focus” segment Metal with a Memory discusses Nitinol, an alloy that “remembers” a shape originally impressed in it. Which elements comprise Nitinol, and why is it classified as an al...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: What is a dipole moment? Give four examples of molecules that
What is a dipole moment? Give four examples of molecules that possess dipole moments, and draw the direction of the dipole as shown in Section 12.3.
See AnswerQ: Sketch a heating/cooling curve for water, starting out at
Sketch a heating/cooling curve for water, starting out at -20 °C and going up to 120 °C, applying heat to the sample at a constant rate. Mark on your sketch the portions of the curve that represent th...
See AnswerQ: For Exercises 51–60 choose one of the following terms to
For Exercises 51–60 choose one of the following terms to match the definition or description given. a. alloy b. specific heat c. crystalline solid d. dipole–dipole attraction e. equilibrium vapor...
See AnswerQ: Given the densities and conditions of ice, liquid water, and
Given the densities and conditions of ice, liquid water, and steam listed in Table 14.1, calculate the volume of 1.0 g of water under each of these circumstances. From table 14.1
See AnswerQ: Which of the substances in each of the following sets would be
Which of the substances in each of the following sets would be expected to have the highest boiling point? Explain why. a. Ga, KBr, O2 b. Hg, NaCl, He c. H2, O2, H2O
See AnswerQ: What are some physical properties that historically led chemists to classify various
What are some physical properties that historically led chemists to classify various substances as acids and bases?
See AnswerQ: How do chemists recognize a system that has reached a state of
How do chemists recognize a system that has reached a state of chemical equilibrium? When writing chemical equations, how do we indicate reactions that come to a state of chemical equilibrium?
See AnswerQ: For each hydrogen or hydroxide ion concentration listed, calculate the concentration
For each hydrogen or hydroxide ion concentration listed, calculate the concentration of the complementary ion and the pH and pOH of the solution. a. [H+] = 5.72 * 10-4 M b. [OH-] = 8.91 * 10-5 M c....
See AnswerQ: Calculate [OH-] in each of the following solutions, and
Calculate [OH-] in each of the following solutions, and indicate whether the solution is acidic, basic, or neutral. a. [H+] = 4.21 * 10-7 M b. [H+] = 0.00035 M c. [H+] = 0.00000010 M d. [H+] = 9.9...
See AnswerQ: You mix 225.0 mL of a 2.5 M
You mix 225.0 mL of a 2.5 M HCl solution with 150.0 mL of a 0.75 M HCl solution. What is the molarity of the final solution?
See AnswerQ: Calculate the hydrogen ion concentration, in moles per liter, for
Calculate the hydrogen ion concentration, in moles per liter, for solutions with each of the following pH or pOH values. a. pOH = 0.90 b. pH = 0.90 c. pOH = 10.3 d. pH = 5.33
See AnswerQ: Calculate the hydrogen ion concentration and the pH of each of the
Calculate the hydrogen ion concentration and the pH of each of the following solutions of strong acids. a. 1.4 * 10-3 M HClO4 b. 3.0 * 10-5 M HCl c. 5.0 * 10-2 M HNO3 d. 0.0010 M HCl
See AnswerQ: A 15.0% (by mass) NaCl solution is
A 15.0% (by mass) NaCl solution is available. Determine what mass of the solution should be taken to obtain the following quantities of NaCl. a. 10.0 g b. 25.0 g c. 100.0 g d. 1.00 lb
See AnswerQ: Calculate the hydrogen ion concentration, in moles per liter, for
Calculate the hydrogen ion concentration, in moles per liter, for solutions with each of the following pH or pOH values. a. pH = 5.41 b. pOH = 12.04 c. pH = 11.91 d. pOH = 3.89
See AnswerQ: Write the formulas for three combinations of weak acid and salt that
Write the formulas for three combinations of weak acid and salt that would act as buffered solutions. For each of your combinations, write chemical equations showing how the components of the buffered...
See AnswerQ: Consider 0.25 M solutions of the following salts: NaCl
Consider 0.25 M solutions of the following salts: NaCl, RbOCl, KI, Ba(ClO4)2, and NH4NO3. For each salt, indicate whether the solution is acidic, basic, or neutral.
See AnswerQ: The three common silver halides (AgCl, AgBr, and AgI
The three common silver halides (AgCl, AgBr, and AgI) are all sparingly soluble salts. Given the values for Ksp for these salts below, calculate the concentration of silver ion, in mol/L, in a saturat...
See AnswerQ: What does it mean to say that a state of chemical or
What does it mean to say that a state of chemical or physical equilibrium is dynamic?
See AnswerQ: Approximately 1.5 * 10-3 g of iron(
Approximately 1.5 * 10-3 g of iron(II) hydroxide, Fe(OH)2(s), dissolves per liter of water at 18 °C. Calculate Ksp for Fe(OH)2(s) at this temperature.
See AnswerQ: Chromium(III) hydroxide dissolves in water only to the extent
Chromium(III) hydroxide dissolves in water only to the extent of 8.21 * 10-5 M at 25 °C. Calculate Ksp for Cr(OH)3 at this temperature.
See AnswerQ: Approximately 0.14 g of nickel(II) hydroxide,
Approximately 0.14 g of nickel(II) hydroxide, Ni(OH)2(s), dissolves per liter of water at 20 °C. Calculate Ksp for Ni(OH)2(s) at this temperature.
See AnswerQ: For each of the following solutions, the mass of the solute
For each of the following solutions, the mass of the solute is given, followed by the total volume of solution prepared. Calculate the molarity. a. 5.0 g of BaCl2; 2.5 L b. 3.5 g of KBr; 75 mL c. 2...
See AnswerQ: You are given 1.00 gram of each of five substances
You are given 1.00 gram of each of five substances. In which of the substances will there be the greatest number of potassium ions when dissolved in water? a. potassium chloride b. potassium chlorat...
See AnswerQ: Magnesium fluoride dissolves in water to the extent of 8.0
Magnesium fluoride dissolves in water to the extent of 8.0 * 10-2 g/L at 25 °C. Calculate the solubility of MgF2(s) in moles per liter, and calculate Ksp for MgF2 at 25 °C.
See AnswerQ: When 200.0 mL of 0.10 M Zn(
When 200.0 mL of 0.10 M Zn(NO3)2 is mixed with 100.0 mL of 0.10 M KOH, a precipitate forms. a. How many moles of precipitate can form in this reaction? b. Calculate the concentration of Zn2+ ions in...
See AnswerQ: Lead(II) chloride, PbCl2(s), dissolves in
Lead(II) chloride, PbCl2(s), dissolves in water to the extent of approximately 3.6 * 10-2 M at 20 °C. Calculate Ksp for PbCl2(s), and calculate its solubility in grams per liter.
See AnswerQ: How many moles and how many grams of the indicated solute does
How many moles and how many grams of the indicated solute does each of the following solutions contain? a. 4.25 L of 0.105 M KCl solution b. 15.1 mL of 0.225 M NaNO3 solution c. 25 mL of 3.0 M HCl...
See AnswerQ: Suppose a reaction has the equilibrium constant K = 4.5
Suppose a reaction has the equilibrium constant K = 4.5 * 10-6 at a particular temperature. If an experiment is set up with this reaction, will there be large relative concentrations of products prese...
See AnswerQ: Consider an initial mixture of N2 and H2 gases that can be
Consider an initial mixture of N2 and H2 gases that can be represented as follows: The gases react to form ammonia gas (NH3) as represented by the following concentration profile: a. Label each plot...
See AnswerQ: Calculate the number of moles of each ion present in each of
Calculate the number of moles of each ion present in each of the following solutions. a. 1.25 L of 0.250 M Na3PO4 solution b. 3.5 mL of 6.0 M H2SO4 solution c. 25 mL of 0.15 M AlCl3 solution d. 1....
See AnswerQ: Mercury(I) chloride, Hg2Cl2, was formerly administered orally
Mercury(I) chloride, Hg2Cl2, was formerly administered orally as a purgative. Although we usually think of mercury compounds as highly toxic, the Ksp of mercury(I) chloride is small enough (1.3 * 10-1...
See AnswerQ: Calculate the new molarity when 150. mL of water is added
Calculate the new molarity when 150. mL of water is added to each of the following solutions. a. 125 mL of 0.200 M HBr b. 155 mL of 0.250 M Ca(C2H3O2)2 c. 0.500 L of 0.250 M H3PO4 d. 15 mL of 18.0...
See AnswerQ: The solubility product of iron(III) hydroxide is very small
The solubility product of iron(III) hydroxide is very small: Ksp = 4 * 10-38 at 25 °C. A classical method of analysis for unknown samples containing iron is to add NaOH or NH3. This precipitates Fe(OH...
See AnswerQ: Consider the reaction between 1.0 L of 3.0
Consider the reaction between 1.0 L of 3.0 M AgNO3(aq) and 1.0 L of 1.0 M CuCl2(aq), according to the equation: 2AgNO3(aq) + CuCl2(aq) ( 2AgCl(s) + Cu(NO3)2(aq) Which of the following will increase t...
See AnswerQ: Consider the following reaction at some temperature: H2O( g
Consider the following reaction at some temperature: H2O( g) + CO( g) â H2( g) + CO2( g) K = 2.0 Some molecules of H2O and CO are placed in a 1.0-L container as shown b...
See AnswerQ: An aqueous solution of ammonium sulfide is mixed with an aqueous solution
An aqueous solution of ammonium sulfide is mixed with an aqueous solution of iron(III) chloride. a. Write a balanced molecular equation, complete ionic equation, and net ionic equation for the two so...
See AnswerQ: For a given reaction at a given temperature, the special ratio
For a given reaction at a given temperature, the special ratio of products to reactants defined by the equilibrium constant is always equal to the same number. Explain why this is true, no matter what...
See AnswerQ: Suppose K = 4.5 * 10-3 at a
Suppose K = 4.5 * 10-3 at a certain temperature for the reaction PCl5(g) ⇌ PCl3(g) + Cl2(g) If it is found that the concentration of PCl5 is twice the concentration of PCl3, what must be the concentr...
See AnswerQ: What volume of 0.250 M HCl is required to neutralize
What volume of 0.250 M HCl is required to neutralize each of the following solutions? a. 25.0 mL of 0.103 M sodium hydroxide, NaOH b. 50.0 mL of 0.00501 M calcium hydroxide, Ca(OH)2 c. 20.0 mL of 0...
See AnswerQ: In general terms, what does the equilibrium constant for a reaction
In general terms, what does the equilibrium constant for a reaction represent? What is the algebraic form of the equilibrium constant for a typical reaction? What do square brackets indicate when we w...
See AnswerQ: For each of the following solutions, the mass of solute taken
For each of the following solutions, the mass of solute taken is indicated, as well as the total volume of solution prepared. Calculate the normality of each solution. a. 15.0 g of HCl; 500. mL b. 4...
See AnswerQ: As you know from Chapter 7, most metal carbonate salts are
As you know from Chapter 7, most metal carbonate salts are sparingly soluble in water. Below are listed several metal carbonates along with their solubility products, Ksp. For each salt, write the equ...
See AnswerQ: Teeth and bones are composed, to a first approximation, of
Teeth and bones are composed, to a first approximation, of calcium phosphate, Ca3(PO4)2(s). The Ksp for this salt is 1.3 * 10-32 at 25 °C. Calculate the concentration of calcium ion in a saturated sol...
See AnswerQ: How many milliliters of 0.105 M NaOH are required to
How many milliliters of 0.105 M NaOH are required to neutralize exactly 14.2 mL of 0.141 M H3PO4?
See AnswerQ: Explain why the development of a vapor pressure above a liquid in
Explain why the development of a vapor pressure above a liquid in a closed container represents an equilibrium. What are the opposing processes? How do we recognize when the system has reached a state...
See AnswerQ: You mix 100.0 mL of 0.100 M calcium
You mix 100.0 mL of 0.100 M calcium chloride with 100.0 mL of 0.100 M silver nitrate. What species are in solution when the reaction is complete? a. calcium ion, chloride ion, nitrate ion, water b....
See AnswerQ: Consider the reaction between 0.156 L of 0.105
Consider the reaction between 0.156 L of 0.105 M magnesium nitrate and 0.166 L of 0.106 M potassium hydroxide. a. What mass of precipitate will form? b. What is the concentration of nitrate ions lef...
See AnswerQ: Consider the following generic reaction: 2A2B( g) ⇌
Consider the following generic reaction: 2A2B( g) â 2A2( g) + B2( g) Some molecules of A2B are placed in a 1.0-L container. As time passes, several snapshots of the reaction mixture...
See AnswerQ: A solution is prepared by dissolving 0.6706 g of oxalic
A solution is prepared by dissolving 0.6706 g of oxalic acid (H2C2O4) in enough water to make 100.0 mL of solution. A 10.00-mL aliquot (portion) of this solution is then diluted to a final volume of 2...
See AnswerQ: What volume of 0.100 M NaOH is required to precipitate
What volume of 0.100 M NaOH is required to precipitate all of the nickel(II) ions from 150.0 mL of a 0.249 M solution of Ni(NO3)2?
See AnswerQ: There is only one value of the equilibrium constant for a particular
There is only one value of the equilibrium constant for a particular system at a particular temperature, but there are an infinite number of equilibrium positions. Explain.
See AnswerQ: A 500.0-mL sample of 0.200 M
A 500.0-mL sample of 0.200 M sodium phosphate is mixed with 400.0 mL of 0.289 M barium chloride. What is the mass of the solid produced?
See AnswerQ: A 450.0-mL sample of a 0.257
A 450.0-mL sample of a 0.257 M solution of silver nitrate is mixed with 400.0 mL of 0.200 M calcium chloride. What is the concentration of Cl- in solution after the reaction is complete?
See AnswerQ: A 50.00-mL sample of aqueous Ca(OH
A 50.00-mL sample of aqueous Ca(OH)2 requires 34.66 mL of a 0.944 M nitric acid for neutralization. Calculate the concentration (molarity) of the original solution of calcium hydroxide.
See AnswerQ: When organic compounds containing sulfur are burned, sulfur dioxide is produced
When organic compounds containing sulfur are burned, sulfur dioxide is produced. The amount of SO2 formed can be determined by the reaction with hydrogen peroxide: H2O2(aq) + SO2(g)...
See AnswerQ: Acetate ion, C2H3O2-, has a stronger affinity for protons than
Acetate ion, C2H3O2-, has a stronger affinity for protons than does water. Therefore, when dissolved in water, acetate ion behaves as a(n) .
See AnswerQ: Draw the structure of the carboxyl group, -COOH. Show
Draw the structure of the carboxyl group, -COOH. Show how a molecule containing the carboxyl group behaves as an acid when dissolved in water.
See AnswerQ: Because of , even pure water contains measurable quantities of H+
Because of , even pure water contains measurable quantities of H+ and OH-.
See AnswerQ: The number of in the logarithm of a number is equal to
The number of in the logarithm of a number is equal to the number of significant figures in the number.
See AnswerQ: A solution with pH = 9 has a (higher/lower
A solution with pH = 9 has a (higher/lower) hydrogen ion concentration than a solution with pOH = 9.
See AnswerQ: A 0.20 M HCl solution contains M hydrogen ion and
A 0.20 M HCl solution contains M hydrogen ion and M chloride ion concentrations.
See AnswerQ: Calculate the percent by mass of solute in each of the following
Calculate the percent by mass of solute in each of the following solutions. a. 2.14 g of potassium chloride dissolved in 12.5 g of water b. 2.14 g of potassium chloride dissolved in 25.0 g of water...
See AnswerQ: A(n) solution contains a conjugate acid–base pair
A(n) solution contains a conjugate acid–base pair and through this is able to resist changes in its pH.
See AnswerQ: In each of the following chemical equations, identify the conjugate acid
In each of the following chemical equations, identify the conjugate acid–base pairs. a. HF(aq) + H2O(l) ⇌ F-(aq) 1 H3O+(aq) b. CN-(aq) + H2O(l) ⇌ HCN(aq) + OH-(aq) c. HCO3-(aq) + H2O(l) ⇌ H2CO3(aq)...
See AnswerQ: Of the following combinations, which would act as buffered solutions?
Of the following combinations, which would act as buffered solutions? a. HClO2 and KClO2 b. H2S and Na2S c. HCOOH and NaHCO d. HClO and HClO4
See AnswerQ: Calculate the pH corresponding to each of the pOH values listed,
Calculate the pH corresponding to each of the pOH values listed, and indicate whether each solution is acidic, basic, or neutral. a. pOH = 4.32 b. pOH = 8.90 c. pOH = 1.81 d. pOH = 13.1
See AnswerQ: Write the equilibrium expression for each of the following heterogeneous equilibria.
Write the equilibrium expression for each of the following heterogeneous equilibria. a. 4Al(s) + 3O2( g) ⇌ 2Al2O3(s) b. NH3( g) + HCl( g) ⇌ NH4Cl(s) c. 2Mg(s) + O2( g) ⇌ 2MgO(s)
See AnswerQ: Write the equilibrium expression for each of the following heterogeneous equilibria.
Write the equilibrium expression for each of the following heterogeneous equilibria. a. P4(s) + 5O2( g) ⇌ P4O10(s) b. CO2( g) + 2NaOH(s) ⇌ Na2CO3(s) + H2O( g) c. NH4NO3(s) ⇌ N2O( g) + 2H2O( g)
See AnswerQ: Suppose the reaction system 2NO(g) + O2(
Suppose the reaction system 2NO(g) + O2(g) ⇌ 2NO2(g) has already reached equilibrium. Predict the effect of each of the following changes on the position of the equilibrium. Tell whether the equilibr...
See AnswerQ: The reaction PCl3(l) + Cl2(g)
The reaction PCl3(l) + Cl2(g) ⇌ PCl5(s) liberates 124 kJ of energy per mole of PCl3 reacted. Will an increase in temperature shift the equilibrium position toward products or toward reactants?
See AnswerQ: For the process CO(g) + H2O(g
For the process CO(g) + H2O(g) ⇌ CO2(g) + H2(g) it is found that the equilibrium concentrations at a particular temperature are [H2] = 1.4 M, [CO2] = 1.3 M, [CO] = 0.71 M, and [H2O] = 0.66 M. Calcu...
See AnswerQ: For the reaction N2(g) + 3H2(g
For the reaction N2(g) + 3H2(g) ⇌ 2NH3(g) K = 1.3 * 10-2 at a given temperature. If the system at equilibrium is analyzed and the concentrations of both N2 and H2 are found to be 0.10 M, what is the...
See AnswerQ: Calculate the percent by mass of solute in each of the following
Calculate the percent by mass of solute in each of the following solutions. a. 6.11 mg of calcium chloride dissolved in 5.25 g of water b. 6.11 mg of calcium chloride dissolved in 52.5 g of water c...
See AnswerQ: The equilibrium constant for the reaction 2NOCl(g) ⇌
The equilibrium constant for the reaction 2NOCl(g) ⇌ 2NO(g) + Cl2(g) has the value 9.2 * 10-6 at a particular temperature. The system is analyzed at equilibrium, and it is found that the concentrati...
See AnswerQ: As you learned in Chapter 7, most metal hydroxides are sparingly
As you learned in Chapter 7, most metal hydroxides are sparingly soluble in water. Write balanced chemical equations describing the dissolving of the following metal hydroxides in water. Write the exp...
See AnswerQ: Approximately 9.0 * 10-4 g of silver chloride
Approximately 9.0 * 10-4 g of silver chloride, AgCl(s), dissolves per liter of water at 10 °C. Calculate Ksp for AgCl(s) at this temperature.
See AnswerQ: Mercuric sulfide, HgS, is one of the least soluble salts
Mercuric sulfide, HgS, is one of the least soluble salts known, with Ksp = 1.6 * 10-54 at 25 °C. Calculate the solubility of HgS in moles per liter and in grams per liter.
See AnswerQ: For the reaction N2( g) + 3H2( g)
For the reaction N2( g) + 3H2( g) 2NH3( g), list the types of bonds that must be broken and the type of bonds that must form for the chemical reaction to take place.
See AnswerQ: What does the activation energy for a reaction represent? How is
What does the activation energy for a reaction represent? How is the activation energy related to whether a collision between molecules is successful?
See AnswerQ: What are the catalysts in living cells called? Why are these
What are the catalysts in living cells called? Why are these biological catalysts necessary?
See AnswerQ: When a reaction system has reached chemical equilibrium, the concentrations of
When a reaction system has reached chemical equilibrium, the concentrations of the reactants and products no longer change with time. Why does the amount of product no longer increase, even though lar...
See AnswerQ: Ammonia, a very important industrial chemical, is produced by the
Ammonia, a very important industrial chemical, is produced by the direct combination of the elements under carefully controlled conditions. N2(g) + 3H2(g) ⇌ 2NH3(g) Suppose, in an experiment, that th...
See AnswerQ: For the reaction 2CO2( g) ⇌ 2CO( g
For the reaction 2CO2( g) ⇌ 2CO( g) + O2( g) an analysis of an equilibrium mixture is performed. At a particular temperature, it is found that [CO] = 0.11 M, [O2] = 0.055 M, and [CO2] = 1.4 M. Calcul...
See AnswerQ: What does it mean to say that an acid is strong in
What does it mean to say that an acid is strong in aqueous solution? What does this reveal about the ability of the acid’s anion to attract protons?
See AnswerQ: At a particular temperature, a 3.50-L flask
At a particular temperature, a 3.50-L flask contains 1.16 moles of NH3, 2.40 moles of H2, and 1.14 moles of N2 in equilibrium. Calculate the value of K for the reaction 3H2(g) + N2(g) ⇌ 2NH3(g)
See AnswerQ: Suppose that for a hypothetical reaction: A2(g)
Suppose that for a hypothetical reaction: A2(g) + 2B(g) ⇌ 2AB(g) It is determined that at a certain temperature the equilibrium concentrations are: [A2] = 0.0090, [B] = 0.940, and [AB] = 5.3 * 10-4....
See AnswerQ: For the reaction: 3O2(g) ⇌ 2O3(
For the reaction: 3O2(g) ⇌ 2O3(g) K = 1.8 * 10-7 at a certain temperature. If at equilibrium [O2] = 0.062 M, calculate the equilibrium O3 concentration.
See AnswerQ: The reaction H2(g) + I2(g)
The reaction H2(g) + I2(g) ⇌ 2HI(g) has Kp = 45.9 at 763 K. A particular equilibrium mixture at 763 K contains HI at a pressure of 4.94 atm and H2 at a pressure of 0.628 atm. Calculate the equilibrium...
See AnswerQ: For the reaction: H2(g) + F2(
For the reaction: H2(g) + F2(g) ⇌ 2HF(g) K = 2.1 * 10-3 at a certain temperature. At equilibrium, [H2] = [F2] = 0.083 M. What is the concentration of HF under these conditions?
See AnswerQ: For the following endothermic reaction at equilibrium: 2SO3(g
For the following endothermic reaction at equilibrium: 2SO3(g) ⇌ 2SO2(g) + O2(g) which of the following changes will increase the value of K? a. increasing the temperature b. decreasing the temp...
See AnswerQ: Consider the following exothermic reaction at equilibrium: N2(g
Consider the following exothermic reaction at equilibrium: N2(g)+ 3H2(g) â 2NH3(g) Predict how the following changes affect the number of moles of each component of the system aft...
See AnswerQ: Write the equilibrium expression for each of the following reactions.
Write the equilibrium expression for each of the following reactions. a. C2H6( g) + Cl2( g) ⇌ C2H5Cl(s) + HCl( g) b. 4NH3( g) + 5O2( g) ⇌ 4NO( g) + 6H2O( g) c. PCl5( g) ⇌ PCl3( g) + Cl2( g)
See AnswerQ: Write the equilibrium expression for each of the following reactions.
Write the equilibrium expression for each of the following reactions. a. N2( g) + 3Cl2( g) ⇌ 2NCl3( g) b. H2( g) + I2( g) ⇌ 2HI( g) c. N2( g) + 2H2( g) ⇌ N2H4( g)
See AnswerQ: Write the equilibrium expression for each of the following reactions.
Write the equilibrium expression for each of the following reactions. a. NO2( g) + ClNO( g) ⇌ ClNO2( g) + NO( g) b. Br2( g) + 5F2( g) ⇌ 2BrF5( g) c. 4NH3( g) + 6NO( g) ⇌ 5N2( g) + 6H2O( g)
See AnswerQ: Calculate how many grams of solute and solvent are needed to prepare
Calculate how many grams of solute and solvent are needed to prepare the following solutions. a. 525 g of 3.91% iron(III) chloride solution b. 225 g of 11.9% sucrose solution c. 1.45 kg of 12.5% sod...
See AnswerQ: Write the equilibrium expression for each of the following reactions.
Write the equilibrium expression for each of the following reactions. a. CO( g) + 2H2( g) ⇌ CH3OH( g) b. 2NO2( g) ⇌ 2NO( g) + O2( g) c. P4( g) + 6Br2( g) ⇌ 4PBr3( g)
See AnswerQ: Suppose that for the reaction PCl5( g) ⇌ PCl3
Suppose that for the reaction PCl5( g) ⇌ PCl3( g) + Cl2( g) it is determined, at a particular temperature, that the equilibrium concentrations are [PCl5( g)] = 0.0711 M, [PCl3( g)] = 0.0302 M, and [C...
See AnswerQ: For the simple reaction 2H2(g) + O2(
For the simple reaction 2H2(g) + O2(g) 2H2O(l) list the types of bonds that must be broken and the types of bonds that must form for the chemical reaction to take place.
See AnswerQ: Ammonia, a very important industrial chemical, is produced by the
Ammonia, a very important industrial chemical, is produced by the direct combination of the following elements under carefully controlled conditions: N2(g) + 3H2(g) ⇌ 2NH3(g) Suppose, in an experimen...
See AnswerQ: At high temperatures, elemental nitrogen and oxygen react with each other
At high temperatures, elemental nitrogen and oxygen react with each other to form nitrogen monoxide. N2(g) + O2(g) ⇌ 2NO(g) Suppose the system is analyzed at a particular temperature, and the equilib...
See AnswerQ: Suppose that for the reaction 2N2O( g) + O2
Suppose that for the reaction 2N2O( g) + O2( g) ⇌ 4NO( g) it is determined, at a particular temperature, that the equilibrium concentrations are [NO( g)] = 0.00341 M, [N2O( g)] = 0.0293 M, and [O2( g...
See AnswerQ: Write the equilibrium expression for each of the following heterogeneous equilibria.
Write the equilibrium expression for each of the following heterogeneous equilibria. a. P4(s) + 6F2( g) ⇌4PF3( g) b. Xe( g) + 2F2( g) ⇌XeF4(s) c. 2SiO(s) + 4Cl2( g) ⇌2SiCl4( l ) + O2( g)
See AnswerQ: Write the equilibrium expression for each of the following heterogeneous equilibria.
Write the equilibrium expression for each of the following heterogeneous equilibria. a. 2LiHCO3(s) ⇌ Li2CO3(s) + H2O( g) + CO2( g) b. PbCO3(s) ⇌ PbO(s) + CO2( g) c. 4Al(s) + 3O2( g) ⇌ 2Al2O3(s)
See AnswerQ: Write the equilibrium expression for each of the following heterogeneous equilibria.
Write the equilibrium expression for each of the following heterogeneous equilibria. a. C(s) + H2O( g) ⇌ H2( g) + CO( g) b. H2O( l ) ⇌ H2O( g) c. 4B(s) + 3O2( g) ⇌ 2B2O3(s)
See AnswerQ: Indicate whether the stated equilibrium expression is correct for each of the
Indicate whether the stated equilibrium expression is correct for each of the following heterogeneous equilibria. For those expressions that are not correct, provide the correct expression along with...
See AnswerQ: How is the strength of an acid related to the fact that
How is the strength of an acid related to the fact that a competition for protons exists in aqueous solution between water molecules and the anion of the acid?
See AnswerQ: In your own words, describe what Le Châtelier’s principle tells us
In your own words, describe what Le Châtelier’s principle tells us about how we can change the position of a reaction system at equilibrium.
See AnswerQ: For an equilibrium involving gaseous substances, what effect, in general
For an equilibrium involving gaseous substances, what effect, in general terms, is realized when the volume of the system is decreased?
See AnswerQ: For the reaction system C(s) + H2O(
For the reaction system C(s) + H2O( g) ⇌ H2( g) + CO( g) which has already reached a state of equilibrium, predict the effect that each of the following changes will have on the position of the equi...
See AnswerQ: For the reaction system P4(s) + 6F2(
For the reaction system P4(s) + 6F2( g) ⇌ 4PF3( g) which has already reached a state of equilibrium, predict the effect that each of the following changes will have on the position of the equilibriu...
See AnswerQ: Suppose the reaction system CH4(g) + 2O2(
Suppose the reaction system CH4(g) + 2O2(g) ⇌ CO2(g) + 2H2O(l) has already reached equilibrium. Predict the effect of each of the following changes on the position of the equilibrium. Tell whether th...
See AnswerQ: Consider the general reaction 2A( g) + B(
Consider the general reaction 2A( g) + B(s) ⇌ C( g) + 3D( g) ∆H = 1115 kJ/mol which has already come to equilibrium. Predict whether the equilibrium will shift to the left, will shift to the right,...
See AnswerQ: Hydrogen gas and chlorine gas in the presence of light react explosively
Hydrogen gas and chlorine gas in the presence of light react explosively to form hydrogen chloride H2( g) + Cl2( g) ⇌ 2HCl( g) The reaction is strongly exothermic. Would an increase in temperature fo...
See AnswerQ: Hydrogen gas, oxygen gas, and water vapor are in equilibrium
Hydrogen gas, oxygen gas, and water vapor are in equilibrium in a closed container. Hydrogen gas is injected into the container, and the system is allowed to return to equilibrium. Which of the follow...
See AnswerQ: The reaction C2H2(g) + 2Br2(g)
The reaction C2H2(g) + 2Br2(g) ⇌ C2H2Br4(g) is exothermic in the forward direction. Will an increase in temperature shift the position of the equilibrium toward reactants or products?
See AnswerQ: When molecules collide, a certain minimum energy called the is needed
When molecules collide, a certain minimum energy called the is needed for the reaction to occur.
See AnswerQ: How do the properties of a nonhomogeneous (heterogeneous) mixture differ
How do the properties of a nonhomogeneous (heterogeneous) mixture differ from those of a solution? Give two examples of nonhomogeneous mixtures.
See AnswerQ: A strong acid has a weak conjugate base, whereas a weak
A strong acid has a weak conjugate base, whereas a weak acid has a relatively strong conjugate base. Explain.
See AnswerQ: Old fashioned “smelling salts” consist of ammonium carbonate, (
Old fashioned “smelling salts” consist of ammonium carbonate, (NH4)2CO3. The reaction for the decomposition of ammonium carbonate (NH4)2CO3(s) ⇌ 2NH3(g) + CO2(g) + H2O(g) is endothermic. What would b...
See AnswerQ: Plants synthesize the sugar dextrose according to the following reaction by absorbing
Plants synthesize the sugar dextrose according to the following reaction by absorbing radiant energy from the sun (photosynthesis). 6CO2(g) + 6H2O(g) ⇌ C6H12O6(s) + 6O2(g) Will an increase in...
See AnswerQ: Suppose a reaction has the equilibrium constant K 5 1.7
Suppose a reaction has the equilibrium constant K 5 1.7 * 10-8 at a particular temperature. Will there be a large or small amount of unreacted starting material present when this reaction reaches equi...
See AnswerQ: For the reaction Br2( g) + 5F2( g
For the reaction Br2( g) + 5F2( g) ⇌ 2BrF5( g) the system at equilibrium at a particular temperature is analyzed, and the following concentrations are found: [BrF5( g)] = 1.01 * 10-9 M, [Br2( g)] = 2...
See AnswerQ: Consider the reaction SO2( g) + NO2( g
Consider the reaction SO2( g) + NO2( g) ⇌ SO3( g) + NO( g) Suppose it is found at a particular temperature that the concentrations in the system at equilibrium are as follows: [SO3( g)] = 4.99 * 10-5...
See AnswerQ: For the reaction 2CO(g) + O2(g
For the reaction 2CO(g) + O2(g) ⇌ 2CO2(g) it is found at equilibrium at a certain temperature that the concentrations are [CO( g)] = 2.7 * 10-4 M, [O2( g)] = 1.9 * 10-3 M, and [CO2( g)] = 1.1 * 10-1...
See AnswerQ: For the reaction CO2( g) + H2( g
For the reaction CO2( g) + H2( g) ⇌ CO( g) + H2O( g) the equilibrium constant, K, has the value 5.21 * 10-3 at a particular temperature. If the system is analyzed at equilibrium at this temperature,...
See AnswerQ: The equilibrium constant for the reaction H2(g) +
The equilibrium constant for the reaction H2(g) + F2(g) ⇌ 2HF(g) has the value 2.1 * 103 at a particular temperature. When the system is analyzed at equilibrium at this temperature, the concentration...
See AnswerQ: How does a catalyst work to speed up a chemical reaction?
How does a catalyst work to speed up a chemical reaction?
See AnswerQ: 2H2O(g) ⇌ 2H2(g) + O2(
2H2O(g) ⇌ 2H2(g) + O2(g) K = 2.4 * 10-3 at a given temperature. At equilibrium it is found that [H2O( g)] = 1.1 * 10-1 M and [H2( g)] = 1.9 * 10-2 M. What is the concentration of O2( g) under these co...
See AnswerQ: An aqueous solution is to be prepared that will be 7.
An aqueous solution is to be prepared that will be 7.51% by mass ammonium nitrate. What mass of NH4NO3 and what mass of water will be needed to prepare 1.25 kg of the solution?
See AnswerQ: For the reaction 3O2( g) ⇌ 2O3( g
For the reaction 3O2( g) ⇌ 2O3( g) The equilibrium constant, K, has the value 1.12 * 10-54 at a particular temperature. a. What does the very small equilibrium constant indicate about the e...
See AnswerQ: For the reaction N2O4(g) ⇌ 2NO2(g
For the reaction N2O4(g) ⇌ 2NO2(g) the equilibrium constant K has the value 8.1 * 10-3 at a particular temperature. If the concentration of N2O4(g) is found to be 5.4 * 10-4 M in the equilibrium syst...
See AnswerQ: What is the special name given to the equilibrium constant for the
What is the special name given to the equilibrium constant for the dissolving of an ionic solute in water?
See AnswerQ: Which of the following will affect the total amount of solute that
Which of the following will affect the total amount of solute that can dissolve in a given amount of solvent? a. The solution is stirred. b. The solute is ground to fine particles before dissolving....
See AnswerQ: Write the balanced chemical equation describing the dissolving of each of the
Write the balanced chemical equation describing the dissolving of each of the following sparingly soluble salts in water. Write the expression for Ksp for each process. a. AgIO3(s) b. Sn(OH)2(s) c....
See AnswerQ: Write the balanced chemical equation describing the dissolving of each of the
Write the balanced chemical equation describing the dissolving of each of the following sparingly soluble salts in water. Write the expression for Ksp for each process. a. NiS(s) b. CuCO3(s) c. BaC...
See AnswerQ: Why are enzymes important? For example, what is the importance
Why are enzymes important? For example, what is the importance of the enzyme carbonic anhydrase in the body?
See AnswerQ: A saturated solution of nickel(II) sulfide contains approximately 3
A saturated solution of nickel(II) sulfide contains approximately 3.6 * 10-4 g of dissolved NiS per liter at 20 °C. Calculate the solubility product Ksp for NiS at 20 °C.
See AnswerQ: Before two molecules can react, chemists envision that the molecules must
Before two molecules can react, chemists envision that the molecules must first collide with one another. Is collision among molecules the only consideration for the molecules to react with one anothe...
See AnswerQ: Why does an increase in temperature favor an increase in the speed
Why does an increase in temperature favor an increase in the speed of a reaction?
See AnswerQ: What does it mean to say that an acid is weak in
What does it mean to say that an acid is weak in aqueous solution? What does this reveal about the ability of the acid’s anion to attract protons?
See AnswerQ: The minimum energy required for molecules to react with each other
The minimum energy required for molecules to react with each other is called the energy.
See AnswerQ: A(n) speeds up a reaction without being consumed.
A(n) speeds up a reaction without being consumed.
See AnswerQ: Equilibrium may be defined as the of two processes, one of
Equilibrium may be defined as the of two processes, one of which is the opposite of the other.
See AnswerQ: When a chemical system has reached equilibrium, the concentrations of all
When a chemical system has reached equilibrium, the concentrations of all reactants and products remain with time.
See AnswerQ: What does it mean to say that all chemical reactions are,
What does it mean to say that all chemical reactions are, to one extent or another, reversible?
See AnswerQ: What does it mean to say that chemical equilibrium is a dynamic
What does it mean to say that chemical equilibrium is a dynamic process?
See AnswerQ: At the point of chemical equilibrium, the rate of the forward
At the point of chemical equilibrium, the rate of the forward reaction the rate of the reverse reaction.
See AnswerQ: Consider the equilibrium process depicted in Fig. 17.6.
Consider the equilibrium process depicted in Fig. 17.6. When does the equilibrium state occur? From figure 17.6:
See AnswerQ: Equilibria involving reactants or products in more than one state are said
Equilibria involving reactants or products in more than one state are said to be .
See AnswerQ: According to Le Châtelier’s principle, when a large excess of a
According to Le Châtelier’s principle, when a large excess of a gaseous reactant is added to a reaction system at equilibrium, the amounts of products .
See AnswerQ: What is a homogeneous equilibrium system? Give an example of a
What is a homogeneous equilibrium system? Give an example of a homogeneous equilibrium reaction. What is a heterogeneous equilibrium system? Write two chemical equations that represent heterogeneous e...
See AnswerQ: Addition of an inert substance (one that does not participate in
Addition of an inert substance (one that does not participate in the reaction) does not change the of an equilibrium.
See AnswerQ: When the volume of a vessel containing a gaseous equilibrium system is
When the volume of a vessel containing a gaseous equilibrium system is decreased, the of the gaseous substances present is initially increased.
See AnswerQ: What is meant by the solubility product for a sparingly soluble salt
What is meant by the solubility product for a sparingly soluble salt? Choose a sparingly soluble salt and show how the salt ionizes when dissolved in water, and write the expression for its solubility...
See AnswerQ: Many sugars undergo a process called mutarotation, in which the sugar
Many sugars undergo a process called mutarotation, in which the sugar molecules interconvert between two isomeric forms, finally reaching an equilibrium between them. This is true for the simple sugar...
See AnswerQ: For the reaction CaCO3(s) ⇌ CaO(s
For the reaction CaCO3(s) ⇌ CaO(s) + CO2(g) the equilibrium constant K has the form K = [CO2]. Using a handbook to find density information about CaCO3(s) and CaO(s), show that the concentrations of...
See AnswerQ: When writing a chemical equation for a reaction that comes to equilibrium
When writing a chemical equation for a reaction that comes to equilibrium, how do we indicate symbolically that the reaction is reversible?
See AnswerQ: How does the collision model account for the fact that a reaction
How does the collision model account for the fact that a reaction proceeds faster when the concentrations of the reactants are increased?
See AnswerQ: How does an increase in temperature result in an increase in the
How does an increase in temperature result in an increase in the number of successful collisions between reactant molecules? What does an increase in temperature mean on a molecular basis?
See AnswerQ: Write the equilibrium expression for each of the following reactions.
Write the equilibrium expression for each of the following reactions. a. H2( g) + Br2( g) ⇌ 2HBr( g) b. 2H2( g) + S2( g) ⇌ 2H2S( g) c. H2( g) + C2N2( g) ⇌ 2HCN( g)
See AnswerQ: Write the equilibrium expression for each of the following reactions.
Write the equilibrium expression for each of the following reactions. a. 2O3( g) ⇌ 3O2( g) b. CH4( g) + 2O2( g) ⇌ CO2( g) + 2H2O( g) c. C2H4( g) + Cl2( g) ⇌ C2H4Cl2( g)
See AnswerQ: True or false? The position of a heterogeneous equilibrium does not
True or false? The position of a heterogeneous equilibrium does not depend on the amounts of pure solid or pure liquid reactants or products present because the concentrations of pure solids and liqui...
See AnswerQ: For the reaction N2(g) + 3Cl2(g
For the reaction N2(g) + 3Cl2(g) ⇌ 2NCl3(g) an analysis of an equilibrium mixture at a particular temperature is performed. It is found that [NCl3] = 1.9 * 10-1 M, [N2] * 1.4 * 10-3 M, and [Cl2] = 4....
See AnswerQ: Gaseous phosphorus pentachloride decomposes according to the reaction PCl5(g
Gaseous phosphorus pentachloride decomposes according to the reaction PCl5(g) ⇌ PCl3(g) + Cl2(g) The equilibrium system was analyzed at a particular temperature, and the concentrations of the substan...
See AnswerQ: Suppose you dissolved a teaspoon of sugar in a glass of water
Suppose you dissolved a teaspoon of sugar in a glass of water. Which substance is the solvent? Which substance is the solute?
See AnswerQ: In a solution, the substance present in the largest amount is
In a solution, the substance present in the largest amount is called the , whereas the other substances present are called the .
See AnswerQ: Which of the following do not represent a conjugate acid–base
Which of the following do not represent a conjugate acid–base pair? For those pairs that are not conjugate acid–base pairs, write the correct conjugate acid–base pair for each species in the pair. a....
See AnswerQ: Which of the following do not represent a conjugate acid–base
Which of the following do not represent a conjugate acid–base pair? For those pairs that are not conjugate acid–base pairs, write the correct conjugate acid–base pair for each species in the pair. a....
See AnswerQ: What does it mean to say that a solution is saturated with
What does it mean to say that a solution is saturated with a solute?
See AnswerQ: If additional solute is added to a(n) solution,
If additional solute is added to a(n) solution, it will dissolve.
See AnswerQ: A solution is a homogeneous mixture and, unlike a compound,
A solution is a homogeneous mixture and, unlike a compound, has composition.
See AnswerQ: The label “concentrated H2SO4” on a bottle means that there
The label “concentrated H2SO4” on a bottle means that there is a relatively amount of H2SO4 present in the solution.
See AnswerQ: Which of the following acids have relatively strong conjugate bases?
Which of the following acids have relatively strong conjugate bases? a. HCN b. H2S c. HBrO4 d. HNO3
See AnswerQ: How do we define the mass percent composition of a solution?
How do we define the mass percent composition of a solution? Give an example of a solution, and explain the relative amounts of solute and solvent present in the solution in terms of the mass percent...
See AnswerQ: A solution that is 9% by mass glucose contains 9 g
A solution that is 9% by mass glucose contains 9 g of glucose in every g of solution.
See AnswerQ: Calculate the mass, in grams, of solute present in each
Calculate the mass, in grams, of solute present in each of the following solutions. a. 375 g of 1.51% ammonium chloride solution b. 125 g of 2.91% sodium chloride solution c. 1.31 kg of 4.92% potas...
See AnswerQ: In each of the following chemical equations, identify the conjugate acid
In each of the following chemical equations, identify the conjugate acid–base pairs. a. NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH-(aq) b. PO43-(aq) + H2O(l) ⇌ HPO42-(aq) + OH-(aq) c. C2H3O2-(aq) + H2O(l) ⇌...
See AnswerQ: A sample of an iron alloy contains 92.1 g Fe
A sample of an iron alloy contains 92.1 g Fe, 2.59 g C, and 1.59 g Cr. Calculate the percent by mass of each component present in the alloy sample.
See AnswerQ: Consider the iron alloy described in Question 19. Suppose it is
Consider the iron alloy described in Question 19. Suppose it is desired to prepare 1.00 kg of this alloy. What mass of each component would be necessary? From 19: A sample of an iron alloy contains 9...
See AnswerQ: Write the formula for the hydronium ion. Write an equation for
Write the formula for the hydronium ion. Write an equation for the formation of the hydronium ion when an acid is dissolved in water.
See AnswerQ: If 67.1 g of CaCl2 is added to 275 g
If 67.1 g of CaCl2 is added to 275 g of water, calculate the mass percent of CaCl2 in the solution.
See AnswerQ: A solution is to be prepared that will be 4.50
A solution is to be prepared that will be 4.50% by mass calcium chloride. To prepare 175 g of the solution, what mass of calcium chloride will be needed?
See AnswerQ: How many grams of KBr are contained in 125 g of a
How many grams of KBr are contained in 125 g of a 6.25% (by mass) KBr solution?
See AnswerQ: Hydrogen peroxide solutions sold in drugstores as an antiseptic typically contain 3
Hydrogen peroxide solutions sold in drugstores as an antiseptic typically contain 3.0% of the active ingredient, H2O2. Hydrogen peroxide decomposes into water and oxygen gas when applied to a wound ac...
See AnswerQ: What mass of each solute is present in 285 g of a
What mass of each solute is present in 285 g of a solution that contains 5.00% by mass NaCl and 7.50% by mass Na2CO3?
See AnswerQ: The “Chemistry in Focus” segment Plants Fight Back discusses how
The “Chemistry in Focus” segment Plants Fight Back discusses how tobacco plants under attack by disease produce salicylic acid. Examine the structure of salicylic acid and predict whether it behaves a...
See AnswerQ: A solvent sold for use in the laboratory contains 0.95
A solvent sold for use in the laboratory contains 0.95% of a stabilizing agent that prevents the solvent from reacting with the air. What mass of the stabilizing agent is present in 1.00 kg of the sol...
See AnswerQ: A solution you used in last week’s lab experiment was labeled “
A solution you used in last week’s lab experiment was labeled “3 M HCl.” Describe in words the composition of this solution.
See AnswerQ: A solution labeled “0.25 M AlCl3” would contain
A solution labeled “0.25 M AlCl3” would contain mole(s) of Al3+ and mole(s) of Cl- in each liter of the solution.
See AnswerQ: Write the conjugate acid for each of the following bases:
Write the conjugate acid for each of the following bases: a. PO43- b. IO3- c. NO3- d. NH2-
See AnswerQ: To prepare 500. mL of 1.02 M sugar solution
To prepare 500. mL of 1.02 M sugar solution, which of the following would you need? a. 500. mL of water and 1.02 mole of sugar b. 1.02 mole of sugar and enough water to make the total volume 500. mL...
See AnswerQ: For each of the following solutions, the number of moles of
For each of the following solutions, the number of moles of solute is given, followed by the total volume of the solution prepared. Calculate the molarity of each solution. a. 0.521 mol NaCl; 125 mL...
See AnswerQ: For each of the following solutions, the number of moles of
For each of the following solutions, the number of moles of solute is given, followed by the total volume of the solution prepared. Calculate the molarity of each solution. a. 0.754 mol KNO3; 225 mL...
See AnswerQ: For each pair of concentrations, tell which represents the more acidic
For each pair of concentrations, tell which represents the more acidic solution. a. [H+] = 1.2 * 10-3 M or [H+] = 4.5 * 10-4 M b. [H+] = 2.6 * 10-6 M or [H+] = 4.3 * 10-8 M c. [H+] = 0.000010 M or...
See AnswerQ: Sulfuric acid has a great affinity for water, and for this
Sulfuric acid has a great affinity for water, and for this reason, the most concentrated form of sulfuric acid available is actually a 98.3% solution. The density of concentrated sulfuric acid is 1.84...
See AnswerQ: For each pair of concentrations, tell which represents the more basic
For each pair of concentrations, tell which represents the more basic solution. a. [H+] = 2.02 * 10-7 M or [OH-] = 5.05 * 10-5 M b. [H+] = 1.79 * 10-5 M or [OH-] = 4.21 * 10-6 M c. [H+] = 1.25 * 10...
See AnswerQ: A laboratory assistant needs to prepare 225 mL of 0.150
A laboratory assistant needs to prepare 225 mL of 0.150 M CaCl2 solution. How many grams of calcium chloride will she need?
See AnswerQ: How many grams of formaldehyde are in 113.1 mL of
How many grams of formaldehyde are in 113.1 mL of a 3.0 M aqueous solution of formaldehyde? The formula for formaldehyde is HCHO.
See AnswerQ: Standard solutions of calcium ion used to test for water hardness are
Standard solutions of calcium ion used to test for water hardness are prepared by dissolving pure calcium carbonate, CaCO3, in dilute hydrochloric acid. A 1.745-g sample of CaCO3 is placed in a 250.0-...
See AnswerQ: An alcoholic iodine solution (“tincture” of iodine) is prepared
An alcoholic iodine solution (“tincture” of iodine) is prepared by dissolving 5.15 g of iodine crystals in enough alcohol to make a volume of 225 mL. Calculate the molarity of iodine in the solution....
See AnswerQ: If 42.5 g of NaOH is dissolved in water and
If 42.5 g of NaOH is dissolved in water and diluted to a final volume of 225 mL, calculate the molarity of the solution.
See AnswerQ: Standard silver nitrate solutions are used in the analysis of samples containing
Standard silver nitrate solutions are used in the analysis of samples containing chloride ion. How many grams of silver nitrate are needed to prepare 250. mL of a 0.100 M AgNO3 solution?
See AnswerQ: Write the conjugate acid for each of the following bases.
Write the conjugate acid for each of the following bases. a. ClO- b. Cl- c. ClO3- d. ClO4-
See AnswerQ: Write the conjugate base for each of the following acids:
Write the conjugate base for each of the following acids: a. H2S b. HS2 c. NH3 d. H2SO3
See AnswerQ: Calculate the pH corresponding to each of the pOH values listed,
Calculate the pH corresponding to each of the pOH values listed, and indicate whether each solution is acidic, basic, or neutral. a. pOH = 4.32 b. pOH = 8.90 c. pOH = 1.81 d. pOH = 13.1
See AnswerQ: Anions containing hydrogen (for example, HCO3- and H2PO42-)
Anions containing hydrogen (for example, HCO3- and H2PO42-) show amphoteric behavior when reacting with other acids or bases. Write equations illustrating the amphoterism of these anions.
See AnswerQ: Calculate the pOH value corresponding to each of the pH values listed
Calculate the pOH value corresponding to each of the pH values listed, and tell whether each solution is acidic or basic. a. pH = 10.75 b. pH = 3.66 c. pH = 1.98 d. pH = 12.47
See AnswerQ: What mass of NaOH pellets is required to prepare 3.5
What mass of NaOH pellets is required to prepare 3.5 L of 0.50 M NaOH solution?
See AnswerQ: What mass of solute is present in 225 mL of 0.
What mass of solute is present in 225 mL of 0.355 M KBr solution?
See AnswerQ: Write the conjugate base for each of the following acids.
Write the conjugate base for each of the following acids. a. HBrO b. HNO2 c. HSO3- d. CH3NH3+
See AnswerQ: Calculate the hydrogen ion concentration, in moles per liter, for
Calculate the hydrogen ion concentration, in moles per liter, for solutions with each of the following pH values. a. pH = 2.75 b. pH = 12.8 c. pH = 4.33 d. pH = 9.61
See AnswerQ: An experiment calls for 125 mL of 0.105 M NaCl
An experiment calls for 125 mL of 0.105 M NaCl solution. What mass of NaCl is required? What mass of NaCl would be required for 1.00 L of the same solution?
See AnswerQ: What volume of a 0.300 M CaCl2 solution is needed
What volume of a 0.300 M CaCl2 solution is needed to prepare 240. mL of a 0.100 M Cl- solution?
See AnswerQ: When a concentrated stock solution is diluted to prepare a less concentrated
When a concentrated stock solution is diluted to prepare a less concentrated reagent, the number of is the same both before and after the dilution.
See AnswerQ: When the volume of a given solution is tripled (by adding
When the volume of a given solution is tripled (by adding water), the new concentration of solute is the original concentration.
See AnswerQ: When 1 mole of gaseous hydrogen chloride is dissolved in enough water
When 1 mole of gaseous hydrogen chloride is dissolved in enough water to make 1 L of solution, approximately how many HCl molecules remain in the solution? Explain.
See AnswerQ: What is meant by the ion-product constant for water,
What is meant by the ion-product constant for water, Kw? What does this constant signify? Write an equation for the chemical reaction from which the constant is derived.
See AnswerQ: A bottle of acid solution is labeled “3 M HNO3.”
A bottle of acid solution is labeled “3 M HNO3.” What are the substances that are actually present in the solution? Are any HNO3 molecules present? Why or why not?
See AnswerQ: Many laboratories keep bottles of 3.0 M solutions of the
Many laboratories keep bottles of 3.0 M solutions of the common acids on hand. Given the following molarities of the concentrated acids, determine how many milliliters of each concentrated acid would...
See AnswerQ: For convenience, one form of sodium hydroxide that is sold commercially
For convenience, one form of sodium hydroxide that is sold commercially is the saturated solution. This solution is 19.4 M, which is approximately 50% by mass sodium hydroxide. What volume of this sol...
See AnswerQ: How would you prepare 275 mL of 0.350 M NaCl
How would you prepare 275 mL of 0.350 M NaCl solution using an available 2.00 M solution?
See AnswerQ: Suppose 325 mL of 0.150 M NaOH is needed for
Suppose 325 mL of 0.150 M NaOH is needed for your experiment. How would you prepare this if all that is available is a 1.01 M NaOH solution?
See AnswerQ: How much water must be added to 500. mL of 0
How much water must be added to 500. mL of 0.200 M HCl to produce a 0.150 M solution? (Assume that the volumes are additive.)
See AnswerQ: During a summer research internship, you are asked to do lab
During a summer research internship, you are asked to do lab work and prepare solutions for experiments to be run on samples that will come in from the field. You need to prepare a 0.300 M NaOH soluti...
See AnswerQ: Write a chemical equation showing how each of the following species can
Write a chemical equation showing how each of the following species can behave as indicated when dissolved in water. a. HSO3- as an acid b. CO32- as a base c. H2PO4- as an acid d. C2H3O2- as a bas...
See AnswerQ: Generally only the carbonates of the Group 1 elements and the ammonium
Generally only the carbonates of the Group 1 elements and the ammonium ion are soluble in water; most other carbonates are insoluble. How many milliliters of 0.125 M sodium carbonate solution would be...
See AnswerQ: Write a chemical equation showing how each of the following species can
Write a chemical equation showing how each of the following species can behave as indicated when dissolved in water. a. O2- as a base b. NH3 as a base c. HSO4- as an acid d. HNO- as an acid
See AnswerQ: According to the Brønsted-Lowry model, an acid is a
According to the Brønsted-Lowry model, an acid is a “proton donor” and a base is a “proton acceptor.” Explain.
See AnswerQ: What happens to the hydroxide ion concentration in aqueous solutions when we
What happens to the hydroxide ion concentration in aqueous solutions when we increase the hydrogen ion concentration by adding an acid? What happens to the hydrogen ion concentration in aqueous soluti...
See AnswerQ: Write an equation showing how HCl(g) behaves as an
Write an equation showing how HCl(g) behaves as an Arrhenius acid when dissolved in water. Write an equation showing how NaOH(s) behaves as an Arrhenius base when dissolved in water.
See AnswerQ: Of the following conditions, which indicate an acidic solution?
Of the following conditions, which indicate an acidic solution? a. pH = 8.95 b. [H+] < 1.0 * 10-7 M c. pOH = 3.46 d. [OH-] = 7.11 * 10-10 M
See AnswerQ: Of the following conditions, which indicate a basic solution?
Of the following conditions, which indicate a basic solution? a. pOH = 12.53 b. pH = 3.64 c. pOH < [H1] d. [OH-] > 1.0 * 10-7 M
See AnswerQ: What volume of 0.502 M NaOH solution would be required
What volume of 0.502 M NaOH solution would be required to neutralize 27.2 mL of 0.491 M HNO3 solution?
See AnswerQ: What volume of a 0.500 M NaOH solution would be
What volume of a 0.500 M NaOH solution would be required to neutralize 40.0 mL of a 0.400 M H2SO4 solution?
See AnswerQ: Is it possible for a solution to have [H+] =
Is it possible for a solution to have [H+] = 0.002 M and [OH-] = 5.2 * 10-6 M at 25 °C? Explain.
See AnswerQ: The total acidity in water samples can be determined by neutralization with
The total acidity in water samples can be determined by neutralization with standard sodium hydroxide solution. What is the total concentration of hydrogen ion, H+, present in a water sample if 100. m...
See AnswerQ: According to Arrhenius, bases are species that produce ions in aqueous
According to Arrhenius, bases are species that produce ions in aqueous solution.
See AnswerQ: According to the Brønsted–Lowry model, a base is a
According to the Brønsted–Lowry model, a base is a species that protons.
See AnswerQ: One equivalent of an acid is the amount of the acid required
One equivalent of an acid is the amount of the acid required to provide .
See AnswerQ: What is a standard solution? Describe the steps involved in preparing
What is a standard solution? Describe the steps involved in preparing a standard solution.
See AnswerQ: A solution that contains 1 equivalent of acid or base per liter
A solution that contains 1 equivalent of acid or base per liter is said to be a solution.
See AnswerQ: An acid such as HCl that strongly conducts an electric current when
An acid such as HCl that strongly conducts an electric current when dissolved in water is said to be a(n) acid.
See AnswerQ: How many equivalents of hydroxide ion are needed to react with 1
How many equivalents of hydroxide ion are needed to react with 1.53 equivalents of hydrogen ion? How did you know this when no balanced chemical equation was provided for the reaction?
See AnswerQ: For each of the following solutions, calculate the normality.
For each of the following solutions, calculate the normality. a. 25.2 mL of 0.105 M HCl diluted with water to a total volume of 75.3 mL b. 0.253 M H3PO4 c. 0.00103 M Ca(OH)2
See AnswerQ: The ion-product constant for water, Kw, has the
The ion-product constant for water, Kw, has the value at 25 °C.
See AnswerQ: Calculate the normality of each of the following solutions. a
Calculate the normality of each of the following solutions. a. 0.250 M HCl b. 0.105 M H2SO4 c. 5.3 * 10-2 M H3PO4
See AnswerQ: Calculate the normality of each of the following solutions. a
Calculate the normality of each of the following solutions. a. 0.134 M NaOH b. 0.00521 M Ca(OH)2 c. 4.42 M H3PO4
See AnswerQ: A solution of phosphoric acid, H3PO4, is found to contain
A solution of phosphoric acid, H3PO4, is found to contain 35.2 g of H3PO4 per liter of solution. Calculate the molarity and normality of the solution.
See AnswerQ: A buffered solution is one that resists a change in when either
A buffered solution is one that resists a change in when either a strong acid or a strong base is added to it.
See AnswerQ: How many milliliters of 0.50 N NaOH are required to
How many milliliters of 0.50 N NaOH are required to neutralize exactly 15.0 mL of 0.35 N H2SO4?
See AnswerQ: Calculate the [H+] in each of the following solutions,
Calculate the [H+] in each of the following solutions, and indicate whether the solution is acidic, basic, or neutral. a. [OH-] = 7.86 * 10-4 M b. [OH-] = 5.44 * 10-2 M c. [OH-] = 3.19 * 10-3 M d....
See AnswerQ: When sodium hydroxide, NaOH, is added dropwise to a buffered
When sodium hydroxide, NaOH, is added dropwise to a buffered solution, the component of the buffer consumes the added hydroxide ion.
See AnswerQ: When hydrochloric acid, HCl, is added dropwise to a buffered
When hydrochloric acid, HCl, is added dropwise to a buffered solution, the component of the buffer consumes the added hydrogen ion.
See AnswerQ: Suppose that 27.34 mL of standard 0.1021 M
Suppose that 27.34 mL of standard 0.1021 M NaOH is required to neutralize 25.00 mL of an unknown H2SO4 solution. Calculate the molarity and the normality of the unknown solution.
See AnswerQ: In each of the following chemical equations, identify the conjugate acid
In each of the following chemical equations, identify the conjugate acid–base pairs. a. CH3NH2 + H2O ⇌ CH3NH3+ + OH- b. CH3COOH + NH3 ⇌ CH3COO- + NH4+ c. HF + NH3 ⇌ F- + NH4+
See AnswerQ: Write the conjugate acid for each of the following. a
Write the conjugate acid for each of the following. a. NH3 b. NH2- c. H2O d. OH-
See AnswerQ: Write the conjugate base for each of the following. a
Write the conjugate base for each of the following. a. H3PO4 b. HCO3- c. HF d. H2SO4
See AnswerQ: If 500. g of water is added to 75 g of
If 500. g of water is added to 75 g of 25% NaCl solution, what is the percent by mass of NaCl in the diluted solution?
See AnswerQ: Name four strong acids. For each of these, write the
Name four strong acids. For each of these, write the equation showing the acid dissociating in water.
See AnswerQ: Organic acids contain the carboxyl group / Using acetic
Organic acids contain the carboxyl group Using acetic acid, CH3-COOH, and propionic acid, CH3CH2-COOH, write equations showing how the carboxyl group enables these substances to behave as weak acids...
See AnswerQ: Calculate the [OH-] in each of the following solutions,
Calculate the [OH-] in each of the following solutions, and indicate whether the solution is acidic or basic. a. [H+] = 4.01 * 10-4 M b. [H+] = 7.22 * 10-6 M c. [H+] = 8.05 * 10-7 M d. [H+] = 5.43...
See AnswerQ: Strictly speaking, the solvent is the component of a solution that
Strictly speaking, the solvent is the component of a solution that is present in the largest amount on a mole basis. For solutions involving water, water is almost always the solvent because there ten...
See AnswerQ: Aqueous ammonia is typically sold by chemical supply houses as the saturated
Aqueous ammonia is typically sold by chemical supply houses as the saturated solution, which has a concentration of 14.5 mol/L. What volume of NH3 at STP is required to prepare 100. mL of concentrated...
See AnswerQ: What volume of hydrogen chloride gas at STP is required to prepare
What volume of hydrogen chloride gas at STP is required to prepare 500. mL of 0.100 M HCl solution?
See AnswerQ: Calculate the pOH corresponding to each of the pH values listed,
Calculate the pOH corresponding to each of the pH values listed, and indicate whether each solution is acidic, basic, or neutral. a. pH = 1.02 b. pH = 13.4 c. pH = 9.03 d. pH = 7.20
See AnswerQ: The concentration of a solution of HCl is 33.1%
The concentration of a solution of HCl is 33.1% by mass, and its density was measured to be 1.147 g/mL. How many milliliters of the HCl solution are required to obtain 10.0 g of HCl?
See AnswerQ: An experiment calls for 1.00 g of silver nitrate,
An experiment calls for 1.00 g of silver nitrate, but all that is available in the laboratory is a 0.50% solution of AgNO3. Assuming the density of the silver nitrate solution to be very nearly that o...
See AnswerQ: Calculate the hydrogen ion concentration, in moles per liter, for
Calculate the hydrogen ion concentration, in moles per liter, for solutions with each of the following pH values. a. pH = 8.34 b. pH = 5.90 c. pH = 2.65 d. pH = 12.6
See AnswerQ: A solution is 0.1% by mass calcium chloride.
A solution is 0.1% by mass calcium chloride. Therefore, 100. g of the solution contains g of calcium chloride.
See AnswerQ: Calculate the mass, in grams, of NaCl present in each
Calculate the mass, in grams, of NaCl present in each of the following solutions. a. 11.5 g of 6.25% NaCl solution b. 6.25 g of 11.5% NaCl solution c. 54.3 g of 0.91% NaCl solution d. 452 g of 12....
See AnswerQ: What is an oxyacid? Write the formulas of three acids that
What is an oxyacid? Write the formulas of three acids that are oxyacids. Write the formulas of three acids that are not oxyacids.
See AnswerQ: Calculate the [OH-] in each of the following solutions,
Calculate the [OH-] in each of the following solutions, and indicate whether the solution is acidic or basic. a. [H+] = 1.02 * 10-7 M b. [H+] = 9.77 * 10-8 M c. [H+] = 3.41 * 10-3 M d. [H+] = 4.79...
See AnswerQ: A certain grade of steel is made by dissolving 5.0
A certain grade of steel is made by dissolving 5.0 g of carbon and 1.5 g of nickel per 100. g of molten iron. What is the mass percent of each component in the finished steel?
See AnswerQ: A sugar solution is prepared in such a way that it contains
A sugar solution is prepared in such a way that it contains 10.% dextrose by mass. What quantity of this solution do we need to obtain 25 g of dextrose?
See AnswerQ: How many grams of Na2CO3 are contained in 500. g of
How many grams of Na2CO3 are contained in 500. g of a 5.5% by mass Na2CO3 solution?
See AnswerQ: What mass of KNO3 is required to prepare 125 g of 1
What mass of KNO3 is required to prepare 125 g of 1.5% KNO3 solution?
See AnswerQ: A solution contains 7.5% by mass NaCl and 2
A solution contains 7.5% by mass NaCl and 2.5% by mass KBr. What mass of each solute is contained in 125 g of the solution?
See AnswerQ: How many moles of each ion are present in 11.7
How many moles of each ion are present in 11.7 mL of 0.102 M Na3PO4 solution?
See AnswerQ: You add 40.0 mL of water to 60.0
You add 40.0 mL of water to 60.0 mL of a 2.00 M calcium chloride solution. How many moles of calcium chloride are in the new solution?
See AnswerQ: Choose pairs in which the species listed first is the conjugate base
Choose pairs in which the species listed first is the conjugate base of the species listed second. a. S2-, HS- b. H+, OH- c. HBr, Br- d. NO2-, HNO2
See AnswerQ: Complete the table for each of the following solutions: /
Complete the table for each of the following solutions:
See AnswerQ: Concentrated hydrochloric acid is made by pumping hydrogen chloride gas into distilled
Concentrated hydrochloric acid is made by pumping hydrogen chloride gas into distilled water. If concentrated HCl contains 439 g of HCl per liter, what is the molarity?
See AnswerQ: For each of the following solutions, the mass of solute is
For each of the following solutions, the mass of solute is given, followed by the total volume of the solution prepared. Calculate the molarity of each solution. a. 3.51 g NaCl; 25 mL b. 3.51 g NaCl...
See AnswerQ: Water is the most common amphoteric substance, which means that,
Water is the most common amphoteric substance, which means that, depending on the circumstances, water can behave either as an acid or as a base. Using HF as an example of an acid and NH3 as an exampl...
See AnswerQ: How many moles of the indicated solute does each of the following
How many moles of the indicated solute does each of the following solutions contain? a. 1.5 L of 3.0 M H2SO4 solution b. 35 mL of 5.4 M NaCl solution c. 5.2 L of 18 M H2SO4 solution d. 0.050 L of...
See AnswerQ: How do the components of a conjugate acid–base pair differ
How do the components of a conjugate acid–base pair differ from one another? Give an example of a conjugate acid–base pair to illustrate your answer.
See AnswerQ: If 10. g of AgNO3 is available, what volume of
If 10. g of AgNO3 is available, what volume of 0.25 M AgNO3 solution can be prepared?
See AnswerQ: The “Chemistry in Focus” segment Garden-Variety Acid–
The “Chemistry in Focus” segment Garden-Variety Acid– Base Indicators discusses acid–base indicators found in nature. What colors are exhibited by red cabbage juice under acid conditions? Under basic...
See AnswerQ: Calcium carbonate, CaCO3, can be obtained in a very pure
Calcium carbonate, CaCO3, can be obtained in a very pure state. Standard solutions of calcium ion are usually prepared by dissolving calcium carbonate in acid. What mass of CaCO3 should be taken to pr...
See AnswerQ: Calculate the pH of each of the following solutions from the information
Calculate the pH of each of the following solutions from the information given. a. [H+] = 4.78 * 10-2 M b. pOH = 4.56 c. [OH-] = 9.74 * 10-3 M d. [H+] = 1.24 * 10-8 M
See AnswerQ: How many milliliters of 18.0 M H2SO4 are required to
How many milliliters of 18.0 M H2SO4 are required to prepare 35.0 mL of 0.250 M solution?
See AnswerQ: Calculate the pH of each of the following solutions from the information
Calculate the pH of each of the following solutions from the information given. a. [H+] = 3.42 * 10-10 M b. pOH = 5.92 c. [OH-] = 2.86 * 10-7 M d. [H+] = 9.11 * 10-2 M
See AnswerQ: When 10. L of water is added to 3.0
When 10. L of water is added to 3.0 L of 6.0 M H2SO4, what is the molarity of the resulting solution? Assume the volumes are additive.
See AnswerQ: For each of the following solutions, the mass of solute is
For each of the following solutions, the mass of solute is given, followed by the total volume of the solution prepared. Calculate the molarity of each solution. a. 5.59 g CaCl2; 125 mL b. 2.34 g CaC...
See AnswerQ: What characteristic properties do buffered solutions possess?
What characteristic properties do buffered solutions possess?
See AnswerQ: How many grams of Ba(NO3)2 are required to
How many grams of Ba(NO3)2 are required to precipitate all the sulfate ion present in 15.3 mL of 0.139 M H2SO4 solution? Ba(NO3)2(aq) + H2SO4(aq) BaSO4(s) + 2HNO3(aq)
See AnswerQ: What minimum volume of 16 M sulfuric acid must be used to
What minimum volume of 16 M sulfuric acid must be used to prepare 750 mL of a 0.10 M H2SO4 solution?
See AnswerQ: According to Arrhenius, produce hydrogen ions in aqueous solution, whereas
According to Arrhenius, produce hydrogen ions in aqueous solution, whereas produce hydroxide ions.
See AnswerQ: What two components make up a buffered solution? Give an example
What two components make up a buffered solution? Give an example of a combination that would serve as a buffered solution.
See AnswerQ: Calculate the normality of each of the following solutions. a
Calculate the normality of each of the following solutions. a. 0.50 M acetic acid, HC2H3O2 b. 0.00250 M sulfuric acid, H2SO4 c. 0.10 M potassium hydroxide, KOH
See AnswerQ: A sodium dihydrogen phosphate solution was prepared by dissolving 5.0
A sodium dihydrogen phosphate solution was prepared by dissolving 5.0 g of NaH2PO4 in enough water to make 500. mL of solution. What are the molarity and normality of the resulting solution?
See AnswerQ: Which component of a buffered solution is capable of combining with an
Which component of a buffered solution is capable of combining with an added strong acid? Using your example from Exercise 60, show how this component would react with added HCl.
See AnswerQ: If 27.5 mL of 3.5 * 10-
If 27.5 mL of 3.5 * 10-2 N Ca(OH)2 solution is needed to neutralize 10.0 mL of nitric acid solution of unknown concentration, what is the normality of the nitric acid?
See AnswerQ: A buffered solution is prepared containing acetic acid, HC2H3O2, and
A buffered solution is prepared containing acetic acid, HC2H3O2, and sodium acetate, NaC2H3O2, both at 0.5 M. Write a chemical equation showing how this buffered solution would resist a decrease in it...
See AnswerQ: Why do scientists tend to express the acidity of a solution in
Why do scientists tend to express the acidity of a solution in terms of its pH, rather than in terms of the molarity of hydrogen ion present? How is pH defined mathematically?
See AnswerQ: Buffered solutions are mixtures of a weak acid and its conjugate base
Buffered solutions are mixtures of a weak acid and its conjugate base. Explain why a mixture of a strong acid and its conjugate base (such as HCl and Cl-) is not buffered.
See AnswerQ: Calculate the concentration of all ions present when 0.160 g
Calculate the concentration of all ions present when 0.160 g of MgCl2 is dissolved in enough water to make 100.0 mL of solution.
See AnswerQ: Of the following acids, which have relatively strong conjugate bases?
Of the following acids, which have relatively strong conjugate bases? a. HNO2 b. HCOOH c. HClO4 d. HNO3
See AnswerQ: A conjugate acid–base pair consists of two substances related by
A conjugate acid–base pair consists of two substances related by the donating and accepting of a(n) .
See AnswerQ: Calculate the [H+] in each of the following solutions,
Calculate the [H+] in each of the following solutions, and indicate whether the solution is acidic or basic. a. [OH-] = 2.32 * 10-4 M b. [OH-] = 8.99 * 10-10 M c. [OH-] = 4.34 * 10-6 M d. [OH-] =...
See AnswerQ: For a hydrogen ion concentration of 2.33 * 10-
For a hydrogen ion concentration of 2.33 * 10-6 M, how many decimal places should we give when expressing the pH of the solution?
See AnswerQ: How do chemists envision reactions taking place in terms of the collision
How do chemists envision reactions taking place in terms of the collision model for reactions? Give an example of a simple reaction and how you might envision the reaction’s taking place by means of a...
See AnswerQ: Consider the reaction 2CO(g) + O2(g
Consider the reaction 2CO(g) + O2(g) ⇌ 2CO2(g) Suppose the system is already at equilibrium, and then an additional mole of CO2(g) is injected into the system at constant temperature. Does the amoun...
See AnswerQ: Calculate the pH corresponding to each of the hydrogen ion concentrations given
Calculate the pH corresponding to each of the hydrogen ion concentrations given below, and indicate whether each solution is acidic or basic. a. [H+] = 4.02 * 10-3 M b. [H+] = 8.99 * 10-7 M c. [H+]...
See AnswerQ: Calculate the pH corresponding to each of the following hydrogen ion concentrations
Calculate the pH corresponding to each of the following hydrogen ion concentrations, and indicate whether each solution is acidic, basic, or neutral. a. [H+] = 0.00512 M b. [H+] = 3.76 * 10-5 M c....
See AnswerQ: How many moles of the indicated solute does each of the following
How many moles of the indicated solute does each of the following solutions contain? a. 4.25 mL of 0.105 M CaCl2 solution b. 11.3 mL of 0.405 M NaOH solution c. 1.25 L of 12.1 M HCl solution d. 27...
See AnswerQ: How many moles of the indicated solute does each of the following
How many moles of the indicated solute does each of the following solutions contain? a. 12.5 mL of 0.104 M HCl b. 27.3 mL of 0.223 M NaOH c. 36.8 mL of 0.501 M HNO3 d. 47.5 mL of 0.749 M KOH
See AnswerQ: What mass of the indicated solute does each of the following solutions
What mass of the indicated solute does each of the following solutions contain? a. 2.50 L of 13.1 M HCl solution b. 15.6 mL of 0.155 M NaOH solution c. 135 mL of 2.01 M HNO3 solution d. 4.21 L of...
See AnswerQ: What mass of the indicated solute does each of the following solutions
What mass of the indicated solute does each of the following solutions contain? a. 17.8 mL of 0.119 M CaCl2 b. 27.6 mL of 0.288 M KCl c. 35.4 mL of 0.399 M FeCl3 d. 46.1 mL of 0.559 M KNO3
See AnswerQ: For each hydrogen ion concentration listed, calculate the pH of the
For each hydrogen ion concentration listed, calculate the pH of the solution as well as the concentration of hydroxide ion in the solution. Indicate whether each solution is acidic or basic. a. [H+] =...
See AnswerQ: For each hydrogen ion concentration listed, calculate the pH of the
For each hydrogen ion concentration listed, calculate the pH of the solution as well as the concentration of hydroxide ion in the solution. Indicate whether each solution is acidic or basic. a. [H+] =...
See AnswerQ: Calculate the number of moles of the indicated ion present in each
Calculate the number of moles of the indicated ion present in each of the following solutions. a. Na+ ion in 1.00 L of 0.251 M Na2SO4 solution b. Cl- ion in 5.50 L of 0.10 M FeCl3 solution c. NO3-...
See AnswerQ: Given the general equation illustrating the reaction of the acid HA in
Given the general equation illustrating the reaction of the acid HA in water, HA(aq) + H2O(l) H3O+(aq) + A-(aq) explain why water is considered a base in the Brønsted-Lowry model....
See AnswerQ: Calculate the number of moles of each ion present in each of
Calculate the number of moles of each ion present in each of the following solutions. a. 10.2 mL of 0.451 M AlCl3 solution b. 5.51 L of 0.103 M Na3PO4 solution c. 1.75 mL of 1.25 M CuCl2 solution...
See AnswerQ: Calculate the hydrogen ion concentration, in moles per liter, for
Calculate the hydrogen ion concentration, in moles per liter, for solutions with each of the following pOH values. a. pOH = 4.95 b. pOH = 7.00 c. pOH = 12.94 d. pOH = 1.02
See AnswerQ: Calculate the hydrogen ion concentration, in moles per liter, for
Calculate the hydrogen ion concentration, in moles per liter, for solutions with each of the following pH or pOH values. a. pOH = 4.99 b. pH = 7.74 c. pOH = 10.74 d. pH = 2.25
See AnswerQ: Calculate the pH corresponding to each of the hydroxide ion concentrations given
Calculate the pH corresponding to each of the hydroxide ion concentrations given below, and indicate whether each solution is acidic or basic. a. [OH-] = 4.73 * 10-4 M b. [OH-] = 5.99 * 10-1 M c. [...
See AnswerQ: Calculate the pH corresponding to each of the following hydroxide ion concentrations
Calculate the pH corresponding to each of the following hydroxide ion concentrations, and indicate whether each solution is acidic or basic. a. [OH-] = 4.85 * 10-5 M b. [OH-] = 3.96 * 10-7 M c. [OH...
See AnswerQ: Calculate the new molarity if each of the following dilutions is made
Calculate the new molarity if each of the following dilutions is made. Assume the volumes are additive. a. 55.0 mL of water is added to 25.0 mL of 0.119 M NaCl solution b. 125 mL of water is added t...
See AnswerQ: Calculate the new molarity that results when 250. mL of water
Calculate the new molarity that results when 250. mL of water is added to each of the following solutions. a. 125 mL of 0.251 M HCl b. 445 mL of 0.499 M H2SO4 c. 5.25 L of 0.101 M HNO3 d. 11.2 mL...
See AnswerQ: Calculate the hydrogen ion concentration and the pH of each of the
Calculate the hydrogen ion concentration and the pH of each of the following solutions of strong acids. a. 1.04 * 10-4 M HCl b. 0.00301 M HNO3 c. 5.41 * 10-4 M HClO4 d. 6.42 * 10-2 M HNO3
See AnswerQ: Calculate the pH of each of the following solutions of strong acids
Calculate the pH of each of the following solutions of strong acids. a. 1.21 * 10-3 M HNO3 b. 0.000199 M HClO4 c. 5.01 * 10-5 M HCl d. 0.00104 M HBr
See AnswerQ: Calculate the hydrogen ion concentration, in moles per liter, for
Calculate the hydrogen ion concentration, in moles per liter, for solutions with each of the following pH values. a. pH = 9.01 b. pH = 6.89 c. pH = 1.02 d. pH = 7.00
See AnswerQ: An oil spill spreads out on the surface of water, rather
An oil spill spreads out on the surface of water, rather than dissolving in the water. Explain why.
See AnswerQ: Ksp for magnesium carbonate, MgCO3, has a value 3.
Ksp for magnesium carbonate, MgCO3, has a value 3.5 * 10-8 at 25 °C. Calculate the solubility of magnesium carbonate in mol/L and g/L at 25 °C.
See AnswerQ: What is the effect on the equilibrium position if an exothermic reaction
What is the effect on the equilibrium position if an exothermic reaction is carried out at a higher temperature? Does the net amount of product increase or decrease? Does the value of the equilibrium...
See AnswerQ: Which component of a buffered solution consumes added strong base? Using
Which component of a buffered solution consumes added strong base? Using your example from Exercise 60, show how this component would react with added NaOH.
See AnswerQ: The amount of nickel(II) present in an aqueous solution
The amount of nickel(II) present in an aqueous solution can be determined by precipitating the nickel with the organic chemical reagent dimethylglyoxime [CH3C(NOH)C(NOH)CH3, commonly abbreviated as “D...
See AnswerQ: Which of the following combinations would act as buffered solutions?
Which of the following combinations would act as buffered solutions? a. HCl and NaCl b. CH3COOH and KCH3COO c. H2S and NaHS d. H2S and Na2S
See AnswerQ: Many metal ions are precipitated from solution by the sulfide ion.
Many metal ions are precipitated from solution by the sulfide ion. As an example, consider treating a solution of copper(II) sulfate with sodium sulfide solution: CuSO4(aq) + Na2S(aq)...
See AnswerQ: Calcium oxalate, CaC2O4, is very insoluble in water. What
Calcium oxalate, CaC2O4, is very insoluble in water. What mass of sodium oxalate, Na2C2O4, is required to precipitate the calcium ion from 37.5 mL of 0.104 M CaCl2 solution?
See AnswerQ: When aqueous solutions of lead(II) ion are treated with
When aqueous solutions of lead(II) ion are treated with potassium chromate solution, a bright yellow precipitate of lead(II) chromate, PbCrO4, forms. How many grams of lead chromate form when a 1.00-g...
See AnswerQ: Aluminum ion may be precipitated from aqueous solution by addition of hydroxide
Aluminum ion may be precipitated from aqueous solution by addition of hydroxide ion, forming Al(OH)3. A large excess of hydroxide ion must not be added, however, because the precipitate of Al(OH)3 wil...
See AnswerQ: The concepts of acid–base equilibria were developed in this chapter
The concepts of acid–base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønst...
See AnswerQ: The “Chemistry in Focus” segment Water, Water Everywhere,
The “Chemistry in Focus” segment Water, Water Everywhere, But . . . discusses the desalinization of ocean water. Explain why many salts are soluble in water. Include molecular-level diagrams in your a...
See AnswerQ: Strong bases are bases that completely ionize in water to produce hydroxide
Strong bases are bases that completely ionize in water to produce hydroxide ion, OH-. The strong bases include the hydroxides of the Group 1 elements. For example, if 1.0 mole of NaOH is dissolved per...
See AnswerQ: A sample of sodium hydrogen carbonate solid weighing 0.1015 g
A sample of sodium hydrogen carbonate solid weighing 0.1015 g requires 47.21 mL of a hydrochloric acid solution to react completely. HCl(aq) + NaHCO3(s) / NaCl(aq) + H2O(l) + CO2(g) Calculate the mol...
See AnswerQ: Despite HCl’s being a strong acid, the pH of 1.
Despite HCl’s being a strong acid, the pH of 1.00 * 10-7 M HCl is not exactly 7.00. Can you suggest a reason why?
See AnswerQ: What volume of 1.00 M NaOH is required to neutralize
What volume of 1.00 M NaOH is required to neutralize each of the following solutions? a. 25.0 mL of 0.154 M acetic acid, HC2H3O2 b. 35.0 mL of 0.102 M hydrofluoric acid, HF c. 10.0 mL of 0.143 M ph...
See AnswerQ: What volume of 0.101 M HNO3 is required to neutralize
What volume of 0.101 M HNO3 is required to neutralize each of the following solutions? a. 12.7 mL of 0.501 M NaOH b. 24.9 mL of 0.00491 M Ba(OH)2 c. 49.1 mL of 0.103 M NH3 d. 1.21 L of 0.102 M KOH...
See AnswerQ: Consider the exothermic reaction CO(g) + 2H2(
Consider the exothermic reaction CO(g) + 2H2(g) ⇌ CH3OH(l) Predict three changes that could be made to the system that would decrease the yield of product over that produced by a system in which no c...
See AnswerQ: Suppose a reaction has the equilibrium constant K = 1.3
Suppose a reaction has the equilibrium constant K = 1.3 * 108. What does the magnitude of this constant tell you about the relative concentrations of products and reactants that will be present once e...
See AnswerQ: Explain why the equivalent weight of H2SO4 is half the molar mass
Explain why the equivalent weight of H2SO4 is half the molar mass of this substance. How many hydrogen ions does each H2SO4 molecule produce when reacting with an excess of OH- ions?
See AnswerQ: Explain how the dissolving of an ionic solute in water represents an
Explain how the dissolving of an ionic solute in water represents an equilibrium process.
See AnswerQ: Why does the amount of excess solid solute present in a solution
Why does the amount of excess solid solute present in a solution not affect the amount of solute that ultimately dissolves in a given amount of solvent?
See AnswerQ: The “Chemistry in Focus” segment Green Chemistry discusses the use
The “Chemistry in Focus” segment Green Chemistry discusses the use of gaseous carbon dioxide in place of CFCs and of liquid carbon dioxide in place of the dry-cleaning chemical PERC. Would you expect...
See AnswerQ: For each of the following solutions, the mass of solute taken
For each of the following solutions, the mass of solute taken is indicated, along with the total volume of solution prepared. Calculate the normality of each solution. a. 0.113 g NaOH; 10.2 mL b. 12...
See AnswerQ: Ksp for copper(II) hydroxide, Cu(OH)
Ksp for copper(II) hydroxide, Cu(OH)2, has a value 2.2 * 10-20 at 25 °C. Calculate the solubility of copper(II) hydroxide in mol/L and g/L at 25 °C.
See AnswerQ: Most hydroxides are not very soluble in water. For example,
Most hydroxides are not very soluble in water. For example, Ksp for nickel(II) hydroxide, Ni(OH)2, is 2.0 * 10-15 at 25 °C. How many grams of nickel(II) hydroxide dissolve per liter at 25 °C?
See AnswerQ: The solubility product constant, Ksp, for calcium carbonate at room
The solubility product constant, Ksp, for calcium carbonate at room temperature is approximately 3.0 * 10-9. Calculate the solubility of CaCO3 in grams per liter under these conditions.
See AnswerQ: A solution of the sparingly soluble base Ca(OH)2
A solution of the sparingly soluble base Ca(OH)2 is prepared in a volumetric flask by dissolving 5.21 mg of Ca(OH)2 to a total volume of 1000. mL. Calculate the molarity and normality of the solution....
See AnswerQ: Calcium sulfate, CaSO4, is only soluble in water to the
Calcium sulfate, CaSO4, is only soluble in water to the extent of approximately 2.05 g/L at 25 °C. Calculate Ksp for calcium sulfate at 25°C.
See AnswerQ: What volume of 0.104 N H2SO4 is required to neutralize
What volume of 0.104 N H2SO4 is required to neutralize 15.2 mL of 0.152 N NaOH? What volume of 0.104 M H2SO4 is required to neutralize 15.2 mL of 0.152 M NaOH? H2SO4(aq) + 2NaOH(aq) / Na2SO4(aq) + 2H...
See AnswerQ: What volume of 0.151 N NaOH is required to neutralize
What volume of 0.151 N NaOH is required to neutralize 24.2 mL of 0.125 N H2SO4? What volume of 0.151 N NaOH is required to neutralize 24.2 mL of 0.125 M H2SO4?
See AnswerQ: The following are representations of acid–base reactions: /
The following are representations of acidâbase reactions: a. Label each of the species in both equations as an acid or base, and explain. b. For those species that are acids, which...
See AnswerQ: A mixture is prepared by mixing 50.0 g of ethanol
A mixture is prepared by mixing 50.0 g of ethanol, 50.0 g of water, and 5.0 g of sugar. What is the mass percent of each component in the mixture? How many grams of the mixture should one take in orde...
See AnswerQ: How does equilibrium represent the balancing of opposing processes? Give an
How does equilibrium represent the balancing of opposing processes? Give an example of an “equilibrium” encountered in everyday life, showing how the processes involved oppose each other.
See AnswerQ: Explain the difference in meaning between the following two solutions: “
Explain the difference in meaning between the following two solutions: “50. g of NaCl dissolved in 1.0 L of water” and “50. g of NaCl dissolved in enough water to make 1.0 L of solution.” For which so...
See AnswerQ: Suppose 50.0 mL of 0.250 M CoCl2 solution
Suppose 50.0 mL of 0.250 M CoCl2 solution is added to 25.0 mL of 0.350 M NiCl2 solution. Calculate the concentration, in moles per liter, of each of the ions present after mixing. Assume that the volu...
See AnswerQ: Under what circumstances can we compare the solubilities of two salts by
Under what circumstances can we compare the solubilities of two salts by directly comparing the values of their solubility products?
See AnswerQ: Calculate the mass of AgCl formed, and the concentration of silver
Calculate the mass of AgCl formed, and the concentration of silver ion remaining in solution, when 10.0 g of solid AgNO3 is added to 50. mL of 1.0 * 10-2 M NaCl solution. Assume there is no volume cha...
See AnswerQ: Calculate [H+] in each of the following solutions, and
Calculate [H+] in each of the following solutions, and indicate whether the solution is acidic, basic, or neutral. a. [OH-] = 4.22 * 10-3 M b. [OH-] = 1.01 * 10-13 M c. [OH-] = 3.05 * 10-7 M d. [O...
See AnswerQ: Many metal ions form insoluble sulfide compounds when a solution of the
Many metal ions form insoluble sulfide compounds when a solution of the metal ion is treated with hydrogen sulfide gas. For example, nickel(II) precipitates nearly quantitatively as NiS when H2S gas i...
See AnswerQ: Which of the following bases have relatively strong conjugate acids?
Which of the following bases have relatively strong conjugate acids? a. F- b. Cl- c. HSO4- d. NO3-
See AnswerQ: Calculate the pH of each of the solutions indicated below. Tell
Calculate the pH of each of the solutions indicated below. Tell whether the solution is acidic, basic, or neutral. a. [H+] = 1.49 * 10-3 M b. [OH-] = 6.54 * 10-4 M c. [H+] = 9.81 * 10-9 M d. [OH-]...
See AnswerQ: Calculate the pH corresponding to each of the hydroxide ion concentrations given
Calculate the pH corresponding to each of the hydroxide ion concentrations given below, and indicate whether each solution is acidic, basic, or neutral. a. [OH] = 1.4 * 10-6 M b. [OH] = 9.35 * 10-...
See AnswerQ: What do we mean when we say that “like dissolves like
What do we mean when we say that “like dissolves like”? Do two molecules have to be identical to be able to form a solution in one another?
See AnswerQ: Give some examples of how we make good use of oxidation–
Give some examples of how we make good use of oxidation– reduction reactions in everyday life.
See AnswerQ: Why is fluorine always assigned an oxidation state of -1?
Why is fluorine always assigned an oxidation state of -1? What oxidation number is usually assigned to the other halogen elements when they occur in compounds? In an interhalogen compound involving fl...
See AnswerQ: Balance each of the following half-reactions, which take place
Balance each of the following half-reactions, which take place in acidic solution. a. SiO2(s) / Si(s) b. S(s) / H2S(g) c. NO3–(aq) / HNO2(aq) d. NO3–(aq) / NO(g)
See AnswerQ: Balance each of the following oxidation–reduction reactions, which take
Balance each of the following oxidation–reduction reactions, which take place in acidic solution, by using the “half-reaction” method. a. I-(aq) + MnO4-(aq) / I2(aq) + Mn2+(aq) b. S2O82-(aq) + Cr3+(...
See AnswerQ: During the research that led to production of the two atomic bombs
During the research that led to production of the two atomic bombs used against Japan in World War II, different mechanisms for obtaining a supercritical mass of fissionable material were investigated...
See AnswerQ: The “Chemistry in Focus” segment Yellow Jeans? discusses the
The “Chemistry in Focus” segment Yellow Jeans? discusses the oxidation–reduction reaction required to turn the dye used in denim jeans from yellow to blue. The reaction is from leucoindigo to indigo....
See AnswerQ: Assign the oxidation state for the element listed in each of the
Assign the oxidation state for the element listed in each of the following compounds:
See AnswerQ: A certain radioactive nuclide has a half-life of 80.
A certain radioactive nuclide has a half-life of 80.9 years. How long does it take for 87.5% of a sample of this substance to decay?
See AnswerQ: Which of the following statement(s) is(are)
Which of the following statement(s) is(are) true? a. A radioactive nuclide that decays from 1.00 * 1010 atoms to 2.5 * 109 atoms in 10 minutes has a half-life of 5.0 minutes. b. Nuclides with large...
See AnswerQ: The most common reaction used in breeder reactors involves the bombardment of
The most common reaction used in breeder reactors involves the bombardment of uranium-238 with neutrons: 238U is converted by this bombardment to 239U. The uranium-239 then undergoes two beta decays,...
See AnswerQ: Each of the following nuclides is known to undergo radioactive decay by
Each of the following nuclides is known to undergo radioactive decay by production of an alpha particle, /. Write a balanced nuclear equation for each process. a. / b. / c. /
See AnswerQ: The sum of all the oxidation states of all the atoms in
The sum of all the oxidation states of all the atoms in H3PO4 is .
See AnswerQ: Which of the following nuclear equations is(are) correct?
Which of the following nuclear equations is(are) correct? a. 4 7
See AnswerQ: An instrument that measures the rate of radioactive decay by registering the
An instrument that measures the rate of radioactive decay by registering the ions and electrons produced as a radioactive particle passes through a gas-filled chamber is called a(n) . A...
See AnswerQ: A list of several important radionuclides is given in Table 19.
A list of several important radionuclides is given in Table 19.4. Which is the âhottestâ? Which is the most stable to decay? From table 19.4:
See AnswerQ: The “Chemistry in Focus” segment PET, the Brain’s Best
The “Chemistry in Focus” segment PET, the Brain’s Best Friend discusses the use of radiotracers to monitor the functioning of organs or to trace the path and final destination of a drug. The isotope 1...
See AnswerQ: How do the energies released by nuclear processes compare in magnitude with
How do the energies released by nuclear processes compare in magnitude with the energies of ordinary chemical processes?
See AnswerQ: Write an equation for the fission of 92 235
Write an equation for the fission of 92 235
See AnswerQ: A(n) is a self-sustaining fission process caused
A(n) is a self-sustaining fission process caused by the production of neutrons that proceed to split other nuclei.
See AnswerQ: What is the nuclear fusion of small nuclei? How does the
What is the nuclear fusion of small nuclei? How does the energy released by fusion compare in magnitude with that released by fission?
See AnswerQ: What must be the sum of the oxidation states of all the
What must be the sum of the oxidation states of all the atoms in a polyatomic ion? For example, the sum of all the oxidation states of all the atoms in PO43- is .
See AnswerQ: What are some reasons why no practical fusion reactor has yet been
What are some reasons why no practical fusion reactor has yet been developed?
See AnswerQ: The sun radiates vast quantities of energy as a consequence of the
The sun radiates vast quantities of energy as a consequence of the nuclear fusion reaction of to form nuclei.
See AnswerQ: Describe the relative penetrating powers of alpha, beta, and gamma
Describe the relative penetrating powers of alpha, beta, and gamma radiation.
See AnswerQ: The number of protons contained in a given nucleus is called the
The number of protons contained in a given nucleus is called the .
See AnswerQ: Write the nuclear symbol for an alpha particle.
Write the nuclear symbol for an alpha particle.
See AnswerQ: A nucleus that spontaneously decomposes is said to be .
A nucleus that spontaneously decomposes is said to be .
See AnswerQ: A(n) , when it is produced by a nucleus
A(n) , when it is produced by a nucleus at high speed, is more commonly called a beta particle.
See AnswerQ: In a nuclear equation, both the mass number and the ______
In a nuclear equation, both the mass number and the ______ number must be conserved.
See AnswerQ: Production of a helium nucleus from a heavy atom is referred to
Production of a helium nucleus from a heavy atom is referred to as decay.
See AnswerQ: The net effect of the production of a beta particle is to
The net effect of the production of a beta particle is to convert a to a .
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following. a. CBr4 b. HClO4 c. K3PO4 d. N2O
See AnswerQ: In addition to particles, many radioactive nuclei also produce high-
In addition to particles, many radioactive nuclei also produce high-energy rays when they decay.
See AnswerQ: When a nuclide decomposes through a series of steps before reaching stability
When a nuclide decomposes through a series of steps before reaching stability, the nuclide is said to have gone through a series.
See AnswerQ: When a nuclide produces a beta particle, the atomic number of
When a nuclide produces a beta particle, the atomic number of the resulting new nuclide is one unit than that of the original nuclide.
See AnswerQ: When a nucleus undergoes ______, the mass number of the nucleus decreases
When a nucleus undergoes ______, the mass number of the nucleus decreases by four units.
See AnswerQ: Machines that increase the speed of species used for nuclear bombardment processes
Machines that increase the speed of species used for nuclear bombardment processes are called .
See AnswerQ: The elements with atomic numbers of 93 or greater are referred to
The elements with atomic numbers of 93 or greater are referred to as the elements.
See AnswerQ: A counter contains argon gas, which is ionized by radiation,
A counter contains argon gas, which is ionized by radiation, making possible the measurement of radioactive decay rates.
See AnswerQ: The time required for half of an original sample of a radioactive
The time required for half of an original sample of a radioactive nuclide to decay is referred to as the of the nuclide.
See AnswerQ: The radioactive nuclide that has been used in determining the age of
The radioactive nuclide that has been used in determining the age of historical wooden artifacts is .
See AnswerQ: Combining two small nuclei to form a larger nucleus is referred to
Combining two small nuclei to form a larger nucleus is referred to as the process of nuclear .
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following. a. NBr3 b. SeF6 c. PBr5 d. CH4
See AnswerQ: A self-sustaining nuclear process, in which the bombarding particles
A self-sustaining nuclear process, in which the bombarding particles needed to produce the fission of further material are themselves produced as the product of the initial fission, is called a...
See AnswerQ: A certain nuclide has a half-life of 45 years.
A certain nuclide has a half-life of 45 years. After 225 years, 4.00 g remains. What was the original mass of the nuclide sample?
See AnswerQ: The decay series from uranium-238 to lead-206 is
The decay series from uranium-238 to lead-206 is indicated in Fig. 19.1. For each step of the process indicated in the figure, specify what type of particle is produced by the particular nucleus invol...
See AnswerQ: Name each of the following alkenes and alkynes. /
Name each of the following alkenes and alkynes.
See AnswerQ: Name each of the following organic compounds.//
Name each of the following organic compounds.
See AnswerQ: Esterification reactions are carried out in the presence of a strong acid
Esterification reactions are carried out in the presence of a strong acid such as H2SO4. A carboxylic acid is warmed with an alcohol, and an ester and water are formed. You may have made a fruity-smel...
See AnswerQ: Rank these organic compounds in terms of increasing water solubility (from
Rank these organic compounds in terms of increasing water solubility (from least water soluble to most water soluble).
See AnswerQ: What makes carbon able to form so many different compounds?
What makes carbon able to form so many different compounds?
See AnswerQ: The chains in normal alkanes are not really straight but zigzag because
The chains in normal alkanes are not really straight but zigzag because the bond angles around the carbon atoms are .
See AnswerQ: What is the oxidation state of sulfur in each of the following
What is the oxidation state of sulfur in each of the following substances? a. S8 c. NaHSO4 b. H2SO4 d. Na2S
See AnswerQ: With very reactive agents, such as the halogen elements, alkanes
With very reactive agents, such as the halogen elements, alkanes undergo reactions, whereby a new atom replaces one or more hydrogen atoms of the alkane.
See AnswerQ: Alkenes and alkynes are characterized by their ability to undergo rapid,
Alkenes and alkynes are characterized by their ability to undergo rapid, complete reactions, by which other atoms attach themselves to the carbon atoms of the double or triple bond.
See AnswerQ: Unsaturated fats may be converted to saturated fats by the process of
Unsaturated fats may be converted to saturated fats by the process of .
See AnswerQ: Benzene is the parent member of the group of hydrocarbons called hydrocarbons
Benzene is the parent member of the group of hydrocarbons called hydrocarbons.
See AnswerQ: An atom or group of atoms that imparts new and characteristic properties
An atom or group of atoms that imparts new and characteristic properties to an organic molecule is called a(n) group.
See AnswerQ: A(n) alcohol is one in which there is only
A(n) alcohol is one in which there is only one hydrocarbon group attached to the carbon atom holding the hydroxyl group.
See AnswerQ: The simplest alcohol, methanol, is prepared industrially by the hydrogenation
The simplest alcohol, methanol, is prepared industrially by the hydrogenation of .
See AnswerQ: Ethanol is commonly prepared by the of certain sugars by yeast.
Ethanol is commonly prepared by the of certain sugars by yeast.
See AnswerQ: Both aldehydes and ketones contain the group, but they differ in
Both aldehydes and ketones contain the group, but they differ in where this group occurs along the hydrocarbon chain.
See AnswerQ: Aldehydes and ketones can be prepared by of the corresponding alcohol.
Aldehydes and ketones can be prepared by of the corresponding alcohol.
See AnswerQ: What is a positron? What are the mass number and charge
What is a positron? What are the mass number and charge of a positron? How do the mass number and atomic number of a nucleus change when the nucleus produces a positron?
See AnswerQ: What is the “general” formula for an alkane? Show
What is the “general” formula for an alkane? Show how this general formula can be used to determine the number of hydrogens that would be present for an alkane with 20 carbon atoms.
See AnswerQ: Which of the following is not an organic molecule? a
Which of the following is not an organic molecule? a. methanol b. acetone c. acetic acid d. magnesium sulfate e. All of the above are organic molecules.
See AnswerQ: The typically sweet-smelling compounds called result from the condensation reaction
The typically sweet-smelling compounds called result from the condensation reaction of an organic acid with a(n) .
See AnswerQ: For each of the following straight-chain alkanes, draw the
For each of the following straight-chain alkanes, draw the structural formula. a. ethane b. butane c. hexane
See AnswerQ: Show (by drawing structures) how the members of a series
Show (by drawing structures) how the members of a series of alkanes differ from the previous or following member of the series by a -CH2- unit.
See AnswerQ: What does it mean to say that a hydrocarbon is saturated?
What does it mean to say that a hydrocarbon is saturated? To how many other atoms is each carbon atom in a saturated hydrocarbon bonded? What name is given to the family of saturated hydrocarbons?
See AnswerQ: How many of the following organic functional groups must contain two oxygen
How many of the following organic functional groups must contain two oxygen atoms? a. alcohols b. esters c. carboxylic acids d. ketones e. aldehydes
See AnswerQ: Give the systematic name for each of the following unsaturated hydrocarbons and
Give the systematic name for each of the following unsaturated hydrocarbons and substituted unsaturated compounds.
See AnswerQ: Give some examples of molecules containing “fused” benzene rings.
Give some examples of molecules containing “fused” benzene rings.
See AnswerQ: Write a structural formula for each of the following compounds.
Write a structural formula for each of the following compounds. a. 2,3-dimethylheptane b. 2,2-dimethyl-3-chloro-1-octanol c. 2-chloro-1-hexene d. 1-chloro-2-hexene e. 2-methylphenol
See AnswerQ: What is the oxidation state of chlorine in each of the following
What is the oxidation state of chlorine in each of the following substances? a. ClF b. Cl2 c. HCl d. HClO
See AnswerQ: Draw the structural formula(s) for, and give the
Draw the structural formula(s) for, and give the name(s) of, the organic product(s) of each of the following reactions. If a mixture of several, similar products is expected, indicate the type of prod...
See AnswerQ: Without drawing a structural formula, tell how many hydrogen atoms would
Without drawing a structural formula, tell how many hydrogen atoms would be present in the straight-chain alkanes with the following numbers of carbon atoms. a. 4 b. 6 c. 17 d. 20
See AnswerQ: How many of the following alcohols are secondary alcohols? a
How many of the following alcohols are secondary alcohols? a. ethanol b. isopropyl alcohol c. tert-butyl alcohol d. methanol
See AnswerQ: The alcohol glycerol (glycerine), which is produced in the human
The alcohol glycerol (glycerine), which is produced in the human body by the digestion of fats, has the following structure. Give the systematic name of glycerol.
See AnswerQ: On the basis of the functional groups listed in Table 20.
On the basis of the functional groups listed in Table 20.5, which of the following organic functional groups does not contain any oxygen atoms? a. halohydrocarbons b. ethers c. esters d. aldehydes...
See AnswerQ: Draw a structure corresponding to each of the following names.
Draw a structure corresponding to each of the following names. a. 2-methylpentanal b. 3-hydroxybutanoic acid c. 2-aminopropanal d. 2,4-hexanedione e. 3-methylbenzaldehyde
See AnswerQ: Write a structural formula for each of the following compounds.
Write a structural formula for each of the following compounds. a. methyl pentyl ketone b. 3-methylpentanal c. 2-methyl-1-pentanol d. 1,2,3-propanetriol e. 2-methyl-3-hexanone
See AnswerQ: Salicylic acid is an interesting molecule; it is both an acid
Salicylic acid is an interesting molecule; it is both an acid and an alcohol, having a hydroxyl group attached to the aromatic ring (phenol). For this reason, salicylic acid can undergo two different...
See AnswerQ: Alpha amino acids are organic acid molecules that also happen to contain
Alpha amino acids are organic acid molecules that also happen to contain an amino group (-NH2) on the second carbon atom of the acidâs chain. Proteins are condensation polymers of su...
See AnswerQ: Complete the following table with the name or structure as needed.
Complete the following table with the name or structure as needed.
See AnswerQ: Consider the three isotopes of magnesium discussed in Exercise 17. Given
Consider the three isotopes of magnesium discussed in Exercise 17. Given that the relative natural abundances of these isotopes are 79%, 10%, and 11%, respectively, without looking at the inside cover...
See AnswerQ: Draw a structural formula for each of the following aromatic compounds.
Draw a structural formula for each of the following aromatic compounds. a. 1,2-dichlorobenzene b. 1,3-dimethylbenzene c. 3-nitrophenol d. p-dibromobenzene e. 4-nitrotoluene
See AnswerQ: Draw structural formulas for all isomeric alkanes having the general formula C7H16
Draw structural formulas for all isomeric alkanes having the general formula C7H16.
See AnswerQ: Give the name of each of the following straight-chain alkanes
Give the name of each of the following straight-chain alkanes. a. CH3-CH2-CH2-CH2-CH2-CH2-CH2-CH3 b. CH3-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH3 c. CH3-CH2-CH2-CH2-CH2-CH3 d. CH=-CH2-CH2-CH3
See AnswerQ: Give the systematic name for each of the following alkanes.
Give the systematic name for each of the following alkanes.
See AnswerQ: Draw a structural formula for each of the following compounds.
Draw a structural formula for each of the following compounds. a. 2,2-dimethylhexane b. 2,3-dimethylhexane c. 3,3-dimethylhexane d. 3,4-dimethylhexane e. 2,4-dimethylhexane
See AnswerQ: Write the formula for the missing reactant or product in each of
Write the formula for the missing reactant or product in each of the following chemical equations. a. CH4(g) + Cl2(g) + HCl(g) b. CH3CH2CH3(g) CH3CH=CH2(g) + c. CHC...
See AnswerQ: Draw structural formulas showing all the isomers of the straight-chain
Draw structural formulas showing all the isomers of the straight-chain alkyne with eight carbon atoms. Name each isomer.
See AnswerQ: Name each of the following aromatic or substituted aromatic compounds.
Name each of the following aromatic or substituted aromatic compounds.
See AnswerQ: On the basis of the functional groups listed in Table 20.
On the basis of the functional groups listed in Table 20.5, identify the family of organic compounds to which each of the following belongs.
See AnswerQ: Draw a structural formula for each of the following alcohols. Indicate
Draw a structural formula for each of the following alcohols. Indicate whether the alcohol is primary, secondary, or tertiary. a. 2-propanol b. 2-methyl-2-propanol c. 4-isopropyl-2-heptanol d. 2,3...
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following. a. CuCl2 b. KClO3 c. KClO4 d. Na2CO3
See AnswerQ: An ester is similar to a carboxylic acid like a.
An ester is similar to a carboxylic acid like a. a primary alcohol is similar to a secondary alcohol. b. an amine is similar to a ketone. c. an ether is similar to an aldehyde. d. an aromatic ring...
See AnswerQ: How are carboxylic acids synthesized? Give an example of an organic
How are carboxylic acids synthesized? Give an example of an organic acid and the molecule from which it is synthesized. What type of reaction is this?
See AnswerQ: Draw the structural formula for each of the following straightchain alkanes.
Draw the structural formula for each of the following straightchain alkanes. a. pentane b. undecane (11 carbon atoms) c. nonane d. heptane
See AnswerQ: Draw a structural formula for each of the following. a
Draw a structural formula for each of the following. a. 3-methylbutanoic acid b. 2-chlorobenzoic acid c. hexanoic acid d. acetic acid
See AnswerQ: Draw the structure of the monomer and the basic repeating unit for
Draw the structure of the monomer and the basic repeating unit for each of the following polymeric substances. a. polyethylene b. polyvinyl chloride c. Teflon d. polypropylene e. polystyrene
See AnswerQ: What are structural isomers? Which is the smallest alkane that has
What are structural isomers? Which is the smallest alkane that has a structural isomer? Draw structures to illustrate the isomers.
See AnswerQ: What is a branched alkane? Draw the structure of a branched
What is a branched alkane? Draw the structure of a branched alkane and circle the branch.
See AnswerQ: Without looking back at the text, draw structural formulas and give
Without looking back at the text, draw structural formulas and give the common names for the three isomers of pentane, C5H12.
See AnswerQ: Draw structural formulas for three isomeric alkanes having the formula C6H14.
Draw structural formulas for three isomeric alkanes having the formula C6H14.
See AnswerQ: How do chemists define the processes of oxidation and reduction? Write
How do chemists define the processes of oxidation and reduction? Write a simple equation illustrating each of your definitions.
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following. a. MgO b. Fe2O3 c. PCl3 d. N2O5
See AnswerQ: Give the root names for the alkanes with three, five,
Give the root names for the alkanes with three, five, seven, and nine carbon atoms.
See AnswerQ: Your roommate, a chemistry major, claims to have synthesized the
Your roommate, a chemistry major, claims to have synthesized the compound CH5 in the lab. Why is that not possible?
See AnswerQ: To what does the root name for a branched hydrocarbon correspond?
To what does the root name for a branched hydrocarbon correspond?
See AnswerQ: What is an alkyl group? How is a given alkyl group
What is an alkyl group? How is a given alkyl group related to its parent alkane?
See AnswerQ: When naming alkanes, find the longest continuous chain of carbon atoms
When naming alkanes, find the longest continuous chain of carbon atoms. This chain (called the chain) determines the base alkane name.
See AnswerQ: What prefixes would be used in the systematic name of an alkane
What prefixes would be used in the systematic name of an alkane to indicate that the alkane contained the following numbers of methyl branches? a. two b. four c. five d. three
See AnswerQ: When naming alkanes, the alkyl groups are listed in alphabetical order
When naming alkanes, the alkyl groups are listed in alphabetical order, disregarding any .
See AnswerQ: Give the systematic name for each of the following branched alkanes.
Give the systematic name for each of the following branched alkanes.
See AnswerQ: Give the systematic name for each of the following alkanes.
Give the systematic name for each of the following alkanes.
See AnswerQ: Draw a structural formula for each of the following branched alkanes.
Draw a structural formula for each of the following branched alkanes. a. 2,3-dimethylpentane b. 2,4-dimethylpentane c. 2,2-dimethylpentane d. 3,3-dimethylpentane
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following ions: a. CO32- b. NO3- c. PO43- d. SO42-
See AnswerQ: Draw a structural formula for each of the following branched alkanes.
Draw a structural formula for each of the following branched alkanes. a. 2,2,4-trimethyloctane b. 2,3,4-trimethyloctane c. 3,3,4-trimethyloctane d. 2,4,4-trimethyloctane
See AnswerQ: What are the major constituents of crude petroleum? What is the
What are the major constituents of crude petroleum? What is the major constituent of natural gas? How were these mixtures formed?
See AnswerQ: What does a double bond represent? How many pairs of electrons
What does a double bond represent? How many pairs of electrons are shared between the atoms in a double bond? Draw the Lewis structure of a simple molecule that contains a double bond.
See AnswerQ: To be used efficiently, petroleum must be separated by boiling into
To be used efficiently, petroleum must be separated by boiling into portions called .
See AnswerQ: What is pyrolytic cracking, and why is the process applied to
What is pyrolytic cracking, and why is the process applied to the kerosene fraction of petroleum?
See AnswerQ: Why was tetraethyl lead, (C2H5)4Pb, added to
Why was tetraethyl lead, (C2H5)4Pb, added to gasoline in the past? Why is the use of this substance being phased out?
See AnswerQ: Explain why alkanes are relatively unreactive.
Explain why alkanes are relatively unreactive.
See AnswerQ: Write an equation showing the combustion of propane, C3H8. How
Write an equation showing the combustion of propane, C3H8. How do we make use of combustion reactions?
See AnswerQ: Indicate the missing molecule in each of the following substitution reactions.
Indicate the missing molecule in each of the following substitution reactions. a. CH4 + Cl2 hv HCl + ? b. CH2Cl2 + Cl2 hv CHCl3 + ? c. ? + Cl2 hv CCl4 +...
See AnswerQ: When an alkane molecule undergoes a(n) reaction, hydrogen
When an alkane molecule undergoes a(n) reaction, hydrogen atoms are removed, and the product is an unsaturated hydrocarbon.
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following ions. a. NH4+ c. OH- b. HCO3- d. Cr2O72-
See AnswerQ: Complete and balance each of the following combustion reactions of alkanes.
Complete and balance each of the following combustion reactions of alkanes. a. C2H6(g) + O2(g) / b. C4H10(g) + O2 / c. C3H8(g) + O2(g) /
See AnswerQ: Complete and balance each of the following chemical equations. a
Complete and balance each of the following chemical equations. a. C8H18(l) + O2(g) ( b. CH3Cl(l) + Cl2(g) ( c. CHCl3(l) + Cl2(g) (
See AnswerQ: What is an alkene? What structural feature characterizes alkenes? Give
What is an alkene? What structural feature characterizes alkenes? Give the general formula for alkenes.
See AnswerQ: How many electron pairs are shared when a triple bond exists between
How many electron pairs are shared when a triple bond exists between two carbon atoms? What must be the geometric arrangement around the carbon atoms in a triple bond? Draw the Lewis structure of a si...
See AnswerQ: What is an alkyne? What structural feature characterizes alkynes? Give
What is an alkyne? What structural feature characterizes alkynes? Give the general formula for alkynes.
See AnswerQ: How is the root name of an alkane modified to indicate that
How is the root name of an alkane modified to indicate that a given hydrocarbon contains a double or triple bond in its longest continuous chain?
See AnswerQ: How is the location of a double or triple bond in the
How is the location of a double or triple bond in the longest continuous chain of an unsaturated hydrocarbon indicated?
See AnswerQ: Indicate the missing molecule in each of the following reactions of alkenes
Indicate the missing molecule in each of the following reactions of alkenes. a. CH2=CH–CH3 + H2 / ? b. ? + Br2 / CH2Br–CHBr–CH3 c. 2CH2=CH–CH3 + 9? / 6CO2 + 6H2O
See AnswerQ: How is hydrogenation used in the production of solid shortenings for cooking
How is hydrogenation used in the production of solid shortenings for cooking? Give an example of a hydrogenation reaction.
See AnswerQ: Give the systematic name for each of the following unsaturated hydrocarbons.
Give the systematic name for each of the following unsaturated hydrocarbons.
See AnswerQ: Oxidation can be defined as a loss of electrons or as an
Oxidation can be defined as a loss of electrons or as an increase in oxidation state. Explain why the two definitions mean the same thing, and give an example to support your explanation.
See AnswerQ: Give the systematic name for each of the following unsaturated hydrocarbons.
Give the systematic name for each of the following unsaturated hydrocarbons.
See AnswerQ: Draw structural formulas and give the systematic names for at least four
Draw structural formulas and give the systematic names for at least four isomeric hydrocarbons containing seven carbon atoms and one double bond.
See AnswerQ: Draw structural formulas showing all possible molecules containing six carbon atoms and
Draw structural formulas showing all possible molecules containing six carbon atoms and having one triple bond.
See AnswerQ: What structure do all aromatic hydrocarbons have in common?
What structure do all aromatic hydrocarbons have in common?
See AnswerQ: When a carbon atom is bonded to four other atoms, what
When a carbon atom is bonded to four other atoms, what geometric arrangement occurs around the carbon atom? Why?
See AnswerQ: How is a monosubstituted benzene named? Give the structures and names
How is a monosubstituted benzene named? Give the structures and names of two examples. Also give two examples of monosubstituted benzenes that have special names.
See AnswerQ: How is the benzene ring named if it is considered a substituent
How is the benzene ring named if it is considered a substituent in another molecule? Give the structures and names of two examples.
See AnswerQ: What do the prefixes ortho-, meta-, and para- refer
What do the prefixes ortho-, meta-, and para- refer to in terms of the relative location of substituents in a disubstituted benzene?
See AnswerQ: Draw a structural formula for each of the following aromatic or substituted
Draw a structural formula for each of the following aromatic or substituted aromatic compounds. a. naphthalene b. 2-bromophenol c. 3-methylstyrene d. 4-nitrochlorobenzene e. 1,3-dinitrobenzene
See AnswerQ: Name the following aromatic or substituted aromatic compounds. /
Name the following aromatic or substituted aromatic compounds.
See AnswerQ: Reduction can be defined as a gain of electrons or as a
Reduction can be defined as a gain of electrons or as a decrease in oxidation state. Explain why the two definitions mean the same thing, and give an example to support your explanation.
See AnswerQ: Without looking back at the text, write the structural formula and
Without looking back at the text, write the structural formula and the name for a representative compound from each of the following families (functional groups). a. amine b. alcohol c. carboxylic...
See AnswerQ: Based on the functional group each molecule below contains, identify the
Based on the functional group each molecule below contains, identify the family of organic compounds to which each belongs.
See AnswerQ: What functional group characterizes an alcohol? What ending is added to
What functional group characterizes an alcohol? What ending is added to the name of the parent hydrocarbon to show that a molecule is an alcohol?
See AnswerQ: Draw the Lewis structures for carbon dioxide and carbon monoxide.
Draw the Lewis structures for carbon dioxide and carbon monoxide.
See AnswerQ: Distinguish among primary, secondary, and tertiary alcohols. Give a
Distinguish among primary, secondary, and tertiary alcohols. Give a structural formula for an example of each type.
See AnswerQ: Give the systematic name for each of the following alcohols. Indicate
Give the systematic name for each of the following alcohols. Indicate whether the alcohol is primary, secondary, or tertiary.
See AnswerQ: Is 1-pentanol a primary, secondary, or tertiary alcohol
Is 1-pentanol a primary, secondary, or tertiary alcohol? Why or why not?
See AnswerQ: Write the equation for the fermentation of glucose to form ethanol.
Write the equation for the fermentation of glucose to form ethanol. Why can’t ethanol solutions of greater than about 13% concentration be made directly by fermentation? How can the ethanol content be...
See AnswerQ: What is the simplest aromatic alcohol commonly called? What is it
What is the simplest aromatic alcohol commonly called? What is it mostly used for in the United States?
See AnswerQ: What functional group is common to both aldehydes and ketones?
What functional group is common to both aldehydes and ketones?
See AnswerQ: What is an oxidizing agent? What is a reducing agent?
What is an oxidizing agent? What is a reducing agent?
See AnswerQ: What is acetone commonly used for in industry? What compound gives
What is acetone commonly used for in industry? What compound gives rancid butter its unpleasant odor?
See AnswerQ: Which of the following molecules are unsaturated? a. CH3
Which of the following molecules are unsaturated? a. CH3-CH2-CH2-CH3 b. CH3-CH=CH-CH3 c. CH3-C (C-CH3 d. CH3-CH2-CH3
See AnswerQ: Write equations showing the oxidation of a primary alcohol and the oxidation
Write equations showing the oxidation of a primary alcohol and the oxidation of a secondary alcohol to produce an aldehyde and a ketone, respectively. Indicate the structure of each alcohol and of the...
See AnswerQ: Aldehydes and ketones both contain the carbonyl group, yet the properties
Aldehydes and ketones both contain the carbonyl group, yet the properties of these two types of compounds are different enough that they are classified separately. Without looking back at the text, dr...
See AnswerQ: Provide an alternative name for the compound 2-butanone.
Provide an alternative name for the compound 2-butanone.
See AnswerQ: Give the systematic name for each of the following aldehydes or ketones
Give the systematic name for each of the following aldehydes or ketones.
See AnswerQ: Draw structural formulas for each of the following aldehydes and ketones.
Draw structural formulas for each of the following aldehydes and ketones. a. dimethyl ketone b. 3-methyl-2-butanone c. propanal d. 2,2-dimethyl-3-pentanone
See AnswerQ: Draw the structure of the group that characterizes organic (carboxylic)
Draw the structure of the group that characterizes organic (carboxylic) acids. Give the general condensed formula for an organic acid.
See AnswerQ: Are carboxylic acids typically strong acids or weak acids? Write an
Are carboxylic acids typically strong acids or weak acids? Write an equation showing the acid CH3CH2COOH ionizing in water.
See AnswerQ: Complete the following equations with the structural formula of the principal organic
Complete the following equations with the structural formula of the principal organic product. /
See AnswerQ: Does an oxidizing agent increase or decrease its own oxidation state when
Does an oxidizing agent increase or decrease its own oxidation state when it acts on another atom? Does a reducing agent increase or decrease its own oxidation state when it acts on another substance?...
See AnswerQ: From what two families of organic compounds are esters synthesized? Give
From what two families of organic compounds are esters synthesized? Give a specific example of a reaction in which an ester is formed, and indicate how the name of the ester in your example is derived...
See AnswerQ: Which of the following molecules are saturated? a. CH3
Which of the following molecules are saturated? a. CH3-CH3 b. CH2=CH2 c. CH3-CH2-CH2-CH3 d. CH3-CH2-CH=CH2
See AnswerQ: What two main functional groups are in acetylsalicylic acid (aspirin)?
What two main functional groups are in acetylsalicylic acid (aspirin)?
See AnswerQ: Give the systematic name for each of the following organic acids:
Give the systematic name for each of the following organic acids:
See AnswerQ: Draw a structural formula for each of the following: a
Draw a structural formula for each of the following: a. methyl butanoate b. ethyl acetate c. o-chlorobenzoic acid d. 2,2-dimethyl-3-chloro-butanoic acid
See AnswerQ: What, in general terms, is a polymer? What is
What, in general terms, is a polymer? What is a monomer?
See AnswerQ: One type of polymerization reaction in which the monomers “add together
One type of polymerization reaction in which the monomers “add together” to form the polymer (and no other products are formed) is called a(n) polymerization.
See AnswerQ: What is condensation polymerization, and how does it differ from addition
What is condensation polymerization, and how does it differ from addition polymerization? Give an example of a common condensation polymer.
See AnswerQ: The “Chemistry in Focus” segment Mother of Invention discusses Stephanie
The “Chemistry in Focus” segment Mother of Invention discusses Stephanie Kwolek and the invention of Kevlar. Is Kevlar a copolymer or a homopolymer?
See AnswerQ: What are some applications of the common polymer polyvinyl chloride (PVC
What are some applications of the common polymer polyvinyl chloride (PVC)?
See AnswerQ: Does an oxidizing agent donate or accept electrons? Does a reducing
Does an oxidizing agent donate or accept electrons? Does a reducing agent donate or accept electrons?
See AnswerQ: For the polymeric substances nylon and Dacron, sketch representations of the
For the polymeric substances nylon and Dacron, sketch representations of the repeating unit in each.
See AnswerQ: The first “organic” compound to be synthesized in the laboratory
The first “organic” compound to be synthesized in the laboratory, rather than being isolated from nature, was , which was prepared from .
See AnswerQ: Figure 20.3 shows the structures of the hydrocarbons propane and
Figure 20.3 shows the structures of the hydrocarbons propane and butane. Discuss the arrangement of the electron pairs around each of the carbon atoms in these molecules. Are these molecules linear? W...
See AnswerQ: A carbon compound containing a carbon–carbon double or triple bond
A carbon compound containing a carbon–carbon double or triple bond is said to be .
See AnswerQ: The general orientation of the four pairs of electrons around the carbon
The general orientation of the four pairs of electrons around the carbon atoms in alkanes is .
See AnswerQ: Alkanes in which the carbon atoms form a single unbranched chain are
Alkanes in which the carbon atoms form a single unbranched chain are said to be alkanes.
See AnswerQ: Structural isomerism occurs when two molecules have the same number of each
Structural isomerism occurs when two molecules have the same number of each type of atom but exhibit different arrangements of the between those atoms.
See AnswerQ: The systematic names of all saturated hydrocarbons have the ending added to
The systematic names of all saturated hydrocarbons have the ending added to a root name that indicates the number of carbon atoms in the molecule.
See AnswerQ: For a branched hydrocarbon, the root name for the hydrocarbon comes
For a branched hydrocarbon, the root name for the hydrocarbon comes from the number of carbon atoms in the continuous chain in the molecule.
See AnswerQ: The positions of substituents along the hydrocarbon framework of a molecule are
The positions of substituents along the hydrocarbon framework of a molecule are indicated by the of the carbon atom to which the substituents are attached.
See AnswerQ: The “Chemistry in Focus” segment Do We Age by Oxidation
The “Chemistry in Focus” segment Do We Age by Oxidation? discusses antioxidants. What does it mean for a chemical to be an antioxidant? How would it work chemically?
See AnswerQ: Kerosene may be converted to gasoline by , which means that the
Kerosene may be converted to gasoline by , which means that the larger, heavier kerosene components are broken down by heat into smaller, lighter gasoline fragments.
See AnswerQ: Tetraethyl lead, (C2H5)4Pb, was added to gasoline
Tetraethyl lead, (C2H5)4Pb, was added to gasoline in the past as a(n) agent.
See AnswerQ: The major use of alkanes has been in reactions, as a
The major use of alkanes has been in reactions, as a source of heat and light.
See AnswerQ: How large is a typical atomic nucleus, and how does the
How large is a typical atomic nucleus, and how does the size of the nucleus of an atom compare with the overall size of the atom?
See AnswerQ: What does the atomic number of an atom represent?
What does the atomic number of an atom represent?
See AnswerQ: The sum of the numbers of neutrons and protons is the .
The sum of the numbers of neutrons and protons is the .
See AnswerQ: What is meant by saying an element exists in several isotopic forms
What is meant by saying an element exists in several isotopic forms? Do isotopes of a given element have similar chemical properties? Explain.
See AnswerQ: For the nuclide , identify the mass number and the atomic number
For the nuclide , identify the mass number and the atomic number.
See AnswerQ: When a nucleus emits a beta particle, by how many atomic
When a nucleus emits a beta particle, by how many atomic mass units does the mass of the nucleus change? By how many units does the atomic number of the nucleus change? Explain.
See AnswerQ: When a nucleus emits a neutron, does the atomic number of
When a nucleus emits a neutron, does the atomic number of the nucleus change? Does the mass number of the nucleus change? Explain.
See AnswerQ: In each of the following reactions, identify which element is being
In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation numbers. a. Fe(s) + CuSO4(aq) FeSO4(aq) + Cu(s) b....
See AnswerQ: Because the chemistry of an atom is determined by the number and
Because the chemistry of an atom is determined by the number and arrangement of its , the properties of the nucleus do not strongly affect the chemical behavior of an atom.
See AnswerQ: What do we mean when we say a nucleus has undergone an
What do we mean when we say a nucleus has undergone an electron capture process? What type of electron is captured by the nucleus in this process?
See AnswerQ: Naturally occurring sulfur consists primarily (94.9%) of the
Naturally occurring sulfur consists primarily (94.9%) of the isotope with mass number 32, but small amounts of the isotopes with mass numbers 33, 34, and 36 also are present. Write the nuclear symbol...
See AnswerQ: What is the oxidation state of nitrogen in each of the following
What is the oxidation state of nitrogen in each of the following substances? a. N2 b. NH3 c. NO2 d. NaNO3
See AnswerQ: What is the oxidation state of manganese in each of the following
What is the oxidation state of manganese in each of the following substances? a. MnCl2 b. KMnO4 c. MnO2 d. Mn(C2H3O2)3
See AnswerQ: Give the nuclear symbol for each of the following. a
Give the nuclear symbol for each of the following. a. a beta particle b. an alpha particle c. a neutron d. a proton
See AnswerQ: Which of the following nuclear processes results in a decrease in the
Which of the following nuclear processes results in a decrease in the neutron-to-proton ratio? Justify your answer. a. ß-particle production b. Positron production c. Electron capture d. α-particl...
See AnswerQ: Complete each of the following nuclear equations by supplying the missing particle
Complete each of the following nuclear equations by supplying the missing particle. a. 88 226
See AnswerQ: Complete each of the following nuclear equations by supplying the missing particle
Complete each of the following nuclear equations by supplying the missing particle. a. ? 2 4
See AnswerQ: For each of the following oxidation–reduction reactions, identify which
For each of the following oxidation–reduction reactions, identify which element is being oxidized and which is being reduced. a. Cl2( g) + I2( g) 2ICl( g) b. Cl2( g) + 2Li(s)...
See AnswerQ: In each of the following reactions, identify which element is being
In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation numbers. a. 2Al(s) + 3S(s) Al2S3(s) b. CH4( g) + 2O2(...
See AnswerQ: Complete each of the following nuclear equations by supplying the missing particle
Complete each of the following nuclear equations by supplying the missing particle. a. 89 210
See AnswerQ: What does a nuclear transformation represent? How is a nuclear transformation
What does a nuclear transformation represent? How is a nuclear transformation performed?
See AnswerQ: What does a gamma ray represent? Is a γ ray a
What does a gamma ray represent? Is a γ ray a particle? Is there a change in mass or atomic number when a nucleus produces only a γ ray?
See AnswerQ: Write a balanced nuclear equation showing the bombardment of / with alpha
Write a balanced nuclear equation showing the bombardment of / with alpha particles to produce /and a neutron.
See AnswerQ: Write a balanced nuclear equation showing the bombardment of /with deuterium
Write a balanced nuclear equation showing the bombardment of /with deuterium atoms (the isotope of hydrogen with A = 2, /) to produce /and an alpha particle.
See AnswerQ: Pennies in the United States consist of a zinc core that is
Pennies in the United States consist of a zinc core that is electroplated with a thin coating of copper. Zinc dissolves in hydrochloric acid, but copper does not. If a small scratch is made on the sur...
See AnswerQ: Iron ores, usually oxides of iron, are converted to the
Iron ores, usually oxides of iron, are converted to the pure metal by reaction in a blast furnace with carbon (coke). The carbon is first reacted with air to form carbon monoxide, which in turn reacts...
See AnswerQ: Although magnesium metal does not react with water at room temperature,
Although magnesium metal does not react with water at room temperature, it does react vigorously with steam at higher temperatures, releasing elemental hydrogen gas from the water. Mg(s) + 2H2O(g)...
See AnswerQ: Consider the isotopes of radium listed in Table 19.3.
Consider the isotopes of radium listed in Table 19.3. Which isotope is most stable against decay? Which isotope is âhottestâ? From table 19.3:
See AnswerQ: The following isotopes (listed with their half-lives) have
The following isotopes (listed with their half-lives) have been used in the medical and biologic sciences. Arrange these isotopes in order of their relative decay activities: 3H (12.2 years), 24Na (15...
See AnswerQ: In each of the following reactions, identify which element is being
In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation states. a. 2Cu(s) + S(s) / Cu2S b. 2Cu2O(s) + O2(g) / 4CuO(s) c. 4B(s) +...
See AnswerQ: Although naturally occurring potassium consists mostly of the isotope of mass number
Although naturally occurring potassium consists mostly of the isotope of mass number 39 (93.25%), isotopes of mass number 41 (6.73%) and 40 (0.01%) also are present. Write the nuclear symbol for each...
See AnswerQ: Technetium-99 has been used as a radiographic agent in bone
Technetium-99 has been used as a radiographic agent in bone scans ( 43 99
See AnswerQ: Naturally occurring magnesium consists primarily of three isotopes, of mass numbers
Naturally occurring magnesium consists primarily of three isotopes, of mass numbers 24, 25, and 26. How many protons does each of these nuclides contain? How many neutrons does each of these nuclides...
See AnswerQ: Complete each of the following nuclear equations by supplying the missing particle
Complete each of the following nuclear equations by supplying the missing particle. a. 80 201
See AnswerQ: Each of the following nuclides is known to undergo radioactive decay by
Each of the following nuclides is known to undergo radioactive decay by production of a beta particle, /. Write a balanced nuclear equation for each process. a. /C b. / c. /
See AnswerQ: Each of the following nuclides is known to undergo radioactive decay by
Each of the following nuclides is known to undergo radioactive decay by production of an alpha particle, /. Write a balanced nuclear equation for each process. a. / b. / c. /
See AnswerQ: Nitric acid is a very strong acid, but is also a
Nitric acid is a very strong acid, but is also a very strong oxidizing agent, and generally behaves as the latter. It will dissolve many metals. Balance the following oxidation–reduction reactions of...
See AnswerQ: How do the forces that hold an atomic nucleus together compare in
How do the forces that hold an atomic nucleus together compare in strength with the forces between atoms in a molecule?
See AnswerQ: During nuclear , a large nucleus is transformed into lighter nuclei.
During nuclear , a large nucleus is transformed into lighter nuclei. During nuclear , small nuclei are combined to make a heavier nucleus. Both process...
See AnswerQ: In each of the following reactions, identify which element is being
In each of the following reactions, identify which element is being oxidized and which is being reduced by assigning oxidation numbers. a. 4KClO3(s) + C6H12O6(s) / 4KCl(s) + 6H2O(l) + 6CO2(g) b. 2C8H...
See AnswerQ: In which direction do electrons flow in a galvanic cell, from
In which direction do electrons flow in a galvanic cell, from anode to cathode or vice versa?
See AnswerQ: What type of reaction takes place at the cathode in a galvanic
What type of reaction takes place at the cathode in a galvanic cell? At the anode?
See AnswerQ: Consider the oxidation–reduction reaction Al(s) +
Consider the oxidation–reduction reaction Al(s) + Ni2+(aq) Al3+(aq) + Ni(s) Sketch a galvanic cell that makes use of this reaction. Which metal ion is reduced? Which metal is oxid...
See AnswerQ: Consider the oxidation–reduction reaction Zn(s) +
Consider the oxidation–reduction reaction Zn(s) + Pb2+(aq) Zn2+(aq) + Pb(s) Sketch a galvanic cell that uses this reaction. Which metal ion is reduced? Which metal is oxidize...
See AnswerQ: Write the chemical equation for the overall cell reaction that occurs in
Write the chemical equation for the overall cell reaction that occurs in a lead storage automobile battery. What species is oxidized in such a battery? What species is reduced? Why can such a battery...
See AnswerQ: What are some advantages of using lithium ion batteries in electrical devices
What are some advantages of using lithium ion batteries in electrical devices? What is a disadvantage?
See AnswerQ: is the process of returning metals to their natural state—
is the process of returning metals to their natural state—the ores from which they were originally obtained. This process involves of the...
See AnswerQ: In a breeder nuclear reactor, nonfissionable is converted to fissionable .
In a breeder nuclear reactor, nonfissionable is converted to fissionable .
See AnswerQ: Pure iron ordinarily rusts quickly, but steel does not corrode nearly
Pure iron ordinarily rusts quickly, but steel does not corrode nearly as fast. How does steel resist corrosion?
See AnswerQ: The “Chemistry in Focus” segment Stainless Steel: It’s the
The “Chemistry in Focus” segment Stainless Steel: It’s the Pits discusses the fact that stainless steel can corrode if there is a deficit of chromium. How does chromium protect stainless steel?
See AnswerQ: What is meant by a nuclear bombardment process? Give an example
What is meant by a nuclear bombardment process? Give an example of such a process, and describe what the net result of the process is.
See AnswerQ: How does an electrolysis cell differ from a galvanic cell?
How does an electrolysis cell differ from a galvanic cell?
See AnswerQ: Although aluminum is one of the most abundant metals on earth,
Although aluminum is one of the most abundant metals on earth, its price until the 1890s made it a “precious metal” like gold and platinum. Why?
See AnswerQ: Explain the difference between somatic damage from radiation and genetic damage.
Explain the difference between somatic damage from radiation and genetic damage. Which type causes immediate damage to the exposed individual?
See AnswerQ: Reactions in which one or more are transferred between species are called
Reactions in which one or more are transferred between species are called oxidation–reduction reactions.
See AnswerQ: Another name for the term oxidation state is .
Another name for the term oxidation state is .
See AnswerQ: Reduction may be described as a(n) of electrons or
Reduction may be described as a(n) of electrons or as a decrease in .
See AnswerQ: In assigning oxidation states for a covalently bonded molecule, we assume
In assigning oxidation states for a covalently bonded molecule, we assume that the more element controls both electrons of the covalent bond.
See AnswerQ: The sum of the oxidation states of the atoms in a polyatomic
The sum of the oxidation states of the atoms in a polyatomic ion is equal to the overall of the ion.
See AnswerQ: What is an oxidizing agent? Is an oxidizing agent itself oxidized
What is an oxidizing agent? Is an oxidizing agent itself oxidized or reduced when it acts on another species?
See AnswerQ: At which electrode (anode/cathode) do species gain electrons
At which electrode (anode/cathode) do species gain electrons in a galvanic cell?
See AnswerQ: What is the half-life of a radioactive nucleus? Does
What is the half-life of a radioactive nucleus? Does a given type of nucleus always have the same half-life? Do nuclei of different elements have the same half-life?
See AnswerQ: are radioactive substances that physicians introduce into the body to enable
are radioactive substances that physicians introduce into the body to enable them to study the absorption and metabolism of the substance or to analyze the functioning of an organ...
See AnswerQ: The most common type of nuclear reactor uses the nuclide as its
The most common type of nuclear reactor uses the nuclide as its fissionable material.
See AnswerQ: Supply the missing particle, and state the type of decay for
Supply the missing particle, and state the type of decay for each of the following nuclear processes.
See AnswerQ: Each of the following isotopes has been used medically for the purpose
Each of the following isotopes has been used medically for the purpose indicated. Suggest reasons why the particular element might have been chosen for this purpose. a. cobalt-57, for study of the bo...
See AnswerQ: Each of the following nuclides is known to undergo radioactive decay by
Each of the following nuclides is known to undergo radioactive decay by production of a ß particle, /. Write a balanced nuclear equation for each process. a. / b. / c. /
See AnswerQ: Zirconium consists of five primary isotopes, of mass numbers and abundances
Zirconium consists of five primary isotopes, of mass numbers and abundances shown below: Zr-90………...51.5% Zr-91………….11.2% Zr-92………...17.1% Zr-94……….17.4% Zr-96…………2.8% Write the nuclear symbol,
See AnswerQ: The element zinc in nature consists of five isotopes with higher than
The element zinc in nature consists of five isotopes with higher than 0.5% natural abundances, with mass numbers 64, 66, 67, 68, and 70. Write the nuclear symbol for each of these isotopes. How many p...
See AnswerQ: Aluminum exists in several isotopic forms, including /Al, /
Aluminum exists in several isotopic forms, including /Al, /Al, and /Al. Indicate the number of protons and the number of neutrons in each of these isotopes.
See AnswerQ: Complete each of the following nuclear equations by supplying the missing particle
Complete each of the following nuclear equations by supplying the missing particle. a. 88 226
See AnswerQ: What do we mean when we say that one radioactive nucleus is
What do we mean when we say that one radioactive nucleus is “hotter” than another? Which element would have more decay events over a given period of time?
See AnswerQ: How many of the following statements regarding the decay of radioactive nuclides
How many of the following statements regarding the decay of radioactive nuclides are true? a. During a given period of time, a radioactive nucleus with a short half-life is much more likely to decay...
See AnswerQ: Write a balanced nuclear equation for the bombardment of 7
Write a balanced nuclear equation for the bombardment of 7 14
See AnswerQ: Write a nuclear equation showing the bombardment of beryllium-9 with
Write a nuclear equation showing the bombardment of beryllium-9 with alpha particles, resulting in production of carbon-12 and a neutron.
See AnswerQ: Each of the following nuclides is known to undergo radioactive decay by
Each of the following nuclides is known to undergo radioactive decay by production of a ß particle, /. Write a balanced nuclear equation for each process. a. 53 136
See AnswerQ: Consider a galvanic cell based on the following oxidation– reduction reaction
Consider a galvanic cell based on the following oxidation– reduction reaction: 2Al3+(aq) + 3Mg(s) ( 2Al(s) + 3Mg2+(aq) What will the electrode found in the cathode portion of the cell be made of? Exp...
See AnswerQ: Consider the oxidation–reduction reaction Mg(s) +
Consider the oxidation–reduction reaction Mg(s) + Cu2+(aq) / Mg2+(aq) + Cu(s) Sketch a galvanic cell that uses this reaction. Which metal ion is reduced? Which metal is oxidized? What half-reaction t...
See AnswerQ: Complete the following table with the nuclear particle that is produced in
Complete the following table with the nuclear particle that is produced in each nuclear reaction.
See AnswerQ: Potassium iodide in solution reacts readily with many reagents. In the
Potassium iodide in solution reacts readily with many reagents. In the following reactions, identify the atoms that are being oxidized and reduced, and specify the oxidizing and reducing agents. a. C...
See AnswerQ: In what two respects must oxidation–reduction reactions be balanced?
In what two respects must oxidation–reduction reactions be balanced?
See AnswerQ: Why is a systematic method for balancing oxidation–reduction reactions necessary
Why is a systematic method for balancing oxidation–reduction reactions necessary? Why can’t these equations be balanced readily by inspection?
See AnswerQ: What is a half-reaction? What does each of the
What is a half-reaction? What does each of the two half- reactions that make up an overall process represent?
See AnswerQ: For each of the following oxidation–reduction reactions, identify which
For each of the following oxidation–reduction reactions, identify which element is oxidized and which is reduced. a. 6Na(s) + N2( g) 2Na3N(s) b. Mg(s) + Cl2( g) MgCl2(s)...
See AnswerQ: Why must the number of electrons lost in the oxidation equal the
Why must the number of electrons lost in the oxidation equal the number of electrons gained in the reduction? Is it possible to have “leftover” electrons in a reaction?
See AnswerQ: Balance each of the following half-reactions. a.
Balance each of the following half-reactions. a. Cu / Cu2+ b. Fe3+ / Fe2+ c. Br– / Br2 d. Fe2+ / Fe
See AnswerQ: Balance each of the following half-reactions. a.
Balance each of the following half-reactions. a. 3N2( g) + 2e- 2N3-(aq) b. O22-(aq) O2( g) c. Zn(s) Zn2+(aq) d. F2( g) F-(aq)
See AnswerQ: Balance each of the following half-reactions, which take place
Balance each of the following half-reactions, which take place in acidic solution. a. HClO(aq) Cl-(aq) b. NO(aq) N2O( g) c. N2O(aq) N2( g) d. ClO3-(aq...
See AnswerQ: Balance each of the following half-reactions, which take place
Balance each of the following half-reactions, which take place in acidic solution. a. O2(g) / H2O(l) b. SO42–(aq) / H2SO3(aq) c. H2O2(aq) / H2O(l) d. NO2–(aq) / NO3–(aq)
See AnswerQ: Balance each of the following oxidation–reduction reactions, which take
Balance each of the following oxidation–reduction reactions, which take place in acidic solution, by using the “half-reaction” method. a. Mg(s) + Hg2+(aq) / Mg2+(aq) + Hg22+(aq) b. NO3–(aq) + Br–(aq)...
See AnswerQ: Balance each of the following oxidation–reduction reactions, which take
Balance each of the following oxidation–reduction reactions, which take place in acidic solution, by using the “half-reaction” method. a. Al(s) + H+(aq) / Al3+(aq) + H2(g) b. S2–(aq) + NO3–(g) / S(s...
See AnswerQ: Iodide ion, I-, is one of the most easily oxidized
Iodide ion, I-, is one of the most easily oxidized species. Balance each of the following oxidation–reduction reactions, which take place in acidic solution, by using the “half-reaction” method. a. I...
See AnswerQ: The element krypton has several radioactive isotopes. Below are listed several
The element krypton has several radioactive isotopes. Below are listed several of these isotopes along with their half-lives. Which of the isotopes is most stable? Which of the isotopes is “hottest”?...
See AnswerQ: Describe in general terms how an archaeological artifact is dated using carbon
Describe in general terms how an archaeological artifact is dated using carbon-14.
See AnswerQ: For each of the following oxidation–reduction reactions, identify which
For each of the following oxidation–reduction reactions, identify which element is being oxidized and which is being reduced. a. Ca(s) + 2H2O(l) Ca(OH)2(s, aq) + H2(g) b. H2(g) + F2...
See AnswerQ: What is a salt bridge? Why is a salt bridge necessary
What is a salt bridge? Why is a salt bridge necessary in a galvanic cell? Can some other method be used in place of the salt bridge?
See AnswerQ: In dating artifacts using carbon-14, an assumption is made
In dating artifacts using carbon-14, an assumption is made about the amount of carbon-14 in the atmosphere. What is this assumption? Why is the assumption important?
See AnswerQ: Why does an ancient wood or cloth artifact contain less 6
Why does an ancient wood or cloth artifact contain less 6 14
See AnswerQ: The thyroid gland is interesting in that it is practically the only
The thyroid gland is interesting in that it is practically the only place in the body where the element iodine is used. How have radiotracers been used to study and treat illnesses of the thyroid glan...
See AnswerQ: What does it mean to say that fissionable material possesses a critical
What does it mean to say that fissionable material possesses a critical mass? Can a chain reaction occur when a sample has less than the critical mass?
See AnswerQ: Describe the purpose of each of the major components of a nuclear
Describe the purpose of each of the major components of a nuclear reactor (moderator, control rods, containment, cooling liquid, and so on).
See AnswerQ: Can a nuclear explosion take place in a reactor? Is the
Can a nuclear explosion take place in a reactor? Is the concentration of fissionable material used in reactors large enough for this?
See AnswerQ: What is a meltdown, and how can it occur? Most
What is a meltdown, and how can it occur? Most nuclear reactors use water as the cooling liquid. Is there any danger of a steam explosion if the reactor core becomes overheated?
See AnswerQ: Explain how some metals, notably aluminum, naturally resist complete oxidation
Explain how some metals, notably aluminum, naturally resist complete oxidation by the atmosphere.
See AnswerQ: Benzene exhibits resonance. Explain this statement in terms of the different
Benzene exhibits resonance. Explain this statement in terms of the different Lewis structures that can be drawn for benzene.
See AnswerQ: For each of the following oxidation–reduction reactions, identify which
For each of the following oxidation–reduction reactions, identify which element is oxidized and which is reduced. a. Mg(s) + Br2( l ) MgBr2(s) b. 2Na(s) + S(s) Na2S(s...
See AnswerQ: If a benzene ring contains several substituents, how are the relative
If a benzene ring contains several substituents, how are the relative locations of the substituents numbered in the systematic name given to the molecule?
See AnswerQ: What type of “fuel” could be used in a nuclear
What type of “fuel” could be used in a nuclear fusion reactor, and why is this desirable?
See AnswerQ: What are some important uses of electrolysis?
What are some important uses of electrolysis?
See AnswerQ: Although the energy transferred per event when a living creature is exposed
Although the energy transferred per event when a living creature is exposed to radiation is small, why is such exposure dangerous?
See AnswerQ: The “Chemistry in Focus” segment Water-Powered Fireplace discusses
The “Chemistry in Focus” segment Water-Powered Fireplace discusses a fireplace that uses the electrolysis of water to produce hydrogen gas. Write the balanced chemical equation for the electrolysis of...
See AnswerQ: Write the equation for the synthesis of ethanol from ethylene. What
Write the equation for the synthesis of ethanol from ethylene. What are some commercial uses of ethanol made by this process?
See AnswerQ: Explain why, although gamma rays are far more penetrating than alpha
Explain why, although gamma rays are far more penetrating than alpha particles, the latter are actually more likely to cause damage to an organism. Which radiation is more effective at causing ionizat...
See AnswerQ: How do the chemical properties of radioactive nuclei (as opposed to
How do the chemical properties of radioactive nuclei (as opposed to the nuclear decay they undergo) influence the degree of damage they do to an organism?
See AnswerQ: Although nuclear processes offer the potential for an abundant source of energy
Although nuclear processes offer the potential for an abundant source of energy, no nuclear power plants have been built in the United States for some time. In addition to the fear of a malfunction in...
See AnswerQ: Why is methanol sometimes called wood alcohol? Describe the modern synthesis
Why is methanol sometimes called wood alcohol? Describe the modern synthesis of methanol. What are some uses of methanol?
See AnswerQ: let’s us keep track of electrons in oxidation– reduction reactions
let’s us keep track of electrons in oxidation– reduction reactions by assigning charges to the various atoms in a compound.
See AnswerQ: What structural feature distinguishes aldehydes from ketones?
What structural feature distinguishes aldehydes from ketones?
See AnswerQ: An oxidizing agent causes the (oxidation/reduction) of another
An oxidizing agent causes the (oxidation/reduction) of another species, and the oxidizing agent itself is (oxidized/reduced).
See AnswerQ: To function as a good reducing agent, a species must electrons
To function as a good reducing agent, a species must electrons easily.
See AnswerQ: When we balance an oxidation–reduction equation, the number of
When we balance an oxidation–reduction equation, the number of electrons lost by the reducing agent must the number of electrons gained by the oxidizing agent.
See AnswerQ: To obtain useful electrical energy from an oxidation–reduction process,
To obtain useful electrical energy from an oxidation–reduction process, we must set up the reaction in such a way that the oxidation half-reaction and the reduction half-reaction are physically...
See AnswerQ: An electrochemical cell that produces a current from an oxidation–reduction
An electrochemical cell that produces a current from an oxidation–reduction reaction is often called a(n) cell.
See AnswerQ: Which process (oxidation/reduction) takes place at the anode
Which process (oxidation/reduction) takes place at the anode of a galvanic cell?
See AnswerQ: What systematic ending is used to show that a molecule is a
What systematic ending is used to show that a molecule is a carboxylic acid? Give an example.
See AnswerQ: In a(n) cell, electrons flow through a wire
In a(n) cell, electrons flow through a wire from the reducing agent to the oxidizing agent.
See AnswerQ: The “pressure” on electrons to flow from one electrode to
The “pressure” on electrons to flow from one electrode to the other in a battery is called the of the battery.
See AnswerQ: Why must the sum of all the oxidation states of the atoms
Why must the sum of all the oxidation states of the atoms in a neutral molecule be zero?
See AnswerQ: The process of involves forcing a current through a cell to produce
The process of involves forcing a current through a cell to produce a chemical change that would not otherwise occur. How is this process different than what occurs in a galvanic...
See AnswerQ: The common acid dry cell battery typically contains an inner casing made
The common acid dry cell battery typically contains an inner casing made of metal, which functions as the anode.
See AnswerQ: Corrosion of a metal represents its by species present in the atmosphere
Corrosion of a metal represents its by species present in the atmosphere.
See AnswerQ: Although aluminum is a reactive metal, pure aluminum ordinarily does not
Although aluminum is a reactive metal, pure aluminum ordinarily does not corrode severely in air because a protective layer of builds up on the metal’s surface.
See AnswerQ: For each of the following unbalanced oxidation–reduction chemical equations,
For each of the following unbalanced oxidation–reduction chemical equations, balance the equation by inspection, and identify which species is the reducing agent. a. Fe(s) + O2(g) / Fe2O3(s) b...
See AnswerQ: In each of the following reactions, identify which element is oxidized
In each of the following reactions, identify which element is oxidized and which is reduced. a. Zn(s) + 2HCl(aq) ZnCl2(aq) + H2( g) b. 2CuI(s) CuI2(s) + Cu(s) c....
See AnswerQ: In each of the following reactions, identify which species is the
In each of the following reactions, identify which species is the oxidizing agent. a. 2Al(s) + 6HCl(aq) ( 2AlCl3(aq) + 3H2(g) b. Cu(s) + H2SO4(aq) ( CuSO4(aq) + H2(g)
See AnswerQ: Carbon compounds containing double bonds (such compounds are called alkenes)
Carbon compounds containing double bonds (such compounds are called alkenes) react readily with many other reagents. In each of the following reactions, identify which atoms are oxidized and which are...
See AnswerQ: Balance each of the following oxidation–reduction reactions by inspection.
Balance each of the following oxidation–reduction reactions by inspection. a. C3H8( g) + O2( g) / CO2( g) + H2O( g) b. CO( g) + H2( g) / CH3OH( l ) c. SnO2(s) + C(s) / Sn(s) + CO( g) d. C2H5OH( l...
See AnswerQ: Balance each of the following oxidation–reduction reactions, which take
Balance each of the following oxidation–reduction reactions, which take place in acidic solution. a. MnO4-(aq) + H2O2(aq) / Mn2+(aq) + O2( g) b. BrO3-(aq) + Cu+(aq) / Br-(aq) + Cu2+(aq) c. HNO2(aq)...
See AnswerQ: Explain why, although it is not an ionic compound, we
Explain why, although it is not an ionic compound, we still assign oxygen an oxidation state of -2 in water, H2O. Give an example of a compound in which oxygen is not in the -2 oxidation state.
See AnswerQ: For each of the following oxidation–reduction reactions of metals with
For each of the following oxidation–reduction reactions of metals with nonmetals, identify which element is oxidized and which is reduced. a. 4Na(s) + O2( g) 2Na2O(s) b. Fe(s) + H2SO4(aq)...
See AnswerQ: For each of the following oxidation–reduction reactions of metals with
For each of the following oxidation–reduction reactions of metals with nonmetals, identify which element is oxidized and which is reduced. a. 3Zn(s) + N2( g) Zn3N2(s) b. Co(s) + S(s)...
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following: a. NH3 b. CO c. CO2 d. NF3
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following: a. PBr3 b. C3H8 c. KMnO4 d. CH3COOH
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following: a. MnO2 b. BaCrO4 c. H2SO3 d. Ca3(PO4)2
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following: a. CrCl3 b. K2CrO4 c. K2Cr2O7 d. Cr(C2H3O2)2
See AnswerQ: Assign oxidation states to all of the atoms in each of the
Assign oxidation states to all of the atoms in each of the following: a. BiO+ b. PO43- c. NO2- d. Hg22+
See AnswerQ: In each of the following reactions, identify which element is oxidized
In each of the following reactions, identify which element is oxidized and which is reduced by assigning oxidation states. a. C(s) + O2( g) / CO2( g) b. 2CO( g) + O2( g) / 2CO2( g)...
See AnswerQ: In each of the following reactions, identify which element is oxidized
In each of the following reactions, identify which element is oxidized and which is reduced by assigning oxidation states. a. 2B2O3(s) + 6Cl2(g) / 4BCl3(l) + 3O2(g) b. GeH4(g) + O2(g) / Ge(s) + 2H2O(...
See AnswerQ: Balance each of the following half-reactions. a.
Balance each of the following half-reactions. a. I-(aq) / I2(s) b. O2( g) / O2-(s) c. P4(s) / P3-(s) d. Cl2( g) / Cl-(aq)
See AnswerQ: What does the average atomic mass of an element represent? What
What does the average atomic mass of an element represent? What unit is used for average atomic mass? Express the atomic mass unit in grams. Why is the average atomic mass for an element typically not...
See AnswerQ: What is matter? What is matter composed of? What are
What is matter? What is matter composed of? What are some of the different types of matter? How do these types of matter differ, and how are they the same?
See AnswerQ: You have learned how the properties of the elements vary systematically,
You have learned how the properties of the elements vary systematically, corresponding to the electron structures of the elements being considered. Discuss how the ionization energies and atomic sizes...
See AnswerQ: In general, what do we mean by a chemical bond?
In general, what do we mean by a chemical bond? What does the bond energy tell us about the strength of a chemical bond? Name the principal types of chemical bonds.
See AnswerQ: What do we mean by ionic bonding? Give an example of
What do we mean by ionic bonding? Give an example of a substance whose particles are held together by ionic bonding. What experimental evidence do we have for the existence of ionic bonding? In genera...
See AnswerQ: What do we mean by covalent bonding and polar covalent bonding?
What do we mean by covalent bonding and polar covalent bonding? How are these two bonding types similar and how do they differ? What circumstance must exist for a bond to be purely covalent? How does...
See AnswerQ: In the formation of a polynucleotide (a short portion of the
In the formation of a polynucleotide (a short portion of the DNA molecule), which components (sugar, base, or phosphate) on adjacent nucleotides bond to each other?
See AnswerQ: What is meant by electronegativity? How is the difference in electronegativity
What is meant by electronegativity? How is the difference in electronegativity between two bonded atoms related to the polarity of the bond? Using Fig. 12.3, give an example of a bond that would be no...
See AnswerQ: What does it mean to say that a molecule has a dipole
What does it mean to say that a molecule has a dipole moment? What is the difference between a polar bond and a polar molecule (one that has a dipole moment)? Give an example of a molecule that has po...
See AnswerQ: How is the attainment of a noble gas electron configuration important to
How is the attainment of a noble gas electron configuration important to our ideas of how atoms bond to each other? When atoms of a metal react with atoms of a nonmetal, what type of electron configur...
See AnswerQ: Give evidence that ionic bonds are very strong. Does an ionic
Give evidence that ionic bonds are very strong. Does an ionic substance contain discrete molecules? With what general type of structure do ionic compounds occur? Sketch a representation of a general s...
See AnswerQ: Why does a Lewis structure for a molecule show only the valence
Why does a Lewis structure for a molecule show only the valence electrons? What is the most important factor for the formation of a stable compound? How do we use this requirement when writing Lewis s...
See AnswerQ: It is important to be able to distinguish between the physical and
It is important to be able to distinguish between the physical and the chemical properties of chemical substances. Choose a chemical substance you are familiar with, then use the Internet or a handboo...
See AnswerQ: In writing Lewis structures for molecules, what is meant by the
In writing Lewis structures for molecules, what is meant by the duet rule? To which element does the duet rule apply? What do we mean by the octet rule? Why is attaining an octet of electrons importan...
See AnswerQ: For three simple molecules of your own choice, apply the rules
For three simple molecules of your own choice, apply the rules for writing Lewis structures. Write your discussion as if you are explaining the method to someone who is not familiar with Lewis structu...
See AnswerQ: What does a double bond between two atoms represent in terms of
What does a double bond between two atoms represent in terms of the number of electrons shared? What does a triple bond represent? When writing a Lewis structure, explain how we recognize when a molec...
See AnswerQ: Although many simple molecules fulfill the octet rule, some common molecules
Although many simple molecules fulfill the octet rule, some common molecules are exceptions to this rule. Give three examples of molecules whose Lewis structures are exceptions to the octet rule.
See AnswerQ: What do we mean by the geometric structure of a molecule?
What do we mean by the geometric structure of a molecule? Draw the geometric structures of at least four simple molecules of your choosing and indicate the bond angles in the structures. Explain the m...
See AnswerQ: An unknown element is a nonmetal and has a valence electron configuration
An unknown element is a nonmetal and has a valence electron configuration of ns2np4. a. How many valence electrons does this element have? b. Which of the following are possible identities for this...
See AnswerQ: Which of the following has the smallest ionization energy? a
Which of the following has the smallest ionization energy? a. Se2- b. Br- c. Sr2+ d. Zr4+ e. Rb+
See AnswerQ: Based on the electron configuration of the simple ions that the following
Based on the electron configuration of the simple ions that the following pairs of elements would be expected to form, predict the formula of the simple binary compound that would be formed by each pa...
See AnswerQ: Draw the Lewis structure for each of the following molecules or ions
Draw the Lewis structure for each of the following molecules or ions. Indicate the number and spatial orientation of the electron pairs around the boldface atom in each formula. Predict the simple geo...
See AnswerQ: Hydrogen gas and oxygen gas react violently to form water. When
Hydrogen gas and oxygen gas react violently to form water. When this occurs, a very loud noise is heard. a. Draw the Lewis structures for hydrogen gas, oxygen gas, and water. b. State whether each mo...
See AnswerQ: What is an element, and what is a compound? Give
What is an element, and what is a compound? Give examples of each. What does it mean to say that a compound has a constant composition? Would samples of a particular compound here and in another part...
See AnswerQ: How are the Arrhenius and Brønsted–Lowry definitions of acids and
How are the Arrhenius and Brønsted–Lowry definitions of acids and bases similar, and how do these definitions differ? Could a substance be an Arrhenius acid but not a Brønsted– Lowry acid? Could a sub...
See AnswerQ: Describe the relationship between a conjugate acid–base pair in the
Describe the relationship between a conjugate acid–base pair in the Brønsted–Lowry model. Write balanced chemical equations showing the following molecules/ions behaving as Brønsted– Lowry acids in wa...
See AnswerQ: Acetic acid is a weak acid in water. What does this
Acetic acid is a weak acid in water. What does this indicate about the affinity of the acetate ion for protons compared to the affinity of water molecules for protons? If a solution of sodium acetate...
See AnswerQ: How is the strength of an acid related to the position of
How is the strength of an acid related to the position of its ionization equilibrium? Write the equations for the dissociation (ionization) of HCl, HNO3, and HClO4 in water. Since all these acids are...
See AnswerQ: Explain how water is an amphoteric substance. Write the chemical equation
Explain how water is an amphoteric substance. Write the chemical equation for the autoionization of water. Write the expression for the equilibrium constant, Kw, for this reaction. What values does Kw...
See AnswerQ: How is the pH scale defined? What range of pH values
How is the pH scale defined? What range of pH values corresponds to acidic solutions? What range corresponds to basic solutions? Why is pH = 7.00 considered neutral? When the pH of a solution changes...
See AnswerQ: Explain the collision model for chemical reactions. What “collides”?
Explain the collision model for chemical reactions. What “collides”? Do all collisions result in the breaking of bonds and formation of products? Why? How does the collision model explain why higher c...
See AnswerQ: Sketch a graph for the progress of a reaction illustrating the activation
Sketch a graph for the progress of a reaction illustrating the activation energy for the reaction. Define “activation energy.” Explain how an increase in temperature for a reaction affects the number...
See AnswerQ: Describe how we write the equilibrium expression for a reaction. Give
Describe how we write the equilibrium expression for a reaction. Give three examples of balanced chemical equations and the corresponding expressions for their equilibrium constants.
See AnswerQ: What is a mixture? What is a solution? How do
What is a mixture? What is a solution? How do mixtures differ from pure substances? What are some of the techniques by which mixtures can be resolved into their components?
See AnswerQ: Although the equilibrium constant for a given reaction always has the same
Although the equilibrium constant for a given reaction always has the same value at the same temperature, the actual concentrations present at equilibrium may differ from one experiment to another. Ex...
See AnswerQ: Compare homogeneous and heterogeneous equilibria. Give a balanced chemical equation and
Compare homogeneous and heterogeneous equilibria. Give a balanced chemical equation and write the corresponding equilibrium constant expression as an example of each of these cases. How does the fact...
See AnswerQ: In your own words, paraphrase Le Châtelier’s principle. Give an
In your own words, paraphrase Le Châtelier’s principle. Give an example (including a balanced chemical equation) of how each of the following changes can affect the position of equilibrium in favor of...
See AnswerQ: Explain how dissolving a slightly soluble salt to form a saturated solution
Explain how dissolving a slightly soluble salt to form a saturated solution is an equilibrium process. Give three balanced chemical equations for solubility processes and write the expressions for Ksp...
See AnswerQ: For each of the following, calculate the indicated quantity.
For each of the following, calculate the indicated quantity. a. [OH-] = 2.11 * 10-4 M, [H+] =? b. [OH2] = 7.34 * 10-6 M, pH 5 ? c. [OH2] = 9.81 * 10-8 M, pOH 5 ? d. pH = 9.32, pOH =? e. [H+] = 5....
See AnswerQ: Calculate the pH and pOH values for each of the following solutions
Calculate the pH and pOH values for each of the following solutions. a. 0.00562 M HClO4 b. 3.98 * 10-4 M KOH c. 0.078 M HNO3 d. 4.71 * 10-6 M Ca(OH)2
See AnswerQ: The solubility product of magnesium carbonate, MgCO3, has the value
The solubility product of magnesium carbonate, MgCO3, has the value Ksp = 6.82 * 10-6 at 25 0C. How many grams of MgCO3 will dissolve in 1.00 L of water?
See AnswerQ: Describe a buffered solution. Give three examples of buffered solutions.
Describe a buffered solution. Give three examples of buffered solutions. For each of your examples, write equations and explain how the components of the buffered solution consume added strong acids o...
See AnswerQ: What are some of the general properties of gases that distinguish them
What are some of the general properties of gases that distinguish them from liquids and solids?
See AnswerQ: How does the pressure of the atmosphere arise? Sketch a representation
How does the pressure of the atmosphere arise? Sketch a representation of the device commonly used to measure the pressure of the atmosphere. Your textbook described a simple experiment to demonstrate...
See AnswerQ: How is the secondary structure of a protein related to its function
How is the secondary structure of a protein related to its function in the body? Give examples.
See AnswerQ: What is the SI unit of pressure? What units of pressure
What is the SI unit of pressure? What units of pressure are commonly used in the United States? Why are these common units more convenient to use than the SI unit? Describe a manometer and explain how...
See AnswerQ: Your textbook gives several definitions and formulas for Boyle’s law for gases
Your textbook gives several definitions and formulas for Boyle’s law for gases. Write, in your own words, what this law really tells us about gases. Now write two mathematical expressions that describ...
See AnswerQ: When using Boyle’s law in solving problems in the textbook, you
When using Boyle’s law in solving problems in the textbook, you may have noticed that questions were often qualified by stating that “the temperature and amount of gas remain the same.” Why was this q...
See AnswerQ: What does Charles’s law tell us about how the volume of a
What does Charles’s law tell us about how the volume of a gas sample varies as the temperature of the sample is changed? How does this volume–temperature relationship differ from the volume–pressure r...
See AnswerQ: Explain how the concept of absolute zero came about through Charles’s studies
Explain how the concept of absolute zero came about through Charles’s studies of gases. Hint: What would happen to the volume of a gas sample at absolute zero (if the gas did not liquefy first)? What...
See AnswerQ: What does Avogadro’s law tell us about the relationship between the volume
What does Avogadro’s law tell us about the relationship between the volume of a sample of gas and the number of molecules the gas contains? Why must the temperature and pressure be held constant for v...
See AnswerQ: What do we mean specifically by an ideal gas? Explain why
What do we mean specifically by an ideal gas? Explain why the ideal gas law (PV = nRT) is actually a combination of Boyle’s, Charles’s, and Avogadro’s gas laws. What is the numerical value and what ar...
See AnswerQ: Dalton’s law of partial pressures concerns the properties of mixtures of gases
Dalton’s law of partial pressures concerns the properties of mixtures of gases. What is meant by the partial pressure of an individual gas in a mixture? How does the total pressure of a gaseous mixtur...
See AnswerQ: Without consulting your textbook, list and explain the main postulates of
Without consulting your textbook, list and explain the main postulates of the kinetic molecular theory for gases. How do these postulates help us account for the following bulk properties of a gas: th...
See AnswerQ: What does “STP” stand for? What conditions correspond to
What does “STP” stand for? What conditions correspond to STP? What is the volume occupied by one mole of an ideal gas at STP?
See AnswerQ: For each of the following, make the indicated conversion, showing
For each of the following, make the indicated conversion, showing explicitly the conversion factor(s) you used. a. 593.2 kg to grams b. 593.2 lbs to grams c. 8.312 km to miles d. 8.312 ft to miles...
See AnswerQ: In general, how do we envision the structures of solids and
In general, how do we envision the structures of solids and liquids? Explain how the densities and compressibilities of solids and liquids contrast with those properties of gaseous substances. How do...
See AnswerQ: Describe some of the physical properties of water. Why is water
Describe some of the physical properties of water. Why is water one of the most important substances on earth?
See AnswerQ: Define the normal boiling point of water. Why does a sample
Define the normal boiling point of water. Why does a sample of boiling water remain at the same temperature until all the water has been boiled? Define the normal freezing point of water. Sketch a rep...
See AnswerQ: Are changes in state physical or chemical changes? Explain. What
Are changes in state physical or chemical changes? Explain. What type of forces must be overcome to melt or vaporize a substance (are these forces intramolecular or intermolecular)? Define the molar h...
See AnswerQ: What is a dipole–dipole attraction? How do the strengths
What is a dipole–dipole attraction? How do the strengths of dipole–dipole forces compare with the strengths of typical covalent bonds? What is hydrogen bonding? What conditions are necessary for hydro...
See AnswerQ: Define London dispersion forces. Draw a picture showing how London forces
Define London dispersion forces. Draw a picture showing how London forces arise. Are London forces relatively strong or relatively weak? Explain. Although London forces exist among all molecules, for...
See AnswerQ: Why does the process of vaporization require an input of energy?
Why does the process of vaporization require an input of energy? Why is it so important that water has a large heat of vaporization? What is condensation? Explain how the processes of vaporization and...
See AnswerQ: Define a crystalline solid. Describe in detail some important types of
Define a crystalline solid. Describe in detail some important types of crystalline solids and name a substance that is an example of each type of solid. Explain how the particles are held together in...
See AnswerQ: Define the bonding that exists in metals and how this model explains
Define the bonding that exists in metals and how this model explains some of the unique physical properties of metals. What are metal alloys? Identify the two main types of alloys, and describe how th...
See AnswerQ: Define a solution. Describe how an ionic solute such as NaCl
Define a solution. Describe how an ionic solute such as NaCl dissolves in water to form a solution. How are the strong bonding forces in a crystal of ionic solute overcome? Why do the ions in a soluti...
See AnswerQ: Without performing the actual calculations, determine to how many significant figures
Without performing the actual calculations, determine to how many significant figures the results of the following calculations should be reported. c. 1.782 + 0.00035 + 2.11 d. (6.521)(5.338 + 2.11)...
See AnswerQ: Define a saturated solution. Does saturated mean the same thing as
Define a saturated solution. Does saturated mean the same thing as saying the solution is concentrated? Explain. Why does a solute dissolve only to a particular extent in water? How does formation of...
See AnswerQ: When a solution is diluted by adding additional solvent, the concentration
When a solution is diluted by adding additional solvent, the concentration of solute changes but the amount of solute present does not change. Explain. Suppose 250. mL of water is added to 125 mL of 0...
See AnswerQ: What is one equivalent of an acid? What does an equivalent
What is one equivalent of an acid? What does an equivalent of a base represent? How is the equivalent weight of an acid or a base related to the substance’s molar mass? Give an example of an acid and...
See AnswerQ: Calculate the indicated quantity for each gas sample. a.
Calculate the indicated quantity for each gas sample. a. The volume occupied by 1.15 g of helium gas at 25 °C and 1.01 atm pressure. b. The partial pressure of each gas if 2.27 g of H2 and 1.03 g of...
See AnswerQ: Chlorine gas, Cl2, can be generated in small quantities by
Chlorine gas, Cl2, can be generated in small quantities by addition of concentrated hydrochloric acid to manganese(IV) oxide. MnO2(s) + 4HCl(aq) / MnCl2(aq) + 2H2O(l) + Cl2(g) The chlorine gas is bub...
See AnswerQ: Calculate the volume (in milliliters) of each of the following
Calculate the volume (in milliliters) of each of the following acid solutions that would be required to neutralize 36.2 mL of 0.259 M NaOH solution. a. 0.271 M HCl b. 0.119 M H2SO4 c. 0.171 M H3PO4...
See AnswerQ: If 125 mL of concentrated sulfuric acid solution (density 1.
If 125 mL of concentrated sulfuric acid solution (density 1.84 g/mL, 98.3% H2SO4 by mass) is diluted to a final volume of 3.01 L, calculate the following information. a. the mass of pure H2SO4 in the...
See AnswerQ: Rank the following species from lowest to highest boiling point:
Rank the following species from lowest to highest boiling point: N2(l), Ne(l), BeO(l), CO(l)
See AnswerQ: In an open flask, 20.0 mL of an aqueous
In an open flask, 20.0 mL of an aqueous solution (density of solution = 1.103 g/mL) is combined with 13.5 g of a solid, and a chemical reaction takes place. One of the reaction products is 1.473 L of...
See AnswerQ: Which of the following solutions contains the greatest number of ions?
Which of the following solutions contains the greatest number of ions? a. 100.0 mL of 1.0 M sodium nitrate b. 100.0 mL of 1.0 M iron(III) nitrate c. 100.0 mL of 1.0 M copper(II) nitrate d. 100.0 m...
See AnswerQ: In general terms, what does the tertiary structure of a protein
In general terms, what does the tertiary structure of a protein describe? Clearly distinguish between the secondary and tertiary structures.
See AnswerQ: a. Fill in the following table as if it is a
a. Fill in the following table as if it is a well plate and you are mixing two aqueous compounds at a time to see if a precipitate forms. If a precipitate is expected to form, indicate that by writing...
See AnswerQ: What kind of visual evidence indicates that a chemical reaction has occurred
What kind of visual evidence indicates that a chemical reaction has occurred? Give an example of each type of evidence you have mentioned. Do all reactions produce visual evidence that they have taken...
See AnswerQ: What, in general terms, does a chemical equation indicate?
What, in general terms, does a chemical equation indicate? What are the substances indicated to the left of the arrow called in a chemical equation? To the right of the arrow?
See AnswerQ: What does it mean to “balance” an equation? Why
What does it mean to “balance” an equation? Why is it so important that equations be balanced? What does it mean to say that atoms must be conserved in a balanced chemical equation? How are the physic...
See AnswerQ: When balancing a chemical equation, why is it not permissible to
When balancing a chemical equation, why is it not permissible to adjust the subscripts in the formulas of the reactants and products? What would changing the subscripts within a formula do? What do th...
See AnswerQ: What is meant by the driving force for a reaction? Give
What is meant by the driving force for a reaction? Give some examples of driving forces that make reactants tend to form products. Write a balanced chemical equation illustrating each type of driving...
See AnswerQ: Explain to your friend what chemists mean by a precipitation reaction.
Explain to your friend what chemists mean by a precipitation reaction. What is the driving force in a precipitation reaction? Using the information provided about solubility in these chapters, write b...
See AnswerQ: Define the term strong electrolyte. What types of substances tend to
Define the term strong electrolyte. What types of substances tend to be strong electrolytes? What does a solution of a strong electrolyte contain? Give a way to determine if a substance is a strong el...
See AnswerQ: Summarize the simple solubility rules for ionic compounds. How do we
Summarize the simple solubility rules for ionic compounds. How do we use these rules in determining the identity of the solid formed in a precipitation reaction? Give examples including balanced compl...
See AnswerQ: In general terms, what are the spectator ions in a precipitation
In general terms, what are the spectator ions in a precipitation reaction? Why are the spectator ions not included in writing the net ionic equation for a precipitation reaction? Does this mean that t...
See AnswerQ: a. Given that 100. mL of ethyl alcohol weighs 78
a. Given that 100. mL of ethyl alcohol weighs 78.5 g, calculate the density of ethyl alcohol. b. What volume would 1.59 kg of ethyl alcohol occupy? c. What is the mass of 1.35 L of ethyl alcohol? d...
See AnswerQ: Describe some physical and chemical properties of acids and bases. What
Describe some physical and chemical properties of acids and bases. What is meant by a strong acid or base? Are strong acids and bases also strong electrolytes? Give several examples of strong acids an...
See AnswerQ: What is a salt? How are salts formed by acid–
What is a salt? How are salts formed by acid–base reactions? Write chemical equations showing the formation of three different salts. What other product is formed when an aqueous acid reacts with an a...
See AnswerQ: What do we call reactions in which electrons are transferred between atoms
What do we call reactions in which electrons are transferred between atoms or ions? What do we call a loss of electrons by an atom or ion? What is it called when an atom or ion gains electrons? Can we...
See AnswerQ: What is a combustion reaction? Are combustion reactions a unique type
What is a combustion reaction? Are combustion reactions a unique type of reaction, or are they a special case of a more general type of reaction? Write an equation that illustrates a combustion reacti...
See AnswerQ: Give an example of a synthesis reaction and of a decomposition reaction
Give an example of a synthesis reaction and of a decomposition reaction. Are synthesis and decomposition reactions always also oxidation–reduction reactions? Explain.
See AnswerQ: List and define all the ways of classifying chemical reactions that have
List and define all the ways of classifying chemical reactions that have been discussed in the text. Give a balanced chemical equation as an example of each type of reaction, and show clearly how your...
See AnswerQ: Balance each of the following chemical equations. a. Na2SO4
Balance each of the following chemical equations. a. Na2SO4(aq) + BaCl2(aq) BaSO4(s) + NaCl(aq) b. Zn(s) + H2O(g) ZnO(s) + H2(g) c. NaOH(aq) + H3PO4(aq)...
See AnswerQ: The reagent shelf in a general chemistry lab contains aqueous solutions of
The reagent shelf in a general chemistry lab contains aqueous solutions of the following substances: silver nitrate, sodium chloride, acetic acid, nitric acid, sulfuric acid, potassium chromate, bariu...
See AnswerQ: Balance each equation. Which equations can be classified as oxidation–
Balance each equation. Which equations can be classified as oxidation–reduction reactions? a. FeO(s) + HNO3(aq) Fe(NO3)2(aq) + H2O(l) b. Mg(s) + CO2(g) + O2(g) MgCO3(s)...
See AnswerQ: Give balanced equations for two examples of each of the following types
Give balanced equations for two examples of each of the following types of reactions. a. precipitation b. single-displacement c. combustion d. synthesis e. oxidation – reduction f. decomposition...
See AnswerQ: What is meant by denaturation of a protein? Give three examples
What is meant by denaturation of a protein? Give three examples of situations in which proteins are denatured.
See AnswerQ: Write the balanced net ionic equation for the reaction that takes place
Write the balanced net ionic equation for the reaction that takes place when aqueous solutions of the following solutes are mixed. If no reaction is likely, explain why no reaction would be expected f...
See AnswerQ: Complete and balance the following equations. a. Pb(
Complete and balance the following equations. a. Pb(NO3)2(aq) + Na2S(aq) / b. AgNO3(aq) + HCl(aq) / c. 2Mg(s) + O2(g) / d. H2SO4(aq) + 2KOH(aq) / e. BaCl2(aq) + H2SO4(aq) / f. Mg(s) + H2SO4(aq) / g...
See AnswerQ: is the study of the chemistry of living systems.
is the study of the chemistry of living systems.
See AnswerQ: What are trace elements, and why are such elements important to
What are trace elements, and why are such elements important to the body’s health?
See AnswerQ: What are proteins? Are proteins polymers? Explain. What molar
What are proteins? Are proteins polymers? Explain. What molar mass ranges are shown by proteins? What fraction of our bodies is made up of proteins?
See AnswerQ: What is an element? Which elements are most abundant on the
What is an element? Which elements are most abundant on the earth? Which elements are most abundant in the human body?
See AnswerQ: Without consulting any reference, write the name and symbol for as
Without consulting any reference, write the name and symbol for as many elements as you can. How many could you name? How many symbols did you write correctly?
See AnswerQ: The symbols for the elements silver (Ag), gold (Au
The symbols for the elements silver (Ag), gold (Au), and tungsten (W) seem to bear no relation to their English names. Explain and give three additional examples.
See AnswerQ: Nonpolar side chains in a-amino acids tend to be ,
Nonpolar side chains in a-amino acids tend to be , whereas polar side chains are most often in an aqueous medium.
See AnswerQ: Given the structures of the amino acids in Fig. 21.
Given the structures of the amino acids in Fig. 21.2, choose two amino acids that you would expect to have hydrophobic side chains and two amino acids that you would expect to have hydrophilic side ch...
See AnswerQ: Perhaps the most important concept in introductory chemistry concerns what a mole
Perhaps the most important concept in introductory chemistry concerns what a mole of a substance represents. The mole concept will come up again and again in later chapters in this book. What does one...
See AnswerQ: Many college students would not choose to take a chemistry course if
Many college students would not choose to take a chemistry course if it were not required for their major. Do you have a better appreciation of why chemistry is a required course for your own particul...
See AnswerQ: Given the structures of the amino acids alanine and serine as shown
Given the structures of the amino acids alanine and serine as shown in Fig. 21.2, draw structures for each of the two dipeptides that these amino acids might form. From figure 21.2
See AnswerQ: How many unique amino acid sequences are possible for a tripeptide containing
How many unique amino acid sequences are possible for a tripeptide containing only the amino acids gly, ala, and cys, with each amino acid occurring only once in each molecule?
See AnswerQ: What is a peptide linkage? Choose two amino acids from Fig
What is a peptide linkage? Choose two amino acids from Fig. 21.2 and draw structures for the two dipeptides those amino acids are capable of forming, circling the peptide linkage in each. From figure...
See AnswerQ: What does the primary structure of a protein rep resent? How
What does the primary structure of a protein rep resent? How are the individual units that make up the overall primary structure of a protein held together?
See AnswerQ: In general terms, what does the secondary structure of a protein
In general terms, what does the secondary structure of a protein represent?
See AnswerQ: Consider the neutron, the proton, and the electron.
Consider the neutron, the proton, and the electron. a. Which is(are) found in the nucleus? b. Which has the largest relative mass? c. Which has the smallest relative mass? d. Which is negatively c...
See AnswerQ: Describe the secondary structure of the protein collagen.
Describe the secondary structure of the protein collagen.
See AnswerQ: Silk consists of a(n) structure in which the individual
Silk consists of a(n) structure in which the individual chains of amino acids are lined up lengthwise next to each other.
See AnswerQ: Complete the following table by giving the symbol, name, atomic
Complete the following table by giving the symbol, name, atomic number, and/or group(family) number as required.
See AnswerQ: An S-S bond between two cysteine amino acids on a
An S-S bond between two cysteine amino acids on a protein is called a(n) . This bond stabilizes the tertiary structure of many proteins.
See AnswerQ: In Chapter 2 of this text, you were introduced to the
In Chapter 2 of this text, you were introduced to the International System (SI) of measurements. What are the basic units of this system for mass, distance, time, and temperature? What are some of the...
See AnswerQ: Which of the following represent physical properties or changes, and which
Which of the following represent physical properties or changes, and which represent chemical properties or changes? a. You curl your hair with a curling iron. b. You curl your hair by getting a “pe...
See AnswerQ: What protein is responsible for the transport of oxygen through the bloodstream
What protein is responsible for the transport of oxygen through the bloodstream?
See AnswerQ: What name is given to proteins that catalyze biochemical reactions in the
What name is given to proteins that catalyze biochemical reactions in the cell?
See AnswerQ: What is the name of the protein found in all cells that
What is the name of the protein found in all cells that extracts energy from food molecules by transferring electrons in a series of oxidation–reduction reactions??
See AnswerQ: How are proteins able to act as buffering agents in the blood
How are proteins able to act as buffering agents in the blood and tissues?
See AnswerQ: How does the efficiency of an enzyme compare with that of inorganic
How does the efficiency of an enzyme compare with that of inorganic catalysts? Are enzymes more or less efficient?
See AnswerQ: Write the formula for each of the following binary ionic compounds.
Write the formula for each of the following binary ionic compounds. a. copper(I) iodide b. cobaltous chloride c. silver sulfide d. mercurous bromide e. mercuric oxide f. chromium(III) sulfide g....
See AnswerQ: What name is given to the specific portion of the enzyme molecule
What name is given to the specific portion of the enzyme molecule where catalysis actually occurs?
See AnswerQ: Calculate the percent by mass of the element whose symbol occurs first
Calculate the percent by mass of the element whose symbol occurs first in the following compounds’ formulas. a. C6H6(l) b. Na2SO4(s) c. CS2(l) d. AlCl3(s) e. Cu2O(s) f. CuO(s) g. Co2O3(s) h....
See AnswerQ: Most people think of science as being a specific, exact discipline
Most people think of science as being a specific, exact discipline, with a “correct” answer for every problem. Yet you were introduced to the concept of uncertainty in scientific measurements. What is...
See AnswerQ: Consider the reaction as represented by the following unbalanced chemical equation:
Consider the reaction as represented by the following unbalanced chemical equation: 2H2(g) + O2(g) ( 2H2O(g) You react 15.0 g of hydrogen gas with 100.0 g of oxygen gas. Determine the amount of re...
See AnswerQ: Many of the most important carbohydrates are , which are large molecules
Many of the most important carbohydrates are , which are large molecules constructed by hooking together many smaller molecules.
See AnswerQ: Sketch the ring structures of glucose and fructose. Based on the
Sketch the ring structures of glucose and fructose. Based on the electron pairs surrounding the atoms of the rings, would you expect these rings to be planar (flat)?
See AnswerQ: What is a hexose sugar? Sketch the straight-chain representation
What is a hexose sugar? Sketch the straight-chain representation of the hexose galactose.
See AnswerQ: What is a disaccharide? What monosaccharide units make up the disaccharide
What is a disaccharide? What monosaccharide units make up the disaccharide sucrose? What is the bond called that forms between the monosaccharide units?
See AnswerQ: Give the name of each of the following compounds. a
Give the name of each of the following compounds. a. XeO2 b. ICl5 c. PCl3 d. CO e. OF2 f. P2O5 g. AsI3 h. SO3
See AnswerQ: Sketch a representation of the disaccharide sucrose (table sugar). Label
Sketch a representation of the disaccharide sucrose (table sugar). Label clearly the portion of the disaccharide that originates from glucose, the portion that originates from fructose, and the glycos...
See AnswerQ: In addition to using numerical prefixes in the general names of sugars
In addition to using numerical prefixes in the general names of sugars to indicate how many carbon atoms are present, we often use the prefixes keto- and aldo- to indicate whether the sugar is a keton...
See AnswerQ: carries the information needed for the synthesis of the various proteins
carries the information needed for the synthesis of the various proteins the cell requires to carry out its life functions.
See AnswerQ: RNA molecules, which are found in the cytoplasm outside the cell
RNA molecules, which are found in the cytoplasm outside the cell nucleus, are much (smaller/larger) than DNA polymers.
See AnswerQ: For each of the following, make the indicated conversion.
For each of the following, make the indicated conversion. a. 4,861,903 to standard scientific notation b. 3.8136 * 102 to ordinary decimal notation c. 5.1 * 10-3 to ordinary decimal notation d. 0....
See AnswerQ: DNA nucleotides contain the pentose , whereas RNA nucleotides contain the pentose
DNA nucleotides contain the pentose , whereas RNA nucleotides contain the pentose .
See AnswerQ: Name the five nitrogen bases found in DNA and RNA. Which
Name the five nitrogen bases found in DNA and RNA. Which base is found commonly in RNA but not in DNA? Which base is found commonly in DNA but not in RNA?
See AnswerQ: Write formulas for each of the following compounds. a.
Write formulas for each of the following compounds. a. mercuric chloride b. iron(III) oxide c. sulfurous acid d. calcium hydride e. potassium nitrate f. aluminum fluoride g. dinitrogen monoxide...
See AnswerQ: A traditional analysis for samples containing calcium ion was to precipitate the
A traditional analysis for samples containing calcium ion was to precipitate the calcium ion with sodium oxalate (Na2C2O4) solution and then to collect and weigh either the calcium oxalate itself or t...
See AnswerQ: Lipids are a group of substances defined in terms of their characteristics
Lipids are a group of substances defined in terms of their characteristics.
See AnswerQ: What are the four classes of lipids? Give an example of
What are the four classes of lipids? Give an example of a member of each class.
See AnswerQ: Sketch the general structure of a triglyceride. What are the components
Sketch the general structure of a triglyceride. What are the components that go into making up a typical triglyceride?
See AnswerQ: Which of the following statements is correct and provides the best explanation
Which of the following statements is correct and provides the best explanation when removing the first two electrons from calcium? a. Energy is released when either electron comes off because calcium...
See AnswerQ: Methane, CH4, is the major component of natural gas.
Methane, CH4, is the major component of natural gas. Methane burns in air, releasing approximately 890 kJ of heat energy per mole. CH4(g) + 2O2(g) CO2(g) + 2H2O(g) a. What quantity o...
See AnswerQ: Chapter 2 introduced the Kelvin and Celsius temperature scales and related them
Chapter 2 introduced the Kelvin and Celsius temperature scales and related them to the Fahrenheit temperature scale commonly used in the United States. a. How is the size of the temperature unit (deg...
See AnswerQ: Which are the valence electrons in an atom? Choose three elements
Which are the valence electrons in an atom? Choose three elements and write their electron configurations, circling the valence electrons in the configurations. Why are the valence electrons more impo...
See AnswerQ: Write the electron configuration for the following atoms, using the appropriate
Write the electron configuration for the following atoms, using the appropriate noble gas to abbreviate the configuration of the core electrons. a. Sr, Z = 38 b. Al, Z = 13 c. Cl, Z = 17 d. K, Z =...
See AnswerQ: What is a steroid? What basic ring structure is common to
What is a steroid? What basic ring structure is common to all steroids? Sketch an example of a steroid found in the body, and highlight the basic ring structure that makes the molecule a steroid.
See AnswerQ: What types of hormones are synthesized in the adrenal glands and are
What types of hormones are synthesized in the adrenal glands and are involved in various regulatory functions in the body? Provide an example of this type of hormone.
See AnswerQ: Choose 10 species that might be expected to behave as Brønsted–
Choose 10 species that might be expected to behave as Brønsted–Lowry acids or bases in aqueous solution. For each of your choices, (a) write an equation demonstrating how the species behaves as an ac...
See AnswerQ: What are bile acids, and from what are they synthesized by
What are bile acids, and from what are they synthesized by the body? What is the most common bile acid, and what function does it serve?
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: Using the ions indicated in Problem 24, write the formulas and
Using the ions indicated in Problem 24, write the formulas and give the names for all possible simple ionic compounds involving these ions. From problem 24: a. Mg2+ b. Fe2+ c. Fe3+ d. F- e. Ni2+...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: Describe enzyme catalysis as a series of steps, with E symbolizing
Describe enzyme catalysis as a series of steps, with E symbolizing the enzyme and S symbolizing the substrate.
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: a. Write the conjugate acid for each of the following Brønsted
a. Write the conjugate acid for each of the following Brønsted– Lowry bases. NO3-, HSO4-, ClO4-, NH3, HCO3- b. Write the conjugate base for each of the following Brønsted– Lowry acids. HCl, H2SO4, N...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: For Exercises 55–76 choose one of the following terms to
For Exercises 55–76 choose one of the following terms to match the description given. a. aldohexose b. antibody c. cellulose d. CH2O e. cysteine f. denaturation g. disaccharides h. disulfide...
See AnswerQ: The substance in the nucleus of the cell that stores and transmits
The substance in the nucleus of the cell that stores and transmits genetic information is DNA, which stands for .
See AnswerQ: RNA molecules have molar masses in the range of 20,000
RNA molecules have molar masses in the range of 20,000 to 40,000 g/mol. How does this molar-mass range compare to the molar mass of DNA?
See AnswerQ: Which of the following formula–name pairs are incorrect? Explain
Which of the following formula–name pairs are incorrect? Explain why for each case. a. Ag(NO3)2 silver nitrate b. Fe2Cl ferrous chloride c. NaH2PO4 sodium hydrogen phosphate d. NH4S ammonium sulfi...
See AnswerQ: The pentose deoxyribose is found in DNA, whereas is found in
The pentose deoxyribose is found in DNA, whereas is found in RNA.
See AnswerQ: The basic linkage in DNA or RNA between the sugar molecule and
The basic linkage in DNA or RNA between the sugar molecule and phosphoric acid is a phosphate linkage.
See AnswerQ: The bases on opposite strands of DNA are said to be to
The bases on opposite strands of DNA are said to be to each other, which means the bases fit together specifically by hydrogen bonding to one another.
See AnswerQ: In a strand of normal DNA, the base is always found
In a strand of normal DNA, the base is always found paired with the base adenine, whereas is always found paired with cytosine.
See AnswerQ: A given segment of the DNA molecule, which contains the molecular
A given segment of the DNA molecule, which contains the molecular coding for a specific protein to be synthesized, is referred to as a .
See AnswerQ: During protein synthesis, RNA molecules attach to and transport specific amino
During protein synthesis, RNA molecules attach to and transport specific amino acids to the appropriate position on the pattern provided by RNA mole...
See AnswerQ: The codes specified by are responsible for assembling the correct primary structure
The codes specified by are responsible for assembling the correct primary structure of proteins.
See AnswerQ: Write the amino acid sequences possible for a tripeptide containing the amino
Write the amino acid sequences possible for a tripeptide containing the amino acids cys, ala, and phe, with each amino acid being used only once in each tripeptide.
See AnswerQ: are esters of the polyhydroxyalcohol glycerol with long-chain carboxylic
are esters of the polyhydroxyalcohol glycerol with long-chain carboxylic acids.
See AnswerQ: Vegetable oils tend to contain fatty acids, whereas animal fats tend
Vegetable oils tend to contain fatty acids, whereas animal fats tend to be .
See AnswerQ: Describe the lock-and-key model for enzymes. Why
Describe the lock-and-key model for enzymes. Why are the shapes of the enzyme and its substrate important in this model? What does it mean to say that an enzyme is inhibited by a particular molecule?...
See AnswerQ: The process of involves treating a fat with sodium hydroxide so that
The process of involves treating a fat with sodium hydroxide so that the fatty acids present are converted to their sodium salts.
See AnswerQ: Fatty acid anions make good soaps because they have both a portion
Fatty acid anions make good soaps because they have both a portion that is miscible with water and a portion that is miscible with grease.
See AnswerQ: The aggregations of fatty acid anions that form when a soap is
The aggregations of fatty acid anions that form when a soap is added to water are called .
See AnswerQ: Cholesterol, adrenocorticoid hormones, sex hormones, and bile acids make
Cholesterol, adrenocorticoid hormones, sex hormones, and bile acids make up what class of lipids?
See AnswerQ: The starting material in the body for the synthesis of other steroids
The starting material in the body for the synthesis of other steroids is .
See AnswerQ: Referring to Fig. 21.25, what is a common
Referring to Fig. 21.25, what is a common characteristic among the structures of steroids? From figure 21.25:
See AnswerQ: Cholic acid and other bile acids act as agents during digestion,
Cholic acid and other bile acids act as agents during digestion, helping to break fats up into smaller droplets that can then be acted on by enzymes.
See AnswerQ: Describe the secondary protein structure known as the a-helix.
Describe the secondary protein structure known as the a-helix. What types of proteins have this secondary structure?
See AnswerQ: How many possible primary structures exist for a small polypeptide containing four
How many possible primary structures exist for a small polypeptide containing four individual amino acids?
See AnswerQ: List three structural uses of proteins in the body.
List three structural uses of proteins in the body.
See AnswerQ: Sketch the straight-chain representations of the aldehyde sugar glucose and
Sketch the straight-chain representations of the aldehyde sugar glucose and of the ketone sugar fructose. Circle the aldehyde or ketone functional group in your structures.
See AnswerQ: What specific protein carries oxygen from the lungs to other body tissues
What specific protein carries oxygen from the lungs to other body tissues?
See AnswerQ: Describe the structure of the protein collagen. What function does collagen
Describe the structure of the protein collagen. What function does collagen have in the body?
See AnswerQ: What is meant by inhibition of an enzyme? What happens when
What is meant by inhibition of an enzyme? What happens when an enzyme is irreversibly inhibited?
See AnswerQ: What general name is given to sugars containing five carbon atoms?
What general name is given to sugars containing five carbon atoms? six carbon atoms? three carbon atoms?
See AnswerQ: Although both starch and cellulose are polymers of glucose, starch is
Although both starch and cellulose are polymers of glucose, starch is digestible by humans and cellulose is not. How do the structures of these polysaccharides differ, resulting in their different dig...
See AnswerQ: Identify the Brønsted–Lowry conjugate acid–base pairs in each
Identify the Brønsted–Lowry conjugate acid–base pairs in each of the following. a. NH3(aq) + H2O( l ) ⇌ NH4+(aq) + OH-(aq) b. H2SO4(aq) + H2O( l ) ⇌ HSO4-(aq) + H3O+(aq) c. O2-(s) + H2O( l ) ⇌...
See AnswerQ: Describe the structure of a wax. Where do waxes occur naturally
Describe the structure of a wax. Where do waxes occur naturally in living creatures, and what function do they serve?
See AnswerQ: What is a phospholipid? How does the structure of a phospholipid
What is a phospholipid? How does the structure of a phospholipid differ from that of a triglyceride? What is the function of the phospholipid lecithin?
See AnswerQ: Write the equilibrium constant expression for each of the following reactions.
Write the equilibrium constant expression for each of the following reactions. a. 4NO( g) ⇌ 2N2O( g) + O2( g) b. 4PF3( g) ⇌ P4(s) + 6F2( g) c. CO( g) + 3H2( g) ⇌ CH4( g) + H2O( g) d. 2BrF5( g) ⇌...
See AnswerQ: Suppose that for the following reaction Br2( g) + Cl2
Suppose that for the following reaction Br2( g) + Cl2( g) ⇌ 2BrCl( g) it is determined that, at a particular temperature, the equilibrium concentrations are as follows: [Br2( g)] = 7.2 * 10-8 M, [Cl2...
See AnswerQ: You have learned the basic way in which scientists analyze problems,
You have learned the basic way in which scientists analyze problems, propose models to explain the systems under consideration, and then experiment to test their models. Suppose you have a sample of a...
See AnswerQ: Without consulting your textbook or notes, state as many points as
Without consulting your textbook or notes, state as many points as you can of Dalton’s atomic theory. Explain in your own words each point of the theory.
See AnswerQ: Write expressions for Ksp for each of the following sparingly soluble substances
Write expressions for Ksp for each of the following sparingly soluble substances. a. Cu(OH)2(s) b. Co2S3(s) c. Hg2(OH)2(s) d. CaCO3(s) e. Ag2CrO4(s) f. Hg(OH)2(s)
See AnswerQ: What happens to a gas sample when it is collected by displacement
What happens to a gas sample when it is collected by displacement of, or by bubbling through, water? How is this taken into account when calculating the pressure of the gas?
See AnswerQ: The concentration of a solution may be expressed in various ways.
The concentration of a solution may be expressed in various ways. Suppose 5.00 g of NaCl were dissolved in 15.0 g of water, which resulted in 16.1 mL of solution after mixing. Explain how you would ca...
See AnswerQ: a. If the pressure on a 125-mL sample of
a. If the pressure on a 125-mL sample of gas is increased from 755 mm Hg to 899 mm Hg at constant temperature, what will the volume of the sample become? b. If a sample of gas is compressed from an i...
See AnswerQ: a. If the temperature of a 255-mL sample of
a. If the temperature of a 255-mL sample of gas is increased from 35 °C to 55 °C at constant pressure, what will be the new volume of the gas sample? b. If a 325-mL sample of gas at 25 °C is immersed...
See AnswerQ: When calcium carbonate is heated strongly, it evolves carbon dioxide gas
When calcium carbonate is heated strongly, it evolves carbon dioxide gas. CaCO3(s) CaO(s) + CO2(g) If 1.25 g of CaCO3 is heated, what mass of CO2 would be produced? What volume would...
See AnswerQ: If an electric current is passed through molten sodium chloride, elemental
If an electric current is passed through molten sodium chloride, elemental chlorine gas is generated as the sodium chloride is decomposed. 2NaCl(l) 2Na(s) + Cl2(g) What volume of chlorin...
See AnswerQ: Calculate the indicated quantity for each solution. a. The
Calculate the indicated quantity for each solution. a. The percent by mass of solute when 2.05 g of NaCl is dissolved in 19.2 g of water. b. The mass of solute contained in 26.2 g of 10.5% CaCl2 sol...
See AnswerQ: Calculate the indicated quantity for each solution. a. The
Calculate the indicated quantity for each solution. a. The mass of solute present in 235 mL of 0.251 M NaOH solution. b. The molarity of the solution when 0.293 mole of KNO3 is dissolved in water to...
See AnswerQ: Calculate the molarities of the solutions resulting when the indicated dilutions are
Calculate the molarities of the solutions resulting when the indicated dilutions are made. Assume that the volumes are additive. a. 25 mL of water is added to 12.5 mL of 1.515 M NaOH solution. b. 75...
See AnswerQ: What is a compound? What is meant by the law of
What is a compound? What is meant by the law of constant composition for compounds and why is this law so important to our study of chemistry?
See AnswerQ: The element carbon undergoes many inorganic reactions, as well as being
The element carbon undergoes many inorganic reactions, as well as being the basis for the field of organic chemistry. Write balanced chemical equations for the reactions of carbon described below. a....
See AnswerQ: The common strong acids are HCl, HNO3, and H2SO4,
The common strong acids are HCl, HNO3, and H2SO4, whereas NaOH and KOH are the common strong bases. Write the neutralization reaction equations for each of these strong acids with each of these strong...
See AnswerQ: Consider the oxidation–reduction reaction 2Na + F2 2NaF. Why
Consider the oxidation–reduction reaction 2Na + F2 2NaF. Why is this chemical equation also classified as a synthesis reaction?
See AnswerQ: What is meant by a nuclear atom? Describe the points of
What is meant by a nuclear atom? Describe the points of Rutherford’s model for the nuclear atom and how he tested this model. Based on his experiments, how did Rutherford envision the structure of the...
See AnswerQ: What are isotopes? To what do the atomic number and the
What are isotopes? To what do the atomic number and the mass number of an isotope refer? How are specific isotopes indicated symbolically (give an example and explain)? Do the isotopes of a given elem...
See AnswerQ: Starch and cellulose both are polymers of glucose that are synthesized by
Starch and cellulose both are polymers of glucose that are synthesized by plants. What do plants use starch for? What do they use cellulose for? Why is starch digestible by humans, but cellulose is no...
See AnswerQ: Are most elements found in nature in the elemental or the combined
Are most elements found in nature in the elemental or the combined form? Why? Name several elements that are usually found in the elemental form.
See AnswerQ: What are ions? How are ions formed from atoms? Do
What are ions? How are ions formed from atoms? Do isolated atoms form ions spontaneously? To what do the terms cation and anion refer? In terms of subatomic particles, how is an ion related to the ato...
See AnswerQ: What are some general physical properties of ionic compounds such as sodium
What are some general physical properties of ionic compounds such as sodium chloride? How do we know that substances such as sodium chloride consist of positively and negatively charged particles? If...
See AnswerQ: What principle do we use in writing the formula of an ionic
What principle do we use in writing the formula of an ionic compound such as NaCl or MgI2? How do we know that two iodide ions are needed for each magnesium ion, whereas only one chloride ion is neede...
See AnswerQ: When writing the name of an ionic compound, which is named
When writing the name of an ionic compound, which is named first, the anion or the cation? Give an example. What ending is added to the root name of an element to show that it is a simple anion in a T...
See AnswerQ: What general functions do fibrous and globular proteins have in the body
What general functions do fibrous and globular proteins have in the body?
See AnswerQ: Describe the system used to name Type III binary compounds (compounds
Describe the system used to name Type III binary compounds (compounds of nonmetallic elements). Give several examples illustrating the method. How does this system differ from that used for ionic comp...
See AnswerQ: Describe the double-helical structure of DNA. What type of
Describe the double-helical structure of DNA. What type of bonding occurs within the chain of each strand of the double helix? What type of bonding exists between strands to link them together?
See AnswerQ: The text states that the key to DNA’s functioning is its doublehelical
The text states that the key to DNA’s functioning is its doublehelical structure with complementary bases on the two strands. Explain, with particular reference to how DNA is replicated.
See AnswerQ: What is a polyatomic ion? Without consulting a reference, list
What is a polyatomic ion? Without consulting a reference, list the formulas and names of at least ten polyatomic ions. When writing the overall formula of an ionic compound involving polyatomic ions,...
See AnswerQ: What is an oxyanion? What special system is used in a
What is an oxyanion? What special system is used in a series of related oxyanions that indicates the relative number of oxygen atoms in each ion? Give examples.
See AnswerQ: What is an acid? How are acids that do not contain
What is an acid? How are acids that do not contain oxygen named? Give several examples. Describe the naming system for the oxyacids. Give examples of a series of oxyacids illustrating this system.
See AnswerQ: Complete the following table by giving the symbol, name, atomic
Complete the following table by giving the symbol, name, atomic number, and/or group (family) number as required.
See AnswerQ: Referring to Table 21.5, give an example of a
Referring to Table 21.5, give an example of a saturated and an unsaturated fatty acid. Are triglycerides from animal sources generally saturated or unsaturated? Are triglycerides from plant sources ge...
See AnswerQ: Using the general formula for a triglyceride, write an equation showing
Using the general formula for a triglyceride, write an equation showing the process of saponification. What is a soap?
See AnswerQ: Describe the mechanism by which a soap is able to remove greasy
Describe the mechanism by which a soap is able to remove greasy dirt from clothing.
See AnswerQ: Consider the 20 most common amino acids shown in Fig. 21
Consider the 20 most common amino acids shown in Fig. 21.2. Although you may not be asked to memorize all these structures, it will help your study if you are familiar with them. Choose any five of th...
See AnswerQ: What is a micelle? How do the micelles formed by soap
What is a micelle? How do the micelles formed by soap molecules suspend greasy dirt in a solution?
See AnswerQ: Your text indicates that the Group 1, Group 2, Group
Your text indicates that the Group 1, Group 2, Group 7, and Group 8 elements all have “family” names (alkali metals, alkaline earth metals, halogens, and noble gases, respectively). Without looking at...
See AnswerQ: Using the periodic table shown in Fig. 4.9,
Using the periodic table shown in Fig. 4.9, for each of the following symbols, write the name of the element and its atomic number. a. Mg b. Ga c. Sn d. Sb e. Sr f. Si g. Cs h. Ca i. Cr j....
See AnswerQ: Give the names of several steroid sex hormones, and indicate their
Give the names of several steroid sex hormones, and indicate their functions in the body.
See AnswerQ: How many electrons, protons, and neutrons are found in isolated
How many electrons, protons, and neutrons are found in isolated atoms having the following atomic symbols? a. 8 17
See AnswerQ: What simple ion does each of the following elements most commonly form
What simple ion does each of the following elements most commonly form? a. Sr b. I c. Ag d. Al e. Se f. O g. Rb h. N i. K j. Mg k. S l. P m. Cl
See AnswerQ: For each of the following simple ions, indicate the number of
For each of the following simple ions, indicate the number of protons and electrons the ion contains. a. Mg2+ b. Fe2+ c. Fe3+ d. F- e. Ni2+ f. Zn2+ g. Co3+ h. N3- i. S2- j. Rb+ k. Se2- l....
See AnswerQ: Give the name of each of the following polyatomic ions.
Give the name of each of the following polyatomic ions. a. CO32- b. MnO4- c. NO3- d. HSO4- e. C2H3O2- f. CrO42- g. OH- h. ClO2- i. HCO3- j. HPO42-
See AnswerQ: Using the negative polyatomic ions listed in Table 5.4,
Using the negative polyatomic ions listed in Table 5.4, write formulas for each of their sodium and calcium compounds. From table 5.4:
See AnswerQ: How do we know that 16.00 g of oxygen contains
How do we know that 16.00 g of oxygen contains the same number of atoms as does 12.01 g of carbon, and that 22.99 g of sodium contains the same number of atoms as each of these? How do we know that 10...
See AnswerQ: Consider the amino acids alanine, cysteine, and asparagine. Which
Consider the amino acids alanine, cysteine, and asparagine. Which of these contain polar side chains? Why?
See AnswerQ: Define molar mass. Using H3PO4 as an example, calculate the
Define molar mass. Using H3PO4 as an example, calculate the molar mass from the atomic masses of the elements.
See AnswerQ: What is meant by the percent composition by mass for a compound
What is meant by the percent composition by mass for a compound? Describe in general terms how this information is obtained by experiment for new compounds. How can this information be calculated for...
See AnswerQ: Define, compare, and contrast what are meant by the empirical
Define, compare, and contrast what are meant by the empirical and molecular formulas for a substance. What does each of these formulas tell us about a compound? What information must be known for a co...
See AnswerQ: When chemistry teachers prepare an exam question on determining the empirical formula
When chemistry teachers prepare an exam question on determining the empirical formula of a compound, they usually take a known compound and calculate the percent composition of the compound from the f...
See AnswerQ: Rather than giving students straight percent composition data for determining the empirical
Rather than giving students straight percent composition data for determining the empirical formula of a compound (see Question 7), sometimes chemistry teachers will try to emphasize the experimental...
See AnswerQ: Balanced chemical equations give us information in terms of individual molecules reacting
Balanced chemical equations give us information in terms of individual molecules reacting in the proportions indicated by the coefficients, and also in terms of macroscopic amounts (that is, moles). W...
See AnswerQ: Consider the unbalanced equation for the combustion of propane: C3H8
Consider the unbalanced equation for the combustion of propane: C3H8(g) + O2(g) / CO2(g) + H2O(g) First, balance the equation. Then, for a given amount of propane, write the mole ratios that would e...
See AnswerQ: In the practice of chemistry one of the most important calculations concerns
In the practice of chemistry one of the most important calculations concerns the masses of products expected when particular masses of reactants are used in an experiment. For example, chemists judge...
See AnswerQ: What is meant by a limiting reactant in a particular reaction?
What is meant by a limiting reactant in a particular reaction? In what way is the reaction “limited”? What does it mean to say that one or more of the reactants are present in excess? What happens to...
See AnswerQ: For a balanced chemical equation of your choice, and using 25
For a balanced chemical equation of your choice, and using 25.0 g of each of the reactants in your equation, illustrate and explain how you would determine which reactant is the limiting reactant. Ind...
See AnswerQ: After studying a few chapters of this text, and perhaps having
After studying a few chapters of this text, and perhaps having done a few lab experiments and taken a few quizzes in chemistry, you are probably sick of hearing the term significant figures. Most chem...
See AnswerQ: What do we mean by the theoretical yield for a reaction?
What do we mean by the theoretical yield for a reaction? What is meant by the actual yield? Why might the actual yield for an experiment be less than the theoretical yield? Can the actual yield be mor...
See AnswerQ: Consider 2.45-g samples of each of the following
Consider 2.45-g samples of each of the following elements or compounds. Calculate the number of moles of the element or compound present in each sample. a. Fe2O3(s) b. P4(s) c. Cl2(g) d. Hg2O(s)...
See AnswerQ: A compound was analyzed and was found to have the following percent
A compound was analyzed and was found to have the following percent composition by mass: sodium, 43.38%; carbon, 11.33%; oxygen, 45.29%. Determine the empirical formula of the compound.
See AnswerQ: For each of the following balanced equations, calculate how many grams
For each of the following balanced equations, calculate how many grams of each product would form if 12.5 g of the reactant listed first in the equation reacts completely (there is an excess of the se...
See AnswerQ: Solid calcium carbide (CaC2) reacts with liquid water to produce
Solid calcium carbide (CaC2) reacts with liquid water to produce acetylene gas (C2H2) and aqueous calcium hydroxide. a. Write the balanced equation for the reaction that is occurring, including all p...
See AnswerQ: What is potential energy? What is kinetic energy? What do
What is potential energy? What is kinetic energy? What do we mean by the law of conservation of energy? What do scientists mean by work? Explain what scientists mean by a state function and give an ex...
See AnswerQ: What does temperature measure? Are the molecules in a beaker of
What does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain. What is heat? Is heat the same as temperature?...
See AnswerQ: When describing a reaction, a chemist might refer to the system
When describing a reaction, a chemist might refer to the system and the surroundings. Explain each of these terms. If a reaction is endothermic, does heat travel from the surroundings into the system,...
See AnswerQ: What is the study of energy and energy changes called? What
What is the study of energy and energy changes called? What is the “first law” of thermodynamics and what does it mean? What do scientists mean by the internal energy of a system? Is the internal ener...
See AnswerQ: How is the calorie defined? Is the thermodynamic calorie the same
How is the calorie defined? Is the thermodynamic calorie the same as the Calorie we are careful of when planning our diets? Although the calorie is our “working unit” of energy (based on its experimen...
See AnswerQ: This chemistry course may have been the first time you have encountered
This chemistry course may have been the first time you have encountered the method of dimensional analysis in problem solving. Explain the terms conversion factor and equivalence statement. Give an ev...
See AnswerQ: What is the enthalpy change for a process? Is enthalpy a
What is the enthalpy change for a process? Is enthalpy a state function? In what experimental apparatus are enthalpy changes measured?
See AnswerQ: Hess’s law is often confusing to students. Imagine you are talking
Hess’s law is often confusing to students. Imagine you are talking to a friend who has not taken any science courses. Using the reactions P4(s) + 6Cl2(g) / 4PCl3(g) (H = 22.44 * 103 kJ 4PCl5(g) / P4...
See AnswerQ: The first law of thermodynamics indicates that the total energy content of
The first law of thermodynamics indicates that the total energy content of the universe is constant. If this is true, why do we worry about “energy conservation”? What do we mean by the quality of ene...
See AnswerQ: What do petroleum and natural gas consist of? Indicate some petroleum
What do petroleum and natural gas consist of? Indicate some petroleum “fractions” and explain what they are used for. What does it mean to “crack” petroleum and why is this done? What was tetraethyl l...
See AnswerQ: What is a driving force? Name two common and important driving
What is a driving force? Name two common and important driving forces, and give an example of each. What is entropy? Although the total energy of the universe is constant, is the entropy of the univer...
See AnswerQ: Suppose we have separate 25-g samples of iron, silver
Suppose we have separate 25-g samples of iron, silver, and gold. If 125 J of heat energy is applied separately to each of the three samples, show by calculation which sample will end up at the highest...
See AnswerQ: What is electromagnetic radiation? Give some examples of such radiation.
What is electromagnetic radiation? Give some examples of such radiation. Explain what the wavelength (λ) and frequency (ν) of electromagnetic radiation represent. Sketch a representation of a wave and...
See AnswerQ: Explain what it means for an atom to be in an excited
Explain what it means for an atom to be in an excited state and what it means for an atom to be in its ground state. How does an excited atom return to its ground state? What is a photon? How is the w...
See AnswerQ: Do atoms in excited states emit radiation randomly, at any wavelength
Do atoms in excited states emit radiation randomly, at any wavelength? Why? What does it mean to say that the hydrogen atom has only certain discrete energy levels available? How do we know this? Why...
See AnswerQ: You have learned about several temperature scales so far in this text
You have learned about several temperature scales so far in this text. Describe the Fahrenheit, Celsius, and Kelvin temperature scales. How are these scales defined? Why were they defined this way? Wh...
See AnswerQ: Schrödinger and de Broglie suggested a “wave–particle duality”
Schrödinger and de Broglie suggested a “wave–particle duality” for small particles—that is, if electromagnetic radiation showed some particle-like properties, then perhaps small particles might exhibi...
See AnswerQ: Describe the general characteristics of the first (lowest-energy)
Describe the general characteristics of the first (lowest-energy) hydrogen atomic orbital. How is this orbital designated symbolically? Does this orbital have a sharp “edge”? Does the orbital represen...
See AnswerQ: Use the wave mechanical picture of the hydrogen atom to describe what
Use the wave mechanical picture of the hydrogen atom to describe what happens when the atom absorbs energy and moves to an “excited” state. What do the principal energy levels and their sublevels repr...
See AnswerQ: Describe the sublevels and orbitals that constitute the third and fourth principal
Describe the sublevels and orbitals that constitute the third and fourth principal energy levels of hydrogen. How is each of the orbitals designated and what are the general shapes of their probabilit...
See AnswerQ: Describe electron spin. How does electron spin affect the total number
Describe electron spin. How does electron spin affect the total number of electrons that can be accommodated in a given orbital? What does the Pauli exclusion principle tell us about electrons and the...
See AnswerQ: Summarize the postulates of the wave mechanical model of the atom.
Summarize the postulates of the wave mechanical model of the atom.
See AnswerQ: List the order in which the orbitals are filled as the atoms
List the order in which the orbitals are filled as the atoms beyond hydrogen are built up. How many electrons overall can be accommodated in the first and second principal energy levels? How many elec...
See AnswerQ: Sketch the overall shape of the periodic table and indicate the general
Sketch the overall shape of the periodic table and indicate the general regions of the table that represent the various s, p, d, and f orbitals being filled. How is an element’s position in the period...
See AnswerQ: Using the general periodic table you developed in Question 25, show
Using the general periodic table you developed in Question 25, show how the valence-electron configuration of most of the elements can be written just by knowing the relative location of the element o...
See AnswerQ: What are the representative elements? In what region(s)
What are the representative elements? In what region(s) of the periodic table are these elements found? In what general area of the periodic table are the metallic elements found? In what general area...
See AnswerQ: Calculate the binding energy per nucleon Eb/A in MeV for
Calculate the binding energy per nucleon Eb/A in MeV for the carbon isotope 6 12
See AnswerQ: The data below is the nitrogen content of soil specimens collected in
The data below is the nitrogen content of soil specimens collected in Black Hawk County, Iowa (Professor M. E. Thompson, Iowa State University). Determine the arithmetic mean and geometric mean soil n...
See AnswerQ: The following dose-response curve plots the central estimate of the
The following dose-response curve plots the central estimate of the adverse (toxic) response from a series of doses. The dose (i.e., body burden) is plotted on a base-10 logarithmic scale (dose units:...
See AnswerQ: For six years, a child has been drinking water containing
For six years, a child has been drinking water containing 0.05 mg dm−3 benzene (CAS Registry Number 71-43-2). Estimate the average daily dose ADD for a child in this case, taking into account the natu...
See AnswerQ: Table 2.1 lists the physical and water retention data for
Table 2.1 lists the physical and water retention data for the Macksburg soil series from Madison County Iowa. The Macksburg soil is located on nearly level (0-2% slopes) upland sites, has moderately h...
See AnswerQ: The Robbs soil from Johnson County, Illinois has a moist bulk
The Robbs soil from Johnson County, Illinois has a moist bulk density of ρt = 1.34 M g • m−3 and a field-capacity volumetric water content of θfc = 0.38 cm•cm−1. The solids-water partition coefficient...
See AnswerQ: The Macksburg soil (Madison County, Iowa) has a retardation
The Macksburg soil (Madison County, Iowa) has a retardation coefficient of Rf = 42.2 for the herbicide Atrazine (CAS Registry Number 1912-24-9). In early spring the Macksburg soil is at field capacity...
See AnswerQ: The Antigo soil (Langlade County, Wisconsin) has a retardation
The Antigo soil (Langlade County, Wisconsin) has a retardation coefficient of Rf = 3.90 for the organophosphate insecticide Phosmet (CAS Registry Number 732-11-6). The Antigo soil has a field capacity...
See AnswerQ: The volumetric moisture content of a fine-sand soil is θ
The volumetric moisture content of a fine-sand soil is θ = 0.12 m3 • m−3. Use the empirical Clapp-Hornberger water retention function in Appendix D to estimate the tension head htension at this water...
See AnswerQ: Use the empirical Clapp-Hornberger unsaturated hydraulic conductivity function in Appendix
Use the empirical Clapp-Hornberger unsaturated hydraulic conductivity function in Appendix D to estimate the hydraulic conductvity kD of a loam- texture soil at field capacity.
See AnswerQ: Use the Thornthwaite potential evapotranspiration model to estimate the mean evapotranspiration water
Use the Thornthwaite potential evapotranspiration model to estimate the mean evapotranspiration water loss during May 2016 in Dane County, Wisconsin. Identify the weather station you use to make your...
See AnswerQ: The estimated evapotranspiration water loss during June 2008 in a Dane County
The estimated evapotranspiration water loss during June 2008 in a Dane County, Wisconsin watershed averaged 4.9 mm of water per day. The average soil depth in the watershed is 100 cm and has a total w...
See AnswerQ: A cylindrical soil core ( L = 20 cm, r =
A cylindrical soil core ( L = 20 cm, r = 3 cm) was collected from a field site in Madison County, Iowa, The weight of the empty metal cylinder is: m1 = 225 g. The metal cylinder containing field-mo...
See AnswerQ: List the stable isotopes for all Period 3 elements (Na through
List the stable isotopes for all Period 3 elements (Na through Ar) and explain why some elements have more stable isotopes than others. Stable isotopes and their relative abundances are compiled by th...
See AnswerQ: A cylindrical soil core ( L = 20 cm, r =
A cylindrical soil core ( L = 20 cm, r = 3 cm) was collected from a field site in Madison County, Iowa, The weight of the empty metal cylinder is: m1 = 225 g. The metal cylinder containing field-mo...
See AnswerQ: Consider a landscape underlain by granite that weathers in situ to residuum
Consider a landscape underlain by granite that weathers in situ to residuum. The x-ray diffraction pattern from the silt-size fraction of the residuum collected near the contact with the underlying gr...
See AnswerQ: Clay mineral layer charge influences a variety of chemical and physical properties
Clay mineral layer charge influences a variety of chemical and physical properties: swelling behavior, surface area, and the exchangeability of interlayer ions. Explain the relationship between layer...
See AnswerQ: Describe the special characteristics of Tschermak cation substitution and its significance for
Describe the special characteristics of Tschermak cation substitution and its significance for cation substitution in layer silicates.
See AnswerQ: Estimate the unit cell composition of a Wyoming montmorillonite specimen Volclay (
Estimate the unit cell composition of a Wyoming montmorillonite specimen Volclay (American Colloid Company) using the oxide mass-fraction w(ExOy) data listed in Table 3.4. Table 3.4:
See AnswerQ: Compute the osmotic head hosmotic of a CaSO4(aq) solution
Compute the osmotic head hosmotic of a CaSO4(aq) solution: cCaSO4 = 1.600 • 10−2 mol • dm−3.
See AnswerQ: Figure 15 ( cf. Chapter 3, Clay Mineralogy and Chemistry
Figure 15 ( cf. Chapter 3, Clay Mineralogy and Chemistry) plots the crystalline swelling of a Na+-saturate smectite specimen. Estimate the number of water layers in the interlayer of this smectite at...
See AnswerQ: Figure 24 ( cf. Chapter 3, Clay Mineralogy and Chemistry
Figure 24 ( cf. Chapter 3, Clay Mineralogy and Chemistry) shows the tension head htension of a 13.5% suspension of Cheto montmorillonite. Compute the actual height of the clay gel above pure water in...
See AnswerQ: Identify the Jackson Weathering Stage where smectite minerals first appear.
Identify the Jackson Weathering Stage where smectite minerals first appear.
See AnswerQ: Identify any crystallographic feature that would permit the solid-state transformation
Identify any crystallographic feature that would permit the solid-state transformation of feldspar minerals into layer silicate minerals.
See AnswerQ: Figure 2 (cf. Chapter 1, Elemental Abundance) plots
Figure 2 (cf. Chapter 1, Elemental Abundance) plots the relative abundance of several elements in the solar system, Earthâs crust and Earthâs soil. Explain the fact...
See AnswerQ: Describe the importance of plasticity in the field identification of clay content
Describe the importance of plasticity in the field identification of clay content and identify the minerals typically found in the clay-size fraction that exhibit plasticity.
See AnswerQ: Apply Pauling’s Radius Ratio rule to determine the preferred coordination of the
Apply Paulingâs Radius Ratio rule to determine the preferred coordination of the cation listed in Table 3.1. The ionic radius of oxygen is: rO2â = 0.140 nm. Table...
See AnswerQ: The structure of four layer silicate minerals appear in Figure 3.
The structure of four layer silicate minerals appear in Figure 3.1. Associate the following with each structure: 1) a specific mineral name, 2) the Jackson chemical weathering stage dominated by each...
See AnswerQ: The specific surface area of kaolinite specimens from the clay (< 0
The specific surface area of kaolinite specimens from the clay (< 0.2 µm) fraction is: as ≈ 10 m2 • g−1. The specific surface area of smectite specimens from the clay (< 0.2 µm) fraction is: as ≈ 700...
See AnswerQ: The Ness soil series (Hodgeman County, Kansas) has a
The Ness soil series (Hodgeman County, Kansas) has a cation exchange capacity CEC of n σ +/m = 38.0 cmolc kg−1 balanced by n σ Ca2+ /m = 33.1 mol kg−1 of exchangeable Ca2+ and n Σ Na+ /m = 4.9 mol kg−...
See AnswerQ: The Maxfield soil series (Olmsted County, MN) has a
The Maxfield soil series (Olmsted County, MN) has a cation exchange capacity CEC of nσ +/m = 41.0 cmolc kg−1 balanced by nσ Ca2+ /m = 39.5 cmolc kg−1 of exchangeable Ca2+ and nσ Na+ /m = 1.5 cmolc kg−...
See AnswerQ: The Bssyz2 horizon of the Duke soil series (Fine, mixed
The Bssyz2 horizon of the Duke soil series (Fine, mixed, active, thermic Sodic Haplusterts; Harmon County, OK) is 64.7% clay, has the following chemical properties (NCSS Pedon ID: S2003OK-057-006):...
See AnswerQ: Quirk and Schofield (1955) measured Na+, Ca2+ exchange
Quirk and Schofield (1955) measured Na+, Ca2+ exchange by a vermiculite dominated soil clay fraction collected at Rothamsted Experiment Station (Harpenden, U. K.). The results are listed. Use the leas...
See AnswerQ: The clay fraction of the Two top soil series (Crook County
The clay fraction of the Two top soil series (Crook County, Wyoming) is predominantly smectite with a reported cation exchange capacity CEC of nσ /m = 76.4 cmolc • kg−1. An asymmetric Ca2+, K+ cation...
See AnswerQ: The Chem EQL database Solid Phase Library (i.e.,
The Chem EQL database Solid Phase Library (i.e., equilibrium solubility constants for mineral species) contains the following entries for the carbonate minerals calcite : CaCO3(s) and dolomite : Ca Mg...
See AnswerQ: List the half-life of the longest-lived isotope for
List the half-life of the longest-lived isotope for each element from Po to Th (84 < Z < 90). A complete Table of the Isotopes is available on the Abundances of the Elements (Kaye and Laby Tables of P...
See AnswerQ: Install Chem EQL and simulate the chemistry of a 10−
Install Chem EQL and simulate the chemistry of a 10−5 mol dm−3 phthalic acid solution at pH 5 (cf. Chem EQL Manual, example simulation of 10−3 mol dm−3 acetic acid solution at pH 4). Save the input fi...
See AnswerQ: Install Chem EQL and simulate the chemistry of a 10−5
Install Chem EQL and simulate the chemistry of a 10−5 mol dm−3 phthalic acid solution at pH 5 without setting mode(H+) = free. Save the input matrix file (.txt) and the output file (.xls) and perform...
See AnswerQ: The standard free energies of formation ∆f tt−◦ (298
The standard free energies of formation âf ttâ⦠(298.15 K) for each component in the fluorapatite : Ca5(PO4)3F(s) solubility reaction appear in...
See AnswerQ: Using the R.I.C.E. table method
Using the R.I.C.E. table method, calculate the pH of a solution containing c0 = 3.80 ⢠10â4 mol ⢠dmâ3 dihydrogen sulfide H2S(aq...
See AnswerQ: Using the R.I.C.E. table method
Using the R.I.C.E. table method, calculate the activities of all hydrogen sulfide species for a solution containing c0 = 3.80 10â4 mol dmâ3 dihydrogen sulfide H2S(a...
See AnswerQ: Variation 1. Using Chem EQL, simulate the pH of a
Variation 1. Using Chem EQL, simulate the pH of a solution containing c0 = 3.80 10−4 mol dm−3 sulfide S2– and an ionic strength of Ic = 3 10−2 mol dm−3. NOTE: There are two more variations of this exe...
See AnswerQ: Simulate the dissolution of gypsum: CaSO4 2 H2O(s),
Simulate the dissolution of gypsum: CaSO4 2 H2O(s), saving both the input matrix file (.txt) and the output file (.xls). Validate the ion activity coefficients γ2± and the gypsum ion activity product...
See AnswerQ: Simulate hydroxyapatite : Ca5(PO4)3OH(s) solubility
Simulate hydroxyapatite : Ca5(PO4)3OH(s) solubility in the pH range: 4 ≤ pH ≤ 9. Save both the input file (.txt) and the output file (.xls) for the simulation. Plot the total solution phosphate concen...
See AnswerQ: Simulate troilite : FeS(s) solubility in the pH range
Simulate troilite : FeS(s) solubility in the pH range: 4 ≤ pH ≤ 9. Save both the input file (.txt) and the output file (.xls) for the simulation.
See AnswerQ: Simulate total soluble lead (Pb) in a 3-phase
Simulate total soluble lead (Pb) in a 3-phase system consisting of an aqueous solution in equilibrium with the phosphate minerals hydroxyapatite : Ca5(PO4)3OH(s) and pyromorphite : Pb5(PO4)3OH(s). Sav...
See AnswerQ: A reactor accident occurred in Chernobyl, Ukraine in 1986 that deposited
A reactor accident occurred in Chernobyl, Ukraine in 1986 that deposited 55 137
See AnswerQ: Simulate the 4-phase system consisting of an aqueous solution in
Simulate the 4-phase system consisting of an aqueous solution in solubility equilibrium with the following three minerals: calcite : CaCO3(s), hydroxyapatite : Ca5(PO4)3OH(s), and pyromorphite : Pb5(P...
See AnswerQ: The Chem EQL Solid Phase Library contains the following entry for the
The Chem EQL Solid Phase Library contains the following entry for the calcium phosphate mineral fluorapatite : Ca10(PO4)6F2(s). Calculate the equilibrium coefficient Kc for this reaction using the D...
See AnswerQ: The Chem EQL database Solid Phase Library (i.e.,
The Chem EQL database Solid Phase Library (i.e., mineral species formation reactions and equilibrium solubility constants) contains the following entry for the mineral calcite : CaCO3(s). Using the...
See AnswerQ: The following table lists the chemical analysis of a groundwater sample from
The following table lists the chemical analysis of a groundwater sample from Green Bay, Wisconsin. The analytic pH is 7.7. Use Chem EQL to simulate the pH of this groundwater sample. Save both the i...
See AnswerQ: Calculate the amount of CaCO 3(s) required to neutralize
Calculate the amount of CaCO 3(s) required to neutralize the acidity in 829 mm of acid precipitation with an average pH of 4.26 falling on a 1-hectare area.
See AnswerQ: Dai et al. (1998) studied the effect of acid
Dai et al. (1998) studied the effect of acid rain on soils from the provinces of Hunan and Guangxi in southern China. The soil chemical properties relevant to acidity of the Hongmaochong Inceptisols (...
See AnswerQ: Porębska et. al (2008) studied the effect of acid
Porębska et. al (2008) studied the effect of acid rain on soils in Poland. The soil chemical properties relevant to acidity of a spodosol near Gubin in western Poland: pH(1 m KCl) = 3.2, CEC7 = 34.2 c...
See AnswerQ: The following table lists the chemical analysis of a groundwater specimen from
The following table lists the chemical analysis of a groundwater specimen from Waukesha, Wisconsin collected in 2003. The electrical (specific) conductivity of the water is EC = 1.05 dS • m−1 and the...
See AnswerQ: The following table lists the chemical analysis of a groundwater specimen from
The following table lists the chemical analysis of a groundwater specimen from Waukesha, Wisconsin collected in 2003. The electrical (specific) conductivity of the water is EC = 1.05 dS • m−1 and the...
See AnswerQ: The Bssyz2 horizon of the Duke soil series (Fine, mixed
The Bssyz2 horizon of the Duke soil series (Fine, mixed, active, thermic Sodic Haplusterts; Harmon County, OK; Pedon ID: S2003OK-057-006 DUKE) is 47% smectite clay. The soil displays a “slight efferve...
See AnswerQ: The Earth’s crust contains thorium and uranium although no stable isotope exists
The Earth’s crust contains thorium and uranium although no stable isotope exists for either element. Explain why these unstable elements are present in the Earth’s crust.
See AnswerQ: The Byz2 horizon of the Duke soil series (Fine, mixed
The Byz2 horizon of the Duke soil series (Fine, mixed, active, thermic Sodic Haplusterts; Harmon County, OK) is 47% smectite clay. The soil dis- plays a “slight effervescence” when treated with dilute...
See AnswerQ: Crandall et al. (1999) published a study of groundwater
Crandall et al. (1999) published a study of groundwater and river water mixing, listing dissolved salts in groundwater from a number of wells and sinkholes and surface water from the Suwannee and Litt...
See AnswerQ: The International Humic Substances Society IHSS supplies reference specimens to researchers.
The International Humic Substances Society IHSS supplies reference specimens to researchers. Using IHSS elemental composition and acidic functional group data, determine the oxygen mole-fraction attri...
See AnswerQ: Table 1.2 in The Chemical Composition of Soils (Helmke
Table 1.2 in The Chemical Composition of Soils (Helmke, 2000) lists the geometric mean Cu content of world soils: 20 mg kgâ1. The soil organic carbon content of the Summit Hill (Chri...
See AnswerQ: Table 1.4 in The Chemical Composition of Soils (Helmke
Table 1.4 in The Chemical Composition of Soils (Helmke, 2000) lists the geometric mean Cu content of U.S. peat soils (Histosols): 193 mg kgâ1. The organic matter content of peat soil...
See AnswerQ: The International Humic Substances Society supplies reference samples to researchers (IHSS
The International Humic Substances Society supplies reference samples to researchers (IHSS Products link at the website www.ihss.gatech.edu/). The Chemical Properties menu leads you to data for Elemen...
See AnswerQ: The Upper Poplar Creek, a mercury-polluted stream located on
The Upper Poplar Creek, a mercury-polluted stream located on the U.S. Department of Energy Oak Ridge reservation, has as dissolve organic carbon content of DOC = 3 mg • dm−3. This aquatic organic matt...
See AnswerQ: Almendros et al. (1991) measured the nitrogen-15
Almendros et al. (1991) measured the nitrogen-15 nuclear magnetic resonance NMR spectrum of a compost material containing 8% nitrogen by weight. From the NMR spectrum, Almendros et al. (1991) estimate...
See AnswerQ: The International Humic Substances Society supplies reference samples to researchers (IHSS
The International Humic Substances Society supplies reference samples to researchers (IHSS Products link at the website www.ihss.gatech.edu/). The Chemical Properties menu leads you to data for Elemen...
See AnswerQ: The International Humic Substances Society supplies reference samples to researchers (IHSS
The International Humic Substances Society supplies reference samples to researchers (IHSS Products link at the website www.ihss.gatech.edu/). The Chemical Properties link leads you to data on the Ele...
See AnswerQ: The Earth’s crust is depleted of certain elements relative to the overall
The Earth’s crust is depleted of certain elements relative to the overall composition of the Solar System. Explain why the following elements (helium, neon, argon, krypton, xenon, silver, gold, platin...
See AnswerQ: Salibia et al. (2002) reports the following composition of
Salibia et al. (2002) reports the following composition of corncob lignin: C9H9.84O3.33(OCH3)0.38. Determine the mean carbon oxidation state OS(C) and carbon reduction ΓC of corncob lignin.
See AnswerQ: Fungal cell walls contain the polymer chitin (CAS Registry Number 1398
Fungal cell walls contain the polymer chitin (CAS Registry Number 1398- 61-4) with chemical formula (C8H13O5N)n . Verify the formal oxidation state of nitrogen OS(N) = 3 and calculate the mean carbon...
See AnswerQ: The International Humic Substances Society IHSS supplies reference specimens to researchers.
The International Humic Substances Society IHSS supplies reference specimens to researchers. Using IHSS elemental composition and acidic functional group data, determine the oxygen mole-fraction attri...
See AnswerQ: An experiment measuring adsorption of the triazine herbicide Cynazine by a Cheshire
An experiment measuring adsorption of the triazine herbicide Cynazine by a Cheshire soil specimen yielded the results listed in the following table (Xing and Pignatello, 1996). Determine whether th...
See AnswerQ: An adsorption experiment of the chloroacetanilide herbicide Alachlor (CAS Registry Number
An adsorption experiment of the chloroacetanilide herbicide Alachlor (CAS Registry Number 15972-60-8) by a shallow organic-rich aquifer near Piketon, Ohio yielded the results listed in the table below...
See AnswerQ: An experiment measuring SO24 adsorption by a by the aluminum oxide γ
An experiment measuring SO24 adsorption by a by the aluminum oxide γâ Al2O3(s) yielded the results listed in the following table. Determine whether the adsorption isoth...
See AnswerQ: The following data (courtesy of T. Ranatunga and R.
The following data (courtesy of T. Ranatunga and R. W. Taylor, Alabama A & M University) are from an experiment measuring Pb2+ adsorption at pH 4 by kaolinite (Clay Minerals Society specimen: KGa-...
See AnswerQ: The following data from Clark and McBride (1984) measures Cu
The following data from Clark and McBride (1984) measures Cu 2+ adsorption by imogolite Al2SiO3(OH)4(s) covering a pH range from about 4 to 7. The suspensions, which were prepared with 5 g â...
See AnswerQ: An Alachlor (CAS Registry Number 15972-60-8)
An Alachlor (CAS Registry Number 15972-60-8) adsorption experiment by a specimen collected from a shallow, organic-rich aquifer near Piketon, Ohio yielded the results listed in the table below. The...
See AnswerQ: An Alachlor (CAS Registry Number 15972-60-8)
An Alachlor (CAS Registry Number 15972-60-8) adsorption experiment by a specimen collected from a shallow, organic-rich aquifer near Piketon, Ohio yielded the results listed in the table below. Aqui...
See AnswerQ: Explain the significance of the following geochemical terms: atmophilic, lithophilic
Explain the significance of the following geochemical terms: atmophilic, lithophilic, siderophilic, and chalcophilic.
See AnswerQ: The transport of 1,2-dibromoethane (CAS Registry Number
The transport of 1,2-dibromoethane (CAS Registry Number 106-93-4) in an aquifer can be estimated using the organic carbon-water partition coefficient measured by any material containing natural organi...
See AnswerQ: Balance the reduction half-reaction involving the anions S3O 2 –
Balance the reduction half-reaction involving the anions S3O 2 –6 and S2O 2 –3.
See AnswerQ: Balance the reduction half-reaction involving cystine18 and cysteine19.
Balance the reduction half-reaction involving cystine18 and cysteine19.
See AnswerQ: Balance the reduction half-reaction involving the mineral s hausmanite
Balance the reduction half-reaction involving the mineral s hausmanite Mn3O4(s) and manganite MnOOH(s).
See AnswerQ: The molecular structures of 4,4’-DDT (1-
The molecular structures of 4,4’-DDT (1-chloro-4-[2,2,2-trichloro-1-(4- chlorophenyl) ethyl] benzene, CAS Registry Number 50-29-3) and 4,4’-DDD (1- chloro-4-[2,2-dichloro-1-(4-chlorophenyl)ethyl]benze...
See AnswerQ: Given the relation between the Free Energy of reaction and the Electro
Given the relation between the Free Energy of reaction and the Electro- chemical Potential for reduction (ârtt = n F E), calculate the electrochemical potential for the 4,4â...
See AnswerQ: Given the relation between the Gibbs energy of reaction and the electrochemical
Given the relation between the Gibbs energy of reaction and the electrochemical potential E of reduction-oxidation reactions, calculate the Standard reduction potential Eââ...
See AnswerQ: The two molecular structures below are flavin mononucleotide (FMN) and
The two molecular structures below are flavin mononucleotide (FMN) and reduced flavin mononucleotide (FMNH2). Reduced flavin mononucleotide FMNH2 serves as an electron donor in a variety of biochemica...
See AnswerQ: A construction worker, age 50 years, ingests soil containing 10
A construction worker, age 50 years, ingests soil containing 10 mg kg−1 toluene (CAS Registry Number 108-88-3). The worker’s oral soil ingestion rate is IR = 330 mg day−1. Work-related exposure durati...
See AnswerQ: Estimate the average daily dose ADD of methylmercury CH3Hg+ for an
Estimate the average daily dose ADD of methylmercury CH3Hg+ for an adult who eats 56 g of tuna daily containing 0.2 ppm CH3Hg+. The biological half-life of CH3Hg+ in humans is 70 days.
See AnswerQ: The following data are the vanadium content of samples of Canadian granite
The following data are the vanadium content of samples of Canadian granite (Ahrens, 1954). Determine the geometric mean and geometric standard deviation from this data set.
See AnswerQ: An adult consuming 100 micrograms a day of a substance whose steady
An adult consuming 100 micrograms a day of a substance whose steady-state level in the body is later established to be 0.1 mg • kg−1 . Estimate the biological half-life t1/2 for elimination of this su...
See AnswerQ: In 1996, the U.S. EPA developed a new
In 1996, the U.S. EPA developed a new reference dose for methylmercury CH3Hg+: Rf D = 0.1 mg • kg−1 • day−1. Estimate the amount of fish a 60 kg woman can safely eat each week if the average CH3Hg+ c...
See AnswerQ: According to a 1992 survey, the drinking water in one-
According to a 1992 survey, the drinking water in one-third of Chicago homes had lead levels of 10 ppb. Identify the most sensitive receptor (resident child or resident adult) and calculate the lead a...
See AnswerQ: Mackay (1982) reports a linear correlation between the bio-
Mackay (1982) reports a linear correlation between the bio-concentration factor BCF of organic compounds in fish and the octanol-water partition coefficients Koââ¦...
See AnswerQ: The U.S. EPA PBT Profiler (cf. Appendix
The U.S. EPA PBT Profiler (cf. Appendix D, Chapter 8, Surface Chemistry and Adsorption) tabulates selected environmental properties for a broad range of organic compounds. Among the tabulated environm...
See AnswerQ: The U.S. EPA PBT Profiler (cf. Appendix
The U.S. EPA PBT Profiler (cf. Appendix D, Chapter 8, Surface Chemistry and Adsorption) tabulates selected environmental properties for a broad range of organic compounds. Identify the toxicological...
See AnswerQ: An adult Bengali has been drinking water from a tube wells in
An adult Bengali has been drinking water from a tube wells in Lalpur, Nadia District, Bangladesh installed 35 years ago. The well water contains cw = 17 mg • dm−3 total dissolved arsenic. Select an a...
See AnswerQ: The lung cancer incremental excess lifetime cancer risk ILECR is estimated to
The lung cancer incremental excess lifetime cancer risk ILECR is estimated to be 10â4 resulting from chronic 222Rn(g) exposure at a level of 10 mBq dmâ3. The ILECR...
See AnswerQ: The exposure factor Ei,j for the shrew—the US
The exposure factor Ei,j for the shrewâthe US EPA mammalian insectivore test specieâis given by the first expression below. The U.S. EPA wildlife risk model ass...
See AnswerQ: The following dose-response curve plots the central estimate of the
The following dose-response curve plots the central estimate of the adverse (toxic) response from a series of doses. The dose (i.e., body burden) is plotted on a linear scale and the adverse response...
See AnswerQ: Convert the following p-functions to molar concentrations: pH
Convert the following p-functions to molar concentrations: pH = 1.102. pOH = 0.0057. pBr = 7.77. pCa = -0.221. pLi = 12.35. pNO3 = 0.054. pMn = 0.135. pCl = 8.92.
See AnswerQ: Briefly describe or define and give an example of a.
Briefly describe or define and give an example of a. A strong electrolyte. b. A Brønsted-Lowry base. c. The conjugate acid of a Brønsted-Lowry base. d. Neutralization, in terms of the Brønsted-Lowr...
See AnswerQ: Why is 1g no longer exactly 1 mole of unified atomic mass
Why is 1g no longer exactly 1 mole of unified atomic mass units?
See AnswerQ: From the Gaussian (normal) error curve, what is the
From the Gaussian (normal) error curve, what is the probability that a result from a population lies between 0 and +1σ of the mean? What is the probability of a result occurring that is between +1σ an...
See AnswerQ: From the normal curve of error, find the probability that a
From the normal curve of error, find the probability that a result is outside the limits of ±2σ from the mean. What is the probability that a result has a more negative deviation from the mean than -2...
See AnswerQ: Consider the following sets of replicate measurements / For each
Consider the following sets of replicate measurements For each set, calculate the (a) mean, (b) median, (c) spread or range, (d) standard deviation, and (e) coefficient of variation.
See AnswerQ: The accepted values for the sets of data in Problem 4-
The accepted values for the sets of data in Problem 4-7 are set A, 9.0; set B, 55.33; set C, 0.630; set D, 5.4; set E, 20.58; and set F, 0.965. For the mean of each set, calculate a. The absolute err...
See AnswerQ: Discuss how the size of the confidence interval for the mean is
Discuss how the size of the confidence interval for the mean is influenced by the following (all the other factors are constant): a. The standard deviation σ. b. The sample size N. c. The confidence l...
See AnswerQ: Consider the following sets of replicate measurements: /
Consider the following sets of replicate measurements: Calculate the mean and the standard deviation for each of these six data sets. Calculate the 95% confidence interval for each set of data. What...
See AnswerQ: Calculate the 95% confidence interval for each set of data in
Calculate the 95% confidence interval for each set of data in Problem 5-4 if s is a good estimate of σ and has a value of set A, 0.015; set B, 0.30; set C, 0.070; set D, 0.20; set E, 0.0090; and set F...
See AnswerQ: The last result in each set of data in Problem 5-
The last result in each set of data in Problem 5-4 may be an outlier. Apply the Q test (95% confidence level) to determine whether or not there is a statistical basis to reject the result.
See AnswerQ: An atomic absorption method for the determination of the amount of iron
An atomic absorption method for the determination of the amount of iron present in used jet engine oil was found from pooling 30 triplicate analyses to have a standard deviation s = 2.9 µg Fe/mL. If s...
See AnswerQ: An atomic absorption method for determination of copper in fuel samples yielded
An atomic absorption method for determination of copper in fuel samples yielded a pooled /reciprocating aircraft engine showed a copper content of 6.87 μg Cu/mL. Calculate the 95% and 99% confidence i...
See AnswerQ: Write expressions for the autoprotolysis of a. H2O.
Write expressions for the autoprotolysis of a. H2O. b. HCOOH. c. CH3NH2. d. NH3.
See AnswerQ: How many replicate measurements are needed to decrease the 95% and
How many replicate measurements are needed to decrease the 95% and 99% confidence limits for the analysis described in Problem 5-7 to ± 1.9 μg Fe/mL?
See AnswerQ: How many replicate measurements are necessary to decrease the 95% and
How many replicate measurements are necessary to decrease the 95% and 99% confidence limits for the analysis described in Problem 5-8 to ± 0.15 μg Cu/mL?
See AnswerQ: A volumetric calcium analysis on triplicate samples of the blood serum of
A volumetric calcium analysis on triplicate samples of the blood serum of a patient believed to be suffering from a hyperparathyroid condition produced the following data: mmol Ca/L = 3.15, 3.25, 3.26...
See AnswerQ: A chemist obtained the following data for percent lindane in the triplicate
A chemist obtained the following data for percent lindane in the triplicate analysis of an insecticide preparation: 7.23, 6.95, and 7.53. Calculate the 90% confidence interval for the mean of the thre...
See AnswerQ: A standard method for the determination of glucose in serum is reported
A standard method for the determination of glucose in serum is reported to have a standard deviation of 0.36 mg/dL. If s = 0.36 is a good estimate of σ, how many replicate determinations should be mad...
See AnswerQ: To test the quality of the work of a commercial laboratory,
To test the quality of the work of a commercial laboratory, duplicate analyses of a purified benzoic acid (68.8% C, 4.953% H) sample were requested. It is assumed that the relative standard /reported...
See AnswerQ: A prosecuting attorney in a criminal case presented as principal evidence small
A prosecuting attorney in a criminal case presented as principal evidence small fragments of glass found embedded in the coat of the accused. The attorney claimed that the fragments were identical in...
See AnswerQ: Sewage and industrial pollutants dumped into a body of water can reduce
Sewage and industrial pollutants dumped into a body of water can reduce the dissolved oxygen concentration and adversely affect aquatic species. In one study, weekly readings are taken from the same l...
See AnswerQ: The ascorbic acid concentration in mmol/L of five different brands
The ascorbic acid concentration in mmol/L of five different brands of orange juice was measured. Six replicate samples of each brand were analyzed. The following partial ANOVA table was obtained. a....
See AnswerQ: A 0.2121-g sample of an organic compound was
A 0.2121-g sample of an organic compound was burned in a stream of oxygen, and the CO2 produced was collected in a solution of barium hydroxide. Calculate the percentage of carbon in the sample if 0.6...
See AnswerQ: Describe in your own words why the confidence interval for the mean
Describe in your own words why the confidence interval for the mean of five measurements is smaller than that for a single result.
See AnswerQ: Calculate the pH of the solution that results when 20.0
Calculate the pH of the solution that results when 20.0 mL of 0.2500 M NH3 is a.Mixed with 20.0 ml of distilled water. b.Mixed with 20.0 ml of 0.250 M hcl solution. c.Mixed with 20.0 ml of 0.300 M hcl...
See AnswerQ: The solubility-product constant for Ce(IO3)3 is
The solubility-product constant for Ce(IO3)3 is 3.2 × 10-10. What is the Ce3+ concentration in a solution prepared by mixing 50.00 mL of 0.0500 M Ce3+with 50.00 mL of a. Water? b. 0.0500 M IO3-? c. 0....
See AnswerQ: A solution is 0.0500 M in NH4Cl and 0.
A solution is 0.0500 M in NH4Cl and 0.0300 M in NH3. Calculate its OH-concentration and its pH a.Neglecting activities. b.Taking activities into account.
See AnswerQ: What is the pH of a solution that is a.
What is the pH of a solution that is a. Prepared by dissolving 6.75 g of lactic acid (90.08 g/mol) and 5.19 g of sodium lactate (112.06 g/mol) in water and diluting to 1.00 L? b. 0.0430 M in acetic ac...
See AnswerQ: What is the pH of a solution that is a.
What is the pH of a solution that is a. Prepared by dissolving 3.30 g of 1NH422SO4 in water, adding 125.0 ml of 0.1011 M naoh, and diluting to 500.0 ml? b. 0.120 M in piperidine and 0.010 M in its chl...
See AnswerQ: Calculate the change in pH that occurs in each of the following
Calculate the change in pH that occurs in each of the following solutions as a result of a tenfold dilution with water. Round calculated values for pH to three figures to the right of the decimal poin...
See AnswerQ: Calculate the change in pH that occurs when 1.00 mmol
Calculate the change in pH that occurs when 1.00 mmol of a strong acid is added to 100 mL of the solutions listed in Problem 12-3
See AnswerQ: Calculate the change in pH that occurs when 1.50 mmol
Calculate the change in pH that occurs when 1.50 mmol of a strong base is added to 100 mL of the solutions listed in Problem 12-34. Calculate values to three decimal places.
See AnswerQ: Calculate the change in pH to three decimal places that occurs when
Calculate the change in pH to three decimal places that occurs when 0.50 mmol of a strong acid is added to 100 mL of a. 0.0100 M lactic acid 1 0.0800 M sodium lactate. b. 0.0800 M lactic acid 1 0.02...
See AnswerQ: A 5.500-g sample of a pesticide was decomposed
A 5.500-g sample of a pesticide was decomposed with metallic sodium in alcohol, and the liberated chloride ion was precipitated as AgCl. Express the results of this analysis in terms of percent DDT 1C...
See AnswerQ: A 50.00-mL aliquot of 0.1000 M
A 50.00-mL aliquot of 0.1000 M NaOH is titrated with 0.1000 M HCl. Calculate the pH of the solution after the addition of 0.00, 10.00, 25.00, 40.00, 45.00, 49.00, 50.00, 51.00, 55.00, and 60.00 mL of...
See AnswerQ: Before agreeing to the purchase of a large order of solvent,
Before agreeing to the purchase of a large order of solvent, a company wants to see conclusive evidence that the mean value of a particular impurity is less than 1.0 ppb. What hypotheses should be tes...
See AnswerQ: Assuming a large number of measurements so that s is a good
Assuming a large number of measurements so that s is a good estimate of Ï, determine what confidence level was used for each of the following confidence intervals.
See AnswerQ: In a titration of 50.00 mL of 0.05000
In a titration of 50.00 mL of 0.05000 M formic acid with 0.1000 M KOH, the titration error must be smaller than 0.05 mL. What indicator can be chosen to realize this goal?
See AnswerQ: In a titration of 50.00 mL of 0.1000
In a titration of 50.00 mL of 0.1000 M ethylamine with 0.1000 M HClO4, the titration error must be no more than 0.05 mL. What indicator can be chosen to realize this goal?
See AnswerQ: Briefly describe or define and give an example of a.
Briefly describe or define and give an example of a. An amphiprotic solvent. b. A differentiating solvent. c. A leveling solvent. d. A mass-action effect.
See AnswerQ: What is the mass in milligrams of solute in a.
What is the mass in milligrams of solute in a. 16.0 mL of 0.350 M sucrose (342 g/mol)? b. 1.92 L of 3.76 × 10-3 M H2O2? c. 356 mL of a solution that contains 2.96 ppm of Pb (NO3)2? d. 5.75 mL of 0.081...
See AnswerQ: Calculate the pH after addition of 0.00, 5.
Calculate the pH after addition of 0.00, 5.00, 15.00, 25.00, 40.00, 45.00, 49.00, 50.00, 51.00, 55.00, and 60.00 mL of 0.1000 M NaOH in the titration of 50.00 mL of a. 0.1000 M HNO2. b. 0.1000 M pyr...
See AnswerQ: Calculate the pH after addition of 0.00, 5.
Calculate the pH after addition of 0.00, 5.00, 15.00, 25.00, 40.00, 45.00, 49.00, 50.00, 51.00, 55.00, and 60.00 mL of 0.1000 M HCl in the titration of 50.00 mL of a. 0.1500 M ammonia. b. 0.1500 M...
See AnswerQ: Calculate the pH after addition of 0.00, 5.
Calculate the pH after addition of 0.00, 5.00, 15.00, 25.00, 40.00, 49.00, 50.00, 51.00, 55.00, and 60.00 mL of reagent in the titration of 50.0 mL of a. 0.01000 M chloroacetic acid with 0.01000 M N...
See AnswerQ: Five different laboratories participated in an interlaboratory study involving determinations of the
Five different laboratories participated in an interlaboratory study involving determinations of the iron level in water samples. The following results are replicate determinations of Fe in ppm for la...
See AnswerQ: Calculate a0 and a1 for a. Acetic acid in a
Calculate a0 and a1 for a. Acetic acid in a solution with a ph of 5.320. b. Picric acid in a solution with a ph of 1.750. c. Hypochlorous acid in a solution with a ph of 7.00. d. Hydroxylamine acid in...
See AnswerQ: Calculate the equilibrium concentration of methyl ammonia in a solution that has
Calculate the equilibrium concentration of methyl ammonia in a solution that has a molar analytical CH3NH2 concentration of 0.120 and a pH of 11.471.
See AnswerQ: Calculate the molar concentration of a solution that is 50.0
Calculate the molar concentration of a solution that is 50.0% NaOH (w/w) and has a specific gravity of 1.52..
See AnswerQ: What factors determine the mass of a gross sample?
What factors determine the mass of a gross sample?
See AnswerQ: Supply the missing data in the following table. /
Supply the missing data in the following table.
See AnswerQ: Why does the typical acid-base indicator exhibit its color change
Why does the typical acid-base indicator exhibit its color change over a range of about 2 pH units?
See AnswerQ: What factors affect end-point sharpness in an acid-base
What factors affect end-point sharpness in an acid-base titration?
See AnswerQ: Consider curves for the titration of 0.10 M NaOH and
Consider curves for the titration of 0.10 M NaOH and 0.010 M NH3 with 0.10 M HCl. a. Briefly account for the differences between curves for the two titrations. b. In what respect will the two curves b...
See AnswerQ: The solubility-product constant for K2PdCl6 is / What
The solubility-product constant for K2PdCl6 is What is the K1 concentration of a solution prepared by mixing 50.0 mL of 0.200 M KCl with 50.0 mL of a. 0.0800 M PdCl62-? b. 0.160 M PdCl62-? c. 0.240 M...
See AnswerQ: Why are the standard reagents used in neutralization titrations generally strong acids
Why are the standard reagents used in neutralization titrations generally strong acids and bases rather than weak acids and bases?
See AnswerQ: The mercury in a 1.0451-g sample was precipitated
The mercury in a 1.0451-g sample was precipitated with an excess of paraperiodic acid, H5IO6: The precipitate was filtered, washed free of precipitating agent, dried, and weighed, and 0.5718 g was r...
See AnswerQ: Suggest an indicator that would give an end point for the titration
Suggest an indicator that would give an end point for the titration of the first two protons in H3AsO4.
See AnswerQ: Suggest a method for determining the amounts of H3PO4 and NaH2PO4 in
Suggest a method for determining the amounts of H3PO4 and NaH2PO4 in an aqueous solution.
See AnswerQ: Suggest a suitable indicator for a titration based on each of the
Suggest a suitable indicator for a titration based on each of the following reactions. Use 0.05 M if an equivalence point concentration is needed. a. H2CO3 + NaOH→ NaHCO3 + H2O b. H2P + 2NaOH → Na2...
See AnswerQ: Calculate the pH of a solution that is 0.0400 M
Calculate the pH of a solution that is 0.0400 M in a. H3PO4. b. H2C2O4. c. H3PO3. d. H2SO3. e. H2S. f. H2NC2H4NH2.
See AnswerQ: The following results were obtained for the determination of calcium in a
The following results were obtained for the determination of calcium in a NIST limestone sample: %CaO = 51.33, 51.22, 51.36, 51.21, and 51.44. Five gross samples were then obtained for a carload of li...
See AnswerQ: Calculate the pH of a solution that is 0.0400 M
Calculate the pH of a solution that is 0.0400 M in a. NaH2PO4. b. NaHC2O4. c. NaH2PO3. d. NaHSO3. e. NaHS. f. H2NC2H4NH3 +CI-.
See AnswerQ: Calculate the pH of a solution that is 0.0400 M
Calculate the pH of a solution that is 0.0400 M in a. Na3PO4. b. Na2C2O4. c. Na2HPO3. d. Na2SO3. e. Na2S. f. C2H4(NH3 1CI2)2.
See AnswerQ: Calculate the pH of a solution that contains the following analytical concentrations
Calculate the pH of a solution that contains the following analytical concentrations: a. 0.0200 M in H3PO4 and 0.0500 M in NaH2PO4. b. 0.0300 M in NaH2AsO4 and 0.0500 M in Na2HAsO4. c. 0.0400 M...
See AnswerQ: Calculate the pH of a solution that contains the following analytical concentrations
Calculate the pH of a solution that contains the following analytical concentrations: a. 0.225 M in H3PO4 and 0.414 M in NaH2PO4. b. 0.0670 M in Na2SO3 and 0.0315 M in NaHSO3. c. 0.640 M in HOC2H4N...
See AnswerQ: Calculate the pH of a solution that is a. 0
Calculate the pH of a solution that is a. 0.0100 M in HCl and 0.0200 M in picric acid. b. 0.0100 M in HCl and 0.0320 M in benzoic acid. c. 0.0100 M in NaOH and 0.075 M in Na2CO3. d. 0.0100 M in Na...
See AnswerQ: The iodide in a sample that also contained chloride was converted to
The iodide in a sample that also contained chloride was converted to iodate by treatment with an excess of bromine: The unused bromine was removed by boiling; an excess of barium ion was then added...
See AnswerQ: What is the mass in grams of solute in a.
What is the mass in grams of solute in a. 250 mL of 0.264 M H2O2? b. 37.0 mL of 5.75 × 10-4 M benzoic acid (122 g/mol)? c. 2.50 L of a solution that contains 37.2 ppm of SnCl2? d. 11.7 mL of 0.0225 M...
See AnswerQ: Calculate the pH of a solution that is a. 0
Calculate the pH of a solution that is a. 0.0100 M in HClO4 and 0.0300 M in monochloroacetic acid. b. 0.0100 M in HCl and 0.0150 M in H2SO4. c. 0.0100 M in NaOH and 0.0300 M in Na2S. d. 0.0100 M i...
See AnswerQ: Identify the principal conjugate acid-base pair and calculate the ratio
Identify the principal conjugate acid-base pair and calculate the ratio between them in a solution that is buffered to pH 6.00 and contains a. H2SO3. b. Citric acid. c. Malonic acid. d. Tartaric a...
See AnswerQ: Identify the principal conjugate acid-base pair and calculate the ratio
Identify the principal conjugate acid-base pair and calculate the ratio between them in a solution that is buffered to pH 9.00 and contains a. H2S. b. ethylenediamine dihydrochloride. c. H3AsO4. d....
See AnswerQ: What mass (g) of Na2HPO4 . 2H2O must be added
What mass (g) of Na2HPO4 . 2H2O must be added to 750 mL of 0.160 M H3PO4 to give a buffer of pH 7.30?
See AnswerQ: A coating that weighs at least 2.00 mg is needed
A coating that weighs at least 2.00 mg is needed to impart adequate shelf life to a pharmaceutical tablet. A random sampling of 200 tablets revealed that 16 failed to meet this requirement. a. Use thi...
See AnswerQ: What mass (g) of dipotassium phthalate must be added to
What mass (g) of dipotassium phthalate must be added to 750 mL of 0.0500 M phthalic acid to give a buffer of pH 5.75?
See AnswerQ: . What is the pH of the buffer formed by mixing 50
. What is the pH of the buffer formed by mixing 50.0 mL of 0.200 M NaH2PO4 with a. 50.0 mL of 0.100 M HCl? b. 50.0 mL of 0.100 M NaOH?
See AnswerQ: What is the pH of the buffer formed by adding 100 mL
What is the pH of the buffer formed by adding 100 mL of 0.150 M potassium hydrogen phthalate to a. 100.0 mL of 0.0800 M NaOH? b. 100.0 mL of 0.0800 M HCl?
See AnswerQ: How would you prepare 1.00 L of a buffer with
How would you prepare 1.00 L of a buffer with a pH of 9.45 from 0.300 M Na2CO3 and 0.200 M HCl?
See AnswerQ: Ammoniacal nitrogen can be determined by treatment of the sample with chloroplatinic
Ammoniacal nitrogen can be determined by treatment of the sample with chloroplatinic acid; the product is slightly soluble ammonium chloroplatinate: The precipitate decomposes on ignition, yielding me...
See AnswerQ: How would you prepare 1.00 L of a buffer with
How would you prepare 1.00 L of a buffer with a pH of 7.00 from 0.200 M H3PO4 and 0.160 M NaOH?
See AnswerQ: How would you prepare 1.00 L of a buffer with
How would you prepare 1.00 L of a buffer with a pH of 6.00 from 0.500 M Na3AsO4 and 0.400 M HCl?
See AnswerQ: The solubility products for a series of iodides are /
The solubility products for a series of iodides are List these four compounds in order of decreasing molar solubility in (a) water. (b) 0.20 M NaI. (c) a 0.020 M solution of the solute cation.
See AnswerQ: Identify by letter the curve you would expect in the titration of
Identify by letter the curve you would expect in the titration of a solution containing a. Disodium maleate, Na2M, with standard acid. b. Pyruvic acid, HP, with standard base. c. Sodium carbonate,...
See AnswerQ: Describe the composition of a solution that would be expected to yield
Describe the composition of a solution that would be expected to yield a curve resembling (see Problem 13-26) a. curve B. b. curve A. c. curve E.
See AnswerQ: Briefly explain why curve B cannot describe the titration of a mixture
Briefly explain why curve B cannot describe the titration of a mixture consisting of H3PO4 and NaH2PO4.
See AnswerQ: Changes in the method used to coat the tablets in Problem 6
Changes in the method used to coat the tablets in Problem 6-6 lowered the percentage of rejects from 8.0% to 3.0%. How many tablets should be taken for inspection if the permissible relative standard...
See AnswerQ: Construct a curve for the titration of 50.00 mL of
Construct a curve for the titration of 50.00 mL of a 0.1000 M solution of compound A with a 0.2000 M solution of compound B in the following table. For each titration, calculate the pH after the addit...
See AnswerQ: Generate a curve for the titration of 50.00 mL of
Generate a curve for the titration of 50.00 mL of a solution in which the analytical concentration of NaOH is 0.1000 M and that for hydrazine is 0.0800 M. Calculate the pH after addition of 0.00, 10.0...
See AnswerQ: Generate a curve for the titration of 50.00 mL of
Generate a curve for the titration of 50.00 mL of a solution in which the analytical concentration of HClO4 is 0.1000 M and that for formic acid is 0.0800 M. Calculate the pH after addition of 0.00, 1...
See AnswerQ: A 0.6447-g portion of manganese dioxide was added
A 0.6447-g portion of manganese dioxide was added to an acidic solution in which 1.1402 g of a chloride containing sample was dissolved. Evolution of chlorine took place as a consequence of the follow...
See AnswerQ: Formulate equilibrium constants for the following equilibria, and determine numerical values
Formulate equilibrium constants for the following equilibria, and determine numerical values for the constants: a. b.
See AnswerQ: Calculate a numerical value for the equilibrium constant for the reaction
Calculate a numerical value for the equilibrium constant for the reaction
See AnswerQ: For pH values of 2.00, 6.00,
For pH values of 2.00, 6.00, and 10.00, calculate the alpha values for each species in an aqueous solution of a. Phthalic acid. b. Tartaric acid. c. Citric acid. d. Periodic acid. e. Phosphorous...
See AnswerQ: Derive equations that define a0, a1, a2, and a3
Derive equations that define a0, a1, a2, and a3 for the acid H3AsO4.
See AnswerQ: Calculate the p-value for each of the listed ions in
Calculate the p-value for each of the listed ions in the following: a. Na1, Cl2, and OH2 in a solution that is 0.0635 M in NaCl and 0.0403 M in NaOH. b. Ba2+, Mn2+, and Cl2 in a solution that is 4.65...
See AnswerQ: Calculate alpha values for the following diprotic acids every 0.5
Calculate alpha values for the following diprotic acids every 0.5 pH units from pH 0.0 to 10.0. Plot the distribution diagram for each of the acids, and label the curve for each species. a. Phthalic...
See AnswerQ: Calculate alpha values for the following triprotic acids every 0.5
Calculate alpha values for the following triprotic acids every 0.5 pH units from pH 0.0 to 14.0. Plot the distribution diagram for each of the acids, and label the curve for each species. a. Citric a...
See AnswerQ: As its name implies, NaHA is an “acid salt”
As its name implies, NaHA is an “acid salt” because it has a proton available to donate to a base. Briefly explain why a pH calculation for a solution of NaHA differs from that for a weak acid of the...
See AnswerQ: Explain the origin and significance of each of the terms on the
Explain the origin and significance of each of the terms on the right side of Equation 13-12. Does the equation make intuitive sense? Why or why not?
See AnswerQ: Find the number of millimoles of solute in a. 2
Find the number of millimoles of solute in a. 2.00 L of 0.0449 M KMnO4. b. 750 mL of 5.35 × 10-3 M KSCN. c. 3.50 L of a solution that contains 6.23 ppm of CuSO4. d. 250 mL of 0.414 mM KCl.
See AnswerQ: Briefly explain why Equation 13-15 can only be used to
Briefly explain why Equation 13-15 can only be used to calculate the hydronium ion concentration of solutions in which NaHA is the only solute that determines the pH.
See AnswerQ: Why is it impossible to titrate all three protons of phosphoric acid
Why is it impossible to titrate all three protons of phosphoric acid in aqueous solution?
See AnswerQ: Indicate whether an aqueous solution of the following compounds is acidic,
Indicate whether an aqueous solution of the following compounds is acidic, neutral, or basic. Explain your answer. a. NaH2PO4 b. Na3PO4 c. NaNO3 d. NaHC2O4 e. Na2C2O4 f. Na2HPO4 g. NH4OAc h. N...
See AnswerQ: Suggest an indicator that could be used to provide an end point
Suggest an indicator that could be used to provide an end point for the titration of the first proton in H3AsO4.
See AnswerQ: What types of organic nitrogen-containing compounds tend to yield low
What types of organic nitrogen-containing compounds tend to yield low results with the Kjeldahl method unless special precautions are taken?
See AnswerQ: Briefly describe the circumstance where the concentration of a sodium hydroxide solution
Briefly describe the circumstance where the concentration of a sodium hydroxide solution will apparently be unaffected by the absorption of carbon dioxide.
See AnswerQ: The solubility products for a series of hydroxides are /
The solubility products for a series of hydroxides are Which hydroxide has a. the lowest molar solubility in H2O? b. the lowest molar solubility in a solution that is 0.35 M in NaOH?
See AnswerQ: How would you prepare 500 mL of a. 0100
How would you prepare 500 mL of a. 0100MHSO24 from a reagent that has a density of 1.1539 g/mL and is 21.8% H2SO4w/w? b. 0.200 M NaOH from the solid? c. 008000MNa2CO3 from the pure solid?...
See AnswerQ: The mishandling of a shipping container loaded with 850 cases of wine
The mishandling of a shipping container loaded with 850 cases of wine caused some of the bottles to break. An insurance adjuster proposed to settle the claim at 20.8% of the value of the shipment, bas...
See AnswerQ: How would you prepare 2.00 L of a.
How would you prepare 2.00 L of a. 0.10 M KOH from the solid? b. 0010MBaOH2 8H2O from the solid? c. 0.150 M HCl from a reagent that has a density of 1.0579 g/mL and is 11.50% HCl (w/w)?
See AnswerQ: A series of sulfate samples is to be analyzed by precipitation as
A series of sulfate samples is to be analyzed by precipitation as BaSO4. If it is known that the sulfate content in these samples ranges between 20% and 55%, what minimum sample mass should be taken t...
See AnswerQ: Standardization of a sodium hydroxide solution against potassium hydrogen phthalate (KHP
Standardization of a sodium hydroxide solution against potassium hydrogen phthalate (KHP) yielded the results in the following table. a. the average molar concentration of the base. b. the standard...
See AnswerQ: The concentration of a perchloric acid solution was established by titration against
The concentration of a perchloric acid solution was established by titration against primary-standard sodium carbonate (product: CO2 ); the following data were obtained.
See AnswerQ: If 1.000 L of 0.2000 M NaOH was
If 1.000 L of 0.2000 M NaOH was unprotected from the air after standardization and absorbed 14.2 mmol of CO2 , what is its new molar concentration when it is standardized against a standard solution o...
See AnswerQ: A NaOH solution was 0.1019 M immediately after standardization.
A NaOH solution was 0.1019 M immediately after standardization. Exactly 500.0 mL of the reagent was left exposed to air for several days and absorbed 0.652 g of CO2 Calculate the relative carbonate...
See AnswerQ: Calculate the molar concentration of a dilute HCl solution if a
Calculate the molar concentration of a dilute HCl solution if a. A 50.00-ml aliquot yielded 0.6027 g of agcl. b. The titration of 25.00 ml of 004096mbaOH2 required 17.93 ml of the acid c. The t...
See AnswerQ: Calculate the molar concentration of a dilute BaOH2
Calculate the molar concentration of a dilute BaOH2 solution if a. 50.00 mL yielded 0.1791 g of BaSO4 b. titration of 0.4512 g of primary-standard potassium hydrogen phthalate (KHP) required 26.46 m...
See AnswerQ: Suggest a range of sample masses for the indicated primary standard if
Suggest a range of sample masses for the indicated primary standard if it is desired to use between 35 and 45 mL of titrant a. 0.180 M HClO4 titrated against Na2CO3(CO2 product) b. 0.102 M HCl titrate...
See AnswerQ: Calculate the relative standard deviation in the computed molar concentration of 0
Calculate the relative standard deviation in the computed molar concentration of 0.0200 M HCl if this acid was standardized against the masses found in Example 14-1 for (a) TRIS, (b) Na2CO3 , and (c)...
See AnswerQ: Calculate the molar H3O+ ion concentration of a solution that has
Calculate the molar H3O+ ion concentration of a solution that has a pH of a. 3.73. b. 3.28. c. 0.59. d. 11.29. e. 7.62. f. 5.19. g. -0.76. h. -0.42.
See AnswerQ: Approximately 15% of the particles in a shipment of silver-
Approximately 15% of the particles in a shipment of silver-bearing ore are judged to be argentite, Ag2S (d = 7.3 g cm-3, 87% Ag); the remainder are siliceous (d = 2.6 g cm-3) and contain essentially n...
See AnswerQ: The addition of dimethylglyoxime, H2C4H6O2N2, to a solution containing nickel
The addition of dimethylglyoxime, H2C4H6O2N2, to a solution containing nickel(II) ion gives rise to a precipitate: Nickel dimethylglyoxime is a bulky precipitate that is inconvenient to manipulate in...
See AnswerQ: a. Compare the masses of potassium hydrogen phthalate (204.
a. Compare the masses of potassium hydrogen phthalate (204.22 g/mol), potassium hydrogen iodate (389.91 g/mol), and benzoic acid (122.12 g/mol) needed for a 50.00-mL standardization of 0.0600 M NaOH....
See AnswerQ: A 50.00-mL sample of a white dinner wine
A 50.00-mL sample of a white dinner wine required 24.57 mL of 0.03291 M NaOH to achieve a phenolphthalein end point. Express the acidity of the wine in grams of tartaric acid H2C4H4O6 ;15009g/mol...
See AnswerQ: A 25.0-mL aliquot of vinegar was diluted to
A 25.0-mL aliquot of vinegar was diluted to 250 mL in a volumetric flask. Titration of 50.0mL aliquots of the diluted solution required an average of 25.23 mL of 0.09041 M NaOH. Express the acidity of...
See AnswerQ: Titration of a 0.7513-g sample of impure Na2B4O7
Titration of a 0.7513-g sample of impure Na2B4O7 required 30.79 mL of 0.1129 M HCl (see Problem 14-16f for reaction). Express the results of this analysis in terms of percent a. Na2B4O7 b. Na2B4O7...
See AnswerQ: A 0.7041-g sample of impure mercury(II
A 0.7041-g sample of impure mercury(II) oxide was dissolved in an unmeasured excess of potassium iodide. Reaction: HgOs4IH2OHgI242OH Calculate the percentage of HgO in the sample if tit...
See AnswerQ: The formaldehyde (HCHO) content of a pesticide preparation was determined
The formaldehyde (HCHO) content of a pesticide preparation was determined by weighing 0.2985 g of the liquid sample into a flask containing 50.0 mL of 0.0959 M NaOH and 50 mL of 3% H2O2Upon heating,...
See AnswerQ: The benzoic acid extracted from 86.7 g of catsup required
The benzoic acid extracted from 86.7 g of catsup required a 15.61-mL titration with 0.0654 M NaOH. Express the results of this analysis in terms of percent sodium benzoate (144.10 g/mol).
See AnswerQ: The active ingredient in Antabuse, a drug used for the treatment
The active ingredient in Antabuse, a drug used for the treatment of chronic alcoholism, is tetraethylthiuram disulfide, (296.54 g/mol). The sulfur in a 0.4169-g sample of an Antabuse preparation was o...
See AnswerQ: A 25.00-mL sample of a household cleaning solution
A 25.00-mL sample of a household cleaning solution was diluted to 250.0 mL in a volumetric flask. A 50.00-mL aliquot of this solution required 43.04 mL of 0.1776 M HCl to reach a bromocresol green end...
See AnswerQ: A 0.1401-g sample of a purified carbonate was
A 0.1401-g sample of a purified carbonate was dissolved in 50.00 mL of 0.1140 M HCl and boiled to eliminate CO2 Back-titration of the excess HCl required 24.21 mL of
See AnswerQ: The aluminum in a 2.200-g sample of impure
The aluminum in a 2.200-g sample of impure ammonium aluminumsulfate was precipitated with aqueous ammonia as the hydrous Al2O3 xH2O. The precipitate was filtered and ignited at 1000°C to give anhydro...
See AnswerQ: The efficiency of a particular catalyst is highly dependent on its zirconium
The efficiency of a particular catalyst is highly dependent on its zirconium content. The starting material for this preparation is received in batches that assay between 68% and 84% ZrCl4. Routine an...
See AnswerQ: In the determination of lead in a paint sample, it is
In the determination of lead in a paint sample, it is known that the sampling variance is 10 ppm while the measurement variance is 4 ppm. Two different sampling schemes are under consideration: Scheme...
See AnswerQ: Calculate the pH of water at 25°C and 50°
Calculate the pH of water at 25°C and 50°C. The values for pKw at these temperatures are 13.99 and 13.26, respectively.
See AnswerQ: A dilute solution of an unknown weak acid required a 28.
A dilute solution of an unknown weak acid required a 28.94-mL titration with 0.1062 M NaOH to reach a phenolphthalein end point. The titrated solution was evaporated to dryness. Calculate the equivale...
See AnswerQ: A 3.00-L sample of urban air was bubbled
A 3.00-L sample of urban air was bubbled through a solution containing 50.0 mL of 00116MBaOH2 , which caused the CO2 in the sample to precipitate as BaCO3 The excess base was back-titrated to a...
See AnswerQ: Air was bubbled at a rate of 30.0 L/
Air was bubbled at a rate of 30.0 L/min through a trap containing 75 mL of 1% H2O2 H2O2 SO2 H2SO4 After 10.0 minutes, the H2SO4 was titrated with 10.95 mL of 0.00242 M NaOH. Calculate concentrat...
See AnswerQ: The digestion of a 0.1417-g sample of a
The digestion of a 0.1417-g sample of a phosphorus-containing compound in a mixture of HNO3 and H2SO4 resulted in the formation of CO2 ,H2O, and HPO34 Addition of ammonium molybdate yielded a solid...
See AnswerQ: A 0.9826-g sample containing dimethyl phthalate, C6H4
A 0.9826-g sample containing dimethyl phthalate, C6H4COOCH3 219419g/mol, and unreactive species was refluxed with 50.00 mL of 0.1104 M NaOH to hydrolyze the ester groups (this process is calle...
See AnswerQ: Neohetramine, C16H22ON428637g/mol,
Neohetramine, C16H22ON428637g/mol, is a common antihistamine. A 0.1247-g sample containing this compound was analyzed by the Kjeldahl method. The ammonia produced was collected in H3BO3 ; the res...
See AnswerQ: The Merck Index indicates that 10 mg of guanidine, CHN53 ,
The Merck Index indicates that 10 mg of guanidine, CHN53 , may be administered for each kilogram of body mass in the treatment of myasthenia gravis. The nitrogen in a 4-tablet sample that had a total...
See AnswerQ: A 0.917-g sample of canned tuna was analyzed
A 0.917-g sample of canned tuna was analyzed by the Kjeldahl method. A volume of 20.59 mL of 0.1249 M HCl was required to titrate the liberated ammonia. Calculate the percentage of nitrogen in the sam...
See AnswerQ: A 0.7891-g sample of a mixture consisting solely
A 0.7891-g sample of a mixture consisting solely of sodium bromide and potassium bromide yields 1.2895 g of silver bromide. What are the percentages of the two salts in the sample?
See AnswerQ: Calculate the mass in grams of protein in a 5.00
Calculate the mass in grams of protein in a 5.00-oz can of tuna in Problem 14-35.
See AnswerQ: The data in the accompanying table represent the concentration of glucose in
The data in the accompanying table represent the concentration of glucose in the blood serum of an adult patient. On four consecutive days, a blood sample was drawn from the patient and analyzed in tr...
See AnswerQ: A 0.5843-g sample of a plant food preparation
A 0.5843-g sample of a plant food preparation was analyzed for its N content by the Kjeldahl method, the liberated NH3 being collected in 50.00 mL of 0.1062 M HCl. The excess acid required an 11.89 mL...
See AnswerQ: Calculate the p-functions for each ion in a solution that
Calculate the p-functions for each ion in a solution that is A. 0.0200 M in NaBr. b. 0.0300 M in BaBr2. c. 4.5 × 10-3 M in Ba(OH)2. d. 0.020 M in HCl and 0.010 M in NaCl. e. 7.2 × 10-3 M in CaCl2 and...
See AnswerQ: A 0.8835-g sample of a wheat flour was
A 0.8835-g sample of a wheat flour was analyzed by the Kjeldahl procedure. The ammonia formed was distilled into 50.00 mL of 0.05078 M HCl; a 8.04-mL back-titration with 0.04829 M NaOH was required. C...
See AnswerQ: A 1.219-g sample containing (NH4)2SO4
A 1.219-g sample containing (NH4)2SO4, NH4NO3, and nonreactive substances was diluted to 200 mL in a volumetric flask. A 50.00-mL aliquot was made basic with strong alkali, and the liberated NH3 was d...
See AnswerQ: A 1.421-g sample of commercial KOH contaminated by
A 1.421-g sample of commercial KOH contaminated by K2CO3 was dissolved in water, and the resulting solution was diluted to 500.0 mL. A 50.00-mL aliquot of this solution was treated with 40.00 mL of 0....
See AnswerQ: A 0.5000-g sample containing NaHCO3 , Na2CO3 ,
A 0.5000-g sample containing NaHCO3 , Na2CO3 , and H2O was dissolved and diluted to 250.0 mL. A 25.00-mL aliquot was then boiled with 50.00 mL of 0.01255 M HCl. After cooling, the excess acid in the...
See AnswerQ: Calculate the volume of 0.06452 M HCl needed to titrate
Calculate the volume of 0.06452 M HCl needed to titrate a. 20.00 mL of 005522MNa3PO4 to a thymolphthalein end point. b. 25.00 mL of 005522MNa3PO4 to a bromocresol green end point. c. 40.00 mL...
See AnswerQ: Calculate the volume of 0.07731 M NaOH needed to titrate
Calculate the volume of 0.07731 M NaOH needed to titrate a. 25.00 mL of a solution that is 0.03000 M in HCl and 0.01000 M in H3PO4 to a bromocresol green end point. b. the solution in (a) to a thymol...
See AnswerQ: A 0.6407-g sample containing chloride and iodide ions
A 0.6407-g sample containing chloride and iodide ions gave a silver halide precipitate weighing 0.4430 g. This precipitate was then strongly heated in a stream of Cl2 gas to convert the AgI to AgCl; o...
See AnswerQ: A series of solutions containing NaOH,Na3AsO4 , and Na2HAsO4 ,
A series of solutions containing NaOH,Na3AsO4 , and Na2HAsO4 , alone or in compatible combination, was titrated with 0.08601 M HCl. In the following table are the volumes of acid needed to titrate 25....
See AnswerQ: A series of solutions containing NaOH,Na2CO3 , and NaHCO3 ,
A series of solutions containing NaOH,Na2CO3 , and NaHCO3 , alone or in compatible combination, was titrated with 0.1202 M HCl. In the following table are the volumes of acid needed to titrate 25.00-m...
See AnswerQ: How did the definition of the mole change with the 2019 redefinition
How did the definition of the mole change with the 2019 redefinition of SI base units?
See AnswerQ: The seller of a mining claim took a random ore sample that
The seller of a mining claim took a random ore sample that weighed approximately 5 lb and had an average particle diameter of 5.0 mm. Inspection revealed that about 1% of the sample was argentite (see...
See AnswerQ: Define the equivalent mass of (a) an acid and (
Define the equivalent mass of (a) an acid and (b) a base
See AnswerQ: Calculate the equivalent mass of oxalic acid dehydrateH2C2O4 2H2O,12066g/
Calculate the equivalent mass of oxalic acid dehydrateH2C2O4 2H2O,12066g/mol when it is titrated to (a) a bromocresol green end point and (b) a phenolphthalein end point.
See AnswerQ: At 25°C, what are the molar H3O1 and OH2
At 25°C, what are the molar H3O1 and OH2 concentrations in a. 0.0300 M HCOOH? b. 0.0600 M HN3? c. 0.200 M ethylamine? d. 0.100 M trimethylamine? e. 0.250 M C6H5COONa (sodium benzoate)? f. 0.0750 M CH3...
See AnswerQ: A 10.00-mL sample of vinegar (acetic acid
A 10.00-mL sample of vinegar (acetic acid, CH3COOH) was pipetted into a flask, two drops of phenolphthalein indicator were added, and the acid was titrated with 0.1008 M NaOH a. If 45.62 mL of the bas...
See AnswerQ: Why is nitric acid seldom used to prepare standard acid solutions?
Why is nitric acid seldom used to prepare standard acid solutions?
See AnswerQ: Describe how Na2CO3 of primary-standard grade can be prepared from
Describe how Na2CO3 of primary-standard grade can be prepared from primary-standard NaHCO3.
See AnswerQ: Four analysts perform replicate sets of Hg determinations on the same analytical
Four analysts perform replicate sets of Hg determinations on the same analytical sample. The results in ppb Hg are shown in the following table: a. State the appropriate hypotheses. b. Do the analyst...
See AnswerQ: The boiling points of HCl and CO2 are nearly the same (
The boiling points of HCl and CO2 are nearly the same (285°C and 278°C). Explain why CO2 can be removed from an aqueous solution by boiling briefly while essentially no HCl is lost even after boiling...
See AnswerQ: Why is it common practice to boil the solution near the equivalence
Why is it common practice to boil the solution near the equivalence point in the standardization of Na2CO3 with acid?
See AnswerQ: Give two reasons why ( ( 3 2 KH IO is preferred
Give two reasons why ( ( 3 2 KH IO is preferred over benzoic acid as a primary standard for a 0.010 M NaOH solution.
See AnswerQ: Briefly explain why the sparingly soluble product must be removed by filtration
Briefly explain why the sparingly soluble product must be removed by filtration before you back-titrate the excess silver ion in the Volhard determination of
See AnswerQ: A method for the determination of the corticosteroid methylprednisolone acetate in solutions
A method for the determination of the corticosteroid methylprednisolone acetate in solutions obtained from pharmaceutical preparations yielded a mean value of 3.7 mg mL-1with a standard deviation of 0...
See AnswerQ: Why does the charge on the surface of precipitate particles change sign
Why does the charge on the surface of precipitate particles change sign at the equivalence point of a titration?
See AnswerQ: Outline a method for the determination of K+ based on argentometry
Outline a method for the determination of K+ based on argentometry. Write balanced equations for the chemical reactions.
See AnswerQ: Outline a method for the determination of K+ based on argentometry
Outline a method for the determination of K+ based on argentometry. Write balanced equations for the chemical reactions.
See AnswerQ: What is the difference between molar species concentration and molar analytical concentration
What is the difference between molar species concentration and molar analytical concentration?
See AnswerQ: Convert the following p-functions to molar concentrations: a
Convert the following p-functions to molar concentrations: a. pH = 1.102. b. pOH = 0.0057. c. pBr = 7.77. d. pCa = -0.221. e. pLi = 12.35. f. pNO3 = 0.054. g. pMn = 0.135. h. pCl = 8.92.
See AnswerQ: The phosphorus in a 0.3019-g sample was precipitated
The phosphorus in a 0.3019-g sample was precipitated as the slightly soluble 1NH423PO4 . 12MoO3. This precipitate was filtered, washed, and then redissolved in acid. Treatment of the resulting solutio...
See AnswerQ: Write equations in terms of the acid dissociation constants and [H
Write equations in terms of the acid dissociation constants and [H+] for the highest alpha value for each of the following weak acid ligands:
See AnswerQ: Write conditional formation constants for 1:1 complexes of Al(
Write conditional formation constants for 1:1 complexes of Al(III) with each of the ligands in Problem 15-11. Express these constants in terms of the α value and the formation constant and in terms of...
See AnswerQ: Write a conditional overall formation constant for [Fe(Ox)
Write a conditional overall formation constant for [Fe(Ox)3] 3− in terms of α2 for oxalic acid and the β value for the complex. Also express the conditional constant in terms of concentrations as in E...
See AnswerQ: Propose a complexometric method for the determination of the individual components in
Propose a complexometric method for the determination of the individual components in a solution containing
See AnswerQ: Given an overall complex formation reaction of / with
Given an overall complex formation reaction of with an overall formation constant of βn, show that the following relationship holds:
See AnswerQ: The sulfate ion concentration in natural water can be determined by measuring
The sulfate ion concentration in natural water can be determined by measuring the turbidity that results when an excess of BaCl2 is added to a measured quantity of the sample. A turbidimeter, the inst...
See AnswerQ: Why is a small amount of MgY2− often added to a
Why is a small amount of MgY2− often added to a water specimen that is to be titrated for hardness?
See AnswerQ: An EDTA solution was prepared by dissolving 3.426 g of
An EDTA solution was prepared by dissolving 3.426 g of purified and dried Na2H2Y · 2H2O in sufficient water to give 1.000 L. Calculate the molar concentration, given that the solute contained 0.3% exc...
See AnswerQ: A solution was prepared by dissolving about 3.0 g of
A solution was prepared by dissolving about 3.0 g of Na2H2Y⋅2H2O in approximately 1 L of water and standardizing against 50.00-mL aliquots of 0. 00397MMg2+ An average titration of 30.27 mL was require...
See AnswerQ: A solution contains 1.569 mg of CoSO4 (155.
A solution contains 1.569 mg of CoSO4 (155.0 g/mol) per milliliter. Calculate
See AnswerQ: What mass in grams of CO2 is evolved in the complete decomposition
What mass in grams of CO2 is evolved in the complete decomposition of a 2.300-g sample that is 38.0% MgCO3 and 42.0% K2CO3 by mass?
See AnswerQ: At 25°C, what is the hydronium ion concentration in
At 25°C, what is the hydronium ion concentration in a. 0.100 M chloroacetic acid? b. 0.100 M sodium chloroacetate? c. 0.0300 M methylamine? d. 0.0300 M methylamine hydrochloride? e. 1.50 3 1023 M...
See AnswerQ: The following data were obtained in calibrating a calcium ion electrode for
The following data were obtained in calibrating a calcium ion electrode for the determination of pCa. A linear relationship between the potential and pCa is known to exist. a. Plot the data, and draw...
See AnswerQ: A 6.881-g sample containing magnesium chloride and sodium
A 6.881-g sample containing magnesium chloride and sodium chloride was dissolved in sufficient water to give 500 mL of solution. Determination of the chloride content of a 50.0-mL aliquot resulted in...
See AnswerQ: Seawater contains an average of 1.08 × 103 ppm of
Seawater contains an average of 1.08 × 103 ppm of Na+ and 270 ppm of SO42-. Calculate a. The molar concentrations of Na+ and SO2- given that the average density of seawater is 1.02 g/mL. b. The pNa a...
See AnswerQ: The following are relative peak areas for chromatograms of standard solutions of
The following are relative peak areas for chromatograms of standard solutions of methyl vinyl ketone (MVK). a. Determine the coefficients of the best fit line using the least-squares method. b. Constr...
See AnswerQ: A 50.0-mL portion of a solution containing 0
A 50.0-mL portion of a solution containing 0.200 g of BaCl2 . 2H2O is mixed with 50.0 mL of a solution containing 0.300 g of NaIO3. Assume that the solubility of Ba1IO322 in water is negligibly small...
See AnswerQ: What is a buffer solution, and what are its properties?
What is a buffer solution, and what are its properties?
See AnswerQ: Define a. ligand. b. chelate.
Define a. ligand. b. chelate. c. tetradentate chelating agent. d. adsorption indicator. e. argentometric titration. f. conditional formation constant. g. EDTA displacement titration. h. water hardness...
See AnswerQ: Why are multidentate ligands preferable to unidentate ligands for complexometric titrations?
Why are multidentate ligands preferable to unidentate ligands for complexometric titrations?
See AnswerQ: The data in the following table were obtained during a colorimetric determination
The data in the following table were obtained during a colorimetric determination of glucose in blood serum. a. Assuming a linear relationship between the variables, find the least-squares estimates o...
See AnswerQ: Describe three general methods for performing EDTA titrations. What are the
Describe three general methods for performing EDTA titrations. What are the advantages of each?
See AnswerQ: When a 100.0-mL portion of a solution containing
When a 100.0-mL portion of a solution containing 0.500 g of AgNO3 is mixed with 100.0 mL of a solution containing 0.300 g of K2CrO4, a bright red precipitate of Ag2CrO4 forms. a. Assuming that the so...
See AnswerQ: Write chemical equations and equilibrium-constant expressions for the stepwise
Write chemical equations and equilibrium-constant expressions for the stepwise formation of
See AnswerQ: Explain how stepwise and overall formation constants are related.
Explain how stepwise and overall formation constants are related.
See AnswerQ: Write chemical formulas for the following complex ions:
Write chemical formulas for the following complex ions:
See AnswerQ: In what respect is the Fajans method superior to the Volhard method
In what respect is the Fajans method superior to the Volhard method for the titration of chloride ion?
See AnswerQ: The standard electrode potential for the reduction of Ni2+ to Ni
The standard electrode potential for the reduction of Ni2+ to Ni is −. 0 25 V. Would the potential of a nickel electrode immersed in a 1.00 M NaOH solution saturated with Ni(OH 2) be more negative tha...
See AnswerQ: Write balanced net ionic equations for the following reactions. Supply H
Write balanced net ionic equations for the following reactions. Supply H+ and/or H O2 as needed to obtain balance.
See AnswerQ: Identify the oxidizing agent and the reducing agent on the left side
Identify the oxidizing agent and the reducing agent on the left side of each equation in Problem 16-7; write a balanced equation for each half-reaction.
See AnswerQ: Average human blood contains 300 nmoles of hemoglobin(Hb) per
Average human blood contains 300 nmoles of hemoglobin(Hb) per liter of plasma and 2.2 mmol per liter of whole blood. Calculate a. The molar concentration in each of these media. b. pHb in plasma in hu...
See AnswerQ: Write balanced net ionic equations for the following reactions. Supply H
Write balanced net ionic equations for the following reactions. Supply H+ and/or H O2 as needed to obtain balance.
See AnswerQ: Generate the solubility-product expression for a. CuBr.
Generate the solubility-product expression for a. CuBr. b. MgCO3. C. PbCl2. d. CaSO4. e. Ag3AsO4.
See AnswerQ: Calculate the solubility of the solutes in Problem 7-10 for
Calculate the solubility of the solutes in Problem 7-10 for solutions in which the anion concentration is 0.030 M.
See AnswerQ: Identify the oxidizing agent and the reducing agent on the left side
Identify the oxidizing agent and the reducing agent on the left side of each equation in Problem 16-9; write a balanced equation for each half-reaction.
See AnswerQ: Consider the following oxidation/reduction reactions: / a
Consider the following oxidation/reduction reactions: a. Write each net process in terms of two balanced half-reactions. b. Express each half-reaction as a reduction. c. Arrange the half-reactions in...
See AnswerQ: Consider the following oxidation/reduction reactions: / a
Consider the following oxidation/reduction reactions: a. Write each net process in terms of two balanced half-reactions. b. Express each half-reaction as a reduction. c. Arrange the half-reactions in...
See AnswerQ: Calculate the potential of a copper electrode immersed in /
Calculate the potential of a copper electrode immersed in
See AnswerQ: Calculate the potential of a zinc electrode immersed in /
Calculate the potential of a zinc electrode immersed in
See AnswerQ: Use activities to calculate the electrode potential of a hydrogen electrode in
Use activities to calculate the electrode potential of a hydrogen electrode in which the electrolyte is 0.0200 M HCl and the activity of H2 is 1.00 atm.
See AnswerQ: calculate the potential of a platinum electrode immersed in a solution that
calculate the potential of a platinum electrode immersed in a solution that is a. 0.0160 M in K2PtCl4 and 0.2450 M in KCl. b. 0.0650 M in Sn1SO422 and 3.5 3 1023 M in SnSO4. c. buffered to a pH...
See AnswerQ: calculate the potential of a platinum electrode immersed in a solution that
calculate the potential of a platinum electrode immersed in a solution that is a. 0.0513 M in K4Fe1CN26 and 0.00589 M in K3Fe1CN26. b. 0.0300 M in FeSO4 and 0.00825 M in Fe21SO423. c. buffered to...
See AnswerQ: If the following half-cells are the right-hand electrode
If the following half-cells are the right-hand electrode in a galvanic cell with a standard hydrogen electrode on the left, calculate the cell potential. If the cell were shorted, indicate whether the...
See AnswerQ: What mass of Cu1IO322 can be formed from 0.475 g
What mass of Cu1IO322 can be formed from 0.475 g of CuSO4 5H2O?
See AnswerQ: Define a. Digestion. b. Adsorption.
Define a. Digestion. b. Adsorption. c. Reprecipitation. d. Precipitation from homogeneous solution. e. Counter-ion layer. f. Mother liquor. g. Supersaturation.
See AnswerQ: The data in the following table represent electrode potential E versus concentration
The data in the following table represent electrode potential E versus concentration c. a. Transform the data to E versus 2log c values. b. Plot E versus 2log c, and find the least-squares estimate of...
See AnswerQ: The following half-cells are on the left and coupled with
The following half-cells are on the left and coupled with the standard hydrogen electrode on the right to form a galvanic cell. Calculate the cell potential. Indicate which electrode would be the cath...
See AnswerQ: The solubility-product constant for Ag2SO3 is 1.5 3
The solubility-product constant for Ag2SO3 is 1.5 3 10214. Calculate E0 for the process
See AnswerQ: The solubility-product constant for The solubility-product constant for
The solubility-product constant for The solubility-product constant for Ni2P2O7 is 1.7 3 10213. Calculate E0 for the process
See AnswerQ: For a Pt |Fe3+,Fe2+ half-cell,
For a Pt |Fe3+,Fe2+ half-cell, find the potential for the following ratios of [Fe3+]/[ Fe2+]. 0.001, 0.0025, 0.005, 0.0075, 0.010, 0.025, 0.050, 0.075, 0.100, 0.250, 0.500, 0.750, 1.00, 1.250, 1.50, 1...
See AnswerQ: Explain the difference between a. A colloidal and a crystalline
Explain the difference between a. A colloidal and a crystalline precipitate. b. A gravimetric precipitation method and a gravimetric volatilization method. c. Precipitation and coprecipitation. d....
See AnswerQ: For a Pt │Ce4+, Ce3+ half-cell,
For a Pt │Ce4+, Ce3+ half-cell, find the potential for the same ratios of [Ce4+]/[Ce3+] as given in Problem 16-27 for [Fe3+]/[Fe2+].
See AnswerQ: A study was made to determine the activation energy EA for a
A study was made to determine the activation energy EA for a chemical reaction. The rate constant k was determined as a function of temperature T, and the data in the following table were obtained. T...
See AnswerQ: A solution was prepared by dissolving 5.76 g of KCl
A solution was prepared by dissolving 5.76 g of KCl .MgCl2 . 6H2O (277.85 g/mol) in sufficient water to give 2.000 L. Calculate a. The molar analytical concentration of KCl . MgCl2 in this solution. b...
See AnswerQ: Plot the half-cell potential versus concentration ratio for the half
Plot the half-cell potential versus concentration ratio for the half-cells of Problems 16-27 and 16-28. How would the plot look if potential were plotted against log(concentration ratio)?
See AnswerQ: Briefly describe or define a. oxidation. b
Briefly describe or define a. oxidation. b. liquid junction. c. salt bridge. d. reductant. e. Nernst equation.
See AnswerQ: Briefly describe or define a. electrode potential.
Briefly describe or define a. electrode potential. b. formal potential. d. standard electrode potential. d. liquid junction potential. e. oxidation potential.
See AnswerQ: Make a clear distinction between a. oxidation and oxidizing agent
Make a clear distinction between a. oxidation and oxidizing agent. b. an electrolytic cell and a galvanic cell. c. the cathode of an electrochemical cell and the right-hand electrode. d. a rever...
See AnswerQ: The following entries are found in a table of standard electrode potentials
The following entries are found in a table of standard electrode potentials: What is the significance of the difference between these two standard potentials?
See AnswerQ: Why is it necessary to bubble hydrogen through the electrolyte in a
Why is it necessary to bubble hydrogen through the electrolyte in a hydrogen electrode?
See AnswerQ: Calculate the theoretical potential of the following cells. Indicate whether the
Calculate the theoretical potential of the following cells. Indicate whether the reaction will proceed spontaneously in the direction considered (oxidation on the left; reduction on the right) or whet...
See AnswerQ: Calculate the theoretical cell potential of the following cells. If the
Calculate the theoretical cell potential of the following cells. If the cell is short-circuited, indicate the direction of the spontaneous cell reaction
See AnswerQ: Calculate the potential of the following two half-cells that are
Calculate the potential of the following two half-cells that are connected by a salt bridge: a. a galvanic cell consisting of a lead electrode (right electrode) immersed in 0.0250 M Pb21 and a zinc e...
See AnswerQ: Water can be determined in solid samples by infrared spectroscopy. The
Water can be determined in solid samples by infrared spectroscopy. The water content of calcium sulfate hydrates is to be measured using calcium carbonate as an internal standard to compensate for som...
See AnswerQ: Use the shorthand notation (page 415) to describe the cells
Use the shorthand notation (page 415) to describe the cells in Problem 17-9. Each cell is supplied with a salt bridge to provide electrical contact between the solutions in the two cell compartments....
See AnswerQ: Which has the greater buffer capacity: (a) a mixture
Which has the greater buffer capacity: (a) a mixture containing 0.100 mol of NH3 and 0.200 mol of NH4Cl or (b) a mixture containing 0.0500 mol of NH3 and 0.100 mol of NH4Cl?
See AnswerQ: Generate equilibrium-constant expressions for the following reactions. Calculate numerical
Generate equilibrium-constant expressions for the following reactions. Calculate numerical values for Keq.
See AnswerQ: Calculate the electrode potential of the system at the equivalence point for
Calculate the electrode potential of the system at the equivalence point for each of the reactions in Problem 17-11. Use 0.100 M where a value for [H+] is needed and is not otherwise specified.
See AnswerQ: If you start with 0.1000 M solutions and the first
If you start with 0.1000 M solutions and the first-named species is the titrant, what will be the concentration of each reactant and product at the equivalence point of titrations (a), (c), (f), and (...
See AnswerQ: Select an indicator from Table 17-3 that might be suitable
Select an indicator from Table 17-3 that might be suitable for each of the titrations in Problem 17-11. Write NONE if no indicator listed in Table 17-3 is suitable.
See AnswerQ: Use a spreadsheet, and construct curves for the following titrations.
Use a spreadsheet, and construct curves for the following titrations. Calculate potentials after the addition of 10.00, 25.00, 49.00, 49.90, 50.00, 50.10, 51.00, and 60.00 mL of the reagent. Where nec...
See AnswerQ: How can the relative supersaturation be varied during precipitate formation?
How can the relative supersaturation be varied during precipitate formation?
See AnswerQ: Use a spreadsheet, and construct curves for the following titrations.
Use a spreadsheet, and construct curves for the following titrations. Calculate potentials after the addition of 10.00, 25.00, 49.00, 49.90, 50.00, 50.10, 51.00, and 60.00 mL of the reagent. Where nec...
See AnswerQ: Briefly define the electrode potential of a system that contains two or
Briefly define the electrode potential of a system that contains two or more redox couples.
See AnswerQ: For an oxidation/reduction titration, briefly distinguish between a
For an oxidation/reduction titration, briefly distinguish between a. equilibrium and equivalence. b. a true oxidation/reduction indicator and a specific indicator.?
See AnswerQ: The level of a pollutant in a river adjacent to a chemical
The level of a pollutant in a river adjacent to a chemical plant is regularly monitored. Over a period of years, the normal level of the pollutant has been established by chemical analyses. Recently,...
See AnswerQ: Potassium can be determined by flame emission spectrometry (flame photometry)
Potassium can be determined by flame emission spectrometry (flame photometry) using a lithium internal standard. The following data were obtained for standard solutions of KCl and an unknown containin...
See AnswerQ: What is unique about the condition of equilibrium in an oxidation/
What is unique about the condition of equilibrium in an oxidation/reduction reaction?
See AnswerQ: How is an oxidation/reduction titration curve generated through the use
How is an oxidation/reduction titration curve generated through the use of standard electrode potentials for the analyte species and the volumetric titrant?
See AnswerQ: A solution was prepared by dissolving 875 mg of K3Fe(CN
A solution was prepared by dissolving 875 mg of K3Fe(CN)6 (329.2 g/mol) in sufficient water to give750 mL. Calculate a. The molar analytical concentration of K3Fe(CN)6. b. The molar concentration of K...
See AnswerQ: How does calculation of the electrode potential of the system at the
How does calculation of the electrode potential of the system at the equivalence point differ from that for any other point of an oxidation/reduction titration?
See AnswerQ: Under what circumstance is the curve for an oxidation/reduction titration
Under what circumstance is the curve for an oxidation/reduction titration asymmetric about the equivalence point?
See AnswerQ: Four different fluorescence flow cell designs were compared to see if they
Four different fluorescence flow cell designs were compared to see if they were significantly different. The following results represented relative fluorescence intensities for four replicate measurem...
See AnswerQ: Calculate the theoretical potential of the following cells. Indicate whether the
Calculate the theoretical potential of the following cells. Indicate whether the reaction will proceed spontaneously in the direction considered (oxidation on the left; reduction on the right) or whet...
See AnswerQ: Calculate the theoretical cell potential of the following cells. If the
Calculate the theoretical cell potential of the following cells. If the cell is short-circuited, indicate the direction of the spontaneous cell reaction. Zn | Zn2+ (0.1000 M) || Co2+ (5.87 Ã&...
See AnswerQ: Calculate the potential of the following two half-cells that are
Calculate the potential of the following two half-cells that are connected by a salt bridge: a. A galvanic cell consisting of a lead electrode (right electrode) immersed in 0.0250 M Pb2+ and a zinc el...
See AnswerQ: Use the shorthand notation (page 415) to describe the cells
Use the shorthand notation (page 415) to describe the cells in Problem 17-9. Each cell is supplied with a salt bridge to provide electrical contact between the solutions in the two cell compartments....
See AnswerQ: Generate equilibrium-constant expressions for the following reactions. Calculate numerical
Generate equilibrium-constant expressions for the following reactions. Calculate numerical values for Keq.
See AnswerQ: Copper was determined in a river water sample by atomic absorption spectrometry
Copper was determined in a river water sample by atomic absorption spectrometry and the method of standard additions. For the addition, 100.0μL of a 1000.0-μg/mL Cu standard was added to 100.0 mL of...
See AnswerQ: Calculate the electrode potential of the system at the equivalence point for
Calculate the electrode potential of the system at the equivalence point for each of the reactions in Problem 17-11. Use 0.100 M where a value for [H+] is needed and is not otherwise specified.
See AnswerQ: If you start with 0.1000 M solutions and the first
If you start with 0.1000 M solutions and the first-named species is the titrant, what will be the concentration of each reactant and product at the equivalence point of titrations (a), (c), (f), and (...
See AnswerQ: If you start with 0.1000 M solutions and the first
If you start with 0.1000 M solutions and the first-named species is the titrant, what will be the concentration of each reactant and product at the equivalence point of titrations (a), (c), (f), and (...
See AnswerQ: Consider solutions prepared by a. Dissolving 8.00 mmol
Consider solutions prepared by a. Dissolving 8.00 mmol of NaOAc in 200 mL of 0.100 M HOAc. b. Adding 100 mL of 0.0500 M NaOH to 100 mL of 0.175 M HOAc. c. Adding 40.0 mL of 0.1200 M HCl to 160.0 mL...
See AnswerQ: An aqueous solution contains NaNO3 and KBr. The bromide ion is
An aqueous solution contains NaNO3 and KBr. The bromide ion is precipitated as AgBr by addition of AgNO3. After an excess of the precipitating reagent has been added, a. What is the charge on the sur...
See AnswerQ: Select an indicator from Table 17-3 that might be suitable
Select an indicator from Table 17-3 that might be suitable for each of the titrations in Problem 17-11. Write NONE if no indicator listed in Table 17-3 is suitable.
See AnswerQ: Use a spreadsheet, and construct curves for the following titrations.
Use a spreadsheet, and construct curves for the following titrations. Calculate potentials after the addition of 10.00, 25.00, 49.00, 49.90, 50.00, 50.10, 51.00, and 60.00 mL of the reagent. Where nec...
See AnswerQ: For an oxidation/reduction titration, briefly distinguish between a
For an oxidation/reduction titration, briefly distinguish between a. Equilibrium and equivalence. b. A true oxidation/reduction indicator and a specific indicator.
See AnswerQ: How is an oxidation/reduction titration curve generated through the use
How is an oxidation/reduction titration curve generated through the use of standard electrode potentials for the analyte species and the volumetric titrant?
See AnswerQ: The method of standard additions was used to determine nitrite in a
The method of standard additions was used to determine nitrite in a soil sample. A 1.00-mL portion of the sample was mixed with 24.00 mL of a colorimetric reagent, and the nitrite was converted to a c...
See AnswerQ: How does calculation of the electrode potential of the system at the
How does calculation of the electrode potential of the system at the equivalence point differ from that for any other point of an oxidation/reduction titration?
See AnswerQ: Under what circumstance is the curve for an oxidation/reduction titration
Under what circumstance is the curve for an oxidation/reduction titration asymmetric about the equivalence point?
See AnswerQ: Why are KMnO4 solutions filtered before they are standardized?
Why are KMnO4 solutions filtered before they are standardized?
See AnswerQ: Briefly explain why the concentration units of milligrams of solute per liter
Briefly explain why the concentration units of milligrams of solute per liter and parts per million can be used interchangeably for a dilute aqueous solution.
See AnswerQ: Why are solutions of KMnO4 and Na2S2O3 generally stored in dark reagent
Why are solutions of KMnO4 and Na2S2O3 generally stored in dark reagent bottles? Answer Standard permanganate and thiosulfate solutions are generally stored in the dark because their decomposition...
See AnswerQ: Briefly explain why there is no term in an equilibrium constant expression
Briefly explain why there is no term in an equilibrium constant expression for water or for a pure solid, even though one (or both) appears in the balanced net ionic equation for the equilibrium.
See AnswerQ: A 5.85% (w/w) Fe(
A 5.85% (w/w) Fe(NO3)3 (241.86 g/mol) solution has a density of 1.059 g/mL. Calculate a. The molar analytical concentration of Fe(NO3)3 in this solution. b. The molar NO3- concentration in the solutio...
See AnswerQ: What is the primary use of standard K2Cr2O7 solutions?
What is the primary use of standard K2Cr2O7 solutions?
See AnswerQ: A standard solution of 2I increased in concentration with standing. Write
A standard solution of 2I increased in concentration with standing. Write a balanced net ionic equation that accounts for the increase.
See AnswerQ: Suggest a way in which a solution of 3 KIO could be
Suggest a way in which a solution of 3 KIO could be used as a source of known quantities of 2I .
See AnswerQ: Write balanced equations showing how 2 2 K Cr O could be
Write balanced equations showing how 2 2 K Cr O could be used as a primary standard for solutions of 7Na S O 2+3.
See AnswerQ: The following atomic absorption results were obtained for determinations of Zn in
The following atomic absorption results were obtained for determinations of Zn in multivitamin tablets. All absorbance values are corrected for the appropriate reagent blank (cZn = 0.0 ng/mL). The mea...
See AnswerQ: In the titration of 2I solutions with Na S O 2+
In the titration of 2I solutions with Na S O 2+ 3 , the starch indicator is never added until just before chemical equivalence. Why?
See AnswerQ: A solution prepared by dissolving a 0.2541-g sample
A solution prepared by dissolving a 0.2541-g sample of electrolytic iron wire in acid was passed through a Jones reductor. The iron(II) in the resulting solution required a 36.76-mL titration. Calcula...
See AnswerQ: Calculations of volumetric analysis ordinarily consist of transforming the quantity of titrant
Calculations of volumetric analysis ordinarily consist of transforming the quantity of titrant used (in chemical units) to a chemically equivalent quantity of analyte (also in chemical units) through...
See AnswerQ: Why are KMnO4 solutions filtered before they are standardized?
Why are KMnO4 solutions filtered before they are standardized?
See AnswerQ: How would you prepare 2.0 L of approximately 0.
How would you prepare 2.0 L of approximately 0.04 M I3 solution? Calculate the molar concentration of 4 KMnO in this solution.
See AnswerQ: How would you prepare 1.000 L of 0.05000
How would you prepare 1.000 L of 0.05000 M KBrO3?
See AnswerQ: A 0.2219-g sample of pure iron wire was
A 0.2219-g sample of pure iron wire was dissolved in acid, reduced to the +2 state, and titrated with 34.65 mL of cerium (IV). Calculate the molar concentration of the 4 Ce +solution.
See AnswerQ: Consult Appendix 3, and pick out a suitable acid-base
Consult Appendix 3, and pick out a suitable acid-base pair to prepare a buffer with a pH of a. 10.3. b. 6.1. c. 4.5. d. 8.1.
See AnswerQ: A 0.1853-g sample of 3 KBrO was dissolved
A 0.1853-g sample of 3 KBrO was dissolved in dilute HCl and treated with an unmeasured excess of KI. The liberated iodine required 44.36 mL of a sodium thiosulfate solution. Calculate the molar concen...
See AnswerQ: Calculate the percentage of MnO2 in a mineral specimen if the 2I
Calculate the percentage of MnO2 in a mineral specimen if the 2I liberated by a 0.1267-g sample in the net reaction
See AnswerQ: There is 0.5690-g specimen of iron ore was
There is 0.5690-g specimen of iron ore was dissolved and passed through a Jones reductor. Titration of the Fe(II) produced required 38.79 mL of 0.01926 M KMnO4. Express the results of this analysis in...
See AnswerQ: Atomic emission measurements were made to determine sodium in a blood serum
Atomic emission measurements were made to determine sodium in a blood serum sample. The following emission intensities were obtained for standards of 5.0 and 10.0 ng/mL and for the serum sample. All e...
See AnswerQ: Treatment of hydroxylamine 2 (H NOH) with an excess of
Treatment of hydroxylamine 2 (H NOH) with an excess of Fe(III) results in the formation of N O2 and an equivalent amount of Fe(II): Calculate the molar concentration of an H N2 OH solution if the Fe(...
See AnswerQ: How many millimoles of solute are contained in a. 2
How many millimoles of solute are contained in a. 2.00 L of 2.76 3 1023 M KMnO4? b. 250.0 mL of 0.0423 M KSCN? c. 500.0 mL of a solution containing 2.97 ppm CuSO4? d. 2.50 L of 0.352 M KCl?
See AnswerQ: The 3 KClO in a 0.1791-g sample of
The 3 KClO in a 0.1791-g sample of an explosive was determined by reaction with 50.00 mL of 0 0. 873 2 MFe + When the reaction was complete, the excess 2 Fe + was back-titrated with 14.95 mL of 4 0 06...
See AnswerQ: An 8.13-g sample of an ant-control
An 8.13-g sample of an ant-control preparation was decomposed by wet ashing with H2SO4 and HNO3. The As in the residue was reduced to the trivalent state with hydrazine. After removal of the excess re...
See AnswerQ: The ethyl mercaptan concentration in a mixture was determined by shaking a
The ethyl mercaptan concentration in a mixture was determined by shaking a 1.795-g sample with 50.00 mL of 2 0 01204 MI. in a tightly stoppered flask: The excess 2I was back-titrated with 15.21 mL of...
See AnswerQ: A sensitive method for I− in the presence of CI−
A sensitive method for I− in the presence of CI− and Br− entails oxidation of the I− to IO3−with Br2. The excess Br2 is then removed by boiling or by reduction with formate ion. The IO3− produced is d...
See AnswerQ: A 2.552-g sample containing both Fe and V
A 2.552-g sample containing both Fe and V was dissolved under conditions that converted the elements to Fe(III) and V(V). The solution was diluted to 500.0 mL, and a 50.00-mL aliquot was passed throug...
See AnswerQ: A gas mixture was passed at the rate of 2.50
A gas mixture was passed at the rate of 2.50 L/min through a solution of sodium hydroxide for a total of 59.00 min. The 2 SO in the mixture was retained as sulfite ion: After acidification with HCl, t...
See AnswerQ: A 11.4% (w/w) NiCl2 (
A 11.4% (w/w) NiCl2 (129.61 g/mol) solution has a density of 1.149 g/mL. Calculate a. The molar concentration of NiCl2 in this solution. b. The molar Cl2 concentration of the solution. c. The mass in...
See AnswerQ: Use a spreadsheet to do the calculations and plot the titration curves
Use a spreadsheet to do the calculations and plot the titration curves for the following titrations. Calculate potentials after the addition of titrant corresponding to 10%, 20%, 30%, 40%, 50%, 60%, 7...
See AnswerQ: Write balanced net ionic equations to describe
Write balanced net ionic equations to describe
See AnswerQ: The following data represent measurements made on a process for 30 days
The following data represent measurements made on a process for 30 days. One measurement was made each day. Assuming that 30 measurements are enough that x S m and s S s, find the mean of the values,...
See AnswerQ: How many millimoles of solute are contained in a. 2
How many millimoles of solute are contained in a. 2.95 mL of 0.0789 M KH2PO4? b. 0.2011 L of 0.0564 M HgCl2? c. 2.56 L of a 47.5 ppm solution of Mg1NO322? d. 79.8 mL of 0.1379 M NH4VO3 1116.98 g>mo...
See AnswerQ: Why is a Walden reductor always used with solutions that contain appreciable
Why is a Walden reductor always used with solutions that contain appreciable concentrations of HCl?
See AnswerQ: Write a balanced net ionic equation for the reduction of UO22+
Write a balanced net ionic equation for the reduction of UO22+ in a Walden reductor.
See AnswerQ: Why are standard solutions of reductants less often used for titrations than
Why are standard solutions of reductants less often used for titrations than standard solutions of oxidants?
See AnswerQ: Why are Ce4+ solutions never used for the titration of reductants
Why are Ce4+ solutions never used for the titration of reductants in basic solutions?
See AnswerQ: Why are Ce4+ solutions never used for the titration of reductants
Why are Ce4+ solutions never used for the titration of reductants in basic solutions?
See AnswerQ: What mass of sodium formate must be added to 500.0
What mass of sodium formate must be added to 500.0 mL of 1.00 M formic acid to produce a buffer solution that has a pH of 3.75?
See AnswerQ: Describe the preparation of a. 500 mL of 5.
Describe the preparation of a. 500 mL of 5.25% (w/v) aqueous ethanol (C2H5OH, 46.1 g/mol). b. 500 g of 5.25% (w/w) aqueous ethanol. c. 500 mL of 5.25% (v/v) aqueous ethanol.
See AnswerQ: What mass of sodium glycolate should be added to 400.0
What mass of sodium glycolate should be added to 400.0 mL of 1.00 M glycolic acid to produce a buffer solution with a pH of 4.25?
See AnswerQ: Describe the preparation of a. 1.50 L of
Describe the preparation of a. 1.50 L of 21.0% (w/v) aqueous glycerol (C3H8O3, 92.1 g/mol). b. 1.50 kg of 21.0% (w/w) aqueous glycerol. c. 1.50 L of 21.0% (v/v) aqueous glycerol.
See AnswerQ: What volume of 0.200 M HCl must be added to
What volume of 0.200 M HCl must be added to 500.0 mL of 0.300 M sodium mandelate to produce a buffer solution with a pH of 3.25?
See AnswerQ: What mass of KIO3 is needed to convert the copper in 0
What mass of KIO3 is needed to convert the copper in 0.1570 g of CuSO4 . 5H2O to Cu1IO322?
See AnswerQ: What mass of solute in milligrams is contained in a.
What mass of solute in milligrams is contained in a. 26.0 mL of 0.250 M sucrose (342 g/mol)? b. 2.92 L of 5.23 3 1024 M H2O2? c. 673 mL of a solution that contains 5.76 ppm Pb1NO322 1331.20 g>mol2?...
See AnswerQ: The following table gives the sample means and standard deviations for six
The following table gives the sample means and standard deviations for six measurements each day of the purity of a polymer in a process. The purity is monitored for 24 days. Determine the overall mea...
See AnswerQ: Describe the preparation of 500 mL of 3.00 M H3PO4from
Describe the preparation of 500 mL of 3.00 M H3PO4from the commercial reagent that is 86% H3PO4(w/w) and has a specific gravity of 1.71.
See AnswerQ: What volume of 2.00 M NaOH must be added to
What volume of 2.00 M NaOH must be added to 200.0 mL of 1.00 M glycolic acid to produce a buffer solution having a pH of 4.15?
See AnswerQ: Give two examples of units derived from the fundamental base SI units
Give two examples of units derived from the fundamental base SI units.
See AnswerQ: Describe the preparation of 750 mL of 3.00 M HNO3
Describe the preparation of 750 mL of 3.00 M HNO3 from the commercial reagent that is 70.5% HNO3 (w/w) and has a specific gravity of 1.42.
See AnswerQ: Is the following statement true or false or both? Define your
Is the following statement true or false or both? Define your answer with equations, examples, or graphs. “A buffer maintains the pH of a solution constant.”
See AnswerQ: Describe the preparation of a. 500 mL of 0.
Describe the preparation of a. 500 mL of 0.1000 M AgNO3 from the solid reagent. b. 1.00 L of 0.1000 M HCl, starting with a 6.00 M solution of the reagent. c. 250 mL of a solution that is 0.0810 M in K...
See AnswerQ: Describe the preparation of a. 2.50 L of
Describe the preparation of a. 2.50 L of 0.0250 M KMnO4 from the solid reagent. b. 4.00 L of 0.250 M HClO4, starting with an 8.00 M solution of the reagent. c. 500 mL of a solution that is 0.0200 M in...
See AnswerQ: What mass of solid La(IO3)3 (663.
What mass of solid La(IO3)3 (663.6 g/mol) is formed when 50.0 mL of 0.250 M La3+ is mixed with 75.0 mL of 0.302 M IO3-?
See AnswerQ: What mass of solid PbCl2 (278.10 g/mol
What mass of solid PbCl2 (278.10 g/mol) is formed when 200 mL of 0.125 M Pb2+ is mixed with 400 mL of 0.175 M Cl?
See AnswerQ: Find the number of millimoles of solute in a. 386
Find the number of millimoles of solute in a. 386 mL of 0.210 M HClO4. b. 25.0 L of 8.05 × 10-3 M K2CrO4. c. 4.50 L of an aqueous solution that contains 6.95 ppm of AgNO3. d. 537 mL of 0.0200 M KOH.
See AnswerQ: Exactly 0.118 g of pure Na2CO3 is dissolved in 100
Exactly 0.118 g of pure Na2CO3 is dissolved in 100.0 mL of 0.0731 M HCl. a. What mass in grams of CO2 is evolved? b. What is the molar concentration of the excess reactant (HCl or Na2CO3)?
See AnswerQ: Find the number of K+ ions in 1.43 mole
Find the number of K+ ions in 1.43 mole of K2HPO4?
See AnswerQ: Exactly 25.0 mL of a 0.3757 M solution
Exactly 25.0 mL of a 0.3757 M solution of Na3PO4 is mixed with 100.00 mL of 0.5151 M HgNO3. a. What mass of solid Hg3PO4 is formed? b. What is the molar concentration of the unreacted species (Na3PO4...
See AnswerQ: Exactly 75.00 mL of a 0.3132 M solution
Exactly 75.00 mL of a 0.3132 M solution of Na2SO3 is treated with 150.0 mL of 0.4025 M HClO4 and boiled to remove the SO2 formed. a. What is the mass in grams of SO2 that is evolved? b. What is the co...
See AnswerQ: What mass of MgNH4PO4 precipitates when 200.0 mL of a
What mass of MgNH4PO4 precipitates when 200.0 mL of a 1.000% (w/v) solution of MgCl2 is treated with 40.0 mL of 0.1753 M Na3PO4 and an excess of NH4+? What is the molar concentration of the excess rea...
See AnswerQ: Identify the acid on the left and its conjugate base on the
Identify the acid on the left and its conjugate base on the right in the following equations:
See AnswerQ: What volume of 0.01000 M AgNO3 is required to precipitate
What volume of 0.01000 M AgNO3 is required to precipitate all of the I- in 150 mL of a solution that contains 22.50 ppt KI?
See AnswerQ: Exactly 750.0 mL of a solution that contains 500.
Exactly 750.0 mL of a solution that contains 500.0 ppm of Ba(NO3)2 is mixed with 200.0 mL of a solution that was 0.04100 M in Al2(SO4)3. a. What mass of solid BaSO4 is formed? b. What is the molar con...
See AnswerQ: Describe at least three systematic errors that might occur while weighing a
Describe at least three systematic errors that might occur while weighing a solid on an analytical balance.
See AnswerQ: Describe at least three ways in which a systematic error might occur
Describe at least three ways in which a systematic error might occur while using a pipet to transfer a known volume of liquid.
See AnswerQ: What mass of solute in grams is contained in a.
What mass of solute in grams is contained in a. 450.0 mL of 0.0986 M H2O2? b. 26.4 mL of 9.36 3 1024 M benzoic acid (122.1 g/mol)? c. 2.50 L of a solution that contains 23.4 ppm SnCl2? d. 21.7 mL o...
See AnswerQ: Describe how systematic method errors may be detected.
Describe how systematic method errors may be detected.
See AnswerQ: What kind of systematic errors are detected by varying the sample size
What kind of systematic errors are detected by varying the sample size?
See AnswerQ: A 0.005-g sample of a rock is to
A 0.005-g sample of a rock is to be analyzed, and iron is to be determined at the ppm level. Determine the type of analysis and type of constituent.
See AnswerQ: A method of analysis yields masses of gold that are low by
A method of analysis yields masses of gold that are low by 0.4 mg. Calculate the percent relative error caused by this result if the mass of gold in the sample is a. 500 mg. b. 250 mg. c. 125 mg....
See AnswerQ: The method described in Problem 3-8 is to be used
The method described in Problem 3-8 is to be used for the analysis of ores that assay about 1.2% gold. What minimum sample mass should be taken if the relative error resulting from a 0.4-mg loss is no...
See AnswerQ: The color change of a chemical indicator requires an overtitration of 0
The color change of a chemical indicator requires an overtitration of 0.03 mL. Calculate the percent relative error if the total volume of titrant is a 50.00 mL. b 10.0 mL. c 25.0 mL. d 30.0 mL
See AnswerQ: A loss of 0.4 mg of Zn occurs in
A loss of 0.4 mg of Zn occurs in the course of an analysis for that element. Calculate the percent relative error due to this loss if the mass of Zn in the sample is a 30 mg. b 100 mg. c 300 mg....
See AnswerQ: Simplify the following quantities using a unit with an appropriate prefix:
Simplify the following quantities using a unit with an appropriate prefix: a. 5.8 × 108 Hz. b. 4.37 × 1027 g. c. 9.31 × 107 mmol. d. 8.3 ×1010 s. e. 3.96 × 106 nm. f. 53,000 g.
See AnswerQ: Find the mean and median of each of the following sets of
Find the mean and median of each of the following sets of data. Determine the deviation from the mean for each data point within the sets, and find the mean deviation for each set. Use a spreadsheet i...
See AnswerQ: Explain the difference between a. random and systematic error.
Explain the difference between a. random and systematic error. b. constant and proportional error. c. absolute and relative error. d. mean and median.
See AnswerQ: Calculate the molar concentration of a solution that is 50.0
Calculate the molar concentration of a solution that is 50.0% NaOH (w/w) and has a specific gravity of 1.52.
See AnswerQ: Suggest two sources of systematic error and two sources of random error
Suggest two sources of systematic error and two sources of random error in measuring the length of a 3-m table with a 1-m metal rule.
See AnswerQ: Estimate the absolute deviation and the coefficient of variation for the results
Estimate the absolute deviation and the coefficient of variation for the results of the following calculations. Round each result so that it contains only significant digits. The numbers in parenthese...
See AnswerQ: What is the object of the sampling step in an analysis?
What is the object of the sampling step in an analysis?
See AnswerQ: The color change of a chemical indicator requires an overtitration of 0
The color change of a chemical indicator requires an overtitration of 0.03 mL. Calculate the percent relative error if the total volume of titrant is
See AnswerQ: Calculate the absolute standard deviation and the coefficient of variation for the
Calculate the absolute standard deviation and the coefficient of variation for the results of the following calculations. Round each result to include only significant figures. The numbers in parenthe...
See AnswerQ: Define a. Sample standard deviation. b. Coefficient
Define a. Sample standard deviation. b. Coefficient of variation. c. Variance. d. Standard error of the mean.
See AnswerQ: The standard deviation in measuring the diameter d of a sphere is
The standard deviation in measuring the diameter d of a sphere is ±0.02 cm. What is the standard deviation in the calculated volume V of the sphere if d = 2.35 cm?
See AnswerQ: Chapter 26 describes inductively coupled plasma atomic emission spectrometry. In that
Chapter 26 describes inductively coupled plasma atomic emission spectrometry. In that method, the number of atoms excited to a particular energy level is a strong function of temperature. For an eleme...
See AnswerQ: Identify the base on the left and its conjugate acid on the
Identify the base on the left and its conjugate acid on the right in the equations for Problem 7-4.
See AnswerQ: Calculate the molar concentration of a 20.0% solution (
Calculate the molar concentration of a 20.0% solution (w/w) of KCl that has
See AnswerQ: Chapter 22 shows that quantitative molecular absorption spectrometry is based on Beer’s
Chapter 22 shows that quantitative molecular absorption spectrometry is based on Beer’s law, which can be written as -log T = εbcX where T is the transmittance of a solution of an analyte X, b is the...
See AnswerQ: Analysis of several plant-food preparations for potassium ion yielded the
Analysis of several plant-food preparations for potassium ion yielded the following data: The preparations were randomly drawn from the same population. Find the mean and standard devia...
See AnswerQ: Six bottles of wine of the same variety were analyzed for residual
Six bottles of wine of the same variety were analyzed for residual sugar content with the following results: / Evaluate the standard deviation s for each set of data. Pool t...
See AnswerQ: In a volumetric determination of an analyte A, the data obtained
In a volumetric determination of an analyte A, the data obtained and their standard deviations are as follows: From the data, find the coefficient of variation of the final result for the %A that is o...
See AnswerQ: State quantitatively the null hypothesis H0 and the alternative hypothesis Ha for
State quantitatively the null hypothesis H0 and the alternative hypothesis Ha for the following situations, and describe the type I and type II errors. If these hypotheses were to be tested statistica...
See AnswerQ: Describe the steps in a sampling operation.
Describe the steps in a sampling operation.
See AnswerQ: Nine samples of illicit heroin preparations were analyzed in duplicate by a
Nine samples of illicit heroin preparations were analyzed in duplicate by a gas chromatographic method. The samples can be assumed to have been drawn randomly from the same population. Pool the follow...
See AnswerQ: Calculate a pooled estimate of s from the following spectrophotometric analysis for
Calculate a pooled estimate of s from the following spectrophotometric analysis for NTA (nitrilotriacetic acid) in water from the Ohio River:
See AnswerQ: Go to http://dx.doi.org/10.
Go to http://dx.doi.org/10.18434/T43G6C, where you will find a link to the NIST Statistical Reference Datasets site. Find the Dataset Archives, locate the Univariate Summary Statistics section, and se...
See AnswerQ: Differentiate between a. Parameter and statistic. b.
Differentiate between a. Parameter and statistic. b. Population mean and sample mean. c. Random and systematic error. d. Accuracy and precision.
See AnswerQ: Write the equilibrium-constant expressions and obtain numerical values for each
Write the equilibrium-constant expressions and obtain numerical values for each constant in a. The basic dissociation of aniline, C6H5NH2. b. The acidic dissociation of hypochlorous acid, HClO. c. Th...
See AnswerQ: Distinguish between a. The sample variance and the population variance
Distinguish between a. The sample variance and the population variance. b. The meaning of the word sample as it is used in a chemical and in a statistical sense.
See AnswerQ: What is the standard error of a mean? Why is the
What is the standard error of a mean? Why is the standard deviation of the mean lower than the standard deviation of the data points in a set?
See AnswerQ: Neglecting any effects caused by volume changes, would you expect the
Neglecting any effects caused by volume changes, would you expect the ionic strength to (1) increase, (2) decrease, or (3) remain essentially unchanged by the addition of iron(III) chloride to a. HCl...
See AnswerQ: Explain why the activity coefficient for dissolved ions in water is usually
Explain why the activity coefficient for dissolved ions in water is usually less than that for water itself.
See AnswerQ: Explain why the activity coefficient for a neutral molecule is usually 1
Explain why the activity coefficient for a neutral molecule is usually 1
See AnswerQ: Explain why the initial slope for Ca21 in Figure 8-3
Explain why the initial slope for Ca21 in Figure 8-3 is steeper than that for K1?
See AnswerQ: What is the numerical value of the activity coefficient of aqueous ammonia
What is the numerical value of the activity coefficient of aqueous ammonia 1NH32 at an ionic strength of 0.2?
See AnswerQ: Calculate the ionic strength of a solution that is a.
Calculate the ionic strength of a solution that is a. 0.025 M in FeSO4. b. 0.25 M in 1NH422CrO4. c. 0.25 M in FeCl3 and 0.15 M in FeCl2. d. 0.025 M in La1NO323 and 0.050 M in Fe1NO322.
See AnswerQ: Use Equation 8-5 to calculate the activity coefficient of
Use Equation 8-5 to calculate the activity coefficient of
See AnswerQ: Express the solubility-product constant for each substance in Problem 7
Express the solubility-product constant for each substance in Problem 7-8 in terms of its molar solubility S.
See AnswerQ: Describe the preparation of a. 500 mL of 0.
Describe the preparation of a. 500 mL of 0.0750 M AgNO3 from the solid reagent. b. 2.00 L of 0.325 M HCl, starting with a 6.00 M solution of the reagent. c. 750 mL of a solution that is 0.0900 M in...
See AnswerQ: Calculate activity coefficients for the species in Problem 8-10 by
Calculate activity coefficients for the species in Problem 8-10 by linear interpolation of the data in Table 8-2.
See AnswerQ: The homogeneity of the chloride level in a water sample from a
The homogeneity of the chloride level in a water sample from a lake was tested by analyzing portions drawn from the top and from near the bottom of the lake, with the following results in ppm Cl: a....
See AnswerQ: For a solution in which m 5 6.5 3 1022
For a solution in which m 5 6.5 3 1022, calculate K9sp for a. AgSCN. b. PbI2. c. La1IO323. d. MgNH4PO4.
See AnswerQ: Use activities to calculate the molar solubility of Zn1OH22 in a
Use activities to calculate the molar solubility of Zn1OH22 in a. 0.0150 M KCl. b. 0.0250 M K2SO4. c. the solution that results when you mix 40.0 mL of 0.250 M KOH with 60.0 mL of 0.0250 M ZnCl2. d....
See AnswerQ: Calculate the solubilities of the following compounds in a 0.0275
Calculate the solubilities of the following compounds in a 0.0275 M solution of Mg1ClO422 using (1) activities and (2) molar concentrations: a. AgSCN. b. PbI2. c. BaSO4. d. Cd2Fe1CN26.
See AnswerQ: Calculate the solubilities of the following compounds in a 0.0167
Calculate the solubilities of the following compounds in a 0.0167 M solution of Ba1NO322 using (1) activities and (2) molar concentrations: a. AgIO3. b. Mg1OH22. c. BaSO4. d. La1IO323.
See AnswerQ: Calculate the % relative error in solubility by using concentrations instead of
Calculate the % relative error in solubility by using concentrations instead of activities for the following compounds in 0.0350 M KNO3 using the thermodynamic solubility products listed in Appendix 2...
See AnswerQ: Calculate the % relative error in hydronium ion concentration by using concentrations
Calculate the % relative error in hydronium ion concentration by using concentrations instead of activities in calculating the pH of the following buffer solutions using the thermodynamic constants fo...
See AnswerQ: Design and construct a spreadsheet to calculate activity coefficients in a format
Design and construct a spreadsheet to calculate activity coefficients in a format similar to Table 8-2. Enter values of aX in cells A3, A4, A5, and so forth, and enter ionic charges in cells B3, B4, B...
See AnswerQ: Make a distinction between a. activity and activity coefficient.
Make a distinction between a. activity and activity coefficient. b. thermodynamic and concentration equilibrium constants.
See AnswerQ: Describe the preparation of a. 1.00 L of
Describe the preparation of a. 1.00 L of 0.150 M KMnO4 from the solid reagent. b. 2.50 L of 0.500 M HClO4, starting with a 9.00 M solution of the reagent. c. 400 mL of a solution that is 0.0500 M i...
See AnswerQ: List several general properties of activity coefficients.
List several general properties of activity coefficients.
See AnswerQ: Find the amount of the indicated element (in moles) in
Find the amount of the indicated element (in moles) in a. 5.32 g of B2O3. b. 195.7 mg of Na2B4O7 ? 10H2O. c. 4.96 g of Mn3O4. d. 333 mg of CaC2O4.
See AnswerQ: Two different analytical methods were used to determine residual chlorine in sewage
Two different analytical methods were used to determine residual chlorine in sewage effluents. Both methods were used on the same samples, but each sample came from various locations with differing am...
See AnswerQ: Neglecting any effects caused by volume changes, would you expect the
Neglecting any effects caused by volume changes, would you expect the ionic strength to (1) increase, (2) decrease, or (3) remain essentially unchanged when NaOH is added to a dilute solution of a....
See AnswerQ: Write the mass-balance expressions for a solution that is
Write the mass-balance expressions for a solution that is a. 0.2 M in HF. b. 0.25 M in NH3. c. 0.10 M in H3PO4. d. 0.15 M in Na2HPO4. e. 0.0500 M in HClO2 and 0.100 M in NaClO2. f. 0.12 M in NaF...
See AnswerQ: Write the charge-balance equations for the solutions in Problem 9
Write the charge-balance equations for the solutions in Problem 9-5.
See AnswerQ: Calculate the molar solubility of ZnC2O4 in a solution that has a
Calculate the molar solubility of ZnC2O4 in a solution that has a fixed H3O1 concentration of a. 1.0 × 10-6 M. b. 1.0 × 10-7 M. c. 1.0 × 10-9 M. d. 1.0 × 10-11 M.
See AnswerQ: Calculate the molar solubility of BaSO4 in a solution in which 3H3O14
Calculate the molar solubility of BaSO4 in a solution in which 3H3O14 is a. 3.5 M. b. 0.75 M. c. 0.080 M. d. 0.100 M.
See AnswerQ: Calculate the molar solubility of PbS in a solution in which 3H3O14
Calculate the molar solubility of PbS in a solution in which 3H3O14 is held constant at a. 3.0 × 10-1 M b. 3.0 × 10-4 M.
See AnswerQ: Calculate the concentration of CuS in a solution in which 3H3O14 is
Calculate the concentration of CuS in a solution in which 3H3O14 is held constant at a. 2.0 × 10-1 M b. 2.0 × 10-4 M.
See AnswerQ: A 0.4723-g sample of primary-standard-
A 0.4723-g sample of primary-standard-grade Na2CO3 required 34.78 mL of an H2SO4 solution to reach the end point in the reaction CO3 22 + 2H1 → H2O + CO21g2 What is the molar concentration of the H2...
See AnswerQ: Calculate the molar solubility of MnS (pink) in a solution
Calculate the molar solubility of MnS (pink) in a solution with a constant 3H3O14 of a. 3.00 × 10-5 M b. 2.50 × 10-7 M
See AnswerQ: Calculate the molar solubility of ZnCO3 in a solution buffered to a
Calculate the molar solubility of ZnCO3 in a solution buffered to a pH of 7.00.
See AnswerQ: Calculate the molar solubility of ZnCO3 in a solution buffered to a
Calculate the molar solubility of ZnCO3 in a solution buffered to a pH of 7.50.
See AnswerQ: Sir William Ramsey (Lord Rayleigh) prepared nitrogen samples by several
Sir William Ramsey (Lord Rayleigh) prepared nitrogen samples by several different methods. The density of each sample was measured as the mass of gas required to fill a particular flask at a certain t...
See AnswerQ: Calculate the solubility-product constant for each of the following substances
Calculate the solubility-product constant for each of the following substances, given that the molar concentrations of their saturated solutions are as indicated:
See AnswerQ: Dilute NaOH is introduced into a solution that is 0.050
Dilute NaOH is introduced into a solution that is 0.050 M in Cu21 and 0.040 M in Mn21. a. Which hydroxide precipitates first? b. What OH2 concentration is needed to initiate precipitation of the fir...
See AnswerQ: A solution is 0.030 M in Na2SO4 and 0.
A solution is 0.030 M in Na2SO4 and 0.040 M in NaIO3.To this is added a solution containing Ba21. Assuming that no HSO4 - is present in the original solution, a. which barium salt will precipitate fi...
See AnswerQ: Silver ion is being considered for separating I- from SCN-
Silver ion is being considered for separating I- from SCN- in a solution that is 0.040 M in KI and 0.080 M in NaSCN. a. What Ag1 concentration is needed to lowerthe I- concentration to 1.0 × 10-6 M?...
See AnswerQ: Using 1.0 × 10-6 M as the criterion
Using 1.0 × 10-6 M as the criterion for quantitative removal, determine whether it is feasible to use a. SO4 22 to separate Ba21 and Sr21 in a solution that is initially 0.030 M in Sr21 and 0.15 M in...
See AnswerQ: What mass of AgBr dissolves in 200 mL of 0.200
What mass of AgBr dissolves in 200 mL of 0.200 M NaCN?
See AnswerQ: A 0.5002-g sample that assayed 96.4
A 0.5002-g sample that assayed 96.4% Na2SO4 required 48.63 mL of a barium chloride solution. Reaction: Ba21 + SO4 22 → BaSO4(s) Calculate the analytical molar concentration of BaCl2 in the solution....
See AnswerQ: The equilibrium constant for formation of CuCl2 2 is given by What
The equilibrium constant for formation of CuCl2 2 is given by What is the solubility of CuCl in solutions having the following analytical NaClconcentrations: a. 5.0 M? b. 5.0 Ã 10-1 M?...
See AnswerQ: In contrast to many salts, calcium sulfate is only partially dissociated
In contrast to many salts, calcium sulfate is only partially dissociated in aqueous so Kd = 5.2 Ã 10-3 The solubility-product constant for CaSO4 is 2.6 Ã 10-5 . Calculate t...
See AnswerQ: Calculate the molar solubility of Tl2S as a function of pH over
Calculate the molar solubility of Tl2S as a function of pH over the range of pH 10 to pH 1. Find values at every 0.5 pH unit, and use the charting function of Excel to plot solubility versus pH.
See AnswerQ: Demonstrate how the sulfide ion concentration is related to the hydronium ion
Demonstrate how the sulfide ion concentration is related to the hydronium ion concentration of a solution that is kept saturated with hydrogen sulfide.
See AnswerQ: The phosphorous content in ppm was measured for three different soil locations
The phosphorous content in ppm was measured for three different soil locations. Five replicate determinations were made on each soil sample. A partial ANOVA table follows: a. Fill in the missing entri...
See AnswerQ: Why are simplifying assumptions in equilibrium problems restricted to relationships that are
Why are simplifying assumptions in equilibrium problems restricted to relationships that are sums or differences?
See AnswerQ: Define a. Molar mass. b. Millimole.
Define a. Molar mass. b. Millimole. c. Millimolar mass. d. Parts per billion.
See AnswerQ: Find the amount in millimoles of the indicated species in a
Find the amount in millimoles of the indicated species in a. 12.92 g of NaHCO3 b. 57 mg of MgNH4PO4. c. 850 mg of P2O5. d. 40.0 g of CO2.
See AnswerQ: In the margin note on page 215, we suggest that the
In the margin note on page 215, we suggest that the term mass-balance equation may be something of a misnomer. Using a specific chemical system, discuss mass balance and show that mass balance and con...
See AnswerQ: Why do molar concentrations of some species appear as multiples in charge
Why do molar concentrations of some species appear as multiples in charge-balance equations?
See AnswerQ: Calculate the solubility of the solutes in Problem 7-10 for
Calculate the solubility of the solutes in Problem 7-10 for solutions in which the cation concentration is 0.030 M.
See AnswerQ: A 0.4126-g sample of primary-standard Na2CO3
A 0.4126-g sample of primary-standard Na2CO3 was treated with 40.00 mL of dilute perchloric acid. The solution was boiled to remove CO2, following which the excess HClO4 was back-titrated with 9.20 mL...
See AnswerQ: Suggest a method by which Pb21 can be precipitated homogeneously as PbS
Suggest a method by which Pb21 can be precipitated homogeneously as PbS.
See AnswerQ: What is peptization, and how is it avoided?
What is peptization, and how is it avoided?
See AnswerQ: Suggest a precipitation method for separation of K+ from Na+
Suggest a precipitation method for separation of K+ from Na+ and Li+.
See AnswerQ: Write an equation showing how the mass of the substance sought can
Write an equation showing how the mass of the substance sought can be converted to the mass of the weighed substance on the right.
See AnswerQ: Treatment of a 0.3500-g sample of impure potassium
Treatment of a 0.3500-g sample of impure potassium chloride with an excess of AgNO3 resulted in the formation of 0.3846 g of AgCl. Calculate the percentage of KCl in the sample.
See AnswerQ: The week 3 measurement in the data set of Problem 5-
The week 3 measurement in the data set of Problem 5-16 is suspected of being an outlier. Use the Q test to determine if the value can be rejected at the 95% confidence level. Answer
See AnswerQ: Titration of 50.00 mL of 0.04715 M Na2C2O4
Titration of 50.00 mL of 0.04715 M Na2C2O4 required 39.25 mL of a potassium permanganate solution. 2MnO4 2 + 5H2C2O4 + 6H1 → 2Mn21 + 10CO21g2 + 8H2O Calculate the molar concentration of the KMnO4 solu...
See AnswerQ: Titration of the I2 produced from 0.1142 g of primary
Titration of the I2 produced from 0.1142 g of primary-standard KIO3 required 27.95 mL of sodium thiosulfate. IO3 2 + 5I2 + 6H1 → 3I2 + 3H2O I2 + 2S2O3 22 → 2I2 + S4O6 22 Calculate the concentration of...
See AnswerQ: What CrO42- concentration is required to a. Initiate precipitation
What CrO42- concentration is required to a. Initiate precipitation of Ag2CrO4 from a solution that is 5.24 × 10-3 M in Ag+? b. Lower the concentration of Ag+ in a solution to 7.82 × 10-7 M?
See AnswerQ: A 4.912-g sample of a petroleum product was
A 4.912-g sample of a petroleum product was burned in a tube furnace, and the SO2 produced was collected in 3% H2O2. Reaction: SO21g2 + H2O2 → H2SO4 A 25.00-mL portion of 0.00873 M NaOH was introduced...
See AnswerQ: A 100.0-mL sample of spring water was treated
A 100.0-mL sample of spring water was treated to convert any iron present to Fe21. Addition of 25.00 mL of 0.002517 M K2Cr2O7 resulted in the reaction 6Fe21 + Cr2O7 22 + 14H1 → 6Fe31 + 2Cr31 + 7H2O Th...
See AnswerQ: Three different analytical methods are compared for determining Ca in a biological
Three different analytical methods are compared for determining Ca in a biological sample. The laboratory is interested in knowing whether the methods differ. The results shown next represent Ca resul...
See AnswerQ: The arsenic in a 1.203-g sample of a
The arsenic in a 1.203-g sample of a pesticide was converted to H3AsO4 by suitable treatment. The acid was then neutralized, and 40.00 mL of 0.05871 M AgNO3 was added to precipitate the arsenic quanti...
See AnswerQ: The thiourea in a 1.455-g sample of organic
The thiourea in a 1.455-g sample of organic material was extracted into a dilute H2SO4 solution and titrated with 37.31 mL of 0.009372 M Hg21 via the reaction 41NH222CS + Hg21 → 31NH222CS44Hg21 Find t...
See AnswerQ: A solution of Ba1OH22 was standardized against 0.1215 g of
A solution of Ba1OH22 was standardized against 0.1215 g of primary-standard-grade benzoic acid, C6H5COOH 1122.12 g>mol2. An end point was observed after addition of 43.25 mL of base. a. Calculate the...
See AnswerQ: What mass of AgI can be produced from a 0.512
What mass of AgI can be produced from a 0.512-g sample that assays 20.1% AlI3?
See AnswerQ: The ethyl acetate concentration in an alcoholic solution was determined by diluting
The ethyl acetate concentration in an alcoholic solution was determined by diluting a 10.00-mL sample to 100.00 mL. A 20.00-mL portion of the diluted solution was refluxed with 40.00 mL of 0.04672 M K...
See AnswerQ: A 0.1475-M solution of Ba1OH22 was used to
A 0.1475-M solution of Ba1OH22 was used to titrate the acetic acid (60.05 g/mol) in a dilute aqueous solution. The following results were obtained. a. Calculate the mean w/v percentage of acetic aci...
See AnswerQ: a. A 0.3147-g sample of primary-
a. A 0.3147-g sample of primary-standard-grade Na2C2O4 was dissolved in H2SO4 and titrated with 31.67 mL of dilute KMnO4: 2MnO4 2 1 5C2O4 22 1 16H1 S 2Mn21 1 10CO21g2 1 8H2O Calculate the molar con...
See AnswerQ: a. A 0.1527-g sample of primary-
a. A 0.1527-g sample of primary-standard AgNO3 was dissolved in 502.3 g of distilled water. Calculate the weight molar concentration of Ag1 in this solution. b. The standard solution described in par...
See AnswerQ: A solution was prepared by dissolving 7.48 g of KCl
A solution was prepared by dissolving 7.48 g of KCl # MgCl2 # 6H2O 1277.85 g>mol2 in sufficient water to give 2.000 L. Calculate a. The molar analytical concentration of kcl.Mgcl2 in this solution....
See AnswerQ: What is the mass in milligrams of a. 0.
What is the mass in milligrams of a. 0.367 mol of HNO3? b. 245 mmol of MgO? c. 12.5 mol of NH4NO3? d. 4.95 mol of 1NH422Ce1NO326 (548.23 g/mol)?
See AnswerQ: A solution was prepared by dissolving 367 mg of K3Fe1CN26 1329.
A solution was prepared by dissolving 367 mg of K3Fe1CN26 1329.2 g>mol2 in sufficient water to give 750.0 mL. Calculate a. The molar analytical concentration of K3Fe1CN26. b. The molar concentration...
See AnswerQ: Apply the Q test to the following data sets to determine whether
Apply the Q test to the following data sets to determine whether the outlying result should be retained or rejected at the 95% confidence level. a. 51.27, 51.61, 51.84, 51.70 b. 7.295, 7.284, 7.388, 7...
See AnswerQ: Define a. Millimole. b. Titration.
Define a. Millimole. b. Titration. c. Stoichiometric ratio. d. Titration error.
See AnswerQ: Write two equations that—along with the stoichiometric factor—form
Write two equations that—along with the stoichiometric factor—form the basis for the calculations of volumetric titrations.
See AnswerQ: Precipitates used in the gravimetric determination of uranium include Na2U2O7 (634
Precipitates used in the gravimetric determination of uranium include Na2U2O7 (634.0 g/mol), (UO2)2P2O7 (714.0 g/mol), and V2O5 . 2UO3 (753.9 g/mol). Which of these weighing forms provides the greate...
See AnswerQ: Distinguish between a. The equivalence point and the end point
Distinguish between a. The equivalence point and the end point of a titration. b. A primary standard and a secondary standard.
See AnswerQ: What variables can cause the pH range of an indicator to shift
What variables can cause the pH range of an indicator to shift?
See AnswerQ: Which solute would provide the sharper end point in a titration with
Which solute would provide the sharper end point in a titration with 0.10 M HCl: a. 0.10 M NaOCl or 0.10 M hydroxylamine? b. 0.10 M hydrazine or 0.10 M NaCN? c. 0.10 M methylamine or 0.10 M hydroxyla...
See AnswerQ: Which solute wouldprovide the sharperend pointinatitration with 0.10MNaOH:
Which solute wouldprovide the sharperend pointinatitration with 0.10MNaOH: a. 0.10 M nitrous acid or 0.10 M iodic acid? b. 0.10 M salicylic acid or 0.10 M acetic acid? c. 0.10 M hypochlorous acid or 0...
See AnswerQ: Before glass electrodes and pH meters became widely used, pH was
Before glass electrodes and pH meters became widely used, pH was often determined by measuring the concentration of the acid and base forms of the indicator colorimetrically (see Chapter 24 for detail...
See AnswerQ: The procedure described in Problem 12-8 was used to determine
The procedure described in Problem 12-8 was used to determine pH with methyl orange as the indicator. The concentration ratio of the acid to base form of the indicator was 1.84. Calculate the pH of th...
See AnswerQ: Values for Kw at 0, 50, and 100C
Values for Kw at 0, 50, and 100C are 1.14 1015, 5.471014, and 4.9 1013, respectively. Calculate the pH for a neutral solution at each of these temperatures.
See AnswerQ: What hydroxide concentration is required to a. Initiate precipitation of
What hydroxide concentration is required to a. Initiate precipitation of Al3+ from a 3.89 × 10-2M solution of Al2(SO4)3? b. Lower the Al3+ concentration in the foregoing solution to 4.75 × 10-7 M?
See AnswerQ: Apply the Q test to the following data sets to determine whether
Apply the Q test to the following data sets to determine whether the outlying result should be retained or rejected at the 95% confidence level. a. 95.10, 94.62, 94.70 b. 95.10, 94.62, 94.65, 94.70
See AnswerQ: Using the data in Problem 12-10, calculate pKw at
Using the data in Problem 12-10, calculate pKw at a. 0°C. b. 50°C. c. 100°C.
See AnswerQ: A 0.7812-g sample of impure Al2(CO3
A 0.7812-g sample of impure Al2(CO3)3 decomposed with HCl; the liberated CO2 was collected on calcium oxide and found to weigh 0.04380 g. Calculate the percentage of aluminum in the sample.
See AnswerQ: Using the data in Problem 12-10, calculate the pH
Using the data in Problem 12-10, calculate the pH of a 150 1022MNaOH solution at a. 0°C. b. 50°C. c. 100°C.
See AnswerQ: What is the pH of an aqueous solution that is 3.
What is the pH of an aqueous solution that is 3.00% HCl by mass and has a density of 1.015 g/mL?
See AnswerQ: Calculate the pH of a solution that contains 2.50%
Calculate the pH of a solution that contains 2.50% (w/w) NaOH and has a density of 1.015 g/mL.
See AnswerQ: What is the pH of a solution that is 2.00
What is the pH of a solution that is 2.00 8 M in NaOH? (Hint: In such a dilute solution, you must take into account the contribution of H2O to the hydroxide ion concentration.)
See AnswerQ: What is the pH of a 215 10
What is the pH of a 215 108 MHCl solution (see hint in Problem 12-15)?
See AnswerQ: What is the pH of the solution that results when 0.
What is the pH of the solution that results when 0.093 g of Mg(OH)2 is mixed with a. 75.0 mL of 0.0500 M HCl? b. 100.0 mL of 0.0500 M HCl? c. 15.0 mL of 0.0500 M HCl? d. 30.0 mL of 0.0500 M MgCl2?
See AnswerQ: Calculate the pH of the solution that results when mixing 15.
Calculate the pH of the solution that results when mixing 15.0 mL of 0.2500 M HCl with 25.0 mL of a. Distilled water. b. 0.132 M AgNO3. c. 0.132 M NaOH. d. 0.132 M NH3. e. 0.232 M NaOH.
See AnswerQ: Calculate the hydronium ion concentration and pH of a solution that is
Calculate the hydronium ion concentration and pH of a solution that is 0.0500 M in HCl a. Neglecting activities. b. Using activities (see Chapter 8).
See AnswerQ: Calculate the hydroxide ion concentration and the pH of a 0.
Calculate the hydroxide ion concentration and the pH of a 0.0150 M Ba1OH22 solution a. Neglecting activities. b. Using activities (see Chapter8).
See AnswerQ: Determination of phosphorous in blood serum gave results of 4.40
Determination of phosphorous in blood serum gave results of 4.40, 4.42, 4.60, 4.48, and 4.50 ppm P. Determine whether the 4.60 ppm result is an outlier or should be retained at the 95% confidence leve...
See AnswerQ: The hydrogen sulfide in a 40.0-g sample of
The hydrogen sulfide in a 40.0-g sample of crude petroleum was removed by distillation and collected in a solution of CdCl2. The precipitated CdS was then filtered, washed, and ignited to CdSO4. Calcu...
See AnswerQ: What is the mass in grams of a. 2.
What is the mass in grams of a. 2.25 mol of KBr? b. 15.5 mmol of PbO? c. 5.04 mol of CaSO4? d. 10.9 mmol of Fe (NH4)2(SO4)2.6H2O?
See AnswerQ: Calculate the pH of an aqueous solution that is a.
Calculate the pH of an aqueous solution that is a. b. c.
See AnswerQ: Calculate the pH of a solution that is a.
Calculate the pH of a solution that is a. b. c.
See AnswerQ: Calculate the pH of an ammonia solution that is a.
Calculate the pH of an ammonia solution that is a. b. c.
See AnswerQ: Calculate the pH of a solution that is a.
Calculate the pH of a solution that is a. b. c.
See AnswerQ: Calculate the pH of a solution in which the concentration of piperidine
Calculate the pH of a solution in which the concentration of piperidine is a. b. c.
See AnswerQ: Calculate the pH of a solution that is a.
Calculate the pH of a solution that is a. b. c.
See AnswerQ: a. Calculate the pH of a solution prepared by b
a. Calculate the pH of a solution prepared by b. Dissolving 36.5 g of lactic acid in water and diluting to 500 mL c. Diluting 25.0 mL of the solution in (a) to 250 mL Diluting 10.0 mL of the solution...
See AnswerQ: Calculate the pH of a solution prepared by a. Dissolving
Calculate the pH of a solution prepared by a. Dissolving 1.87 g of picric acid, (NO2)3C6H2OH(229.11 g>mol), in 100 mL of water. b. diluting 10.0 mL of the solution in (a) to 100 mL c. diluting 10.0 mL...
See AnswerQ: Calculate the pH of the solution that results when 20.0
Calculate the pH of the solution that results when 20.0 mL of 0.1750 M formic acid is a. Diluted to 45.0 ml with distilled water. b. Mixed with 25.0 ml of 0.140 M NaOH solution. c. Mixed with 25.0 ml...
See AnswerQ: Briefly describe or define (a) Indicator electrode.
Briefly describe or define (a) Indicator electrode. (b) Reference electrode. (c) Electrode of the first kind. (d) Electrode of the second kind. Answers: a) Indicator electrode: An indicator electrod...
See AnswerQ: How does a gas-sensing probe differ from other membrane electrodes
How does a gas-sensing probe differ from other membrane electrodes?
See AnswerQ: One common way to determine phosphorus in urine is to treat the
One common way to determine phosphorus in urine is to treat the sample after removing the protein with molybdenum (VI) and then reducing the resulting 12-molybdophosphate complex with ascorbic acid to...
See AnswerQ: Nitrite is commonly determined by a colorimetric procedure using a reaction called
Nitrite is commonly determined by a colorimetric procedure using a reaction called the Griess reaction. In this reaction, the sample containing nitrite is reacted with sulfanilimide and N-(1-Napthyl)...
See AnswerQ: The equilibrium constant for the reaction 2CrO42- + 2H+
The equilibrium constant for the reaction 2CrO42- + 2H+ â Cr2O72- + H2O is 4.2 x 1014. The molar absorptivities for the two principal species in a solution of K2CrO7 are Four soluti...
See AnswerQ: In a solution of pH 5.3, the indicator bromocresol
In a solution of pH 5.3, the indicator bromocresol purple exhibits a yellow color, but when the pH is 6.0, the indicator solution changes to purple. Discuss why these colors are observed in terms of t...
See AnswerQ: What is the relationship between (a) Absorbance and transmittance
What is the relationship between (a) Absorbance and transmittance? (b) Concentration c and molar absorptivity ε?
See AnswerQ: Identify factors that cause the Beer’s law relationship to be nonlinear.
Identify factors that cause the Beer’s law relationship to be nonlinear.
See AnswerQ: Describe the differences between “real” deviations from Beer’s law and
Describe the differences between “real” deviations from Beer’s law and those due to instrumental or chemical factors.
See AnswerQ: Why do quantitative and qualitative analyses often require different monochromator slit widths
Why do quantitative and qualitative analyses often require different monochromator slit widths?
See AnswerQ: Why are photomultiplier tubes unsuited for the detection of infrared radiation?
Why are photomultiplier tubes unsuited for the detection of infrared radiation?
See AnswerQ: Why is iodine sometimes introduced into a tungsten lamp?
Why is iodine sometimes introduced into a tungsten lamp?
See AnswerQ: What is the source of a) The asymmetry potential in
What is the source of a) The asymmetry potential in a membrane electrode? b) The boundary potential in a membrane electrode? c) A junction potential in a glass/calomel electrode system? d) The potenti...
See AnswerQ: Describe the differences between the following pairs of terms, and list
Describe the differences between the following pairs of terms, and list any particular advantages of one over the other: (a) Spectrophotometers and photometers. (b) Spectrographs and spectrometers. (...
See AnswerQ: The Wien displacement law states that the wavelength maximum in micrometers for
The Wien displacement law states that the wavelength maximum in micrometers for blackbody radiation is (maxT = 2.90 × 103 Where T is the temperature in kelvins. Calculate the wavelength maximum for a...
See AnswerQ: Stefan’s law states that the total energy emitted by a blackbody per
Stefan’s law states that the total energy emitted by a blackbody per unit time and per unit area is Et = αT4 where α is 5.69 × 10-8W/m2 K4. Calculate the total energy output in W>m2 for the blackbodi...
See AnswerQ: The relationships described in Problems 23-7 and 23-8
The relationships described in Problems 23-7 and 23-8 may be of help in solving the following. a) Calculate the wavelength of maximum emission of a tungsten-filament bulb operated at 2870 K and at 30...
See AnswerQ: What minimum requirement is needed to obtain reproducible results with a single
What minimum requirement is needed to obtain reproducible results with a single-beam spectrophotometer?
See AnswerQ: What is the purpose of a) The 0% T
What is the purpose of a) The 0% T adjustment b) The 100% T adjustment of a spectrophotometer?
See AnswerQ: What non-instrumental variables must be controlled to assure reproducible absorbance
What non-instrumental variables must be controlled to assure reproducible absorbance data?
See AnswerQ: What are the major advantages of Fourier transform IR instruments over dispersive
What are the major advantages of Fourier transform IR instruments over dispersive IR instruments?
See AnswerQ: A photometer with a linear response to radiation gave a reading of
A photometer with a linear response to radiation gave a reading of 625 mV with a blank in the light path and 149 mV when the blank was replaced by an absorbing solution. Calculate a) The percent trans...
See AnswerQ: A portable photometer with a linear response to radiation registered a photocurrent
A portable photometer with a linear response to radiation registered a photocurrent of 75.9 μA with a blank solution in the light path. Replacement of the blank with an absorbing solution yielded a re...
See AnswerQ: How does information supplied by a direct potentiometric measurements of pH differ
How does information supplied by a direct potentiometric measurements of pH differ from that obtained from a potentiometric acid-base titration?
See AnswerQ: Why does a hydrogen lamp produce a continuum rather than a line
Why does a hydrogen lamp produce a continuum rather than a line spectrum in the ultraviolet?
See AnswerQ: What are the differences between a photon detector and a thermal detector
What are the differences between a photon detector and a thermal detector?
See AnswerQ: Describe the basic design difference between a spectrometer for emission measurements and
Describe the basic design difference between a spectrometer for emission measurements and one for absorption studies.
See AnswerQ: Describe how an absorption photometer and a fluorescence photometer differ from each
Describe how an absorption photometer and a fluorescence photometer differ from each other.
See AnswerQ: What is the difference between an absorption filter and an interference filter
What is the difference between an absorption filter and an interference filter?
See AnswerQ: Define (a) Transducer. (b) Photocurrent
Define (a) Transducer. (b) Photocurrent. (c) N-type semiconductor. (d) Majority carrier. (e) Depletion layer. (f) Dynodes in a photomultiplier tube.
See AnswerQ: An interference filter is to be constructed for isolation of the CS2
An interference filter is to be constructed for isolation of the CS2 absorption band at 4.54 µm. a) If the determination is to be based on first-order interference, how thick should the dielectric la...
See AnswerQ: The following data were taken from a diode-array spectrophotometer in
The following data were taken from a diode-array spectrophotometer in an experiment to measure the spectrum of the Co (II)-EDTA complex. The column labeled Psolution is the relative signal obtained wi...
See AnswerQ: Describe the differences between the following pairs of terms, and list
Describe the differences between the following pairs of terms, and list any particular advantages possessed by one over the other: (a) Solid-state photodiodes and phototubes as detectors for electrom...
See AnswerQ: Define the term spectral bandpass of a monochromator.
Define the term spectral bandpass of a monochromator.
See AnswerQ: Give several advantages of a potentiometric titration over a direct potentiometric measurement
Give several advantages of a potentiometric titration over a direct potentiometric measurement.
See AnswerQ: The molar absorptivity for the complex formed between bismuth (III)
The molar absorptivity for the complex formed between bismuth (III) and thiourea is 9.32 × 103 L cm-1 mol-1 at 470 nm. Calculate the range of permissible concentrations for the complex if the absorban...
See AnswerQ: The molar absorptivity for aqueous solutions of phenol at 211 nm is
The molar absorptivity for aqueous solutions of phenol at 211 nm is 5.28 × 103 L cm-1 mol-1. Calculate the permissible range of phenol concentrations if the transmittance is to be less than 85% and gr...
See AnswerQ: The logarithm of the molar absorptivity for acetone in ethanol is 2
The logarithm of the molar absorptivity for acetone in ethanol is 2.75 at 366 nm. Calculate the range of acetone concentrations that can be used if the absorbance is to be greater than 0.100 and less...
See AnswerQ: The logarithm of the molar absorptivity of phenol in aqueous solution is
The logarithm of the molar absorptivity of phenol in aqueous solution is 4.297 at 211 nm. Calculate the range of phenol concentrations that can be used if the absorbance is to be greater than 0.150 an...
See AnswerQ: A photometer with a linear response to radiation gave a reading of
A photometer with a linear response to radiation gave a reading of 690 mV with a blank in the light path and 169 mV when the blank was replaced by an absorbing solution. Calculate a) The transmittanc...
See AnswerQ: A portable photometer with a linear response to radiation registered 75.
A portable photometer with a linear response to radiation registered 75.5 µA with a blank solution in the light path. Replacement of the blank with an absorbing solution yielded a response of 23.7 µA....
See AnswerQ: Sketch a photometric titration curve for the titration of Sn2+ with
Sketch a photometric titration curve for the titration of Sn2+ with MnO-4. What color radiation should be used for this titration? Explain.
See AnswerQ: Iron(III) reacts with thiocyanate ion (SCN) to
Iron(III) reacts with thiocyanate ion (SCN) to form the red complex, Fe(SCN)2+. Sketch a photometric titration curve for Fe(III) with thiocyanate ion when a photometer with a green filter is used to c...
See AnswerQ: Ethylenediaminetetraacetic acid displaces bismuth(III) from its thiourea complex:
Ethylenediaminetetraacetic acid displaces bismuth(III) from its thiourea complex: Bi(tu)63+ + H2Y2- → BiY- + 6tu + 2H+ where tu is the thiourea molecule, (NH2)2CS. Predict the shape of a photometric...
See AnswerQ: The accompanying data (1.00-cm cells) were
The accompanying data (1.00-cm cells) were obtained for the spectrophotometric titration of 10.00 mL of Pd(II) with 2.44 Ã 10-4 M Nitroso R (O. W. Rollins and M. M. Oldham, Anal. Chem., 1...
See AnswerQ: What is the “operational definition of pH”? Why is it
What is the “operational definition of pH”? Why is it used?
See AnswerQ: A 5.24-g petroleum specimen was decomposed by wet
A 5.24-g petroleum specimen was decomposed by wet ashing and subsequently diluted to 500 mL in a volumetric flask. Cobalt was determined by treating 25.00-mL aliquots of this diluted solution as follo...
See AnswerQ: Iron(III) forms a complex with thiocyanate ion that has
Iron(III) forms a complex with thiocyanate ion that has the formula Fe(SCN) 2+. The complex has an absorption maximum at 580 nm. A specimen of well water was assayed according to the following scheme....
See AnswerQ: A. J. Mukhedkar and N. V. Deshpande (
A. J. Mukhedkar and N. V. Deshpande (Anal. Chem., 1963, 35, 47, DOI: 10.1021/ac60194a014) report on a simultaneous determination for cobalt and nickel based on absorption by their 8-quinolinol complex...
See AnswerQ: Molar absorptivity data for the cobalt and nickel complexes with 2,
Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol are εCo = 36,400 and εNi = 5520 at 510 nm and εCo = 1240 and εNi = 17,500 at 656 nm. A 0.425-g sample was dissol...
See AnswerQ: The indicator HIn has an acid dissociation constant of 4.80
The indicator HIn has an acid dissociation constant of 4.80 Ã 10-6 at ordinary temperatures. The accompanying absorbance data are for 8.00 Ã 10-5 M solutions of the indicator...
See AnswerQ: Calculate the absorbance (1.00-cm cells) at
Calculate the absorbance (1.00-cm cells) at 450 nm of a solution in which the total molar concentration of the indicator described in Problem 24-19 is 8.00 × 10-5M and the pH is a) 4.92, b) 5.46, c)...
See AnswerQ: What is the absorbance at 595 nm (1.00-
What is the absorbance at 595 nm (1.00-cm cells) of a solution that is 1.25 × 10-4M in the indicator of Problem 24-19 and has a pH of a) 5.30, b) 5.70, c) 6.10? Indicator of Problem 24-19: The in...
See AnswerQ: Several buffer solutions were made 1.00 x 10-4M
Several buffer solutions were made 1.00 x 10-4M in the indicator of Problem 24-19. Absorbance data (1.00-cm cells) are Calculate the pH of each solution. Indicator of Problem 24-19: Indicator HIn
See AnswerQ: Constr uct an absorption spectr um for a 7.00 ×
Constr uct an absorption spectr um for a 7.00 Ã 10-5 M solution of the indicator of Problem 24-19 when measurements are made with 1.00-cm cells and a) b) c) Incicator of Problem 24-19:...
See AnswerQ: Solutions of P and Q individually obey Beer’s law over a large
Solutions of P and Q individually obey Beerâs law over a large concentration range. Spectral data for these species in 1.00-cm cells are a) Plot an absorption spectrum for a solutio...
See AnswerQ: a) Calculate E0 for the process / (
a) Calculate E0 for the process (b) Use the shorthand notation to describe a cell consisting of a saturated calomel reference electrode and a silver indicator electrode that could be used to measure...
See AnswerQ: Use the data in Problem 24-24 to calculate the molar
Use the data in Problem 24-24 to calculate the molar concentration of P and Q in each of the following solutions: Data from Problem 24-24: Solutions of P and Q individually obey Beerâ...
See AnswerQ: A standard solution was put through appropriate dilutions to give the concentrations
A standard solution was put through appropriate dilutions to give the concentrations of iron shown in the accompanying table. The iron(II)-1,10,phenanthroline complex was then formed in 25.0-mL aliquo...
See AnswerQ: The method developed in Problem 24-26 was used for the
The method developed in Problem 24-26 was used for the routine determination of iron in 25.0-mL aliquots of ground water. Express the concentration (as ppm Fe) in samples that yielded the accompanying...
See AnswerQ: The sodium salt of 2-quinizarinsulfonic acid (NaQ) forms
The sodium salt of 2-quinizarinsulfonic acid (NaQ) forms a complex with Al3+ that absorbs strongly at 560 nm19. The data collected on this system are shown in the accompanying table. a) Find the formu...
See AnswerQ: The accompanying data were obtained in a slope-ratio investigation of
The accompanying data were obtained in a slope-ratio investigation of the complex formed between Ni2+ and 1-cyclopentene-1-dithiocarboxylic acid (CDA). The measurements were made at 530 nm in 1.00-cm...
See AnswerQ: The accompanying absorption data were recorded at 390 nm in 1.
The accompanying absorption data were recorded at 390 nm in 1.00-cm cells for a continuous-variations study of the colored product formed between Cd2+ and the complexing reagent R. a) Find the ligand...
See AnswerQ: Palladium(II) forms an intensely colored complex at pH 3
Palladium(II) forms an intensely colored complex at pH 3.5 with arsenazo III at 660 nm.20 A meteorite was pulverized in a ball mill, and the resulting powder was digested with various strong mineral a...
See AnswerQ: Mercury(II) forms a 1:1 complex with triphenyltetrazolium
Mercury(II) forms a 1:1 complex with triphenyltetrazolium chloride (TTC) that exhibits an absorption maximum at 255 nm.21 The mercury(II) in a soil sample was extracted into an organic solvent contain...
See AnswerQ: Estimate the frequencies of the absorption maxima in the IR spectrum of
Estimate the frequencies of the absorption maxima in the IR spectrum of methylene chloride shown in Figure 24F-2. From these frequencies, assign molecular vibrations of methylene chloride to each of t...
See AnswerQ: The equilibrium constant for the conjugate acid-base pair /
The equilibrium constant for the conjugate acid-base pair is 8.00 x 10-5. From the additional information a) Calculate the absorbance at 430 nm and 600 nm for the following indicator concentrations...
See AnswerQ: a) Calculate E0 for the process / b
a) Calculate E0 for the process b) Use the shorthand notation to describe a cell consisting of a Ag/AgCl reference electrode and a lead indicator electrode that could be used for the measurement of p...
See AnswerQ: Predict the shape of photometric titration curves (after correction for volume
Predict the shape of photometric titration curves (after correction for volume change) ifâat the wavelength selectedâthe molar absorptivities for the analyte A, the...
See AnswerQ: Describe the differences between the following pairs of terms, and list
Describe the differences between the following pairs of terms, and list any particular advantages of one over the other: a) Spectrophotometers and photometers. b) Single-beam and double-beam instrum...
See AnswerQ: What minimum requirement is needed to obtain reproducible results with a single
What minimum requirement is needed to obtain reproducible results with a single-beam spectrophotom?
See AnswerQ: What experimental variables must be controlled to assure reproducible absorbance data?
What experimental variables must be controlled to assure reproducible absorbance data?
See AnswerQ: What is(are) advantage(s) of the multiple
What is(are) advantage(s) of the multiple standard additions method over the single-point standard addition method?
See AnswerQ: Describe the characteristics of organic compounds that fluoresce.
Describe the characteristics of organic compounds that fluoresce.
See AnswerQ: Explain why fluoresence emission often occurs at a longer wavelength than absorption
Explain why fluoresence emission often occurs at a longer wavelength than absorption.
See AnswerQ: Describe the components of a filter fluorometer and a spectrofluorometer.
Describe the components of a filter fluorometer and a spectrofluorometer.
See AnswerQ: Why are phosphorescence lifetimes much longer than fluorescence lifetimes?
Why are phosphorescence lifetimes much longer than fluorescence lifetimes?
See AnswerQ: Why are fluorometers often more useful than spectrofluorometers for quantitative analysis?
Why are fluorometers often more useful than spectrofluorometers for quantitative analysis?
See AnswerQ: Use the shorthand notation to describe a cell consisting of a saturated
Use the shorthand notation to describe a cell consisting of a saturated calomel reference electrode and a silver indicator electrode for the measurement of (a) pI. (b) pCl. (c) pPO4. (d) pCN.
See AnswerQ: The reduced form of nicotinamide adenine dinucleotide (NADH) is an
The reduced form of nicotinamide adenine dinucleotide (NADH) is an important and highly fluorescent coenzyme. It has an absorption maximum of 340 nm and an emission maximum at 465 nm. Standard solutio...
See AnswerQ: The volumes of a 1.10 ppm standard solution of Zn2
The volumes of a 1.10 ppm standard solution of Zn2+ shown in the following table were pipetted into separatory funnels each containing 5.00 mL of an unknown zinc solution. Each was extracted with thre...
See AnswerQ: Quinine in a 1.664-g antimalarial tablet was dissolved
Quinine in a 1.664-g antimalarial tablet was dissolved in sufficient 0.10 M HCl to give 500 mL of solution. A 15.00-mL aliquot was then diluted to 100.0 mL with the acid. The fluorescence intensity fo...
See AnswerQ: The determination in Problem 25-12 was modified to use the
The determination in Problem 25-12 was modified to use the standard additions method. In this case, a 2.196-g tablet was dissolved in sufficient 0.10 M HCl to give 1.000 L. Dilution of a 20.00-mL aliq...
See AnswerQ: Briefly describe or define (a) Fluorescence. (
Briefly describe or define (a) Fluorescence. (b) Non-radiative relaxation. (c) Internal conversion. (d) Chemiluminescence. (e) Stokes shift. (f) Secondary absorption. (g) Inner-filter effect. (h) Tri...
See AnswerQ: Why are fluorescence methods potentially more sensitive than absorption methods?
Why are fluorescence methods potentially more sensitive than absorption methods?
See AnswerQ: Which compound in each of the following pairs would you expect to
Which compound in each of the following pairs would you expect to have a greater fluorescence quantum yield? Explain. a) b)
See AnswerQ: Why do some absorbing compounds show no fluorescence?
Why do some absorbing compounds show no fluorescence?
See AnswerQ: Why are ionization interferences usually not as severe in the ICP as
Why are ionization interferences usually not as severe in the ICP as they are in flames?
See AnswerQ: Why is source modulation used in atomic absorption spectroscopy?
Why is source modulation used in atomic absorption spectroscopy?
See AnswerQ: Generate an equation that relates pAnion to Ecell for each of the
Generate an equation that relates pAnion to Ecell for each of the cells in Problem 19-17. Cells in Problem 19-17: (a) pI. (b) pCl. (c) pPO4. (d) pCN.
See AnswerQ: Why are higher resolution monochromators found in ICP atomic emission spectrometers than
Why are higher resolution monochromators found in ICP atomic emission spectrometers than in flame atomic absorption spectrometers?
See AnswerQ: Why are the lines from a hollow-cathode lamp generally narrower
Why are the lines from a hollow-cathode lamp generally narrower than the lines emitted by atoms in a flame?
See AnswerQ: In flame AA with a hydrogen/oxygen flame, the absorbance
In flame AA with a hydrogen/oxygen flame, the absorbance for calcium decreases in the presence of large concentrations of phosphate ion. a) Suggest an explanation for this observation. b) Suggest th...
See AnswerQ: Name four characteristics of inductively coupled plasmas that make them suitable for
Name four characteristics of inductively coupled plasmas that make them suitable for atomic emission spectrometry.
See AnswerQ: Why is the ICP rarely used for atomic absorption measurements?
Why is the ICP rarely used for atomic absorption measurements?
See AnswerQ: Discuss the differences that result in ICP atomic emission when the plasma
Discuss the differences that result in ICP atomic emission when the plasma is viewed axially rather than radially.
See AnswerQ: In the atomic absorption determination of uranium, there is a linear
In the atomic absorption determination of uranium, there is a linear relationship between the absorbance at 351.5 nm and concentration from 500 to 2000 ppm of U. At concentrations much lower than 500...
See AnswerQ: A 5.00-mL sample of blood was treated with
A 5.00-mL sample of blood was treated with trichloroacetic acid to precipitate proteins. After centrifugation, the resulting solution was brought to pH 3 and extracted with two 5-mL portions of methyl...
See AnswerQ: The chromium in a series of steel samples was determined by ICP
The chromium in a series of steel samples was determined by ICP emission spectroscopy. The spectrometer was calibrated with a series of standards containing 0, 2.0, 4.0, 6.0, and 8.0 μg...
See AnswerQ: The copper in an aqueous sample was determined by atomic absorption flame
The copper in an aqueous sample was determined by atomic absorption flame spectrometry. First, 10.0 mL of the unknown were pipetted into each of five 50.0-mL volumetric flasks. Various volumes of a st...
See AnswerQ: Calculate (a) pI if the cell in Problem 19
Calculate (a) pI if the cell in Problem 19-17(a) has a potential of -196 mV. (b) pCl if the cell in Problem 19-17(b) has a potential of -0.137 V. (c) pPO4 if the cell in Problem 19-17(c) has a potenti...
See AnswerQ: Lead was determined in a brass sample by atomic absorption and the
Lead was determined in a brass sample by atomic absorption and the method of standard additions. The original sample was dissolved and diluted to 50.0 mL. This solution was introduced into an AA spect...
See AnswerQ: Describe the basic differences among atomic emission, atomic absorption, and
Describe the basic differences among atomic emission, atomic absorption, and atomic fluorescence spectroscopy.
See AnswerQ: Define (a) Atomization. (b) Pressure
Define (a) Atomization. (b) Pressure broadening. (c) Doppler broadening. (d) Aerosol. (e) Plasma. (f) Nebulization. (g) Hollow-cathode lamp. (h) Sputtering. (i) Additive interference. (j) Ionization...
See AnswerQ: Why is atomic emission more sensitive to flame instability than atomic absorption
Why is atomic emission more sensitive to flame instability than atomic absorption?
See AnswerQ: Briefly describe or define a) Liquid junction potential.
Briefly describe or define a) Liquid junction potential. b) Boundary potential. c) Asymmetry potential. d) Combination electrode
See AnswerQ: The cell SCE||Ag2CrO4(sat'd), (x M
The cell SCE||Ag2CrO4(sat'd), (x M)|Ag is used for the determination of pCrO4. Calculate pCrO4 when the cell potential is 0.389 V.
See AnswerQ: The cell SCE||H+(a = x)| glass
The cell SCE||H+(a = x)| glass electrode has a potential of 0.2106 V when the solution in the right-hand compartment is a buffer of pH 4.006. The following potentials are obtained when the buffer is r...
See AnswerQ: A 0.4021-g sample of a purified organic acid
A 0.4021-g sample of a purified organic acid was dissolved in water and titrated potentiometrically. A plot of the data revealed a single end point after 18.62 mL of 0.1243 M NaOH had been introduced....
See AnswerQ: Calculate the potential of a silver indicator electrode versus the standard calomel
Calculate the potential of a silver indicator electrode versus the standard calomel electrode after the addition of 5.00, 15.00, 25.00, 30.00, 35.00, 39.00, 39.50, 36.60, 39.70, 39.80, 39.90, 39.95, 3...
See AnswerQ: A 40.00-mL aliquot of 0.05000 M
A 40.00-mL aliquot of 0.05000 M HNO2 is diluted to 75.00 mL and titrated with 0 0800 MCe4+ The pH of the solution is maintained at 1.00 throughout the titration; the formal potential of the cerium sys...
See AnswerQ: The titration of Fe(II) with permanganate yields a particularly
The titration of Fe(II) with permanganate yields a particularly asymmetrical titration curve because of the different number of electrons involved in the two half-reactions. Consider the titration of...
See AnswerQ: The Na+ concentration of a solution was determined by measurements with
The Na+ concentration of a solution was determined by measurements with a sodium ion-selective electrode. The electrode system developed a potential of −0.2462 V when immersed in 10.0 mL of the soluti...
See AnswerQ: The F− concentration of a solution was determined by measurements with
The F− concentration of a solution was determined by measurements with a liquid-membrane electrode. The electrode system developed a potential of 0.5021 V when immersed in 25.00 mL of the sample, and...
See AnswerQ: A lithium ion-selective electrode gave the potentials given next for
A lithium ion-selective electrode gave the potentials given next for the following standard solutions of LiCl and two samples of unknown concentration: (a) Construct a calibration curve of potential...
See AnswerQ: A fluoride electrode was used to determine the amount of fluoride in
A fluoride electrode was used to determine the amount of fluoride in drinking water samples. The results given in the table that follows were obtained for four standards and two unknowns. Constant ion...
See AnswerQ: You need to choose between determining an analyte by measuring an electrode
You need to choose between determining an analyte by measuring an electrode potential or by performing a titration. Explain which you would choose if you needed to know (a) The absolute amount of the...
See AnswerQ: The phenol content of water downstream from a coking furnace was determined
The phenol content of water downstream from a coking furnace was determined by coulometric analysis. A 100-mL sample was rendered slightly acidic, and an excess of KBr was introduced. To produce Br2 f...
See AnswerQ: At a potential of −1.0 V (versus SCE
At a potential of â1.0 V (versus SCE), CCl4 in methanol is reduced to CHCl3 at a mercury cathode: 2CCl4 + 2H+ + 2e- + 2Hg(l) ( 2CHCl3 + Hg2Cl2(s) At -1.80 V, the CHCl3 further reacts...
See AnswerQ: Construct a coulometric titration curve of 100.0 mL of a
Construct a coulometric titration curve of 100.0 mL of a 1 M H2SO4 solution containing Fe(II) titrated with Ce(IV) generated from 0.075 M Ce(III). The titration is monitored by potentiometry. The init...
See AnswerQ: Traces of aniline, C6H5NH2, in drinking water can be determined
Traces of aniline, C6H5NH2, in drinking water can be determined by reaction with an excess of electrolytically generated Br2: The polarity of the working electrode is then reversed, and the excess Br...
See AnswerQ: Quinone can be reduced to hydroquinone with an excess of electrolytically generated
Quinone can be reduced to hydroquinone with an excess of electrolytically generated Sn(II): The polarity of the working electrode is then reversed, and the excess Sn(II) is oxidized with Br2 generate...
See AnswerQ: How do concentration polarization and kinetic polarization resemble one another? How
How do concentration polarization and kinetic polarization resemble one another? How do they differ?
See AnswerQ: Describe conditions that favor kinetic polarization in an electrochemical cell.
Describe conditions that favor kinetic polarization in an electrochemical cell.
See AnswerQ: What is a supporting electrolyte, and what is its role in
What is a supporting electrolyte, and what is its role in electrochemistry?
See AnswerQ: How do electro gravimetric and coulometric methods differ from potentiometric methods?
How do electro gravimetric and coulometric methods differ from potentiometric methods? Consider currents, voltages, and instrumentation in your answer.
See AnswerQ: What is meant by Nernstian behavior in an indicator electrode?
What is meant by Nernstian behavior in an indicator electrode?
See AnswerQ: Why is the working electrode normally isolated from the counter electrode in
Why is the working electrode normally isolated from the counter electrode in a controlled-potential coulometric analysis?
See AnswerQ: Why is an auxiliary reagent always required in a coulometric titration?
Why is an auxiliary reagent always required in a coulometric titration?
See AnswerQ: Calculate the theoretical potential at 25°C needed to initiate the
Calculate the theoretical potential at 25°C needed to initiate the deposition of (a) Copper from a solution that is 0.250 M in Cu2+ and buffered to a pH of 3.00. Oxygen is evolved at the an...
See AnswerQ: Calculate the initial potential needed for a current of 0.065
Calculate the initial potential needed for a current of 0.065 A in the cell if this cell has a resistance of 4.50 Ω.
See AnswerQ: The cell Sn|Sn2+ (6.18 x
The cell Sn|Sn2+ (6.18 x 10-4 M) || Cd2+(5.95 x 10-2 M)|Cd has a resistance of 3.95 Ω. Calculate the initial potential that will be needed for a current of 0.062 A in this cell.
See AnswerQ: Copper is to be deposited from a solution that is 0.
Copper is to be deposited from a solution that is 0.250 M in Cu(II) and is buffered to a pH of 4.00. Oxygen is evolved from the anode at a partial pressure of 730 torr. The cell has a resistance of 3....
See AnswerQ: Nickel is to be deposited on a platinum cathode (area =
Nickel is to be deposited on a platinum cathode (area = 120 cm2) from a solution that is 0.250 M in Ni2+ and buffered to a pH of 2.50. Oxygen is evolved at a partial pressure of 1.00 atm at a platinum...
See AnswerQ: A solution is 0.200 M in Co2+ and 0
A solution is 0.200 M in Co2+ and 0.0650 M in Cd2+. Calculate (a) The Co2+ concentration in the solution as the first cadmium starts to deposit. (b) The cathode potential needed to lower the Co2+ conc...
See AnswerQ: A solution is is 0.0350 M in BiO+ and
A solution is is 0.0350 M in BiO+ and 0.0250 M in Co2+ and has a pH of 2.50. (a) What is the concentration of the more easily reduced cation at the onset of deposition of the less reducible one? (b) W...
See AnswerQ: Describe the source of pH dependence in a glass-membrane electrode
Describe the source of pH dependence in a glass-membrane electrode.
See AnswerQ: Electrogravimetric analysis with control of the cathode potential is proposed as a
Electrogravimetric analysis with control of the cathode potential is proposed as a means for separating Bi3+ and Sn2+ in a solution that is 0.250 M in each ion and buffered to pH 1.95. (a) Calculate t...
See AnswerQ: A solution is 0.200 M in each of two reducible
A solution is 0.200 M in each of two reducible cations, A and B. Removal of the more reducible species (A) is deemed complete when [A] has been decreased to 1.00 Ã 10â5...
See AnswerQ: Calculate the time needed for a constant current of 0.8510
Calculate the time needed for a constant current of 0.8510 A to deposit 0.250 g of Co(II) as (a) Elemental cobalt on the surface of a cathode. (b) Co3O4 on an anode. Assume 100% current efficiency for...
See AnswerQ: Calculate the time needed for a constant current of 1.25
Calculate the time needed for a constant current of 1.25 A to deposit 0.550 g of (a) Tl(III) as the element on a cathode. (b) Tl(I) as Tl2O3 on an anode. (c) Tl(I) as the element on a cathode.
See AnswerQ: A 0.1330-g sample of a purified organic acid
A 0.1330-g sample of a purified organic acid was neutralized by the hydroxide ion produced in 5 minutes and 24 s by a constant current of 300 mA. Calculate the equivalent mass of the acid in grams.
See AnswerQ: The CN− concentration of 10.0 mL of a plating
The CN− concentration of 10.0 mL of a plating solution was determined by titration with electrogenerated hydrogen ion to a methyl orange end point. A color change occurred after 3 minutes and 55 s wit...
See AnswerQ: Electrolytically generated I2 was used to determine the amount of H2S in
Electrolytically generated I2 was used to determine the amount of H2S in 100.0 mL of brackish water. Following addition of excess KI, a titration at a constant current of 56.8 mA required 9.13 minutes...
See AnswerQ: The nitrobenzene in 300 mg of an organic mixture was reduced to
The nitrobenzene in 300 mg of an organic mixture was reduced to phenylhydroxylamine at a constant potential of â0.96 V (versus SCE) applied to a mercury cathode: The sample was diss...
See AnswerQ: Briefly distinguish between (a) Concentration polarization and kinetic polarization
Briefly distinguish between (a) Concentration polarization and kinetic polarization. (b) A reference electrode and a working electrode. (c) Diffusion and migration. (d) An ampere and a coulomb. (e) Th...
See AnswerQ: Why is it necessary for the glass in the membrane of a
Why is it necessary for the glass in the membrane of a pH-sensitive electrode to be appreciably hygroscopic?
See AnswerQ: Briefly define (a) Ohmic potential. (b
Briefly define (a) Ohmic potential. (b) Overvoltage. (c) Controlled-potential electrolysis. (d) Coulometric titration. (e) Current efficiency. (f) Potentiostat.
See AnswerQ: Describe three mechanisms responsible for the transport of dissolved species to and
Describe three mechanisms responsible for the transport of dissolved species to and from an electrode surface.
See AnswerQ: How does a current in an electrochemical cell affect its potential?
How does a current in an electrochemical cell affect its potential?
See AnswerQ: What experimental variables affect concentration polarization in an electrochemical cell?
What experimental variables affect concentration polarization in an electrochemical cell?
See AnswerQ: List the advantages and disadvantages of the hanging mercury drop electrode compared
List the advantages and disadvantages of the hanging mercury drop electrode compared with platinum or carbon electrodes.
See AnswerQ: Suggest how Equation 21-13 could be used to determine the
Suggest how Equation 21-13 could be used to determine the number of electrons n involved in a reversible reaction at an electrode.
See AnswerQ: Quinone undergoes a reversible reduction at a voltammetric working electrode. The
Quinone undergoes a reversible reduction at a voltammetric working electrode. The reaction is (a) Assume that the diffusion coefficients for quinone and hydroquinone are approximately the same, and c...
See AnswerQ: Sulfate ion can be determined by an amperometric titration procedure using Pb2
Sulfate ion can be determined by an amperometric titration procedure using Pb2+ as the titrant. If the potential of a rotating mercury film electrode is adjusted to -1.00 V versus SCE, the current can...
See AnswerQ: It has been suggested that many polarograms can be obtained on a
It has been suggested that many polarograms can be obtained on a solution without depleting the electroactive analyte. Suppose that in a polarographic experiment we monitor the limiting current for 45...
See AnswerQ: An unknown cadmium (II) solution was analysed polarographically by the
An unknown cadmium (II) solution was analysed polarographically by the method of standard additions. A 25.00-mL sample of the unknown solution produced a diffusion current of 1.86 μA. Following additi...
See AnswerQ: List several sources of uncertainty in pH measurements with a glass/
List several sources of uncertainty in pH measurements with a glass/calomel electrode system.
See AnswerQ: (a) What are the advantages of performing voltammetry with microelectrodes
(a) What are the advantages of performing voltammetry with microelectrodes? (b) Is it possible for an electrode to be too small? Explain your answer
See AnswerQ: Distinguish between (a) Voltammetry and amperometry. (
Distinguish between (a) Voltammetry and amperometry. (b) Linear-scan voltammetry and cyclic voltammetry. (c) Differential-pulse voltammetry and square-wave voltammetry. (d) A rotating disk electrode...
See AnswerQ: Define (a) Voltammograms. (b) Hydrodynamic
Define (a) Voltammograms. (b) Hydrodynamic voltammetry. (c) Nernst diffusion layer. (d) Dropping mercury electrode. (e) Half-wave potential. (f) Limiting current.
See AnswerQ: Why is a high supporting electrolyte concentration used in most electroanalytical procedures
Why is a high supporting electrolyte concentration used in most electroanalytical procedures?
See AnswerQ: Why is the reference electrode placed near the working electrode in a
Why is the reference electrode placed near the working electrode in a three-electrode cell?
See AnswerQ: Why is it necessary to buffer solutions in organic voltammetry?
Why is it necessary to buffer solutions in organic voltammetry?
See AnswerQ: Why are stripping methods more sensitive than other voltammetric procedures?
Why are stripping methods more sensitive than other voltammetric procedures?
See AnswerQ: What is the purpose of the electrodeposition step in stripping analysis?
What is the purpose of the electrodeposition step in stripping analysis?
See AnswerQ: How does an electronic transition resemble a vibrational transition? How do
How does an electronic transition resemble a vibrational transition? How do they differ?
See AnswerQ: Calculate the frequency in hertz of (a) An X
Calculate the frequency in hertz of (a) An X-ray beam with a wavelength of 2.65 Å. (b) An emission line for manganese at 403.1 nm. (c) The line at 694.3 nm produced by a ruby laser. (d) The output of...
See AnswerQ: What experimental factor places a limit on the number of significant figures
What experimental factor places a limit on the number of significant figures in the response of a membrane electrode?
See AnswerQ: Calculate the wavelength in centimeters of (a) An airport
Calculate the wavelength in centimeters of (a) An airport tower transmitting at 118.6 MHz. (b) A VOR (radio navigation aid) transmitting at 117.95 kHz. (c) An NMR signal at 105 MHz. (d) An infrared a...
See AnswerQ: A sophisticated ultraviolet/visible/near-IR instrument has a
A sophisticated ultraviolet/visible/near-IR instrument has a wavelength range of 189 to 2900 nm. What are its wavenumber and frequency ranges?
See AnswerQ: A typical simple infrared spectrophotometer covers a wavelength range from 3 to
A typical simple infrared spectrophotometer covers a wavelength range from 3 to 15 µm. Express its range (a) In wavenumbers and (b) In hertz.
See AnswerQ: Calculate the frequency in hertz and the energy in joules of an
Calculate the frequency in hertz and the energy in joules of an X-ray photon with a wavelength of 1.66 Å
See AnswerQ: Calculate the wavelength and the energy in joules associated with a signal
Calculate the wavelength and the energy in joules associated with a signal at 220 MHz
See AnswerQ: Calculate the wavelength of a) The sodium line at 589
Calculate the wavelength of a) The sodium line at 589 nm in an aqueous solution with a refractive index of 1.35. b) The output of a ruby laser at 694.3 nm when it is passing through a piece of quart...
See AnswerQ: What are the units for absorptivity when the path length is given
What are the units for absorptivity when the path length is given in centimeters and the concentration is expressed in (a) Parts per million? (b) Micrograms per liter? (c) Mass-volume percent? (d) Gr...
See AnswerQ: Express the following absorbances in terms of percent transmittance. (
Express the following absorbances in terms of percent transmittance. (a) 0.0356 (b) 0.909 (c) 0.379 (d) 0.092 (e) 0.485 (f) 0.623
See AnswerQ: Convert the accompanying transmittance data to absorbances. (a)
Convert the accompanying transmittance data to absorbances. (a) 27.2% (b) 0.579 (c) 30.6% (d) 15.29% (e) 0.093 (f) 79.6%
See AnswerQ: Calculate the percent transmittance of solutions that have twice the absorbance of
Calculate the percent transmittance of solutions that have twice the absorbance of the solutions in Problem 22-14. Absorbance of the solution in problem 22-14: a) %T = 92.1% b) %T = 12.3 c) %T = 41...
See AnswerQ: Calculate the absorbances of solutions with half the transmittance of those in
Calculate the absorbances of solutions with half the transmittance of those in Problem 22-15. Absorbances of solutions in Problem 22-15: a) A = 0.565 b) A = 0.237 c) A = 0.514 d) A = 0.816 e) A =...
See AnswerQ: Evaluate the missing quantities in the accompanying table. Where needed,
Evaluate the missing quantities in the accompanying table. Where needed, use 200 for the molar mass of the analyte.
See AnswerQ: A solution containing 5.61 ppm KMnO4 exhibits 55.3
A solution containing 5.61 ppm KMnO4 exhibits 55.3 %T in a 1.00-cm cell at 520 nm. Calculate the molar absorptivity of KMnO4 at this wavelength.
See AnswerQ: Beryllium (II) forms a complex with acetylacetone (166.
Beryllium (II) forms a complex with acetylacetone (166.2 g/mol). Calculate the molar absorptivity of the complex, given that a 2.25-ppm solution has a transmittance of 37.5% when measured in a 1.00-cm...
See AnswerQ: At 580 nm, the wavelength of its maximum absorption, the
At 580 nm, the wavelength of its maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of 7.00 X 103 L cm-1 mol-1. Calculate (a) The absorbance of a 3.40 X 10-5 M solution of the complex...
See AnswerQ: A 2.50-mL aliquot of a solution that contains
A 2.50-mL aliquot of a solution that contains 4.33 ppm iron (III) is treated with an appropriate excess of KSCN and diluted to 50.0 mL. What is the absorbance of the resulting solution at 580 nm in a...
See AnswerQ: A solution containing the complex formed between Bi(III) and
A solution containing the complex formed between Bi(III) and thiourea has a molar absorptivity of 9.32 x 103 L cm-1 mol-1 at 470 nm. (a) What is the absorbance of a 5.67 x 10-5M solution of the compl...
See AnswerQ: The complex formed between Cu(I) and 1, 10
The complex formed between Cu(I) and 1, 10-phenanthroline has a molar absorptivity of 6850 L cm-1 mol-1 at 435 nm, the wavelength of maximum absorption. Calculate (a) The absorbance of a 4.42 x 10-5...
See AnswerQ: A solution with a “true” absorbance [A = -
A solution with a “true” absorbance [A = -log(P0/P)] of 2.10 was placed in a spectrophotometer with a stray light percentage (Ps/P0) of 0.75. What absorbance A’ would be measured? What percentage erro...
See AnswerQ: A compound X is to be determined by UV/visible spectrophotometry
A compound X is to be determined by UV/visible spectrophotometry. A calibration curve is constructed from standard solutions of X with the following results: 0.50 ppm, A = 0.24; 1.5 ppm, A = 0.36; 2.5...
See AnswerQ: Determine the number of ions undergoing electron transfer at the surface of
Determine the number of ions undergoing electron transfer at the surface of an electrode during each second that an electrochemical cell is operated at 0.0175 A at 100% current efficiency and the part...
See AnswerQ: A single mixture containing only CHCl3 and CH2Cl2 was divided into five
A single mixture containing only CHCl3 and CH2Cl2 was divided into five parts to obtain samples for replicate determinations. Each sample was dissolved in methanol and electrolyzed in a cell containin...
See AnswerQ: Define (a) Dalton. (b) Quadrupole
Define (a) Dalton. (b) Quadrupole mass filter. (c) Mass number. (d) Sector analyzer. (e) Time-of-flight analyzer. (f) Electron multiplier.
See AnswerQ: Is it easier to couple a GC with a mass spectrometer or
Is it easier to couple a GC with a mass spectrometer or an HPLC? Why is this the case? What are the major difficulties in these couplings?
See AnswerQ: Indicate the order in which the following compounds would be eluted from
Indicate the order in which the following compounds would be eluted from an HPLC column containing a reversed-phase packing: a) Benzene, diethyl ether, n-hexane. b) Acetone, dichloroethane, acetamid...
See AnswerQ: Describe the effect of pressure on supercritical fluid chromatography.
Describe the effect of pressure on supercritical fluid chromatography.
See AnswerQ: How do instruments for supercritical fluid chromatography differ from those for
How do instruments for supercritical fluid chromatography differ from those for (a) HPLC and (b) GC?
See AnswerQ: List some of the advantageous properties of super critical CO2 as a
List some of the advantageous properties of super critical CO2 as a mobile phase for chromatographic separations.
See AnswerQ: What important property of supercritical fluids is related to their densities?
What important property of supercritical fluids is related to their densities?
See AnswerQ: Compare supercritical fluid chromatography with other column chromatographic methods.
Compare supercritical fluid chromatography with other column chromatographic methods.
See AnswerQ: For supercritical carbon dioxide, predict the effect that the following changes
For supercritical carbon dioxide, predict the effect that the following changes will have on the elution time in an SFC experiment. a) Increase the flow rate (at constant temperature and pressure)....
See AnswerQ: What is the effect of pH on the separation of amino acids
What is the effect of pH on the separation of amino acids by electrophoresis? Why?
See AnswerQ: What is electroosmotic flow? Why does it occur?
What is electroosmotic flow? Why does it occur?
See AnswerQ: How could electroosmotic flow be repressed? Why would one want to
How could electroosmotic flow be repressed? Why would one want to repress it?
See AnswerQ: What is the difference between a precursor ion and a product ion
What is the difference between a precursor ion and a product ion in tandem mass spectrometry?
See AnswerQ: What is the principle of separation by capillary zone electrophoresis?
What is the principle of separation by capillary zone electrophoresis?
See AnswerQ: A certain inorganic cation has a electrophoretic mobility of 6.97
A certain inorganic cation has a electrophoretic mobility of 6.97 × 10-4 cm2 s-1 V-1. This same ion has a diffusion coefficient of 7.8 × 10-6 cm2 s-1. If this ion is separated by capillary zone electr...
See AnswerQ: The cationic analyte of Problem 32-14 was separated by capillary
The cationic analyte of Problem 32-14 was separated by capillary zone electrophoresis in a 50-cm capillary at 20 kV. Under the separation conditions, the electroosmotic flow rate was 0.65 mm s 21 towa...
See AnswerQ: What is the principle of micellar electrokinetic capillary chromatography? How does
What is the principle of micellar electrokinetic capillary chromatography? How does it differ from capillary zone electrophoresis?
See AnswerQ: Describe a major advantage of micellar electrokinetic capillary chromatography over conventional liquid
Describe a major advantage of micellar electrokinetic capillary chromatography over conventional liquid chromatography.
See AnswerQ: What determines the elution order in sedimentation FFF?
What determines the elution order in sedimentation FFF?
See AnswerQ: Three large proteins are ionized at the pH at which an electrical
Three large proteins are ionized at the pH at which an electrical FFF separation is carried out. If the ions are designated A2+, B+, and C3+, predict the order of elution.
See AnswerQ: List the major advantages and limitations of FFF compared to chromatographic methods
List the major advantages and limitations of FFF compared to chromatographic methods.
See AnswerQ: List the types of substances to which each of the following separation
List the types of substances to which each of the following separation methods is most applicable: a) Supercritical fluid chromatography. b) Thin-layer chromatography. c) Capillary zone electrophor...
See AnswerQ: Define: a) Supercritical fluid. b) Critical
Define: a) Supercritical fluid. b) Critical point. c) Two-dimensional thin-layer chromatography. d) Electrophoretic mobility. e) Critical micelle concentration. f) Electrical fff
See AnswerQ: Some ionization sources, known as soft ionization sources, do not
Some ionization sources, known as soft ionization sources, do not produce as many fragments as an electron ionization source, which is a hard ionization source. Which type of ionization source (hard o...
See AnswerQ: What properties of a supercritical fluid are important in chromatography?
What properties of a supercritical fluid are important in chromatography?
See AnswerQ: Copper(II) forms a 1:1 complex with the
Copper(II) forms a 1:1 complex with the organic complexing agent R in acidic medium. The formation of the complex can be monitored by spectrophotome try at 480 nm. Use the following data collected und...
See AnswerQ: Aluminum forms a 1:1 complex with 2-hydroxy-
Aluminum forms a 1:1 complex with 2-hydroxy-1-naphthaldehyde p-methoxybenzoylhydraxonal that exhibits fluorescence emission at 475 nm. Under pseudo-first-order conditions, a plot of the initial rate o...
See AnswerQ: The enzyme monoamine oxidase catalyzes the oxidation of amines to aldehydes.
The enzyme monoamine oxidase catalyzes the oxidation of amines to aldehydes. For tryptamine, Km for the enzyme is 4.0 × 10-4 M, and vmax = k2[E]0 = 1.6 × 10-3 μM/min at pH 8. Find the concentration of...
See AnswerQ: The following data represent the product concentrations versus time during the initial
The following data represent the product concentrations versus time during the initial stages of pseudo-first-order reactions with different initial concentrations of analyte [A]0: For each concentra...
See AnswerQ: Calculate the product concentrations versus time for a pseudo-first-
Calculate the product concentrations versus time for a pseudo-first-order reaction with k’ = 0.015 s-1 and [A]0 = 0.005 M. Use times of 0.000 s, 0.001 s, 0.01 s, 0.1 s, 0.2 s 0.5 s, 1.0 s, 2.0 s, 5.0...
See AnswerQ: Explain why pseudo-first-order conditions are utilized in many
Explain why pseudo-first-order conditions are utilized in many kinetic methods.
See AnswerQ: Derive an expression for the half-life of the reactant in
Derive an expression for the half-life of the reactant in a first-order process in terms of the rate constant k.
See AnswerQ: Name three characteristics of inductively coupled plasmas that make them suitable for
Name three characteristics of inductively coupled plasmas that make them suitable for atomic mass spectrometry.
See AnswerQ: Find the natural lifetime in seconds for first-order reactions corresponding
Find the natural lifetime in seconds for first-order reactions corresponding to a) k = 0.497s-1 . b) k = 5.35 h-1. c) [A]0 = 3.16 M, and [A]t = 0.496 M at t = 3876 s. d) [P]∞ = 0.255 M, and [P]t =...
See AnswerQ: Find the first-order rate constant for a reaction that is
Find the first-order rate constant for a reaction that is 75.0% complete in a) 0.0100 s. b) 0.400 s c) 1.00 s. d) 3299 s e) 26.8 s f) 9.38 ns.
See AnswerQ: Find the number of half-lives required to reach the following
Find the number of half-lives required to reach the following levels of completion: a) 10%. b) 90%. c) 99.9%. d) 50%. e) 99%. f) 99.99%.
See AnswerQ: Calculate the number of lifetimes t required for a pseudo-first
Calculate the number of lifetimes t required for a pseudo-first-order reaction to achieve the levels of completion listed in Problem 28-8. Levels of completion listed in Problem 28-8: a) 10%. b) 90%...
See AnswerQ: Find the relative error associated with the assumption that k’ is invariant
Find the relative error associated with the assumption that kâ is invariant during the course of a pseudo-first order reaction under the following conditions:
See AnswerQ: Show mathematically that, for an enzyme reaction obeying Equation 28-
Show mathematically that, for an enzyme reaction obeying Equation 28-19, the substrate concentration for which the rate equals vmax/2 is equal to Km. Equation 28-19:
See AnswerQ: Equation 28-19 can be rearranged to produce the equation
Equation 28-19 can be rearranged to produce the equation where vmax = k2[E]0, the maximum velocity when [S] is large. a) Suggest a way to use this equation in the construction of a calibration (work...
See AnswerQ: Define the following terms as they are used in kinetic methods of
Define the following terms as they are used in kinetic methods of analysis. (a) Order of a reaction (b) Pseudo-first-order (c) Enzyme (d) Activator (e) Michaelis constant (f) Differential method...
See AnswerQ: The analysis of a multicomponent mixture by kinetic methods is sometimes referred
The analysis of a multicomponent mixture by kinetic methods is sometimes referred to as a “kinetic separation.” Explain the meaning of this term.
See AnswerQ: List three advantages of kinetic methods. Can you think of two
List three advantages of kinetic methods. Can you think of two possible limitations of kinetic methods when compared to equilibrium methods?
See AnswerQ: What function does the ICP torch serve in mass spectrometry?
What function does the ICP torch serve in mass spectrometry?
See AnswerQ: List the variables that lead to band broadening in chromatography.
List the variables that lead to band broadening in chromatography.
See AnswerQ: If VS and VM for the column in Problem 29-28
If VS and VM for the column in Problem 29-28 are 19.6 and 62.6 mL, respectively, and a nonretained air peak appears after 1.9 minutes, calculate a) The retention factor for each compound. b) The dis...
See AnswerQ: From distribution studies, species M and N are known to have
From distribution studies, species M and N are known to have water/hexane distribution constants of 5.99 and 6.16 (K = [X]H2O/[X]hex), where X = M or N. The two species are to be separated by elution...
See AnswerQ: Repeat the calculations in Problem 29-32 assuming KM = 5
Repeat the calculations in Problem 29-32 assuming KM = 5.81 and KN = 6.20. Data from Problem 29-32: From distribution studies, species M and N are known to have water/hexane distribution constants of...
See AnswerQ: What are the major differences between gas-liquid and liquid-
What are the major differences between gas-liquid and liquid-liquid chromatography?
See AnswerQ: Describe a method for determining the number of plates in a column
Describe a method for determining the number of plates in a column.
See AnswerQ: Describe two general methods for improving the resolution of two substances on
Describe two general methods for improving the resolution of two substances on a chromatographic column.
See AnswerQ: The distribution constant for X between n-hexane and water is
The distribution constant for X between n-hexane and water is 8.9. Calculate the concentration of X remaining in the aqueous phase after 50.0 mL of 0.200 M X is treated by extraction with the followin...
See AnswerQ: The distribution coefficient for Z between n-hexane and water is
The distribution coefficient for Z between n-hexane and water is 5.85. Calculate the percent of Z remaining in 25.0 mL of water that was originally 0.0550 M in Z after extraction with the following vo...
See AnswerQ: What volume of n-hexane is required to decrease the concentration
What volume of n-hexane is required to decrease the concentration of X in Problem 29-11 to 1.00 x 10-4 M if 25.0 mL of 0.0500 M X is extracted with a) 25.0-mL portions? b) 10.0-mL portions? c) 2.0-...
See AnswerQ: What are the y-axis and the x-axis of
What are the y-axis and the x-axis of an ordinary mass spectrum?
See AnswerQ: What volume of n-hexane is required to decrease the concentration
What volume of n-hexane is required to decrease the concentration of Z in Problem 29-12 to 2.00 x 10-5 M if 40.0 mL of 0.0200 M Z is extracted with a) 50.0-mL portions of n-hexane? b) 25.0-mL portio...
See AnswerQ: What is the minimum distribution coefficient that permits removal of 99%
What is the minimum distribution coefficient that permits removal of 99% of a solute from 50.0 mL of water with a) Two 25.0-mL extractions with toluene? b) Five 10.0-mL extractions with toluene?
See AnswerQ: If 30.0 mL of water that is 0.0500
If 30.0 mL of water that is 0.0500 M in Q is to be extracted with four 10.0-mL portions of an immiscible organic solvent, what is the minimum distribution coefficient that allows transfer of all but t...
See AnswerQ: A 0.150 M aqueous solution of the weak organic acid
A 0.150 M aqueous solution of the weak organic acid HA was prepared from the pure compound, and three 50.0-mL aliquots were transferred to 100.0-mL volumetric flasks. Solution 1 was diluted to 100.0 m...
See AnswerQ: To determine the equilibrium constant for the reaction /
To determine the equilibrium constant for the reaction 25.0 mL of a 0.0100 M aqueous solution of I2 was extracted with 10.0 mL of CHCl3. After extraction, spectrophotometric measurements revealed tha...
See AnswerQ: The total cation content of natural water is often determined by exchanging
The total cation content of natural water is often determined by exchanging the cations for hydrogen ions on a strong-acid ion-exchange resin. A 25.0-mL sample of a natural water was diluted to 100 mL...
See AnswerQ: Describe the preparation of exactly 1.00 L of 0.
Describe the preparation of exactly 1.00 L of 0.1000 M HCl from primary-standard-grade NaCl using a cation-exchange resin.
See AnswerQ: An aqueous solution containing MgCl2 and HCl was analyzed by first titrating
An aqueous solution containing MgCl2 and HCl was analyzed by first titrating a 25.00-mL aliquot to a bromocresol green end point with 17.53 mL of 0.02932 M NaOH. A 10.00-mL aliquot was then diluted to...
See AnswerQ: An open tubular column used for gas chromatography had an inside diameter
An open tubular column used for gas chromatography had an inside diameter of 0.15 mm. A volumetric flow rate of 0.85 mL/min was used. Find the linear flow velocity in cm/s at the column outlet.
See AnswerQ: A packed column in gas chromatography had an inside diameter of 5
A packed column in gas chromatography had an inside diameter of 5.0 mm. The measured volumetric flow rate at the column outlet was 48.0 mL/min. If the column porosity was 0.43, what was the linear flo...
See AnswerQ: What types of interferences are encountered in ICPMS?
What types of interferences are encountered in ICPMS?
See AnswerQ: The following data are for a liquid chromatographic column: /
The following data are for a liquid chromatographic column: A chromatogram of a mixture of species A, B, C, and D provided the following data: Calculate a) The number of plates from each peak. b)...
See AnswerQ: From the data in Problem 29-24, calculate for A
From the data in Problem 29-24, calculate for A, B, C, and D a) The retention factor. b) The distribution constant. Data from 29.24: The following data are for a liquid chromatographic column: A c...
See AnswerQ: From the data in Problem 29-24, calculate for species
From the data in Problem 29-24, calculate for species B and C a) The resolution. b) The selectivity factor. c) The length of column necessary to separate the two species with a resolution of 1.5....
See AnswerQ: From the data in Problem 29-24, calculate for species
From the data in Problem 29-24, calculate for species C and D a) The resolution. b) The length of column necessary to separate the two species with a resolution of 1.5. Data from Problem 29-24: The...
See AnswerQ: The following data were obtained by gas-liquid chromatography on a
The following data were obtained by gas-liquid chromatography on a 40-cm packed column: Calculate a) An average number of plates from the data. b) The standard deviation for the average in (a). c)...
See AnswerQ: Referring to Problem 29-28, calculate the resolution for
Referring to Problem 29-28, calculate the resolution for a) Methylcyclohexene and methylcyclohexane. b) Methylcyclohexene and toluene. c) Methylcyclohexane and toluene. Data from Problem 29-28: The...
See AnswerQ: What is a collector ion, and how is it used?
What is a collector ion, and how is it used?
See AnswerQ: What does the term salting out a protein mean? What is
What does the term salting out a protein mean? What is the salting in effect?
See AnswerQ: What does the term salting out a protein mean? What is
What does the term salting out a protein mean? What is the salting in effect?
See AnswerQ: Name three methods based on mechanical phase separation.
Name three methods based on mechanical phase separation.
See AnswerQ: What are the requirements of an internal standard in ICPMS?
What are the requirements of an internal standard in ICPMS?
See AnswerQ: Define a) Elution. b) Eluent. Diffusion
Define a) Elution. b) Eluent. Diffusion. c) Stationary phase. d) Distribution constant. e) Retention time. f) Longitudinal g) Selectivity factor. h) Plate height.
See AnswerQ: How do strong- and weak-acid synthetic ion-exchange
How do strong- and weak-acid synthetic ion-exchange resins differ in structure?
See AnswerQ: Explain how you would use one of the flow meters in Figure
Explain how you would use one of the flow meters in Figure 30-2. Figure 30-2:
See AnswerQ: Describe a chromatogram, and explain what type of information it contains
Describe a chromatogram, and explain what type of information it contains.
See AnswerQ: What is meant by temperature programming in gas chromatography?
What is meant by temperature programming in gas chromatography?
See AnswerQ: Describe the physical differences between capillary and packed columns. What are
Describe the physical differences between capillary and packed columns. What are the advantages and disadvantages of each?
See AnswerQ: What variables must be controlled if satisfactory qualitative data are to be
What variables must be controlled if satisfactory qualitative data are to be obtained from chromatograms?
See AnswerQ: What is meant by temperature programming in gas chromatography?
What is meant by temperature programming in gas chromatography?
See AnswerQ: Describe the principle on which each of the following GC detectors are
Describe the principle on which each of the following GC detectors are based: a) Thermal conductivity, b) Flame ionization, c) Electron capture, d) Thermionic, e) Photoionization.
See AnswerQ: What are the principal advantages and the principal limitations of each of
What are the principal advantages and the principal limitations of each of the detectors listed in Problem 30-10? Detectors listed in Problem 30-10: a) Thermal conductivity, b) Flame ionization, c)...
See AnswerQ: Why are detection limits for ICPMS often lower with double-focusing
Why are detection limits for ICPMS often lower with double-focusing mass spectrometers than with quadrupole mass spectrometers?
See AnswerQ: What are hyphenated gas chromatographic methods? Briefly describe three hyphenated methods
What are hyphenated gas chromatographic methods? Briefly describe three hyphenated methods.
See AnswerQ: What are megabore open tubular columns? Why are they used?
What are megabore open tubular columns? Why are they used?
See AnswerQ: How do the following capillary columns differ? a) PLOT
How do the following capillary columns differ? a) PLOT columns b) WCOT columns c) SCOT columns
See AnswerQ: Why are gas chromatographic stationary phases often bonded and cross-linked
Why are gas chromatographic stationary phases often bonded and cross-linked? What do these terms mean?
See AnswerQ: What properties should the stationary phase liquid for gas chromatography possess?
What properties should the stationary phase liquid for gas chromatography possess?
See AnswerQ: What are the advantages of fused-silica capillary columns compared with
What are the advantages of fused-silica capillary columns compared with glass or metal columns?
See AnswerQ: What is the effect of stationary phase film thickness on gas chromatograms
What is the effect of stationary phase film thickness on gas chromatograms?
See AnswerQ: List the variables that lead to a) Band broadening
List the variables that lead to a) Band broadening b) Band separation in gas-liquid chromatography.
See AnswerQ: One method for quantitative determination of the concentration of constituents in a
One method for quantitative determination of the concentration of constituents in a sample analyzed by gas chromatography is the area normalization method. In this method, complete elution of all the...
See AnswerQ: Peak areas and relative detector responses are to be used to determine
Peak areas and relative detector responses are to be used to determine the concentration of the five species in a sample. The area normalization method described in Problem 30-20 is to be used. The re...
See AnswerQ: How do electron and electrospray ionization sources differ? What are the
How do electron and electrospray ionization sources differ? What are the advantages and disadvantages of each?
See AnswerQ: For the data given in Example 30-1, compare the
For the data given in Example 30-1, compare the method of external standards to the internal standard method. Plot the analyte peak height versus percent analyte, and determine the unknown without usi...
See AnswerQ: How do gas-liquid and gas-solid chromatography differ?
How do gas-liquid and gas-solid chromatography differ?
See AnswerQ: Why is gas-solid chromatography not used as extensively as gas
Why is gas-solid chromatography not used as extensively as gas-liquid chromatography?
See AnswerQ: What kind of mixtures are separated by gas-solid chromatography?
What kind of mixtures are separated by gas-solid chromatography?
See AnswerQ: Indicate the order of elution of the following compounds from a normal
Indicate the order of elution of the following compounds from a normal-phase packed HPLC column: a) Ethyl acetate, acetic acid, dimethylamine. b) Propylene, hexane, benzene, dichlorobenzene.
See AnswerQ: Describe the fundamental difference between adsorption and partition chromatography.
Describe the fundamental difference between adsorption and partition chromatography.
See AnswerQ: Describe the fundamental difference between ion exchange and size-exclusion chromatography
Describe the fundamental difference between ion exchange and size-exclusion chromatography.
See AnswerQ: Describe the difference between gel-filtration and gel-permeation chromatography
Describe the difference between gel-filtration and gel-permeation chromatography.
See AnswerQ: What types of species can be separated by GC but not by
What types of species can be separated by GC but not by HPLC?
See AnswerQ: What is the major difference between isocratic elution and gradient elution?
What is the major difference between isocratic elution and gradient elution? For what types of compounds are these two elution methods most suited?
See AnswerQ: Why are fragments often produced with electron ionization?
Why are fragments often produced with electron ionization?
See AnswerQ: Describe two types of pumps used in HPLC. What are the
Describe two types of pumps used in HPLC. What are the advantages and disadvantages of each?
See AnswerQ: Describe the differences between single-column and suppressor-column ion
Describe the differences between single-column and suppressor-column ion chromatography.
See AnswerQ: Mass spectrometry is an extremely versatile detection system for gas chromatography.
Mass spectrometry is an extremely versatile detection system for gas chromatography. Describe the major reasons why it is more difficult to combine HPLC with mass spectrometry than it is to combine GC...
See AnswerQ: Which of the GC detectors in Table 30-1 are suitable
Which of the GC detectors in Table 30-1 are suitable for HPLC? Why are some of these unsuitable for HPLC? Table 30-1:
See AnswerQ: The ideal detector for GC is described in Section 30A-4
The ideal detector for GC is described in Section 30A-4. Which of the eight characteristics of an ideal GC detector are applicable to HPLC detectors? What additional characteristics would be added to...
See AnswerQ: Although temperature does not have nearly the effect on HPLC separations that
Although temperature does not have nearly the effect on HPLC separations that it has on GC separations, it nonetheless can play an important role. Discuss how and why temperature might or might not in...
See AnswerQ: Two components in an HPLC separation have retention times that differ by
Two components in an HPLC separation have retention times that differ by 22 s. The first peak elutes in 10.5 minutes, and the peak widths are approximately equal. The void time, tM, was 63 s. Use a sp...
See AnswerQ: An HPLC method was developed for the separation and determination of ibuprofen
An HPLC method was developed for the separation and determination of ibuprofen in rat plasma samples as part of a study of the time course of the drug in laboratory animals. Several standards were chr...
See AnswerQ: List the types of substances to which each of the following chromatographic
List the types of substances to which each of the following chromatographic methods is most applicable: a) Gas-liquid. b) Liquid-liquid. c) Ion. d) Adsorption. e) Gel permeation. f) Affinity. g...
See AnswerQ: Define a) Isocratic elution. b) Gradient elution
Define a) Isocratic elution. b) Gradient elution. c) Normal-phase packing. d) Reversed-phase packing. e) Bonded-phase packing f) Chiral chromatography. g) Ion-pair chromatography. h) Eluent-su...
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